JPS60208221A - Method for mechanically bonding different synthetic resin material - Google Patents
Method for mechanically bonding different synthetic resin materialInfo
- Publication number
- JPS60208221A JPS60208221A JP59066545A JP6654584A JPS60208221A JP S60208221 A JPS60208221 A JP S60208221A JP 59066545 A JP59066545 A JP 59066545A JP 6654584 A JP6654584 A JP 6654584A JP S60208221 A JPS60208221 A JP S60208221A
- Authority
- JP
- Japan
- Prior art keywords
- synthetic resin
- plate member
- molten material
- resin materials
- resin material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 59
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 59
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000000155 melt Substances 0.000 claims description 13
- 230000002745 absorbent Effects 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- -1 polyethylene Polymers 0.000 abstract description 14
- 239000012768 molten material Substances 0.000 abstract description 13
- 229920005989 resin Polymers 0.000 abstract description 13
- 239000011347 resin Substances 0.000 abstract description 13
- 239000004743 Polypropylene Substances 0.000 abstract description 12
- 229920001155 polypropylene Polymers 0.000 abstract description 12
- 238000010438 heat treatment Methods 0.000 abstract description 10
- 238000002844 melting Methods 0.000 abstract description 6
- 230000008018 melting Effects 0.000 abstract description 6
- 229920001577 copolymer Polymers 0.000 abstract description 4
- 239000004698 Polyethylene Substances 0.000 abstract description 2
- 229920000573 polyethylene Polymers 0.000 abstract description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 9
- 238000005476 soldering Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 6
- XEEYBQQBJWHFJM-BJUDXGSMSA-N Iron-55 Chemical compound [55Fe] XEEYBQQBJWHFJM-BJUDXGSMSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 229910052779 Neodymium Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- CPBQJMYROZQQJC-UHFFFAOYSA-N helium neon Chemical compound [He].[Ne] CPBQJMYROZQQJC-UHFFFAOYSA-N 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010979 ruby Substances 0.000 description 1
- 229910001750 ruby Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/82—Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
- B29C66/826—Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined
- B29C66/8266—Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined using fluid pressure directly acting on the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
- B29C65/16—Laser beams
- B29C65/1629—Laser beams characterised by the way of heating the interface
- B29C65/1632—Laser beams characterised by the way of heating the interface direct heating the surfaces to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/56—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits
- B29C65/60—Riveting or staking
- B29C65/606—Riveting or staking the rivets being integral with one of the parts to be joined, i.e. staking
- B29C65/609—Riveting or staking the rivets being integral with one of the parts to be joined, i.e. staking the integral rivets being plunge-formed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
- B29C66/712—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined the composition of one of the parts to be joined being different from the composition of the other part
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/814—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
- B29C66/8141—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
- B29C66/81427—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined comprising a single ridge, e.g. for making a weakening line; comprising a single tooth
- B29C66/81429—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined comprising a single ridge, e.g. for making a weakening line; comprising a single tooth comprising a single tooth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
- B29C66/832—Reciprocating joining or pressing tools
- B29C66/8322—Joining or pressing tools reciprocating along one axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
- B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
- B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/81—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps
- B29C66/814—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps
- B29C66/8141—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined
- B29C66/81411—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat
- B29C66/81415—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat being bevelled
- B29C66/81417—General aspects of the pressing elements, i.e. the elements applying pressure on the parts to be joined in the area to be joined, e.g. the welding jaws or clamps characterised by the design of the pressing elements, e.g. of the welding jaws or clamps characterised by the surface geometry of the part of the pressing elements, e.g. welding jaws or clamps, coming into contact with the parts to be joined characterised by its cross-section, e.g. transversal or longitudinal, being non-flat being bevelled being V-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/06—PVC, i.e. polyvinylchloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/18—Polymers of nitriles
- B29K2033/20—PAN, i.e. polyacrylonitrile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0085—Copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Electromagnetism (AREA)
- Toxicology (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、異種合成樹脂材料の機械的接合方法に関する
ものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for mechanically joining dissimilar synthetic resin materials.
従来、合成樹脂材料と合成樹脂材料とを接合する際には
、熱を加えて溶着する物理的接合方法と接着剤を用いて
接着する化学的接合方法が広く利用されている。Conventionally, when joining synthetic resin materials, a physical joining method in which heat is applied to weld them, and a chemical joining method in which they are joined together using an adhesive have been widely used.
すなわち、前者の物理的接合力法は、接合しようとする
合成樹脂材料の接合面にメタルメツシフ。In other words, the former physical bonding force method applies metal mesh to the joint surfaces of the synthetic resin materials to be joined.
等の発熱体を発熱させて両者の合成樹脂材料の接合面を
溶融させつつ加圧・冷却し、両合成樹脂材料を接合する
方法である。また、後者の化学的接合方法は、接合しよ
うとする合成樹脂材料の接合面にボンドメルト等の接着
剤を介在させ、一方の合成樹脂材料の表面から高周波ま
たは超音波を(:j与させて接着剤を加熱・溶融さゼた
後、両者の合成樹脂材料を加圧しつつ冷却し、両合成樹
脂4421を接合する方法である。This is a method of joining both synthetic resin materials by causing a heating element such as the above to generate heat to melt the joint surfaces of both synthetic resin materials while pressurizing and cooling them. In addition, the latter chemical bonding method involves interposing an adhesive such as bondmelt on the joint surfaces of the synthetic resin materials to be bonded, and applying high frequency or ultrasonic waves (:j) from the surface of one synthetic resin material to bond them. After heating and melting the agent, both synthetic resin materials are cooled while being pressurized, and both synthetic resins 4421 are joined.
しかし、nii者の物理的接合方法においては、同種の
合成樹脂材料を接合する際には接合しようとする両者の
合成樹脂材t4の溶融温度が同一であるとともに、相溶
性を有するので、両合成樹脂祠料の接合には通している
が、異種の合成樹脂相$4を接合する際には両者の合成
樹脂+J r4の溶融温度が異なるとともに、相溶性が
悪いことから、両合成樹脂材料の接合は困難である。ま
た、後者の化学的接合方法においては、同種の合成樹脂
材料を接合する際には前者の物理的接合方法と同様に適
しているが、異種の合成樹脂材料を接合する際には合成
樹脂材料の材質によって接着剤の接着力が低下し、両合
成樹脂材料を強固に接合することは困難である。However, in the physical joining method of the second person, when joining the same type of synthetic resin materials, both synthetic resin materials t4 to be joined have the same melting temperature and are compatible. Although it is used for joining resin abrasive materials, when joining different types of synthetic resin phase $4, the melting temperatures of both synthetic resins + J r4 are different and the compatibility is poor, so the two synthetic resin materials are Joining is difficult. In addition, the latter chemical bonding method is as suitable as the former physical bonding method when bonding synthetic resin materials of the same type, but it is suitable for bonding synthetic resin materials of different types. The adhesive force of the adhesive decreases depending on the material of the material, making it difficult to firmly join both synthetic resin materials.
上述のようなことから、異種の合成樹脂材料を接合する
際には、機械的接合方法が多く利用されている。その代
表例を第2図に示すポリプロピレン樹脂とカラス繊維で
強化されたスチレン−アクリロニトリル共重合体の接合
方法によって説明する。For the reasons described above, mechanical joining methods are often used when joining different types of synthetic resin materials. A typical example thereof will be explained using a method of joining a polypropylene resin and a styrene-acrylonitrile copolymer reinforced with glass fibers as shown in FIG.
第2図において、51はスチレン−アクリロニトリル共
重合体からなる板部材であって、この板部材51の上部
にはポリプロピレン樹脂からなる板部材52が配設され
ており、その中央部には段差を有する貫通孔53が形成
され、その薄肉部54はQ、 5 +uないし3關の厚
さに形成されている。In FIG. 2, reference numeral 51 denotes a plate member made of styrene-acrylonitrile copolymer, and a plate member 52 made of polypropylene resin is disposed on the upper part of this plate member 51, and a step is formed in the center of the plate member 52. A through hole 53 is formed, and its thin portion 54 is formed to have a thickness of Q, 5 +u to 3 times.
そして、両板部材51.52を接合する際には、ハンダ
鏝55の先端に設けられている加熱部56を20W程度
で加熱しておき、その加熱部5Gをポリプロピレン樹脂
からなる板部材52のF4通几53から挿入し、スチレ
ン−°1クリロニトリル共重合体からなる板部材51に
押し当°ζつつ、その表面を溶融させる。その際、板部
材51の溶融物51aはハンダ饅55の加熱部56が挿
入されるにつれて、貫通孔53の間隙から上方に盛り上
がり、その溶融物51aによって貫通孔53の薄肉部5
4が覆われる。そして、?8融物51aで薄肉部54が
十分に覆われた後、ハンダ鏝55の加熱部56を板部材
51から引き上げる。これにより、溶融物51aが硬化
して両板部材51.52が接合される。When joining the plate members 51 and 52, the heating part 56 provided at the tip of the soldering iron 55 is heated at about 20 W, and the heating part 5G is connected to the plate member 52 made of polypropylene resin. It is inserted through the F4 port 53 and pressed against the plate member 51 made of styrene-1-crylonitrile copolymer to melt its surface. At this time, as the heating part 56 of the solder cake 55 is inserted, the molten material 51a of the plate member 51 swells upward from the gap in the through hole 53, and the molten material 51a causes the thin part 5 of the through hole 53 to bulge upward.
4 is covered. and,? After the thin part 54 is sufficiently covered with the melt 51a, the heating part 56 of the soldering iron 55 is pulled up from the plate member 51. As a result, the molten material 51a hardens and the two plate members 51 and 52 are joined.
しかしながら、このような機械的接合方法においては、
スチレン−アクリロニトリル共重合体からなる板部材5
1を加熱・溶融する際に、ハンダ鏝55の加熱部56を
板部材51に直接接触さ・υて溶融させるため、接合後
におけるハンダ鏝55を引き上げる際に溶融物51aが
加熱部56に付着することはもとより、接合を行うたび
に溶融物51aを除去しなければならない不具合がある
。However, in such mechanical joining methods,
Plate member 5 made of styrene-acrylonitrile copolymer
1, the heating part 56 of the soldering iron 55 directly contacts the plate member 51 and melting it, so when the soldering iron 55 is pulled up after joining, the molten material 51a adheres to the heating part 56. In addition to this, there is a problem in that the melt 51a must be removed every time joining is performed.
本発明は、上記の不具合を解消するためになされたもの
で、その目的は接合する異種合成樹脂材料のうち、下部
の合成樹脂材料をレーザ光によって加熱・溶融させるこ
とにより、溶融物の付着と除去作業を皆無とすることが
できる異種合成樹脂材料の機械的接合方法を提供するこ
とにある。The present invention was made to solve the above-mentioned problems, and its purpose is to heat and melt the lower synthetic resin material of different types of synthetic resin materials to be joined by laser light, thereby preventing the adhesion of molten material. An object of the present invention is to provide a method for mechanically joining dissimilar synthetic resin materials that can eliminate any removal work.
上記の目的を達成するために、本発明に係る異種合成樹
脂材料の機械的接合方法の構成は、異種の合成樹脂材料
を重ね合わせて両者を機械的に接合するに当り、前記重
ね合わされた合成樹脂材料のうち、少なくとも下部の合
成樹脂材料をレーザ光に対して吸収性とし、上部の合成
樹脂材料に貫通孔を形成せしめ、この貫通孔の上方から
下部の合成樹脂材料の表面にレーザ光を照射して溶融さ
せるとともに、その溶融部位に圧縮気体を吹き付けて、
前記貫通孔から溶融物を上部の合成樹脂(イ料の表面に
盛り上げるようにしたものである。In order to achieve the above object, the structure of the method for mechanically joining different types of synthetic resin materials according to the present invention is such that, when overlapping different types of synthetic resin materials and mechanically joining them, Among the resin materials, at least the lower synthetic resin material is made absorbent to laser light, a through hole is formed in the upper synthetic resin material, and the laser beam is directed from above the through hole to the surface of the lower synthetic resin material. At the same time as irradiating and melting, compressed gas is sprayed onto the melted area.
The molten material is pumped through the through hole onto the surface of the upper synthetic resin.
そして、上部の合成樹脂材料としては、ポリエチレン、
塩化ビニール、ポリプロピレン、スチレン−アクリロニ
トリル共重合体等を挙げることができ、レーザ光に対し
ご吸収性を有する下部の合成樹脂材料としては、カーボ
ンブラック等の補助材料を添加したポリプロピレン樹脂
、カラス繊維で強化され、かつカーボンブランクが添加
されたスチレン−アクリロニトリル共重合体等を挙げる
ことができる。そして、これらの合成樹脂材料はレーデ
光に対して非吸収性を有するものとなる、組み合せにお
いて自由に選択して接合することができる。The synthetic resin material for the upper part is polyethylene,
Vinyl chloride, polypropylene, styrene-acrylonitrile copolymer, etc. can be mentioned.As for the synthetic resin material of the lower part which has the property of absorbing laser light, polypropylene resin added with auxiliary materials such as carbon black, glass fiber etc. Examples include reinforced styrene-acrylonitrile copolymers to which a carbon blank is added. These synthetic resin materials can be freely selected and bonded in combinations that do not absorb Rede light.
また、異種合成樹脂材料の接合時に使用されるレーザと
しては、ガラス;ネオジウム3゛レーザ、YAG :
ネオジウム3ル−ザ、ルビーレーザ、ヘリウム−ネオン
レーザ、クリプトンレーザ、アルゴンレーザ、H2レー
リ゛、N2レーザ等を挙げることができ、このうぢ、特
にYAG :不オジウムゴレーザが最も適している。In addition, lasers used when joining different types of synthetic resin materials include glass; neodymium 3゛ laser; YAG:
Neodymium lasers, ruby lasers, helium-neon lasers, krypton lasers, argon lasers, H2 lasers, N2 lasers, etc. may be used, and among these, YAG:inodium lasers are most suitable.
また、異種合成樹脂材料の接合時に用いられるレーザの
波長としては、接合する合成樹脂材料に適合し、た波長
が必要であって1.06μm以下が最も優れζおり、そ
の波長が1.06μm以上の場合には異種の合成樹脂材
料を溶融させて接合することは不可能である。また、レ
ーザの出力においては、5Wないし30Wが通しており
、その出力が5W以下の場合には合成樹脂材料を溶融さ
せることができず、30W以上の場合には合成樹脂材料
が蒸発したり、変質したりして接合が不可能である。In addition, the wavelength of the laser used when joining dissimilar synthetic resin materials needs to be compatible with the synthetic resin materials to be joined, and the best wavelength is 1.06 μm or less, and the wavelength is 1.06 μm or more. In this case, it is impossible to melt and join different types of synthetic resin materials. In addition, the output of the laser is 5W to 30W, and if the output is less than 5W, the synthetic resin material cannot be melted, and if it is more than 30W, the synthetic resin material may evaporate, It is impossible to join due to deterioration.
(実施例〕
以下、本発明の一実施例を図面に基づいて詳細に説明す
る。(Example) Hereinafter, one example of the present invention will be described in detail based on the drawings.
第1図は本発明に係る異種合成樹脂材料の機械的接合方
法を説明する概略断面図を示すものである。FIG. 1 is a schematic cross-sectional view illustrating a method for mechanically joining dissimilar synthetic resin materials according to the present invention.
第1図の(a)ないしくd)において、lはガラス繊維
が添加されて強化されたスチレン−7クリロニトリル共
重合体からなる板部材であって、この板部材lの原材料
色はカーボンブラックが111人されて黒色となってお
り、1.06μm以下のレーザ光に対しては吸収性の性
質を有している。In (a) to d) of FIG. 1, 1 is a plate member made of styrene-7crylonitrile copolymer reinforced with glass fiber, and the raw material color of this plate member 1 is carbon black. It has a black color with 111 particles, and has the property of absorbing laser light of 1.06 μm or less.
また、板部材1の上部にはポリプロピレン樹脂からなる
板部(42が配設されており、その中央部には段差を有
する貫通孔3が形成され、その薄肉部4の厚さは0.5
鰭ないし3鰭に形成されている。Further, a plate part (42) made of polypropylene resin is disposed on the upper part of the plate member 1, and a through hole 3 having a step is formed in the center thereof, and the thickness of the thin part 4 is 0.5 mm.
It is formed into a fin or three fins.
そして、この板部材2の材料色はカーボンブラ。The material color of this plate member 2 is carbon bra.
りが添加されて黒色となっており、1,06μIn以下
のレーリ゛′光に対しては吸収性の性質を41している
。It has a black color due to the addition of silica, and has the property of absorbing Rayleigh light of 1.06 μIn or less.
そして、第1図の(a)に示すように七ノドされた異種
合成樹脂材料の板部材1.2を接合する際には、第1図
の(b)に示すようにポリプロピレン樹脂の板部材2に
形成されている貫通孔3の上部にYAG :ネオジウム
3゛レーザの照射ノズル5を当接させるとともに、その
照射ノズル5がら波長が1.06μm、出力が20Wの
YAGレーザ光5aを凸レンズ6に1lll過させて照
射する。As shown in FIG. 1(a), when joining the board members 1.2 made of different synthetic resin materials, the plate members 1.2 made of polypropylene resin are bonded together as shown in FIG. 1(b). A YAG: neodymium 3゜ laser irradiation nozzle 5 is brought into contact with the upper part of the through hole 3 formed in the through hole 3, and a YAG laser beam 5a with a wavelength of 1.06 μm and an output of 20 W is emitted from the irradiation nozzle 5 through a convex lens 6. It is irradiated by passing 1 lll.
そして、板部材lに達したYAGレーザ光5aは、その
部位でエネルギとして蓄積されるとともに、そのエネル
ギによっ゛C板部材1の表面がすみやかに加熱・溶融さ
れる。そして、第1図の(C)に示ずようにYAGレー
ザ光5aによって板部材lの一部を十分に溶融させて溶
融物1aを形成させた後、YAGレーザ光5aの照射を
停止するとともに、照射ノズル5を貫通孔3の上方から
後退させる。The YAG laser beam 5a that reaches the plate member 1 is accumulated as energy at that location, and the surface of the C plate member 1 is quickly heated and melted by the energy. Then, as shown in FIG. 1(C), after a part of the plate member l is sufficiently melted by the YAG laser beam 5a to form a melt 1a, the irradiation of the YAG laser beam 5a is stopped. , the irradiation nozzle 5 is retreated from above the through hole 3.
つぎに、第1図の(d)に示すように板部材2に形成さ
れている貫通孔3の上方に、空気、ガス、空気およびガ
スの混合気体等からなる圧縮気体の供給源(図示せず)
に接続されているパイプ7を移動させ、その先端を板部
材lの溶融物1aの上方に位置させる。その後、パイプ
7に設けられているバルブ8を開放させて圧縮気体を溶
融物1aの表面に吹き(=Jける。その際、板部)イl
の溶融物1aは圧縮気体の吹き付は圧力に比例し、凹み
を形成するとともに、その凹みが生じた量の溶融物1a
が目通孔3から上方に盛り上がり、貫通孔3の薄肉部4
が溶融物1aによってIWねれる。Next, as shown in FIG. 1(d), a compressed gas supply source (not shown) consisting of air, gas, a mixture of air and gas, etc. is placed above the through hole 3 formed in the plate member 2. figure)
The pipe 7 connected to is moved so that its tip is positioned above the melt 1a of the plate member l. After that, the valve 8 provided on the pipe 7 is opened to blow compressed gas onto the surface of the melt 1a.
The blowing of the compressed gas is proportional to the pressure, and the melt 1a forms a depression, and the amount of the melt 1a that creates the depression is
bulges upward from the through hole 3, and the thin wall portion 4 of the through hole 3
is twisted IW by the melt 1a.
そして、溶融物1aによって貫通孔3の薄肉部4が十分
に覆われた後、パイプ7のバルブ8を閉めて圧縮気体の
供給を停止するとともに、そのパイプ7をポリプロピレ
ン樹脂からなる板部材2の上方から後退させる。これに
より、板部材1の溶融物1aが板部材2に形成されてい
る貫通孔3の薄肉部4を覆った状態で硬化し、スチレン
ニーアクリロニトリル共重合体からなる板部材1とポリ
プロピレン樹脂からなる板部十42とが強固に接合され
る。After the thin wall portion 4 of the through hole 3 is sufficiently covered with the melt 1a, the valve 8 of the pipe 7 is closed to stop the supply of compressed gas, and the pipe 7 is connected to the plate member 2 made of polypropylene resin. Retreat from above. As a result, the melt 1a of the plate member 1 is cured while covering the thin wall portion 4 of the through hole 3 formed in the plate member 2, and the plate member 1 is made of styrene-acrylonitrile copolymer and polypropylene resin. The plate portion 142 is firmly joined.
〔発明の効果]
以上説明したように、本発明に係る異種合成樹脂材料の
機械的接合方法においては、接合しようとする異種合成
樹脂材料のうち、下部の合成樹脂材料をレーザ光によっ
て加熱 溶融さ−υた後、その溶融部位に圧縮気体を吹
き付りて、上部の合成樹脂材料の表面に盛り上がらせて
接合するようにしたから、従来のハンダ鏝のように加熱
部を直接接触させて溶融させる必要がないので、上部の
合成樹脂材料の表面に盛り上がらせることができ、接合
強度を向上させることができる効果がある。[Effects of the Invention] As explained above, in the method for mechanically joining dissimilar synthetic resin materials according to the present invention, the lower synthetic resin material of the dissimilar synthetic resin materials to be joined is heated and melted by a laser beam. After -υ, compressed gas is sprayed onto the melted part to raise it on the surface of the upper synthetic resin material and join it, so the heating part can be brought into direct contact with it like a conventional soldering iron and melted. Since it is not necessary to raise the layer, it can be raised on the surface of the upper synthetic resin material, which has the effect of improving the bonding strength.
また、本発明においては、異種合成樹脂材料の一方から
レーザ光を照射することによって、一方の合成樹脂材料
が溶融させるので、従来のハンダ鏝に比較してすみゃ力
弓コ容融させることができ、接合作業を著しく向上させ
ることができる効果がある。Furthermore, in the present invention, by irradiating laser light from one side of the different synthetic resin materials, one of the synthetic resin materials is melted, so it is easier to melt the sumya force than with a conventional soldering iron. This has the effect of significantly improving the joining work.
また、本発明においては、板部材の溶融物に圧縮気体を
吹きイ1け、他方の板部材の表面に盛り上げるようにし
たから、従来のようにハンダ鏝を溶融物に押し付ける必
要がないので、接合時におりる溶融物の付着を皆無とす
ることができ、接合を行うたびに溶融物を除去する作業
を皆無とすることができる効果がある。In addition, in the present invention, compressed gas is blown onto the melt on one plate member so that it rises onto the surface of the other plate member, so there is no need to press the soldering iron against the melt as in the past. This has the effect that there is no adhesion of molten material during bonding, and there is no need to remove molten material every time bonding is performed.
第1図は本発明に係る異種合成樹脂材料の機械的接合方
法を説明する概略断面図である。
第2図は従来の異種合成樹脂材料の機械的接合方法を説
明する概略断面図である。
lo ガラス繊維で強化されたスチレン−アクリロニ1
ヘリル共重合体からなる板部材la −溶融物
2 ポリプロピレン樹脂からなる板部材3 貫通孔
4 薄肉部
5 照射ノズル
sa YAGレーザ光
6 凸レンズ
7−パイプ
8 −バルブ
出願人 トヨタ自動車体式会社
(8)(い
)
第1図
!
第2図FIG. 1 is a schematic cross-sectional view illustrating a method for mechanically joining dissimilar synthetic resin materials according to the present invention. FIG. 2 is a schematic cross-sectional view illustrating a conventional mechanical joining method of dissimilar synthetic resin materials. lo Glass fiber reinforced styrene-acryloni 1
Plate member la made of helial copolymer - Melt 2 Plate member 3 made of polypropylene resin Through hole 4 Thin wall portion 5 Irradiation nozzle sa YAG laser beam 6 Convex lens 7 - Pipe 8 - Valve applicant Toyota Motor Body Engineering Co., Ltd. (8) ( i) Figure 1! Figure 2
Claims (1)
するに当り、前記重ね合わされた合成樹脂材料のうち、
少なくとも下部の合成樹脂材料をレーザ光に対して吸収
性とし、上部の合成樹脂材料に貫通孔を形成せしめ、こ
の貫通孔の上方から下部の合成樹脂材料の表面にレーザ
光を照射して溶融させるとともに、その溶融部位に圧縮
気体を吹き付けて、前記貫通孔から溶融物を上部の合成
樹脂材料の表面に盛り上げることを特1vlとする異種
合成樹脂材料の機械的接合方法。When overlapping different types of synthetic resin materials and mechanically joining them, among the overlapping synthetic resin materials,
At least the lower synthetic resin material is made absorbent to laser light, a through hole is formed in the upper synthetic resin material, and the surface of the lower synthetic resin material is irradiated with laser light from above the through hole to melt it. A method for mechanically joining dissimilar synthetic resin materials, which also comprises blowing compressed gas to the melted portion and causing the melt to rise from the through hole onto the surface of the upper synthetic resin material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59066545A JPS60208221A (en) | 1984-04-02 | 1984-04-02 | Method for mechanically bonding different synthetic resin material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59066545A JPS60208221A (en) | 1984-04-02 | 1984-04-02 | Method for mechanically bonding different synthetic resin material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60208221A true JPS60208221A (en) | 1985-10-19 |
JPS6249170B2 JPS6249170B2 (en) | 1987-10-17 |
Family
ID=13318974
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59066545A Granted JPS60208221A (en) | 1984-04-02 | 1984-04-02 | Method for mechanically bonding different synthetic resin material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60208221A (en) |
-
1984
- 1984-04-02 JP JP59066545A patent/JPS60208221A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6249170B2 (en) | 1987-10-17 |
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