JPS60127092A - Brazing material - Google Patents

Brazing material

Info

Publication number
JPS60127092A
JPS60127092A JP23389483A JP23389483A JPS60127092A JP S60127092 A JPS60127092 A JP S60127092A JP 23389483 A JP23389483 A JP 23389483A JP 23389483 A JP23389483 A JP 23389483A JP S60127092 A JPS60127092 A JP S60127092A
Authority
JP
Japan
Prior art keywords
weight
brazing
wax
total
brazing material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP23389483A
Other languages
Japanese (ja)
Inventor
Kozo Kashiwagi
孝三 柏木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tanaka Kikinzoku Kogyo KK
Original Assignee
Tanaka Kikinzoku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tanaka Kikinzoku Kogyo KK filed Critical Tanaka Kikinzoku Kogyo KK
Priority to JP23389483A priority Critical patent/JPS60127092A/en
Publication of JPS60127092A publication Critical patent/JPS60127092A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/32Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
    • B23K35/325Ti as the principal constituent

Abstract

PURPOSE:To permit easy brazing operation without producing an intermetallic compd. with Ti by incorporating specific wt% of Ti, Cu, Ni, and one or plural kinds of Ga, Ge, Sn and In by adequate %. CONSTITUTION:A brazing material contains 35-75% Ti, 2-20% Cu and 3-30% Ni, contains 0.5-25% at least one kind of Ga and Ge or is combined with 0.5- 15% at least one kind of Sn and In or is incorporated therein with 0.5-25% at least >= one kind of Ga and Ge and 0.5-15% at least >= one kind of Sn and In. Since such brazing material has excellent fluidity and a low m.p., working is easy and such diffusion by which the compsn. is changed is obviated without producing an intermetallic compd. with Ti. Brazing with good quality is thus accomplished.

Description

【発明の詳細な説明】 本発明は、Ti、Zr基合金用のろう材に関するもので
ある。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a brazing filler metal for Ti and Zr based alloys.

Ti、Zr基合金などをAr又は真空中の雰囲気中でA
gろう付すると、T iとAgの金属間化合物を作り易
く、Agろう中のAg以外のCu。
Ti, Zr-based alloys, etc. are heated in Ar or vacuum atmosphere.
When brazing, it is easy to form an intermetallic compound of Ti and Ag, and Cu other than Ag in the Ag brazing.

Mn等のT iへの拡散が早いので、ろうの組成変化が
著しくろう旬が極めて難しいものである。
Since the diffusion of Mn, etc. into Ti is rapid, the composition of the wax changes significantly, making wax removal extremely difficult.

本発明は斯かる問題をIW消すへくなされたもので、T
iを他の金属にろう付するに用いた際、ろうと金属間化
合物を作らず、ろうのT iへの極端な拡散も起さず、
ろう流れが良くて融点も低いろう材を提供せんとするも
のである。
The present invention has been made to eliminate such problems, and T
When Ti is used to braze other metals, it does not form intermetallic compounds with the solder and does not cause extreme diffusion of the solder into the Ti.
The purpose of the present invention is to provide a brazing filler metal that has good brazing flow and a low melting point.

本発明のろう祠の1つは、T i 35〜75重量%と
Cu2〜20重景%とNi3〜30重量%とGa、Ge
の少なくとも1種を合計で0.5〜25重量%と 0.
3重量%以下の不可避不純物より成る。
One of the wax shrines of the present invention contains 35-75% by weight of Ti, 2-20% of Cu, 3-30% of Ni, and Ga, Ge.
A total of 0.5 to 25% by weight of at least one of: 0.
Consists of 3% by weight or less of unavoidable impurities.

本発明のろう祠の他の1つは、′I’ i 35〜75
i量%とCu2〜20重里%とN i 3〜30;7d
ii%とS rI。
Another one of the wax shrines of the present invention is 'I' i 35-75
i amount %, Cu2~20 Shigesato% and N i 3~30;7d
ii% and SrI.

Inの少なくとも1種を合計0.5〜15重量%と0.
3重量%以下の不可避不純物より成る。
A total of 0.5 to 15% by weight of at least one type of In and 0.5% to 15% by weight of In.
Consists of 3% by weight or less of unavoidable impurities.

本発明のろう材の更に他の1つば、−f’ i 35〜
75重量%とCu2〜20重量%とNi3〜30重量%
とG’a 、 (J eの少なくとも1種を合計で0.
5〜25重址%とSn、Inの少なくとも1種を合計で
0.5〜15市量%と0,3重量%以下の不可避不純物
より成る。
Yet another brim of the brazing filler metal of the present invention, -f' i 35~
75% by weight, 2-20% by weight of Cu, and 3-30% by weight of Ni.
and G'a, (Je) with a total of 0.
It consists of 5 to 25 weight percent, at least one of Sn and In in total, 0.5 to 15 weight percent, and 0.3 weight percent or less of unavoidable impurities.

これら本発明のろう材に於いて、”I” i 35〜7
5重量%とじたのは、ろ・う付するT + 、Z r基
合金等の近イ声の組織のろう付部を得る為で、35重量
%未l茜ではそれができず、75重量%を超えると母材
との化合物を作り易く、拡散が早くてろう付が困Hとな
る。
In these brazing materials of the present invention, "I" i 35 to 7
The reason for adding 5% by weight was to obtain a brazed part with a structure similar to that of T+, Zr-based alloys, etc., which is to be brazed. If it exceeds %, it is easy to form a compound with the base material, and diffusion is rapid, making brazing difficult.

Cu2〜20Lff量%としたのは、ろうの融点を低く
する為で、2重量%未満ではろうの融点が低くならず、
ろう流れが悪くなり、20重量%を超えると′]゛iと
もろい化合物を作り、ろう付部の強度が低下することに
なる。
The reason why the amount of Cu is 2 to 20 Lff is to lower the melting point of the wax, and if it is less than 2% by weight, the melting point of the wax will not be lowered.
If the amount exceeds 20% by weight, a brittle compound will be formed and the strength of the brazed portion will be reduced.

Ni3〜30重量%としたのは、Tiへのろう拡散を防
J13゛る為とろうの流れ過きを防く為で、3型開%未
八でし、1それかできず、30市量%を超えるとろうの
副:点が上がり、ろっ流れが悪くなる。
The reason why Ni was set at 3 to 30% by weight was to prevent the diffusion of wax into Ti and to prevent the flow of wax. If the amount exceeds the amount %, the waxy vice: the score will increase and the flow will become worse.

Ga、Geの少なくとも1種を合計で0.5〜25重量
%とじたのは、ろうの融点を低くし、ろ・う流れを良く
する為で、0,5重量%未l^δではそれができず、2
5重量%を超えると加」ニ性が悪くなる。
The reason why at least one of Ga and Ge is added in a total of 0.5 to 25% by weight is to lower the melting point of the wax and improve the flow of the wax. 2
If it exceeds 5% by weight, the adhesion properties will deteriorate.

Sn、Inの少なくとも1種を合計0.5〜15重量%
としたのはGa、Geの場合と同様ろうの融点を低くし
、ろう流れを良くする為で、0.5車量%未満でばそれ
ができず、15重量%を超えると加工性が悪くなる。
A total of 0.5 to 15% by weight of at least one of Sn and In
The reason for this is to lower the melting point of the solder and improve the flow of the solder as in the case of Ga and Ge, but if it is less than 0.5% by weight, this cannot be achieved, and if it exceeds 15% by weight, the processability is poor. Become.

次に本発明のろう材の具体的な実施例と従来例について
説明する。
Next, specific examples and conventional examples of the brazing filler metal of the present invention will be described.

下記の表−1に示す成分組成の実施例1〜3のろう材と
従来例のろう材を用いてステンレス鋼にTiをろう何す
る試験を行った処、下記の表−2に示すような結果を得
た。
A test was conducted to braze Ti onto stainless steel using the brazing fillers of Examples 1 to 3 and the conventional brazing filler metal with the compositions shown in Table 1 below, and the results were as shown in Table 2 below. Got the results.

表−1 表−2 上記の表−2の結果で明らか゛なように従来例のろう祠
ではろう付部にTiとの金属間化合物が多かったのに対
し、実施例1〜3のろう+Jではろう41部にi” i
化合物が無いことが判る。また実施例1〜3のろう材は
、−ろうの流動性が従来例のろう祠に比べて優れ、しか
も実施例1〜3のろう祠は従来例のろう祠よりも著しく
融点が低いことが判る。
Table 1 Table 2 As is clear from the results in Table 2 above, in the conventional brazing area, there were many intermetallic compounds with Ti in the brazed area, whereas in Examples 1 to 3, there were many intermetallic compounds with Ti. +J to Deaf 41 section i”i
It turns out that there is no compound. In addition, the brazing fillers of Examples 1 to 3 have superior fluidity compared to the conventional brazing pads, and the melting points of the brazing pads of Examples 1 to 3 are significantly lower than that of the conventional brazing pads. I understand.

以上の説明で判るように本発明のろう祠は、Tiをろう
(=Jするのに用いた際、脆い金属間化合物を作らず、
ろうの組成か著しく変化するような拡散もなく、またろ
うの流動性に優れ、しがも融点が著しく低くてろう付作
業が容易であるので、従来のろう材にとって代わること
のできる画期的なものと云える。
As can be seen from the above explanation, the brazing shrine of the present invention does not create brittle intermetallic compounds when Ti is used for brazing (=J).
There is no diffusion that would significantly change the composition of the solder, the fluidity of the solder is excellent, and the melting point is extremely low, making it easy to braze, making it an innovative product that can replace conventional brazing materials. It can be said that it is something.

出願人 田中貴金属工業株式会社Applicant Tanaka Kikinzoku Kogyo Co., Ltd.

Claims (1)

【特許請求の範囲】 1 ) ’T’ i 35〜75i量%とCu2〜20
重量%とNi3〜30市量%とGa、−Geの少なくと
も1種を合計で0.5〜25重量%と不可避不純物より
成るろう祠。 2 ) i’ i 35〜75ffi Fit%とCu
2〜20重量%とNi3〜30市贋%とSn、lnの少
なくとも1種を合計で0.5〜15重量%と、不可避不
純物より成るろう月。 3 ) i’ i 35〜75重量%とCu2〜20重
量%とNi3〜3(川[%とGa、Geの少なくとも1
種を合計で0.5〜25重量%とSn、Inの少なくと
も1■・l(を合d1で0.5〜15重量%と不可避不
純物より成るろう(、イ。
[Claims] 1) 'T' i 35-75i amount% and Cu2-20
% by weight of Ni, 3-30% by market weight of Ni, a total of 0.5-25% by weight of at least one of Ga and -Ge, and unavoidable impurities. 2) i'i 35~75ffi Fit% and Cu
2 to 20% by weight of Ni, 3 to 30% of Ni, and at least one of Sn and In in a total of 0.5 to 15% by weight, and unavoidable impurities. 3) i'i 35 to 75 wt%, Cu2 to 20 wt%, Ni3 to 3 (River [% and at least 1 of Ga, Ge
A wax consisting of a total of 0.5 to 25% by weight of seeds and at least 1.1 cm of Sn and In (total of 0.5 to 15% by weight of d1 and unavoidable impurities).
JP23389483A 1983-12-12 1983-12-12 Brazing material Pending JPS60127092A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23389483A JPS60127092A (en) 1983-12-12 1983-12-12 Brazing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23389483A JPS60127092A (en) 1983-12-12 1983-12-12 Brazing material

Publications (1)

Publication Number Publication Date
JPS60127092A true JPS60127092A (en) 1985-07-06

Family

ID=16962231

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23389483A Pending JPS60127092A (en) 1983-12-12 1983-12-12 Brazing material

Country Status (1)

Country Link
JP (1) JPS60127092A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0238433A2 (en) * 1986-02-18 1987-09-23 United Technologies Corporation Titanium-copper-nickel braze filler metal
US7419086B2 (en) * 2003-07-14 2008-09-02 Honeywell International Inc. Low cost brazes for titanium
US8834347B2 (en) 2008-08-22 2014-09-16 Dymedix Corporation Anti-habituating sleep therapy for a closed loop neuromodulator
US11178497B2 (en) 2017-06-23 2021-11-16 USound GmbH In-ear receiver

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5811389A (en) * 1981-07-02 1983-01-22 キヤリア・コ−ポレイシヨン High-performance heat-transfer pipe and its manufacture

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5811389A (en) * 1981-07-02 1983-01-22 キヤリア・コ−ポレイシヨン High-performance heat-transfer pipe and its manufacture

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0238433A2 (en) * 1986-02-18 1987-09-23 United Technologies Corporation Titanium-copper-nickel braze filler metal
US7419086B2 (en) * 2003-07-14 2008-09-02 Honeywell International Inc. Low cost brazes for titanium
US8834347B2 (en) 2008-08-22 2014-09-16 Dymedix Corporation Anti-habituating sleep therapy for a closed loop neuromodulator
US8834346B2 (en) 2008-08-22 2014-09-16 Dymedix Corporation Stimulus sequencer for a closed loop neuromodulator
US11178497B2 (en) 2017-06-23 2021-11-16 USound GmbH In-ear receiver

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