JPS60187506A - Method of treating veneer - Google Patents

Method of treating veneer

Info

Publication number
JPS60187506A
JPS60187506A JP4266684A JP4266684A JPS60187506A JP S60187506 A JPS60187506 A JP S60187506A JP 4266684 A JP4266684 A JP 4266684A JP 4266684 A JP4266684 A JP 4266684A JP S60187506 A JPS60187506 A JP S60187506A
Authority
JP
Japan
Prior art keywords
veneer
resin
treating
thermosetting resin
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4266684A
Other languages
Japanese (ja)
Inventor
歩 安田
隆 岸本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Electric Works Co Ltd
Original Assignee
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works Ltd filed Critical Matsushita Electric Works Ltd
Priority to JP4266684A priority Critical patent/JPS60187506A/en
Publication of JPS60187506A publication Critical patent/JPS60187506A/en
Pending legal-status Critical Current

Links

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  • Finished Plywoods (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔技術分野〕 この発明は、単板の表面に保@膜を作る単板の処理法に
関する。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a method for treating a veneer to form a protective film on the surface of the veneer.

〔背景技術〕[Background technology]

化粧板用の突き版として、人工化粧単板が用いられる。 Artificial decorative veneer is used as the embossment for decorative boards.

この人工化粧単板は、普通、次のようにしてつくられる
。すなわち、ロータリスライスなどして得た単板を脱脂
、脱色したのち染色し、得られた染色単板を接着剤を介
して積層し、加圧成形して集成フリッチを得、これをス
ライスすることにより得られている。このような工程を
経て作られた人工化粧単板は、合板に貼着された後塗装
されて製品化される。その塗装時に単板内に塗料が吸い
込まれるのを防止するため、従来は、単板に熱硬化性樹
脂等の樹脂を含浸させる等して単板表面に保護膜を作る
表向処理(シール処理)が行われていた。しかしながら
、人工化粧単板に多量の樹脂が含浸されると、単板の透
明度が上がり、単板貼涜後に白根の色や模様が単板を通
して透けて見えるという「裏映り」現象が生じたり、単
板の木憤感が損われたりするとGう問題があった。
This artificial decorative veneer is usually made as follows. That is, the veneers obtained by rotary slicing are degreased and bleached, then dyed, the obtained dyed veneers are laminated with an adhesive, pressure molded to obtain an assembled flitch, and this is sliced. It is obtained by The artificially decorated veneer made through this process is attached to plywood and then painted to become a product. In order to prevent paint from being sucked into the veneer during painting, conventional surface treatments (sealing treatments) that create a protective film on the surface of the veneer, such as impregnating the veneer with resin such as thermosetting resin, have been applied. ) was being carried out. However, when artificial decorative veneers are impregnated with a large amount of resin, the transparency of the veneer increases, and after the veneer is pasted, the color and pattern of the white root can be seen through the veneer, resulting in a "bleed-through" phenomenon. There was a problem that the texture of the wood veneer would be damaged.

まだ、多量の樹脂が含浸された人工化粧単板は、サンデ
ィングの除、含浸樹脂が軟かい樹脂である場合には研#
AL’(の目詰りを生じ易いためサンディングしにくい
という問題があった。他方、含浸樹脂が硬い樹脂である
場合には割れやすくなるといつ問題があった。
Artificial decorative veneers impregnated with a large amount of resin should not be sanded or polished if the impregnated resin is a soft resin.
There was a problem that it was difficult to sand because the AL' was easily clogged.On the other hand, when the impregnated resin was a hard resin, there was a problem that it was easy to break.

また、別に、次のような問題もあった。すなわち、人工
化粧単機を作る前の集成用スライス単板Oま、その1枚
で人工化粧単板の木目の一部を構成している。しかしな
がら、集成時に塗布する接着剤がスライス単板に浸透し
てしまい、出来上がりの人工化粧単板の木目を不揃いに
させていた。特に、着色接着剤を用いた場合にはその傾
向が著しかつ是。そこで、スライス単板への接着剤の浸
透r防ぐために、従来、単板表面に樹脂を塗面硬化させ
て保護膜ヲ作るという処理を行っていた。ところが、こ
の場合にも、多量の含浸樹脂のために出来上がりの人工
化粧単板の木質感が損われるという問題が発生していた
In addition, there were other problems as follows. In other words, the sliced veneer for lamination before making the artificial decorative single machine, one of which constitutes a part of the grain of the artificial decorative veneer. However, the adhesive applied during lamination penetrated into the sliced veneer, causing the grain of the finished artificially decorated veneer to be uneven. This tendency is particularly pronounced when colored adhesives are used. Therefore, in order to prevent the adhesive from penetrating into the sliced veneer, a process has conventionally been carried out in which a protective film is formed by hardening the resin applied to the surface of the veneer. However, even in this case, a problem occurred in that the wood texture of the finished artificially decorated veneer was impaired due to the large amount of impregnated resin.

〔発明の目的〕[Purpose of the invention]

そこで、この発明は、塗料や接着剤の単板内への浸透を
防ぐ効果を確保した土で、単板Vこ「a映り」現象を発
生させることがなく、また、単板の木質感を損ねること
がなく、サンディング性を向上させることのできる単板
の処理法を提供することを目的とする。
Therefore, this invention uses soil that has the effect of preventing paints and adhesives from penetrating into the veneer, does not cause the "a reflection" phenomenon on the veneer, and improves the wood texture of the veneer. The purpose of the present invention is to provide a method for treating a veneer that can improve sanding properties without damaging the veneer.

〔発明の開示〕[Disclosure of the invention]

発明者らは、上記の目的を達成するtめに鋭意検討を重
ねた。その結果、単板−に付着させた熱硬化性樹脂をそ
のまま即熱硬化させるのではなく、その樹脂を浴解し得
る浴剤蒸気中で蒸気により加熱硬化させ、その後乾燥に
よって溶剤全気化させるならば、良好な結果が得られる
ことを見出し、この発明を完成した。
The inventors have made extensive studies to achieve the above object. As a result, instead of immediately heat-curing the thermosetting resin attached to the veneer, it is possible to heat-cure the resin in a bath agent vapor that can be dissolved in the bath, and then dry it to completely vaporize the solvent. The present invention was completed based on the discovery that good results could be obtained.

この、壱明は、熱硬化性樹脂が付着された直後の車俵の
表向に前記熱硬化性樹脂全溶解し得る溶剤の加熱蒸気を
当てるようにするli板の処理法をその要旨とする。以
下に、これを詳述する。
The gist of this Ichimei is a method for treating Li plates in which heated steam of a solvent capable of completely dissolving the thermosetting resin is applied to the surface of the car trunk immediately after the thermosetting resin has been attached. . This will be explained in detail below.

集成フリツナをスライスして得られた人工化粧単板に対
して表面処理を行う場合について述べる;ます、人工化
粧単板に対して熱硬化性11脂を付着させる。付着の方
法には、樹脂液中へ単機を浸漬する方法や単機表面に樹
脂液を塗布する方法等がめる。函・j四肢は、溶剤を用
いた樹IJF1溶液でも液化樹脂でも良い。熱硬化性樹
脂が付着された直後の人工化粧単板を、付着している樹
脂を溶解し得る溶剤の加熱蒸気に当てるようにする。樹
脂が付着された直後の単板を加熱処理するのは、単板中
へ樹脂が含浸してしまう以前に樹!指を単板表面におい
て硬化冗看させる心安があるからである。また、FM脂
を俗解し得る溶剤の加熱蒸気を用いて加熱処理を行うの
は、溶剤を含んだ状態で樹脂を硬化さ竺るためである。
A case will be described in which surface treatment is performed on an artificial decorative veneer obtained by slicing a laminated frituna; first, thermosetting 11 fat is applied to the artificial decorative veneer. Adhering methods include immersing the unit in a resin liquid and applying resin liquid to the surface of the unit. The box/j limbs may be made of IJF1 solution using a solvent or liquefied resin. The artificial decorative veneer immediately after the thermosetting resin has been attached is exposed to heated vapor of a solvent capable of dissolving the attached resin. Heat treating the veneer immediately after the resin has been applied is done before the resin is impregnated into the veneer! This is because it provides peace of mind by allowing the fingers to harden on the surface of the veneer. Further, the reason why heat treatment is performed using heated vapor of a solvent that can be commonly understood as FM resin is to harden the resin in a state containing the solvent.

すなわち、溶剤を含んだ状態で(資))1旨が硬化した
人工化粧単板を、その後乾燥させると、溶剤のみが気化
してその部分に空隙が生じ、結果的に、樹脂を発泡硬化
させることができるからである。それにより、人工化粧
単機の表面には、少量の樹脂が均一に付着硬化した保@
映が形成されるのである。得られる保護(碇の状態を調
整するには、単板へ樹H旨を付着させる際のm脂治液に
おける浴剤の址、加熱蒸気中の蒸気量や温間等を調整す
れは良い。それにより、樹脂の発泡度や泡の大小を調整
し得る。樹脂が発泡硬化した人工化粧i板はいその後1
1台板に貼着される等した後、サンディング、塗装等の
工程を経て製品化される。サンディング工程時には、も
ろい発泡樹脂に対してサンディングするため、樹脂が軟
かいものであっても良好にサンディングできる。
In other words, when an artificial decorative veneer that has been cured in a state containing a solvent is then dried, only the solvent evaporates and voids are created in that area, resulting in the resin foaming and hardening. This is because it is possible. As a result, a small amount of resin is uniformly adhered and hardened to the surface of the artificial makeup unit.
A reflection is formed. To adjust the state of the resulting protection (anchor), it is best to adjust the amount of bath agent in the curing solution when attaching the resin to the veneer, the amount of steam in the heated steam, the temperature, etc. By doing so, the degree of foaming of the resin and the size of the bubbles can be adjusted.
After being pasted onto a board, it is manufactured into a product through processes such as sanding and painting. During the sanding process, the brittle foamed resin is sanded, so even soft resin can be sanded well.

使用する熱硬化性樹脂と、そのml口11解し得る浴剤
との組合せには次のようなものがある。例えば、酢酸ビ
ニルをメラミン樹11旨、尿素樹η旨、スナレン樹脂等
の熱硬化性樹脂で変性させて作られた熱硬化性樹脂とこ
れを溶解する水との組合せ、ポリウレタン樹B旨、ポリ
エステル樹j)旨とこれを溶解するメタノールやトルエ
ンとの組合せ、メラミンtat脂、尿素樹脂、アクリル
tti指等とこれらを溶解−仁る水やメタノールとの組
合せなどである。し〃・し、これらの組合せに限られる
ものではない。
The following combinations of thermosetting resins and bath additives can be used: For example, combinations of thermosetting resins made by modifying vinyl acetate with thermosetting resins such as melamine resin 11, urea resin η, sunalene resin and water to dissolve it, polyurethane resin B, polyester Examples include a combination of resin and methanol or toluene to dissolve it, and a combination of melamine tat fat, urea resin, acrylic resin, etc. and water or methanol to dissolve them. However, the combination is not limited to these combinations.

以下に、実施例を挙げる。Examples are given below.

(実施例1) 硬化剤として硫酸アンモニウムを用い、酢酸ビニルτメ
ラミン樹1指で熱硬化性樹脂に変性させた。
(Example 1) Using ammonium sulfate as a curing agent, vinyl acetate τ melamine resin was modified into a thermosetting resin with one finger.

この樹脂を界面活性剤を用いて水に溶解し、レジンコン
テントを50重量係とした。この樹脂溶液を人工化粧単
板の片面にロールコータで50 g/m2伍布した。こ
の人工化粧単機を、乾燥させることなく、密閉容器内で
150℃の飽和水蒸気に15分間当てた。その後、人工
化粧単機を乾燥させ、jit !l旨が発泡硬化した人
工化粧単板が得られた。
This resin was dissolved in water using a surfactant to bring the resin content to 50% by weight. This resin solution was applied to one side of an artificially decorated veneer at a rate of 50 g/m2 using a roll coater. This artificial makeup unit was exposed to saturated steam at 150° C. for 15 minutes in a closed container without drying. After that, let the artificial makeup machine dry and jit! An artificially decorated veneer in which the foam was cured was obtained.

(実施例2) 水浴性のポリウレタン樹脂を水に浴解し、レジンコンテ
ントを;(0重量係とした。この111脂浴液を人工化
粧単機の片面にフローコータにより50g/rr+2 
塗布した。この人工化粧単機を、乾燥させることなく、
密閉容器内で100℃の飽和トルエン蒸気に30分間当
てた。その後、人工化粧単板を乾燥させ、樹脂が発泡硬
化した人工化粧単機が得られた。なお、メタノールを用
いたのは、蒸気が容易に得ら几るからである。
(Example 2) A water-bathable polyurethane resin was bath-dissolved in water, and the resin content was set to 0 weight.This 111 fat bath liquid was coated on one side of an artificial makeup unit with a flow coater at 50g/rr+2.
Coated. This single artificial makeup machine can be used without drying out.
It was exposed to saturated toluene vapor at 100° C. for 30 minutes in a closed container. Thereafter, the artificial decorative veneer was dried to obtain an artificial decorative veneer in which the resin was foamed and hardened. Note that methanol was used because steam can be easily obtained and quenched.

(実施例3) メラミンのエマルジョンを用い、あとは実施例1と同じ
処理を行った。これにより、樹脂が発泡硬化した人工化
粧単板が得られた。
(Example 3) The same treatment as in Example 1 was carried out using a melamine emulsion. As a result, an artificial decorative veneer in which the resin was foamed and hardened was obtained.

(実施例4) アクリルのエマルジョンを用い、あとは実施例2と同じ
処理を行った。これにより、樹脂が発泡硬化した人工化
粧単板が得られた。
(Example 4) The same treatment as in Example 2 was performed using an acrylic emulsion. As a result, an artificial decorative veneer in which the resin was foamed and hardened was obtained.

(実施例5) 無溶剤のポリウレタン樹脂液を人工化粧単機の片面にロ
ールコータで50g/m2 塗布した。この人工化粧単
板を、乾燥させることなく、密閉容器内で150℃の飽
和トルエン蒸気[20分間当てた。その後、人工化駐車
&を乾燥させ、樹脂が発泡硬化した人工化粧単板を得た
(Example 5) Solvent-free polyurethane resin liquid was applied at 50 g/m2 onto one side of an artificial makeup unit using a roll coater. This artificial decorative veneer was exposed to saturated toluene steam at 150° C. for 20 minutes in a closed container without drying. Thereafter, the artificial parking lot was dried to obtain an artificial decorative veneer in which the resin was foamed and hardened.

(実施例6) レジンコンテントが60重量係のポリエヌテル樹脂トル
エン浴液を、人工化粧単板の片面に70−」−夕で70
g、/rn2 塗布した。その′後、この人工化粧単板
を、実施例5と同様にして加熱および乾燥を行った。こ
れにより、樹脂が発泡硬化した人工化粧単板が得られた
(Example 6) A polyester resin toluene bath solution with a resin content of 60% by weight was applied to one side of an artificial decorative veneer at 70% by weight.
g,/rn2 was applied. Thereafter, this artificial decorative veneer was heated and dried in the same manner as in Example 5. As a result, an artificial decorative veneer in which the resin was foamed and hardened was obtained.

つぎに、集成用スライス単板に対する表面処理について
説明する。なお、この場合において、この表面処理ずみ
スライス単板を集成、スライスして得られる人工化粧単
板に対して、既に述べたような保護膜形成の表面処理を
行うようにしても良い。
Next, surface treatment of the sliced veneer for assembly will be explained. In this case, the artificial decorative veneer obtained by assembling and slicing the surface-treated sliced veneers may be subjected to surface treatment to form a protective film as described above.

集成用スライス単板に対して、まず、熱硬化性樹脂を付
着させる。付着方法は、人工化粧単板における樹脂付着
方決と同様であるので、ここでは述べない。熱硬化性樹
脂が付着された直後のスライス単板を、付着している樹
脂を溶解し得る溶剤の加熱蒸気に当てるようにする。そ
の後、スライス単板を乾燥させて、浴剤のみを気化させ
、単板表面に樹脂が発泡状に均一に付着硬化した保ff
L漢を形成させるのである。樹脂が発泡硬化したスライ
ス単板は、接着剤を介して集成され、フリッチ成形され
たのち、スライスされて人工化粧単機となる。
First, a thermosetting resin is applied to the sliced veneer for assembly. The attachment method is the same as the resin attachment method for artificial decorative veneers, so it will not be described here. Immediately after the thermosetting resin has been applied, the sliced veneer is exposed to heated vapor of a solvent capable of dissolving the adhered resin. After that, the sliced veneer is dried, only the bath agent is vaporized, and the resin is uniformly adhered to the surface of the veneer in a foamed form and hardened.
This will form L-han. Sliced veneers made of foamed and hardened resin are assembled with adhesive, flitch-molded, and then sliced to create artificial makeup units.

単板表面に得られる保護膜の状態を調整する方法や使用
する樹脂、溶剤等は既述の人工化粧単機に対する処理法
と同様である。
The method of adjusting the state of the protective film obtained on the surface of the veneer, the resin and solvent used, etc. are the same as the treatment method for the artificial makeup unit described above.

以下に、集成用スライス単板に対する処理法の実施例を
挙げる。
Examples of processing methods for sliced veneers for assembly are listed below.

(実施例7) 実施例1と同じ熱硬化性1tJ d旨溶液をスライス単
機の両面にロールコータで各50g//r+12遣布し
た。
(Example 7) 50g//r+12 of the same thermosetting 1tJd solution as in Example 1 was applied to both sides of a single slice machine using a roll coater.

その後、実施例1と同様の処理を一行/ない、樹脂が発
泡硬化したスライス単機を得た。
Thereafter, a single slice machine in which the resin was foamed and hardened was obtained by performing the same treatment as in Example 1.

(実施例8) 実施例2と同様のポリウレタン樹脂溶液を用いて、実施
例2と同様にしてスライス単機に対する処理を行った。
(Example 8) Using the same polyurethane resin solution as in Example 2, a single slice machine was treated in the same manner as in Example 2.

その結果、樹脂が発泡硬化したスライス単板を得た。As a result, a sliced veneer in which the resin was foamed and hardened was obtained.

(実施例9) 実施tlJ 3と同様のメラミンのエマルジョンヲ用い
、スライス単板の両面にロールコータで各50g/rT
12 塗布した。その後、実施例3と同様の処理を行っ
た。これVこより、掘り旨が発泡硬化したスライス単板
を得た。
(Example 9) Using the same melamine emulsion as in Example 3, 50 g/rT was applied to both sides of the sliced veneer using a roll coater.
12 applied. Thereafter, the same treatment as in Example 3 was performed. From this process, a sliced veneer with foam hardening was obtained.

(実施例10) 実施例4と同様のアクリルのエマルジョンIllい、ス
ライス単板に対して実施例4と同様の処理を行った。こ
れにより、樹脂が発泡硬化したスライス単板を得た。
(Example 10) The same treatment as in Example 4 was performed on a sliced veneer using the same acrylic emulsion as in Example 4. As a result, a sliced veneer in which the resin was foamed and hardened was obtained.

(実施例11) 実施例5と同様の無浴剤のポリウレタン樹脂液を、スラ
イス単板の両面に対してロールコータで各50 g/m
2m布した。その後、実施例5と同様の処理を行い、樹
脂が発泡硬化したスライス単板を得た。
(Example 11) The same bath-free polyurethane resin solution as in Example 5 was applied to both sides of a sliced veneer at a rate of 50 g/m each using a roll coater.
I made a 2m cloth. Thereafter, the same treatment as in Example 5 was performed to obtain a sliced veneer in which the resin was foamed and hardened.

(実施例12) 実施例6と同様のポリエステル樹脂トルエン溶液ケ用い
、スライス単板に対して実施例6と同様の処理を行った
。これにより、樹1j旨が発泡硬化したスライス単板を
得た。
(Example 12) Using the same polyester resin toluene solution as in Example 6, a sliced veneer was subjected to the same treatment as in Example 6. As a result, a sliced veneer in which the wood 1j was foamed and hardened was obtained.

〔発明の効果〕〔Effect of the invention〕

この発明にかかる単板の処理法は、熱硬化性樹脂が付着
された直後の単板の表面に前記熱硬化性樹脂を溶解し得
る溶剤の加熱蒸気を当てるようにするので、少量の樹脂
で単板表面に塗料や接着剤の浸透を遮断する保護膜を形
成させることができ、眼板内に含浸してしまう樹脂の量
が少なくなるため、「裏映り」現象の発生を抑制するこ
とができ、単板の木質感を損わせることがないという効
果がもたらされる。また、処理後の単板表面には樹脂が
発泡状に付着するため、サンディング性が向上するとい
う効果ももたらされるのである。
The veneer treatment method according to the present invention involves applying heated vapor of a solvent capable of dissolving the thermosetting resin to the surface of the veneer immediately after the thermosetting resin has been attached, so that only a small amount of resin can be used. It is possible to form a protective film on the surface of the veneer that blocks the penetration of paint and adhesives, reducing the amount of resin impregnated into the eyeplate, thereby suppressing the occurrence of the "bleed-through" phenomenon. This has the effect of not damaging the wood feel of the veneer. Furthermore, since the resin adheres to the surface of the veneer in a foamed form after the treatment, sanding properties are improved.

代理人 弁理士 松 本 武 がAgent: Patent attorney Takeshi Matsumoto

Claims (1)

【特許請求の範囲】 (1)熱硬化性樹脂が付着された直後の単板の表面に前
記熱硬化性樹脂を浴解し得る溶剤の加熱蒸気を当てるよ
うにする単板の処理法。 (2)単板が人工化粧単板である特許請求の範囲第1項
記載の単板の処理法。 (3)単板が゛集成用ヌライス単板である特許請求の範
囲第1′sJi記載の単板の処理法。 (ω 熱硬化性樹脂が酢酸ビニルを熱硬化性樹脂で変性
させたものであり、溶剤が水である特許請求の範囲第1
項ないし第3項のいずれかに記載の単板の処理法。 (5)熱硬化性樹脂がポリウレタン樹脂であり、溶剤が
ツタノールである特許請求の範囲第1項ないし第3項の
いずれかに記載の単板の処理法。 (6)熱硬化性樹脂がポリウレタン樹脂であり、溶剤が
トルエンである特許請求の範囲第13JI々いし第3項
のいずれかに記載の単板の処理法。 (7)熱硬化性樹脂がポリエステル樹脂であり、浴剤が
トルエンである特許請求の範囲端1.Inないし第3項
のいずれかに記載の単板の処理法。
[Scope of Claims] (1) A method for treating a veneer in which the surface of the veneer immediately after the thermosetting resin is attached is exposed to heated vapor of a solvent capable of bath-dissolving the thermosetting resin. (2) The method for treating a veneer according to claim 1, wherein the veneer is an artificially decorated veneer. (3) The method for treating a veneer according to claim 1'sJi, wherein the veneer is a nullice veneer for lamination. (ω Claim 1 in which the thermosetting resin is vinyl acetate modified with a thermosetting resin, and the solvent is water.
The method for treating a veneer according to any one of Items 1 to 3. (5) The method for treating a veneer according to any one of claims 1 to 3, wherein the thermosetting resin is a polyurethane resin and the solvent is tutanol. (6) The method for treating a veneer according to any one of Claims 13 and 3, wherein the thermosetting resin is a polyurethane resin and the solvent is toluene. (7) The thermosetting resin is a polyester resin, and the bath agent is toluene. The method for treating a veneer according to any one of In to 3.
JP4266684A 1984-03-05 1984-03-05 Method of treating veneer Pending JPS60187506A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4266684A JPS60187506A (en) 1984-03-05 1984-03-05 Method of treating veneer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4266684A JPS60187506A (en) 1984-03-05 1984-03-05 Method of treating veneer

Publications (1)

Publication Number Publication Date
JPS60187506A true JPS60187506A (en) 1985-09-25

Family

ID=12642337

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4266684A Pending JPS60187506A (en) 1984-03-05 1984-03-05 Method of treating veneer

Country Status (1)

Country Link
JP (1) JPS60187506A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6323256B1 (en) * 1996-12-13 2001-11-27 Data Sciences International, Inc. Biocompatible medical devices with polyurethane surface

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6323256B1 (en) * 1996-12-13 2001-11-27 Data Sciences International, Inc. Biocompatible medical devices with polyurethane surface
US6774157B2 (en) 1996-12-13 2004-08-10 Transoma Medical, Inc. Biocompatible medical devices with polyurethane surface

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