JPS6013047A - High-strength aluminum alloy with superior cold workability - Google Patents

High-strength aluminum alloy with superior cold workability

Info

Publication number
JPS6013047A
JPS6013047A JP11982183A JP11982183A JPS6013047A JP S6013047 A JPS6013047 A JP S6013047A JP 11982183 A JP11982183 A JP 11982183A JP 11982183 A JP11982183 A JP 11982183A JP S6013047 A JPS6013047 A JP S6013047A
Authority
JP
Japan
Prior art keywords
alloy
cold workability
workability
aluminum alloy
strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11982183A
Other languages
Japanese (ja)
Other versions
JPS6237706B2 (en
Inventor
Shigeyuki Kikuchi
菊地 茂幸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Altemira Co Ltd
Original Assignee
Showa Aluminum Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Aluminum Corp filed Critical Showa Aluminum Corp
Priority to JP11982183A priority Critical patent/JPS6013047A/en
Publication of JPS6013047A publication Critical patent/JPS6013047A/en
Publication of JPS6237706B2 publication Critical patent/JPS6237706B2/ja
Granted legal-status Critical Current

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  • Conductive Materials (AREA)
  • Forging (AREA)

Abstract

PURPOSE:To obtain the titled alloy with superior bulging workability as well as corrosion resistance, stress corrosion cracking resistance and extrusibility by preparing a specified composition consisting of Zn, Mg, Cu, Zr, Mn, Cr, Ti, V, B and Al. CONSTITUTION:This Al alloy with superior cold workability, especially bulging workability and high strength consists of, by weight, 5.5-10.0% Zn, 1.5-2.2% Mg, 0.65-2.0% Cu and 0.05-0.25% Zr as essential components, <=0.08% Mn, <=0.1% Cr, one or more among 0.001-0.1% Ti, 0.05-0.25% V and 0.0001-0.08% B, and the balance Al with inevitable impurities. The alloy has necessary performance with respect to corrosion resistance, stress corrosion cracking resistance and extrusibility which are required when the alloy is put to practical use.

Description

【発明の詳細な説明】 この発明は、冷間加工性に優れた高強度アルミニウム合
金、特に例えばオートバイのリム材のように、張出し加
工等の冷間加工を必要とする高強度材料に使用されるA
Q−Zn−Mg−Qu系合金に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention is applicable to high-strength aluminum alloys with excellent cold workability, particularly for high-strength materials that require cold working such as stretching, such as motorcycle rim materials. A
The present invention relates to a Q-Zn-Mg-Qu alloy.

オートバイ用等のリム材に使用されるようなアルミニウ
ム合金は、強度、耐食性等にすぐれていることのほか、
スポーク取付用のくぼみ部等を張出し加工によって形成
しなければならないため、冷間加工性にも優れた性質を
有するものであることが要請される。ところが、従来、
高強度アルミニウム合金として既知の八ρ−Zn −M
g−Cu系合金では、溶体化状態ないし所go材状態等
の加工の容易な調質状態でも冷間加工性に劣り、上記張
出し加工等により割れを発生し易い難点がある。
Aluminum alloys, such as those used for motorcycle rim materials, have excellent strength and corrosion resistance.
Since recesses and the like for attaching spokes must be formed by stretching, it is required to have excellent cold workability. However, conventionally,
Hataρ-Zn-M, known as a high-strength aluminum alloy
The g-Cu alloy has poor cold workability even in a tempered state where it is easy to work, such as a solution state or a go-to material state, and has the disadvantage that it is easily cracked by the above-mentioned overhang processing.

この原因につき種々研究したところ、八ρ−Zn −M
y−Cu系合金においては、その結晶粒形状を調整する
ために通常添加されるMnやCrが悪影響を及ぼしてい
るものであることが知見された。一方、従来合金として
、上記Maヤcr (7)代すに:Zr e添加したA
u−Zn−Ma−CU系合金、例えばA7050合金の
ようなものが知られているが、これらの合金においては
、Qu量が多すぎるために、やはり、依然として張出し
加工等の冷間加工性が劣るものとなつていることが知見
された。
After conducting various studies on the cause of this, we found that 8ρ-Zn-M
It has been found that in y-Cu alloys, Mn and Cr, which are usually added to adjust the crystal grain shape, have an adverse effect. On the other hand, as a conventional alloy, the above-mentioned Ma and cr (7) are substituted with: Zr e added A
U-Zn-Ma-CU alloys, such as A7050 alloy, are known, but these alloys still have poor cold workability such as stretch processing due to the excessive Qu content. It has been found that the quality has become inferior.

この発明は上記のような知見に基づき、殊にMn及びC
rの蒼有聞を規制すると共に、Quの含有量をも特定範
囲に制限することにより、高強度を保有しつつ冷間加工
性、特に張出し加工性に優れた、両特性を同時に満足す
るアルミニウム合金であって、その信実用面から要求さ
れる耐食性、耐応力腐食割れ性、押出性等の面でも所要
性能を備えたアルミニウム合金を提供しようとするもの
である。
This invention is based on the above-mentioned findings, and in particular Mn and C.
By regulating the blueness of r and limiting the content of Qu to a specific range, aluminum can simultaneously satisfy both properties: high strength and excellent cold workability, especially stretch workability. The present invention aims to provide an aluminum alloy that has the required performance in terms of corrosion resistance, stress corrosion cracking resistance, extrudability, etc., which are required from the viewpoint of reliability.

上記の目的において、この発明に係る冷間加工性に優れ
た高強度アルミニウム合金は、Zn5.5〜10.0%
、MOl、5〜2.2%、Cu 0.65〜2.0%、
Zr0.05〜0゜25%を必須成分として含み、かつ
Mn 0.08%以下およびCr0.1%以下と、その
他T+ o、oo1〜0.1%、Vo、05〜0.25
%、80.0001〜0.08%のうちの少なくとも1
11以上を含み、残りアルミニウム及び不可避不純物か
らなることを特徴とするものである。
For the above purpose, the high strength aluminum alloy with excellent cold workability according to the present invention contains 5.5 to 10.0% Zn.
, MOI, 5-2.2%, Cu 0.65-2.0%,
Contains Zr0.05-0°25% as an essential component, Mn 0.08% or less, Cr 0.1% or less, and other T+ o, oo1-0.1%, Vo, 05-0.25
%, at least 1 from 80.0001 to 0.08%
11 or more, with the remainder consisting of aluminum and unavoidable impurities.

なお、この明細書において1%」はいずれも重量基準で
示すものである。
In this specification, "1%" is expressed on a weight basis.

この発明に係る上記アルミニウム合金の含有成分とその
成分割合の意義について説明すれば次のとおりである。
The significance of the components contained in the aluminum alloy and the proportions thereof according to the present invention will be explained as follows.

ZOは、硬化要素として合金の強度の増大のために不可
欠の元素であり、5.5%未満ではその効果が少なく、
また10.0%を超えて多く含有されると耐腐食割れ性
が劣化する。Znの最も好ましい含有範囲は6.0〜8
.0%程度である。
ZO is an essential element for increasing the strength of alloys as a hardening element, and if it is less than 5.5%, its effect is small;
Moreover, if the content exceeds 10.0%, corrosion cracking resistance will deteriorate. The most preferable content range of Zn is 6.0 to 8.
.. It is about 0%.

MQは、これもZnと同様に強度を増大するのに必須の
成分であり、1.5%未満ではその効果が少なく、2.
2%を超えて含有しても強度の向上に寄与することは少
なく、逆に冷間加工性、熱間加工性が低下する欠点が派
生する。
Like Zn, MQ is also an essential component for increasing strength, and if it is less than 1.5%, its effect is small; 2.
Even if it is contained in an amount exceeding 2%, it hardly contributes to improvement in strength, and on the contrary, a drawback arises in that cold workability and hot workability deteriorate.

最も好ましい含有範囲は1.6〜1.8%程度である。The most preferable content range is about 1.6 to 1.8%.

Quは、強度の向上と同時に耐応力割れ性を改善するの
に必須の重要な元素であるが、0゜65%未満ではその
、効果が少なく、2.0%を超えると冷間加工性が低下
し、強度向上への寄与も少ない。最も好ましい範囲は、
0.7〜1゜5%程度である。
Qu is an important element that is essential for improving stress cracking resistance at the same time as improving strength, but if it is less than 0.65%, its effect is small, and if it exceeds 2.0%, it will reduce cold workability. and its contribution to strength improvement is also small. The most preferred range is
It is about 0.7 to 1°5%.

2「は、合金中の粗大再結晶を抑止し、結晶粒形状をu
&雑組織化して組織の安定化をはかると共に、張出し加
工性の改善のために有効なものであるが、0.05%未
満ではそれらの効果が少なく、0.25%を超えると粗
大な晶出物が生成して靭性等を劣化させる。最も好まし
い範囲は0.1〜0.15%程度である。
2" suppresses coarse recrystallization in the alloy and changes the crystal grain shape.
& It is effective for stabilizing the structure by creating a coarse structure and improving stretchability, but if it is less than 0.05%, these effects are small, and if it exceeds 0.25%, it may cause coarse crystals. Extrusions are generated and the toughness deteriorates. The most preferable range is about 0.1 to 0.15%.

Mnは、元来結晶粒形状の調整に有効なものであるが、
逆にその添加によって冷間加工性を劣化させる傾向があ
る。しかし0.08%未満であれば、その有害な影響は
少ない。
Mn is originally effective for adjusting crystal grain shape, but
On the contrary, its addition tends to deteriorate cold workability. However, if it is less than 0.08%, its harmful effects are small.

Crは、これもM、nと同じく冷間加工性を劣化させる
ものであるが、0.01%未満であれば、その影響は少
ない。
Cr, like M and n, deteriorates cold workability, but if it is less than 0.01%, the effect is small.

r+、v、Bは、いずれも組織の安定化をはかる上から
有効なものであるが、それらの少なくとも1種以上を、
T+ o、oo1%以上、Vo、0596JX上、BO
,0O01%lX上の少量含有させることによってその
効果を得ることができる。ただし、それらの多すぎる含
有は押出性等を劣化させるため、Ti 0.1%以下、
Vo、25%以下、80.08%以下の範囲にそれぞれ
制限される。
r+, v, and B are all effective for stabilizing the tissue, but at least one of them is
T+ o, oo1% or more, Vo, 0596JX upper, BO
,0O01%lX or more can achieve this effect. However, since too much content of these deteriorates extrudability, etc., Ti is 0.1% or less,
Vo is limited to 25% or less and 80.08% or less, respectively.

この発明に係るアルミニウム合金は、下記の実施例の参
酌によって明らかであるように、引張り強さ、耐力、伸
び等の機械的性質において従来既知であるような各種比
較合金に較べて何ら遜色のない、むしろそれより優れた
性質を保有しつつ、張出し加工等の冷間加工性に優れた
ものであり、オートバイ用等のリム材としてはもとより
、高強度とともに随げ加工、プレス加工、絞り加工、し
ごき加工等の冷間加工を施1必要のために延性の要求さ
れる各種用途の材料として好適使用しうるちのである。
As is clear from the following Examples, the aluminum alloy according to the present invention is comparable in mechanical properties such as tensile strength, yield strength, and elongation to various conventionally known comparative alloys. In fact, it possesses superior properties and is excellent in cold workability such as stretch processing, and can be used not only as a rim material for motorcycles, etc., but also with high strength and can be used in trail processing, press processing, drawing processing, etc. Because it requires cold working such as ironing, it can be suitably used as a material for various applications that require ductility.

なお1、この発明に係る合金は、上記リム材のように押
出材として使用される場合のほか、シート材としても使
用し得るもので−ある。
Note that the alloy according to the present invention can be used not only as an extruded material like the above-mentioned rim material, but also as a sheet material.

次にこの発明の実施例を示す。、。Next, examples of this invention will be shown. ,.

実施例 第1表 第1表に示す各種化学組成のアルミニウム合金の常法に
よって製造した押出材を、470℃で1時間溶体化処理
し、水冷後、120℃で24時間の時効処理を施したも
のを試料とした。そして、この各試料につき、その機械
的性質と張出し加工性を調べたところ、結果は下記第2
表に示すとおりであった。
Examples Table 1 Extruded materials manufactured by conventional methods for aluminum alloys having various chemical compositions shown in Table 1 were solution-treated at 470°C for 1 hour, cooled with water, and then aged at 120°C for 24 hours. The sample was taken as a sample. Then, we investigated the mechanical properties and stretchability of each sample, and the results are as follows.
It was as shown in the table.

[以下余白] 第2表 なお、上記第2表において、張出し加工性は、肉厚6m
の押出材を試料とし、直?!!17綱のポンチを有する
エリクセン機により球面状に張出し加工した場合の、試
料に割れを生じるまでの張り出し高さを測定したもので
ある。また、評価はいずれもリム材としての用途を基準
として、0:良好 Δ:やや良好 ×:不可 で示した。
[Margins below] Table 2 In addition, in the above Table 2, the overhang workability is determined when the wall thickness is 6 m.
Take the extruded material as a sample, and directly? ! ! The height of the overhang until cracking occurred in the sample was measured when the sample was overhanged into a spherical shape using an Erichsen machine with a 17-wire punch. In addition, all evaluations were based on the use as a rim material, and were expressed as 0: good Δ: somewhat good ×: poor.

以上 特許出願人 昭和アルミニウム株式会社that's all patent applicant Showa Aluminum Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] Zn 5.5〜10.0%、M91.5〜2゜2%、O
LI 0.65〜2.0%、Zr 0.05〜0.25
%を必須成分として含み、かつMn0808%以下およ
びCr0.1%以下と、その他Ti 0.001〜o、
i%、Vo、05〜0.25%、so、oooi〜0.
08%のうちの少なくとも1種以上を含み、残りアルミ
ニウム及び不可避不純物からなることを特徴とする冷間
加工性に優れた高強度アルミニウム合金。
Zn 5.5-10.0%, M91.5-2゜2%, O
LI 0.65-2.0%, Zr 0.05-0.25
% as an essential component, and Mn 080% or less and Cr 0.1% or less, and Ti 0.001~o,
i%, Vo, 05-0.25%, so, oooi-0.
1. A high-strength aluminum alloy with excellent cold workability, characterized in that it contains at least one kind of 0.08% and the remainder consists of aluminum and unavoidable impurities.
JP11982183A 1983-06-30 1983-06-30 High-strength aluminum alloy with superior cold workability Granted JPS6013047A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11982183A JPS6013047A (en) 1983-06-30 1983-06-30 High-strength aluminum alloy with superior cold workability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11982183A JPS6013047A (en) 1983-06-30 1983-06-30 High-strength aluminum alloy with superior cold workability

Publications (2)

Publication Number Publication Date
JPS6013047A true JPS6013047A (en) 1985-01-23
JPS6237706B2 JPS6237706B2 (en) 1987-08-13

Family

ID=14771079

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11982183A Granted JPS6013047A (en) 1983-06-30 1983-06-30 High-strength aluminum alloy with superior cold workability

Country Status (1)

Country Link
JP (1) JPS6013047A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4863528A (en) * 1973-10-26 1989-09-05 Aluminum Company Of America Aluminum alloy product having improved combinations of strength and corrosion resistance properties and method for producing the same
US5221377A (en) * 1987-09-21 1993-06-22 Aluminum Company Of America Aluminum alloy product having improved combinations of properties
US5496426A (en) * 1994-07-20 1996-03-05 Aluminum Company Of America Aluminum alloy product having good combinations of mechanical and corrosion resistance properties and formability and process for producing such product
JP2003024164A (en) * 2001-07-18 2003-01-28 Takano Co Ltd Control mechanism for chair and gas spring
EP1306455A1 (en) * 2000-08-01 2003-05-02 Federalnoe Gosudarstvennoe Unitarnoe Predpryatie "Vserossiysky Nauchno-Issledovatelsky Institut Aviatsionnykh Materialov" High-strength alloy based on aluminium and a product made of said alloy
JP2006504871A (en) * 2002-09-21 2006-02-09 ユニヴァーサル アロイ コーポレイション Extruded aluminum-zinc-magnesium-copper alloy
JP2006522871A (en) * 2003-04-10 2006-10-05 コラス・アルミニウム・バルツプロドウクテ・ゲーエムベーハー Al-Zn-Mg-Cu alloy
JP2006522872A (en) * 2003-04-10 2006-10-05 コラス・アルミニウム・バルツプロドウクテ・ゲーエムベーハー High strength Al-Zn alloy and method for producing such an alloy product
JP2009114514A (en) * 2007-11-08 2009-05-28 Sumitomo Light Metal Ind Ltd Al-Zn-Mg-Cu ALLOY EXTRUDED MATERIAL WITH EXCELLENT WARM WORKABILITY, ITS MANUFACTURING METHOD, AND WARM WORKED MATERIAL USING THE EXTRUDED MATERIAL
JP2013518184A (en) * 2010-01-29 2013-05-20 北京有色金属研究総院 Aluminum alloy product for manufacturing structural member and method for manufacturing the same

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4863528A (en) * 1973-10-26 1989-09-05 Aluminum Company Of America Aluminum alloy product having improved combinations of strength and corrosion resistance properties and method for producing the same
US5221377A (en) * 1987-09-21 1993-06-22 Aluminum Company Of America Aluminum alloy product having improved combinations of properties
US5496426A (en) * 1994-07-20 1996-03-05 Aluminum Company Of America Aluminum alloy product having good combinations of mechanical and corrosion resistance properties and formability and process for producing such product
EP1306455A1 (en) * 2000-08-01 2003-05-02 Federalnoe Gosudarstvennoe Unitarnoe Predpryatie "Vserossiysky Nauchno-Issledovatelsky Institut Aviatsionnykh Materialov" High-strength alloy based on aluminium and a product made of said alloy
EP1306455A4 (en) * 2000-08-01 2004-10-20 Federalnoe G Unitarnoe Predpr High-strength alloy based on aluminium and a product made of said alloy
JP2003024164A (en) * 2001-07-18 2003-01-28 Takano Co Ltd Control mechanism for chair and gas spring
JP2006504871A (en) * 2002-09-21 2006-02-09 ユニヴァーサル アロイ コーポレイション Extruded aluminum-zinc-magnesium-copper alloy
JP2006522871A (en) * 2003-04-10 2006-10-05 コラス・アルミニウム・バルツプロドウクテ・ゲーエムベーハー Al-Zn-Mg-Cu alloy
JP2006522872A (en) * 2003-04-10 2006-10-05 コラス・アルミニウム・バルツプロドウクテ・ゲーエムベーハー High strength Al-Zn alloy and method for producing such an alloy product
JP2012214905A (en) * 2003-04-10 2012-11-08 Aleris Aluminum Koblenz Gmbh Al-Zn-Mg-Cu ALLOY
JP2009114514A (en) * 2007-11-08 2009-05-28 Sumitomo Light Metal Ind Ltd Al-Zn-Mg-Cu ALLOY EXTRUDED MATERIAL WITH EXCELLENT WARM WORKABILITY, ITS MANUFACTURING METHOD, AND WARM WORKED MATERIAL USING THE EXTRUDED MATERIAL
JP2013518184A (en) * 2010-01-29 2013-05-20 北京有色金属研究総院 Aluminum alloy product for manufacturing structural member and method for manufacturing the same
US9993865B2 (en) 2010-01-29 2018-06-12 Grimat Engineering Institute Co., Ltd. Aluminum alloy products for manufacturing structural components and method of producing the same

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