JPS60141406A - Peeling die - Google Patents

Peeling die

Info

Publication number
JPS60141406A
JPS60141406A JP24888083A JP24888083A JPS60141406A JP S60141406 A JPS60141406 A JP S60141406A JP 24888083 A JP24888083 A JP 24888083A JP 24888083 A JP24888083 A JP 24888083A JP S60141406 A JPS60141406 A JP S60141406A
Authority
JP
Japan
Prior art keywords
die
vapor deposition
chemical vapor
coating layer
peeling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24888083A
Other languages
Japanese (ja)
Inventor
Osamu Terada
修 寺田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Die Co Ltd
Original Assignee
Fuji Die Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Die Co Ltd filed Critical Fuji Die Co Ltd
Priority to JP24888083A priority Critical patent/JPS60141406A/en
Publication of JPS60141406A publication Critical patent/JPS60141406A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/308Oxynitrides

Abstract

PURPOSE:To sharply improve wear resistance by forming a hard coating layer having bad affinity to workpiece metal on the surface of a die tip by chemical vapor deposition. CONSTITUTION:A hard coating layer having bad affinity to workpiece metal is formed on the surface coating layer of the tip of a die snap by chemical vapor deposition of at least any one of carbide, nitride, boride, charbon/nitrogen compound, nitorgen/boron compound, cabonate compound, exygen/nitrogen compound, aluminium oxide belonging to 4a, 5a, or 6a groups of periodic table, or their combination. The chemical vapor deposition is effected for example under the atmosphere of reduced pressure less than 100Torr and in the temperature range from 900-1,030 deg.C.

Description

【発明の詳細な説明】 (イ)技術分野 本発明は皮剥ダイス、特に耐焼付き性と耐摩耗性を同上
しダイスの寿命を伸ばすことのできる皮剥ダイスに関す
る。
DETAILED DESCRIPTION OF THE INVENTION (a) Technical Field The present invention relates to a peeling die, and particularly to a peeling die that has the same seizure resistance and wear resistance as well as extends the life of the die.

(ロ) 従来技術と問題点 皮剥ダイスは線材、棒材等を引張シ、その李 表面の皮剥を行なうダイスとして良く知られ第1図及び
第2図で示す如く、通常そのダイステップ1は工具鋼又
は超硬合金で形成され皮剥きの厳しい東件に耐えられる
ように形成されているものである。しかしながら、従来
知られている皮剥ダイスは、比較的短時間で刃先2の先
端に構成刃先3を形成し、切削抵抗の増大及び被加工材
の寸法変化や表面粗さをもたらし例えばlコイル分皮剥
きすると使用に耐えない状態となるのが通常であった。
(b) Prior Art and Problems A stripping die is well known as a die for pulling wire rods, bars, etc. and stripping the surface of the material.As shown in Figs. It is made of steel or cemented carbide and is designed to withstand severe peeling. However, conventionally known peeling dies form a built-up cutting edge 3 at the tip of the cutting edge 2 in a relatively short period of time, resulting in an increase in cutting resistance, dimensional changes and surface roughness of the workpiece, and, for example, l-coil peeling. When removed, it usually became unusable.

このため皮剥ダイスの耐焼付き性を向上し、構成刃先3
の生成を防止することが望まれていたものである。尚、
図中4は切りくずを示している。
For this reason, the seizure resistance of the peeling die has been improved, and the built-up cutting edge 3
It was desired to prevent the formation of still,
4 in the figure indicates chips.

(ハ) 目的 本発明は、従来の比較的寿命の短い皮剥ダイスに着目し
てなされたもので、ダイスチツゾを化学蒸着することに
よりその表面へ被加工拐金属との親和性の恋い硬質被覆
層を形成することによって構成刃先が生じなく、シかも
耐摩耗性を格段と向上することのできる皮剥ダイスを提
供ぜんとすることを目的としている。
(c) Purpose The present invention was made with a focus on conventional stripping dies, which have a relatively short lifespan, and by chemical vapor deposition of the die coating, a hard coating layer is formed on the surface of the die, which has a high affinity with the stripped metal. The object of the present invention is to provide a peeling die that does not produce a built-up edge and can significantly improve wear resistance.

に) オ湾成 本発明に係る皮剥ダイスは、上記の目的を達成するため
その構成をダイスチップの刃先に、元素周期率表の4a
、5gまたは6a族の、炭化物、窒化物、硼化物、炭窒
化物、炭硼化物、窒硼化物、炭酸化物、酸窒化物、酸化
アルミニウム、又は酸窒化アルミニウムの少なくともい
ずれかを又はそれを組合わせて被層に化学蒸着し、表面
へ被加工材金属との親和性の悪い硬質被核層を形成した
ことを要旨としている。
In order to achieve the above-mentioned purpose, the peeling die according to the present invention has a structure in which the cutting edge of the die tip has the structure 4a of the periodic table of elements.
, at least one of carbides, nitrides, borides, carbonitrides, carbon borides, boron nitrides, carbonates, oxynitrides, aluminum oxides, or aluminum oxynitrides of Group 5g or 6a, or a combination thereof. The gist is that the coating layer is also chemically vapor deposited to form a hard nucleation layer on the surface that has poor affinity with the metal of the workpiece.

(ホ)実施例 以下本発明の詳MJlを、第3図を参照して説明する。(e) Examples The detailed MJl of the present invention will be explained below with reference to FIG.

尚従来と共通する部分は同一符号で示すものとし重複説
明は省略するものである。
Incidentally, parts common to the conventional one are indicated by the same reference numerals, and redundant explanation will be omitted.

この発明では、先ず皮剥ダイスのダイスチツ2′1の全
面にわたシそして刃先2に硬質被aMBを化学蒸着にて
形BI;、するものである。
In this invention, first, a hard coating of aMB is formed on the entire surface of the die 2'1 of the peeling die and on the cutting edge 2 by chemical vapor deposition.

硬質被神層5の材質としては鉄、チタン等の被加工材金
属との親−相性の悪い元素周期率表の4a、5aまたは
6a族の炭化物、窒化物、硼化物、炭窒化物、炭硼化物
、蟹硼化物、炭酸化物、酸窒化物、酸化アルミニウム、
又は醒璧化アルミニウムの少なくともいずれかを又はそ
れを組合わせて使用するものとし、特にチタン、ジルコ
ニウム、ハフニウム、クロムの炭化物、窒化物、炭窒化
物、アルミナの酸化物、炭窒化物等の採用が好ましいも
のである。
The material of the hard layer 5 includes carbides, nitrides, borides, carbonitrides, and carbons of groups 4a, 5a, or 6a of the periodic table of elements that have poor compatibility with workpiece metals such as iron and titanium. Boride, boride, carbonate, oxynitride, aluminum oxide,
or at least one of aluminum alloys or a combination thereof, especially titanium, zirconium, hafnium, chromium carbides, nitrides, carbonitrides, alumina oxides, carbonitrides, etc. is preferred.

前述したように硬質被核層5の形成には化学蒸着を用い
るものであり、例えはグイステップ1を極めて減圧下(
例えばl 00Torr以下)のT i O+4+H2
+OH4又はT to 14+H2+N*の雰囲気の下
で、900〜1030℃の温度範囲により、数時間化学
蒸着を行なえば%011S以下の平渭度を有する昇面強
度の篩いチタンの屍、窒化物の硬質被核層5を形成でき
るものである。
As mentioned above, chemical vapor deposition is used to form the hard nucleation layer 5, and for example, the step 1 is performed under extremely reduced pressure (
For example, T i O+4+H2 (less than l 00 Torr)
+OH4 or T to 14+H2+N* atmosphere, temperature range from 900 to 1030℃, chemical vapor deposition for several hours can produce sieving titanium carcasses, hard nitrides with a flatness of less than %011S. The nucleation layer 5 can be formed thereon.

化学蒸着の技術そのものは他の熱分解法、水素分解法、
置換反応法等と共に通常OVD法として公知のものなの
でここでは化学蒸着それ自体を詳述することを省略する
。ところで、化学蒸着を施ぜばその母材の耐摩耗性が向
上することは一般的に知られているものの。
Chemical vapor deposition technology itself is similar to other thermal decomposition methods, hydrogen decomposition methods,
Since this method is generally known as the OVD method along with the substitution reaction method, etc., a detailed explanation of the chemical vapor deposition itself will be omitted here. By the way, it is generally known that chemical vapor deposition improves the wear resistance of the base material.

しかしながら表面アラサや被核層の剥離し易さ、寸法変
化、再生処理の困難さなどの問題がiノることと、皮剥
ダイスと被加工材金属との親イ]」性がダイスの人命を
決める大きな要因であることが注目されなかったため皮
剥ダイスに灰%蟹化物等を化学蒸着をした例は知られて
おらず従来この櫛のダイスに化学蒸着するメリットが殆
どないと思われていたのが笑情である。そこで本晃明者
等はあえて皮剥ダイスへ化学蒸着をすべく徳々の災験を
繰フ返した結果、夕゛イステップ1へ特殊な前処理を施
し、そしてそごへMWの高い化学蒸着を行なうことによ
つ1、密着度の島い、寸法精度の高い、そして仕上は処
理が殆ど不要なほど高精度なそして被加工拐金属との親
和性の悪い硬質被覆M5を形成した皮剥ダイスを得たも
のであり、このような硬質被核層5の厚さは最大10ミ
クロン程度でよくあまシFj <硬質被核層5を形成す
る必要のないことが種々の来月によシ確認されている。
However, there are problems such as surface roughness, easy peeling of the nucleation layer, dimensional changes, and difficulty in reprocessing, and the close relationship between the peeling die and the metal to be processed can endanger the life of the die. Because it was not noticed that this was a major factor in determining comb dies, there were no known cases of chemical vapor deposition of ash% crabmide, etc. on peeling dies, and it was thought that there was little merit in chemical vapor deposition on comb dies. is humorous. Therefore, the inventors of the present invention dared to apply chemical vapor deposition to the peeling die, and as a result of repeating the unfortunate experience, they applied a special pretreatment to step 1 of the die, and then applied chemical vapor deposition with a high MW to the peeling die. By doing this, we created a peeling die with a hard coating M5 that has low adhesion, high dimensional accuracy, and finish that requires almost no processing, and has a poor affinity with the metal to be processed. The thickness of such a hard enucleation layer 5 is approximately 10 microns at most, and it is not necessary to form the hard enucleation layer 5. ing.

例えばダイスチップ1の母材の4」質によっては硬質板
a層5と母月との昇面にη層(Oo、 W2C,、脆弱
層)が生じると摩耗量やチッピングが多くなることが判
かシこの4層量を少なくするためにはダイステップ1の
母材を高炭素合金(6,14%C以上)とすることが好
ましいことが判明し、そして高炭素合金製のダイスチッ
プ1に対し硬質被核層5としてTム0を極く薄く、例え
は朽2乃至4ミクロンby化学蒸着することによって耐
チッピング性?]l−損うことなく、構成刃先の生成を
β)J止して、しかも耐摩耗性を格段と同上することが
できた。
For example, depending on the quality of the base material of the die chip 1, if an η layer (Oo, W2C, brittle layer) is formed on the ascending surface of the hard plate a layer 5 and the mother plate, the amount of wear and chipping will increase. In order to reduce the amount of four layers of carbon, it was found that it is preferable to make the base material of die step 1 a high carbon alloy (6.14% C or more). On the other hand, as the hard nucleation layer 5, the chipping resistance can be improved by chemically depositing Tm0 to an extremely thin layer, for example, 2 to 4 microns by chemical vapor deposition. ] It was possible to stop the formation of a built-up cutting edge by β) without any damage, and to significantly improve the wear resistance.

ところで、硬質υν横層5は複JiVi’のものとして
化学蒸着でき、ダイスチップ1の母材が超硬合金の場合
に、その刃先2へTi01.5μの硬jJ仮(すMを形
成し、仄いて巣にTiN1.5μのI+′、l!11被
1〆被合4層したところ、 TiNは焼付き防止と(j
11成刃先3の生成防止に効果的で。
By the way, the hard υν horizontal layer 5 can be chemically vapor deposited as a compound JiVi', and when the base material of the die tip 1 is made of cemented carbide, a hard layer of Ti01.5μ is formed on the cutting edge 2, When I applied 4 layers of TiN 1.5μ I+', 1!11 coat and 1〆 coat to the nest, I found that TiN has anti-seizure properties and (j
11 Effective in preventing the formation of a grown cutting edge 3.

似合このriN層が摩滅してもその下の正に(He貝の
’11’ i 0層が刃先2を十分に保護しダイスのh
命を非常に伸ばすことができることを確認できfr:、
Even if this riN layer wears out, the '11' i 0 layer underneath it (He shell) sufficiently protects the cutting edge 2 and the h of the die.
It can be confirmed that life can be greatly extended fr:,
.

(へ)効呆 本発明に係る皮剥ダイスは、そのダイスチップの刃先に
化学蒸着によシ被加工材金属との811.相性の悪い硬
質被覆層を形成することによってtJ4成刃先の生成防
止とl111摩耗性の向上が一段と期待されるものであ
り、この硬質板8を層の形成されていないLL来の皮剥
ダイスに比べその寿命は4倍乃至10倍も長くなること
が神々の実験により確認できた。そしてこのような硬質
被覆層の形成にあたっては硬質被植層とダイスチップの
母相との界面にη)Hが発生することを避けるため、ダ
イスチップの母相として高炭素合金を用いチタンの炭化
物をA・!IL<薄く化学蒸着すれば非常に寿命の長い
皮剥ダイスが得られるものである。
(f) Effects The peeling die according to the present invention has an 811. By forming an incompatible hard coating layer, it is expected that the formation of the tJ4 cutting edge will be prevented and the l111 abrasion resistance will be further improved. Experiments by the gods have confirmed that their lifespans are 4 to 10 times longer. When forming such a hard coating layer, in order to avoid the generation of η)H at the interface between the hard coating layer and the matrix of the die chip, a high carbon alloy is used as the matrix of the die chip, and titanium carbide is used as the matrix of the die chip. A・! If IL < thin chemical vapor deposition, a peeling die with a very long life can be obtained.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、従来の皮剥ダイスのダイスチップの縦1所面
図、 第2図は第1図中の矢示8部の拡大断面図、そして 第3図は硬質被憬層が刃先に形成された本発明に係る皮
剥ダイスのダイスチップを示す第2図相当の拡大断面図
である。 1・・・ダイスチップ 2・・・刃先 3・・・構成刃先 4・・・切りくず 5・・・硬難被核層
Figure 1 is a vertical view of the die tip of a conventional peeling die, Figure 2 is an enlarged sectional view of the section indicated by the arrow 8 in Figure 1, and Figure 3 is a hard coating layer formed on the cutting edge. FIG. 2 is an enlarged sectional view corresponding to FIG. 2 showing the die tip of the peeling die according to the present invention. 1...Dice tip 2...Blade tip 3...Constructed cutting edge 4...Chip 5...Hard core layer

Claims (2)

【特許請求の範囲】[Claims] (1) ダイスチップの刃先に、元素周期率表の411
゜5aまたは6a族の、炭化物、窒化物、硼化物、炭窒
化物、炭硼化物、窒硼化物、炭酸化物、酸窒化物、酸化
アルミニウム、又は酸窒化アルミニウムの少なくともい
ずtl、4を又はそれを組合わせて複層に化学蒸着し、
表面へ被加工材金属との親和性の悪い硬質被績層を形成
したことを特徴とする皮剥ダイス。
(1) 411 of the periodic table of elements is placed on the cutting edge of the die tip.
At least one of carbides, nitrides, borides, carbonitrides, carbon borides, boron nitrides, carbonates, oxynitrides, aluminum oxides, or aluminum oxynitrides of Group 5a or 6a, or They are combined and chemically vapor deposited into multiple layers.
A peeling die characterized by having a hard coating layer formed on the surface that has poor affinity with the metal of the workpiece.
(2) ダイスチップが高炭素合金で形成されその刃先
に、チタンの炭化物が2乃至4ミクロン化学蒸着された
ことを特徴とする特許請求の範囲第1項記載の皮剥ダイ
ス。
(2) The stripping die according to claim 1, wherein the die tip is made of a high carbon alloy and has a cutting edge thereof coated with a titanium carbide of 2 to 4 microns by chemical vapor deposition.
JP24888083A 1983-12-27 1983-12-27 Peeling die Pending JPS60141406A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24888083A JPS60141406A (en) 1983-12-27 1983-12-27 Peeling die

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24888083A JPS60141406A (en) 1983-12-27 1983-12-27 Peeling die

Publications (1)

Publication Number Publication Date
JPS60141406A true JPS60141406A (en) 1985-07-26

Family

ID=17184804

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24888083A Pending JPS60141406A (en) 1983-12-27 1983-12-27 Peeling die

Country Status (1)

Country Link
JP (1) JPS60141406A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62280363A (en) * 1986-05-29 1987-12-05 Nippon Tungsten Co Ltd Coated hard tool

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5289583A (en) * 1975-11-14 1977-07-27 Fulmer Res Inst Ltd Dies and process for preparing the same
JPS55128574A (en) * 1979-02-07 1980-10-04 Gen Electric Coated hard alloy product
JPS5775744A (en) * 1980-10-31 1982-05-12 Toshiba Tungaloy Co Ltd Tool containing and coated with dispersed material
JPS58115081A (en) * 1981-12-24 1983-07-08 メタルウエルク・プランゼ−・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Anti-abrasive member
JPS58136765A (en) * 1982-02-09 1983-08-13 Mitsubishi Metal Corp Surface-coated sintered hard alloy member for cutting tool and abrasion resistant tool

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5289583A (en) * 1975-11-14 1977-07-27 Fulmer Res Inst Ltd Dies and process for preparing the same
JPS55128574A (en) * 1979-02-07 1980-10-04 Gen Electric Coated hard alloy product
JPS5775744A (en) * 1980-10-31 1982-05-12 Toshiba Tungaloy Co Ltd Tool containing and coated with dispersed material
JPS58115081A (en) * 1981-12-24 1983-07-08 メタルウエルク・プランゼ−・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Anti-abrasive member
JPS58136765A (en) * 1982-02-09 1983-08-13 Mitsubishi Metal Corp Surface-coated sintered hard alloy member for cutting tool and abrasion resistant tool

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62280363A (en) * 1986-05-29 1987-12-05 Nippon Tungsten Co Ltd Coated hard tool

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