JPS60177125A - Manufacture of tough and hard cast iron - Google Patents

Manufacture of tough and hard cast iron

Info

Publication number
JPS60177125A
JPS60177125A JP3193884A JP3193884A JPS60177125A JP S60177125 A JPS60177125 A JP S60177125A JP 3193884 A JP3193884 A JP 3193884A JP 3193884 A JP3193884 A JP 3193884A JP S60177125 A JPS60177125 A JP S60177125A
Authority
JP
Japan
Prior art keywords
cast iron
mold
tough
spheroidal graphite
released
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3193884A
Other languages
Japanese (ja)
Inventor
Yoshimi Aoyama
青山 善美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Motor Corp filed Critical Toyota Motor Corp
Priority to JP3193884A priority Critical patent/JPS60177125A/en
Publication of JPS60177125A publication Critical patent/JPS60177125A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

PURPOSE:To obtain tough and hard cast iron by releasing alloyed graphite cast iron contg. prescribed percentages of C, Si, Mn, Mg, Ni and Mo from a mold at a temp. in the austenite range and by heat treating the cast iron under prescribed conditions. CONSTITUTION:Alloyed graphite cast iron consisting of, by weight, 3-4.5% C, 1.5-3% Si, 0.2-1% Mn, 0.02-0.1% Mg, 0.6-1.4% Ni, 0.2-0.8% Mo and the balance Fe is melted, cast in a mold, and released from the mold at a temp. in the austenite range of 850-950 deg.C. The released cast iron is hardened by controlled cooling from 850-950 deg.C to <=150 deg.C at >=75 deg.C/min average cooling rate, and it is tempered at 400-650 deg.C.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、強靭鋳鉄の製造方法に関し、詳しくは、合金
球状黒鉛鋳鉄を用いて簡略な熱処理を行うことにより、
強靭鋳鉄とすることのできる強靭鋳鉄の製造方法にかか
る。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for manufacturing strong cast iron, and more specifically, by performing a simple heat treatment using alloy spheroidal graphite cast iron,
The present invention relates to a method for manufacturing strong cast iron that can be made into strong cast iron.

〔従来技術〕[Prior art]

従来、強靭鋳鉄としては、一般に、球状黒鉛鋳鉄(JI
S規格FCD70)が用いられている。
Traditionally, spheroidal graphite cast iron (JI
S standard FCD70) is used.

そして、特に高強度を必要とする場合には、上記JIS
規格FCD70を焼入焼もどし処理したり、いわゆる、
オーステンパー処理といわれる恒温処理を実施して強靭
鋳鉄としている。
When particularly high strength is required, the above JIS
Quenching and tempering standard FCD70, so-called
It is made into strong cast iron by performing constant temperature treatment called austempering treatment.

しかし、上述の熱処理方法では、一旦、鋳造成形して室
温まで冷却した後、再加熱して上述の熱処理を実施する
必要があることから、大量の熱処理エネルギを必要とす
るばかりでなく、熱処理に長い処理時間を要し、生産コ
ストが高く生産性に劣るという問題点がある。
However, in the above-mentioned heat treatment method, it is necessary to perform the above-mentioned heat treatment by casting and cooling it to room temperature and then reheating it, which not only requires a large amount of heat treatment energy but also requires a large amount of heat treatment. There are problems in that it requires a long processing time, high production cost, and poor productivity.

〔発明の目的〕[Purpose of the invention]

本発明は、このような従来技術の問題点を解決するため
になされたもので、Ni、 Moを添加して焼入性を改
善した合金球状黒鉛鋳鉄を用いて鋳造し、離型後の冷却
過程において制御冷却することにより焼入し、その後、
焼もどしするという簡略な熱処理工程にて、強靭鋳鉄を
製造することのできる強靭鋳鉄の製造方法を提供するこ
とを目的としている。
The present invention was made in order to solve the problems of the prior art, and is made by casting using alloy spheroidal graphite cast iron whose hardenability has been improved by adding Ni and Mo, and cooling it after release from the mold. Quenched by controlled cooling in the process, then
The purpose of the present invention is to provide a method for manufacturing strong cast iron that can produce strong cast iron through a simple heat treatment process of tempering.

〔発明の構成〕[Structure of the invention]

このような目的は、本発明によれば、重量比率でc;a
、o 〜4.5%、Si;1.5〜3.0%、Mn ;
 0−2〜1.0%、Mg;0.02〜0.10%、N
i;0.6〜1.4%、Mo; 0.20〜0.80%
、残部実質的にFeからなる合金球状黒鉛鋳鉄にて鋳造
後、850〜950℃のオーステナイト領域において離
型し、ついで、上記温度範囲から150℃以下に至る温
度域を、75℃/ll1in以上の平均冷却速度にて制
御冷却して焼入した後、400〜650℃の温度範囲で
焼もどしすることを特徴とする強靭鋳鉄の製造方法によ
って達成される。
Such an objective is achieved according to the invention by weight ratio c; a
, o ~4.5%, Si; 1.5~3.0%, Mn;
0-2~1.0%, Mg; 0.02~0.10%, N
i; 0.6-1.4%, Mo; 0.20-0.80%
After casting in alloyed spheroidal graphite cast iron, the remainder of which is essentially Fe, the mold is released in the austenite region of 850 to 950°C, and then the temperature range from the above temperature range to 150°C or less is cast at 75°C/11in or more. This is achieved by a method for manufacturing strong cast iron, which is characterized by controlling cooling at an average cooling rate, quenching, and then tempering at a temperature range of 400 to 650°C.

〔発明の作用〕 以下、本発明の作用について説明する。[Action of the invention] Hereinafter, the effects of the present invention will be explained.

まず、本発明材における各々の合金添加元素の範囲限定
理由について説明する。
First, the reason for limiting the range of each alloy additive element in the material of the present invention will be explained.

なお、C,St、 Mn、 Mgについては、一般的な
球状黒鉛鋳鉄組成と同じ範囲であり、かつ、範囲限定理
由も良く知られた理由に基づ(ものであるため説明を省
略する。
Note that C, St, Mn, and Mg are in the same range as the general spheroidal graphite cast iron composition, and the range limitation is based on well-known reasons, so the explanation will be omitted.

Niは球状黒鉛鋳鉄の焼入性を向上させるために有効で
あるが、0.6%未満ではその効果が十分でなく、0.
6%以上ではその添加量に応じて焼入性が向上するもの
の、1.4%を越えて添加しても添加量に見合った焼入
性向上効果が得られないばかりでなく、材料コストを高
騰させることから0.6〜1.4%とした。
Ni is effective in improving the hardenability of spheroidal graphite cast iron, but if it is less than 0.6%, the effect is not sufficient;
If it exceeds 6%, the hardenability will improve depending on the amount added, but if it is added in excess of 1.4%, not only will it not be possible to obtain a hardenability improvement effect commensurate with the amount added, but the material cost will be reduced. The price was set at 0.6% to 1.4% because it would cause the price to rise.

また、MoはNiと同様に球状黒鉛鋳鉄の焼入性を向上
させることから有効であり、特に、Niと複合添加する
ことにより、球状黒鉛鋳鉄の安定かつ優れた焼入性を確
保することができるが、0.2%未満ではその焼入性向
上効果が十分でなく、一方、0.8%を越えて添加する
と炭化物を形成しやすくなり、また、延性を低下させる
等球状黒鉛鋳鉄としての材料特性を悪化させることから
0.2〜0.8%とした。
In addition, like Ni, Mo is effective because it improves the hardenability of spheroidal graphite cast iron, and in particular, by adding it in combination with Ni, it is possible to ensure stable and excellent hardenability of spheroidal graphite cast iron. However, if it is less than 0.2%, the hardenability improvement effect will not be sufficient. On the other hand, if it is added in excess of 0.8%, it will tend to form carbides and will reduce the ductility. Since it deteriorates material properties, it is set at 0.2 to 0.8%.

つぎに、上述のような合金元素を添加した合金球状黒鉛
鋳鉄を鋳造して、850〜950℃のオーステナイト領
域にて離型後、150’t:以下に至る領域を75℃/
wr i n以上の平均冷却速度で制御冷却するのは、
冷却過程においてパーライト変態およびソルバイト・ト
ルースタイト変態を起こすことなく、マルテンサイト変
態もしくはベイナイト変態を起こさせて、十分な焼入硬
さを確保するためである。
Next, alloy spheroidal graphite cast iron to which the alloying elements described above have been added is cast, and after being released from the mold in an austenite region of 850 to 950°C, a region of 150't: or less is cast to 75°C/
Controlled cooling at an average cooling rate of wr i n or higher is as follows:
This is to ensure sufficient quenching hardness by causing martensitic transformation or bainite transformation without causing pearlite transformation or sorbite-troostite transformation in the cooling process.

〔実施例〕〔Example〕

以下、添付図面に基づいて、本発明の詳細な説明する。 Hereinafter, the present invention will be described in detail based on the accompanying drawings.

第1表に示す化学成分の合金球状黒鉛鋳鉄溶湯を注湯し
て、φ50mX200−amの棒状素材を、第1図の熱
処理サイクルに示すように、鋳造後920℃のオーステ
ナイト域にて離型し、ついで、水噴霧冷却により147
℃/minの平均冷却速度で600℃まで冷却し、つぎ
に、50’C/winの平均冷却速度で100℃まで強
制空冷して焼入した。
Molten alloy spheroidal graphite cast iron having the chemical composition shown in Table 1 is poured into a rod-shaped material of φ50m x 200-am. After casting, the mold is released in the austenitic region at 920°C as shown in the heat treatment cycle of Fig. 1. , then 147 by water spray cooling.
It was cooled to 600°C at an average cooling rate of 50°C/min, and then forced air cooled to 100°C at an average cooling rate of 50'C/win for quenching.

第1表 2図に示す。Table 1 Shown in Figure 2.

なお、上述の方法により製造した本発明材の強靭鋳鉄の
素材組織は、若干のベイナイト組織を含有するマルテン
サイト組織であった。
Note that the material structure of the strong cast iron of the present invention material manufactured by the above method was a martensitic structure containing some bainite structure.

そして、本発明材においては、上述の方法により製造し
た鋳造素材を600’CX 1時間の焼もどし処理を実
施して、また、比較材においては、本発明材と同一組成
・形状の鋳造材を、第3図の熱処理サイクルに示すよう
なオーステンパー処理した後、これらの鋳造素材がらJ
IS規格4号の引張試験片を削り出し、引張試験を実施
した。
For the inventive material, the cast material produced by the method described above was tempered at 600'C for 1 hour, and for the comparative material, a cast material with the same composition and shape as the inventive material was used. , After austempering treatment as shown in the heat treatment cycle in Figure 3, these cast materials J
A tensile test piece of IS standard No. 4 was cut out and a tensile test was conducted.

その試験結果を第2表に示す。The test results are shown in Table 2.

第2表 第2表から明らかなように、本発明法により製造した合
金球状黒鉛鋳鉄は、従来の強靭鋳鉄の一つであるオース
テンパー処理鋳鉄材に匹敵する強度および靭性を併せも
った強靭鋳鉄となっていることが理解される。
Table 2 As is clear from Table 2, the alloy spheroidal graphite cast iron produced by the method of the present invention is a tough cast iron that has strength and toughness comparable to austempered cast iron, which is one of the conventional tough cast irons. It is understood that

〔発明の効果〕〔Effect of the invention〕

以上により明らかなように、本発明にかかる強靭鋳鉄の
製造方法によれば、N1%MOを添加して焼入性を改善
した合金球状黒鉛鋳鉄を用いて鋳造し、離型後の冷却過
程において制御冷却することにより焼入し、その後、焼
もどしするという簡略な熱処理工程にて、従来のオース
テンパー処理鋳鉄に匹敵する強靭鋳鉄を製造することが
できる利点がある。
As is clear from the above, according to the method for producing strong cast iron according to the present invention, alloy spheroidal graphite cast iron whose hardenability has been improved by adding N1% MO is used for casting, and in the cooling process after demolding, It has the advantage of being able to produce strong cast iron comparable to conventional austempered cast iron through a simple heat treatment process of quenching through controlled cooling and then tempering.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明法の熱処理サイクルを示す図、第2図
は、本発明法により製造した強靭鋳鉄の焼入硬さおよび
焼もどし硬さ曲線を示す図、第3図は、従来のオーステ
ンパー処理の熱処理サイクルを示す図である。 1−−−−−−−・鋳造工程 2−・−離型工程 3−−−−−−−一制御冷却工程 4−・・−放冷工程 a・・−・・・焼入硬さ b・−一一一一一焼もどし硬さ曲線 IIFt1%l (Hr) 燻tとLIL&(“Co) 第2図 時間(Hr) 第3図
Fig. 1 is a diagram showing the heat treatment cycle of the method of the present invention, Fig. 2 is a diagram showing the quenching hardness and tempering hardness curves of tough cast iron produced by the method of the present invention, and Fig. 3 is a diagram showing the conventional heat treatment cycle. FIG. 3 is a diagram showing a heat treatment cycle of austempering treatment. 1---------Casting process 2--Mold release process 3--Controlled cooling process 4--Cooling process a---Quenching hardness b・-11111 Tempering hardness curve IIFt1%l (Hr) Smoking t and LIL & (“Co) Fig. 2 Time (Hr) Fig. 3

Claims (1)

【特許請求の範囲】[Claims] 1、重量比率でC;3.0〜4.5%、Si 71.5
〜3.0%、+4n;0.2〜1.0%、)Igi O
,02〜0.10%、Ni ; 0.6〜1.4%、M
o;0,20〜0.80%、残部実質的にFeからなる
合金球状黒鉛鋳鉄にて鋳造後、850〜950℃のオー
ステナイト領域において離型し、ついで、上記温度範囲
から150℃以下に至る温度域を、75℃/ m i 
n以上の平均冷却速度にて制御冷却して焼入した後、4
00〜650℃の温度範囲で焼もどしすることを特徴と
する強靭鋳鉄の製造方法。
1. C by weight ratio: 3.0-4.5%, Si 71.5
~3.0%, +4n; 0.2-1.0%, )IgiO
, 02-0.10%, Ni; 0.6-1.4%, M
o: After casting in alloy spheroidal graphite cast iron consisting of 0.20 to 0.80% and the remainder substantially Fe, it is released from the mold in the austenite region of 850 to 950°C, and then the temperature reaches 150°C or less from the above temperature range. Temperature range: 75℃/mi
After controlled cooling and quenching at an average cooling rate of n or more, 4
A method for producing strong cast iron, characterized by tempering at a temperature range of 00 to 650°C.
JP3193884A 1984-02-22 1984-02-22 Manufacture of tough and hard cast iron Pending JPS60177125A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3193884A JPS60177125A (en) 1984-02-22 1984-02-22 Manufacture of tough and hard cast iron

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3193884A JPS60177125A (en) 1984-02-22 1984-02-22 Manufacture of tough and hard cast iron

Publications (1)

Publication Number Publication Date
JPS60177125A true JPS60177125A (en) 1985-09-11

Family

ID=12344909

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3193884A Pending JPS60177125A (en) 1984-02-22 1984-02-22 Manufacture of tough and hard cast iron

Country Status (1)

Country Link
JP (1) JPS60177125A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0829551A2 (en) * 1996-09-11 1998-03-18 Harzer Graugusswerke GmbH Cast-iron alloy for heat resistant motor parts
EP1566454A1 (en) * 2004-02-10 2005-08-24 Magna Drivetrain AG & Co KG Process for producing nodular cast iron products and products obtained
CN103060669A (en) * 2013-01-10 2013-04-24 鞍钢集团铁路运输设备制造公司 Sintering machine heat insulation pad material and thermal treatment method of same
CN110760738A (en) * 2019-09-17 2020-02-07 上海烟草机械有限责任公司 Method for manufacturing low-temperature impact-resistant ductile cast iron

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0829551A2 (en) * 1996-09-11 1998-03-18 Harzer Graugusswerke GmbH Cast-iron alloy for heat resistant motor parts
EP0829551A3 (en) * 1996-09-11 1999-06-16 Harzer Graugusswerke GmbH Cast-iron alloy for heat resistant motor parts
EP1566454A1 (en) * 2004-02-10 2005-08-24 Magna Drivetrain AG & Co KG Process for producing nodular cast iron products and products obtained
CN103060669A (en) * 2013-01-10 2013-04-24 鞍钢集团铁路运输设备制造公司 Sintering machine heat insulation pad material and thermal treatment method of same
CN110760738A (en) * 2019-09-17 2020-02-07 上海烟草机械有限责任公司 Method for manufacturing low-temperature impact-resistant ductile cast iron
CN110760738B (en) * 2019-09-17 2022-01-14 上海烟草机械有限责任公司 Method for manufacturing low-temperature impact-resistant ductile cast iron

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