JPS6012305B2 - How to glaze ceramics - Google Patents

How to glaze ceramics

Info

Publication number
JPS6012305B2
JPS6012305B2 JP12993476A JP12993476A JPS6012305B2 JP S6012305 B2 JPS6012305 B2 JP S6012305B2 JP 12993476 A JP12993476 A JP 12993476A JP 12993476 A JP12993476 A JP 12993476A JP S6012305 B2 JPS6012305 B2 JP S6012305B2
Authority
JP
Japan
Prior art keywords
paper
pongee
yuzu
medicine
ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP12993476A
Other languages
Japanese (ja)
Other versions
JPS5354213A (en
Inventor
猛郎 和田
益男 宮地
克己 松本
英男 中井
賢策 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takeda Pharmaceutical Co Ltd
Original Assignee
Takeda Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takeda Chemical Industries Ltd filed Critical Takeda Chemical Industries Ltd
Priority to JP12993476A priority Critical patent/JPS6012305B2/en
Publication of JPS5354213A publication Critical patent/JPS5354213A/en
Publication of JPS6012305B2 publication Critical patent/JPS6012305B2/en
Expired legal-status Critical Current

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Description

【発明の詳細な説明】 本発明は特殊な紬薬紙を用いて陶磁器額を施柚、成形す
る方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for forming and forming ceramic frames using special pongee paper.

最近、陶磁器業界では柚薬の経時による発色変化や施柚
時の重金属酸化物の粉塵などを防ぐために「たとえば熱
溶融性合成繊維状物とセルロースパルプとからなる繊維
材料を柚薬と組み合わせたシート(紬薬紙)を用いて施
紬することが提案されている。
Recently, in the ceramics industry, in order to prevent the color change of yuzu over time and the dust of heavy metal oxides when applying yuzu, ``for example, sheets made of fibrous material made of heat-melting synthetic fibers and cellulose pulp combined with yuzu. It has been proposed to use pongee paper (pongee paper).

しかしながら、これはシート中に如何に多量の袖薬を含
有させるかを主目的とするもので、紬薬紙としての強度
が十分ではなかった。本発明者らは「 この純薬紙で施
紬した陶磁器類を焼成したところ、有機質プルプによる
還元現象がみられ、安定した色調を出すことができなか
った。また、この柚薬紙を湿つた陶磁器原料の主体面(
陶磁器素地)にはりつけた後、乾燥すると袖薬紙と陶磁
器原料との収縮率が異なるので表面にしわができ、湿っ
た陶磁器素地の施紬には使用できないことがわかつた。
一方、和紙などに紬薬または顔料のインキを用いて印刷
し、これを陶磁器素地に転写印刷したり、謄写版のよう
に陶磁器素地に直接、印刷、施柚する方法も知られてい
るが、これは下絵付とか上絵付といわれるもので、一旦
陶磁器素地を乾燥したり、白素地などを焼き付けた後に
施すものである。
However, the main purpose of this method was to incorporate a large amount of medicine into the sheet, and it did not have sufficient strength as pongee medicine paper. The inventors stated, ``When we fired ceramics made with this medicinal paper, a reduction phenomenon due to organic pulp was observed, and we were unable to produce a stable color tone. The main surface of ceramic raw materials (
It was discovered that when the paper was pasted onto a ceramic base (ceramic base) and dried, wrinkles formed on the surface due to the difference in shrinkage rates between the cuff paper and the ceramic raw material, making it unusable for pongee binding on damp ceramic bases.
On the other hand, other methods are known, such as printing on Japanese paper using pongee or pigment ink and transferring this onto a ceramic base, or directly printing and applying it on a ceramic base like a mimeograph. This is called underglaze or overglaze, and is applied after the ceramic base has been dried or a white base has been fired.

この方法では、上記の乾燥工程や焼き付け工程のほかに
紙成分だけを除く工程が必要であった。本発明者らは、
このような事情に鑑み、鋭意検討した結果、柚薬を山皮
の水分散液に分散させ、これを紙状に抄いた柚薬を用い
ると柚薬紙と湿った陶磁器素地とが乾燥時にほぼ同じよ
うな割合で収縮し、陶磁器素地の表面にしわができない
ことを知見した。
In addition to the above-mentioned drying and baking steps, this method required a step to remove only the paper components. The inventors
In view of these circumstances, after careful consideration, we found that by dispersing yuzu medicine in an aqueous dispersion of mountain bark and using the yuzu medicine made by paper-shaping it, the yuzu medicine paper and the wet ceramic base will be almost completely separated when dry. They found that the ceramic material shrinks at a similar rate and does not cause wrinkles on the surface of the ceramic material.

また、このように微少の厚さの袖薬紙を使用すれば微少
圧で陶磁器素地表面の成形が可能となることを知見した
。しかも柚薬紙中の全ての成分が純薬となり得るので、
紙成分だけを除く工程も不要であることなどを知見した
。本発明はこのような知見にもとづくものである。
We also discovered that by using such a minutely thick cuff paper, it is possible to shape the surface of a ceramic base with a minute pressure. Moreover, all the ingredients in the Yuyaku paper can be pure medicine, so
It was discovered that there was no need for a process to remove just the paper component. The present invention is based on such knowledge.

すなわち、本発明は柚薬を山皮の水分散液中に分散させ
、かかる分散液を紙状に抄いて得られる柚薬紙を陶磁器
原料の成形時もしくは成形後にその主体面に付着させる
ことを特徴とする陶磁器類の施紬方法である。
That is, the present invention involves dispersing yuzu medicine in an aqueous dispersion of mountain bark, and making yuzu paper from the dispersion into a paper form and attaching it to the main surface of the ceramic raw material during or after the molding. This is a distinctive method of pongee-laying ceramics.

本発明に用いられる山皮とはその表面に多数の水酸基を
有する粘土性鉱物であり、含水マグネシウム シリケ
‐ト(hy也o船 ma凱esi肌silicaに)の
セピオライト(sepiolite),含水マグネシウ
ム アルミナムシリケート(hydrousmagne
−slumaluminmmsilicaに)のアタパ
ルジヤイト(atねpulgiに)(別名;パリゴルス
カイトpaly−go鷹kite)をいう。
The mountain bark used in the present invention is a clay mineral having a large number of hydroxyl groups on its surface, and includes hydrated magnesium silicate (sepiolite) and hydrated magnesium aluminum silicate. (hydrousmagne
Attapulgiite (another name: palygorskite) of -slumaluminmmsilica).

通称マウンテンコルク(moun−bin cork)
,マウンテンレザー(mountain lea比er
),マウ ン テン ウ ツド(mountainwぴ
幻)と呼ばれている鉱物の総称であり、日本でいう海泡
石もこの一種である。本発明に用いられる山皮の水分散
液とは、たとえば山皮の濃度が0.05〜5の重量%好
ましくは0.1〜1の重量%の分散液である。この水分
散液は他の粘土類と同様、単に山皮を水中に入れて適宜
の手段で縄梓混合することによって得られる。この水分
散液を作る場合、たとえば過酸化水素水やグリコール類
,グリセリン,砂糖などの多価アルコール類を予め山皮
に作用させると一層容易に分散させることができる。ま
た、水に、たとえばメタノール,エタノールなどのアル
コール類,アセトンなどのケトン類,酢酸エチルなどの
ェステル類を予め加えてもよい。水のかわりに湯を用い
ることによって山皮の分散を促進させることもできる。
分散に際しては如何なる分散方法を用いてもよいが、山
皮の濃度が約1重量%以下の分散液についてはたとえば
高速ミキサーによって分散させることができる。高濃度
の分散液については、たとえば三本ロールのような方法
を用いることができる。1〜5重量%の分散液について
は、たとえば製紙用クレーの分散機などの鷹拝と練り込
みが同時におこなわれる分散方法が好ましい。
Commonly known as mountain cork
, mountain leather
), is a general term for minerals called mountain rocks, and meerschaum in Japan is also a type of this mineral. The aqueous dispersion of mountain bark used in the present invention is, for example, a dispersion in which the concentration of mountain bark is 0.05 to 5% by weight, preferably 0.1 to 1% by weight. This aqueous dispersion, like other clays, can be obtained by simply placing mountain bark in water and mixing it with a suitable method. When making this aqueous dispersion, dispersion can be made easier if, for example, hydrogen peroxide, glycols, glycerin, polyhydric alcohols such as sugar are applied to the mountain bark in advance. Furthermore, alcohols such as methanol and ethanol, ketones such as acetone, and esters such as ethyl acetate may be added to water in advance. Dispersion of mountain bark can also be promoted by using hot water instead of water.
Any dispersion method may be used for dispersion, but a dispersion having a concentration of mountain bark of about 1% by weight or less can be dispersed, for example, by a high-speed mixer. For highly concentrated dispersions, a method such as a three-roll method can be used, for example. For dispersions of 1 to 5% by weight, a dispersion method in which mixing and kneading are carried out simultaneously, such as using a dispersing machine for papermaking clay, is preferred.

分散に際しては、たとえばポリリン酸ソーダ,ポリリン
酸アンモニウム,アルミナゾル,シリカゾル,ポリビニ
ールアルコール,CMC,合成ゴムラテツクス,つのま
た,ふのり,とるろあおし、,こんにやく,うつぎなど
の分散助剤や接着剤などを添加してもよい。
For dispersion, dispersion aids and adhesives such as sodium polyphosphate, ammonium polyphosphate, alumina sol, silica sol, polyvinyl alcohol, CMC, synthetic rubber latex, Tsunomata, Funori, Toruro Aoshi, Konniyaku, Utsugi, etc. may be added.

また、山皮以外の無機質繊維あるいは有機質繊維を共分
散させてもよい。
Further, inorganic fibers or organic fibers other than mountain bark may be co-dispersed.

無機質繊維としては、たとえばガラス繊維,岩綿,鉱,
線,カオリン繊維,ホウ素繊維,カーボン繊維,セラミ
ックファイバー,石英繊維,溶融シリカ繊維などが挙げ
られる。有機質繊維としては、たとえば唐松,椴松など
の針葉樹から得られるパルプ,みつまた,こうぞ,がん
びなどの和紙用長繊維類,麻,木綿などの繊維があげら
れる。長繊維を混合,分散させる場合は、アジター型の
擁梓機を用いることが好ましい。本発明に用いられる紬
薬としては、一般に陶磁器などの分野で用いられる柚薬
であれば如何なるものでもよい。
Examples of inorganic fibers include glass fiber, rock wool, ore,
Examples include wire, kaolin fiber, boron fiber, carbon fiber, ceramic fiber, quartz fiber, and fused silica fiber. Examples of organic fibers include pulp obtained from coniferous trees such as Japanese pine and Japanese pine, long fibers for Japanese paper such as mitsumata, kozo, and ganbi, fibers of hemp, cotton, and the like. When mixing and dispersing long fibers, it is preferable to use an agitator-type retainer. The pongee medicine used in the present invention may be any pongee medicine that is generally used in the field of ceramics and the like.

具体的には、たとえば、a 高火度柚(SK8〜10) 川鉄柚 夫目柚(SK 8〜9岬),鉄砂袖(SK 9〜1のF
,RF),そば袖(SK 9岬),伊羅保柚(SK9岬
),朱斑袖(SK 9価),黄瀬戸柚(SK8〜9価)
■鋼紬識部柚(SK8〜9岬),青識部柚(SK8〜9
価),均窯紬(SK 9〜1皿F‘31マット紬 辰砂柚(SK 9〜1皿F),白色マット柚(SK 8
〜9岬),白色マット柚(SK 8〜9価),金茶色マ
ット袖(SK9価),紺青色マット柚(SK9岬)【4
ー 結晶紬 チタン結晶柚(SK9帆),コバルト結晶紬(SK9帆
),マンガン結晶紬(SK 8〜9岬),亜鉛結晶紬(
SK9価),{51白濁柚 白萩紬(SK 8〜9岬),志野柚(SK8〜9価),
乳白柚(SK 8〜9価)‘6} その他 るり紬(SK9岬),薩摩柚(SK8岬),b、低火度
紬(SKOI傘〜SKO$)‘1)標準フリットを使用
した紬 アンチモン黄袖(830〜850午0),マンガン繋紬
(830〜85ぴ0),鋼緑紬(800〜830午○)
,鉄黄柚(830〜850℃),クロム赤紬(800〜
総oqo),トルコ青紬(850〜滋0℃),ウラン叢
稗(850〜87ぴ0)■ その他 セレン赤柚(810〜840℃),ウラン朱色細く85
0〜870℃),トルコ青柚(950〜弊0℃),クロ
ム黄紬(970〜99ぴ○)などがあげられる。
Specifically, for example, a High fire rate Yuzu (SK 8-10), Kawatetsu Yuzuume Yuzu (SK 8-9 Misaki), Tetsusasode (SK 9-1 F
, RF), Soba Sode (SK 9 Misaki), Irabo Yuzu (SK 9 Misaki), Vermilion Sode (SK 9 valence), Kiseto Yuzu (SK 8-9 valence)
■ Kotsumugi Shikibu Yuzu (SK8~9 Misaki), Aoshikibu Yuzu (SK8~9
price), uniform kiln pongee (SK 9 to 1 plate F'31 matte Tsumugi cinnabar yuzu (SK 9 to 1 plate F), white matte yuzu (SK 8
- 9 Misaki), white matte yuzu (SK 8-9 valence), golden brown matt sleeve (SK 9 valence), dark blue matte yuzu (SK 9 valence) [4
- Crystal pongee Titanium crystal pongee (SK9 sail), Cobalt crystal pongee (SK9 sail), Manganese crystal pongee (SK 8-9 Misaki), Zinc crystal pongee (
SK 9 valence), {51 white cloudy yuzu white hagitsumugi (SK 8-9 cape), Shino yuzu (SK 8-9 valence),
Opalescent yuzu (SK 8-9 valence) '6} Others Ruri Tsumugi (SK9 Misaki), Satsuma Yuzu (SK8 Misaki), b, low-temperature pongee (SKOI umbrella ~ SKO $) '1) Tsumugi antimony using standard frit Yellow sleeves (830-850 p.m.), manganese Tsumugi (830-85 p.o.), steel green pongee (800-830 p.m.)
, iron yellow yuzu (830~850℃), chrome red pongee (800~
Total oqo), Turkish blue pongee (850~87℃), uranium mulberry (850~87pi0)■ Other selenium red yuzu (810~840℃), uranium vermilion thin 85
0 to 870°C), Turkish blue yuzu (950 to 0°C), and chrome yellow pongee (970 to 99 pi○).

上記の柚薬のほかに、紬薬の成分となるものをそれぞれ
別に加えてもよく、更には山皮や金属などの粉末を加え
てもよい。
In addition to the above-mentioned yuzu medicine, other components of pongee medicine may be added separately, and powders of mountain bark, metal, etc. may also be added.

紬薬の形状は平均粒径が約10血〃〜0.25帆の微粉
末状のものであってもよく、更には平均粒径が約0.5
肋〜2.5側の米粒大の粒子であってもよい。紬薬と山
皮の比率は、用いられる紬薬の種類や分散液中に混入さ
れる種々の繊維成分などによって変わるが、紬薬と山皮
の乾燥重量比が約0.01〜500の音、好ましくは約
0.1〜100の苦、更に好ましくは約0.1〜5M音
程度である。
The shape of Tsumugi medicine may be in the form of a fine powder with an average particle size of about 10 to 0.25, and more preferably, an average particle size of about 0.5.
It may be grain-sized particles of rice grains on the rib side to 2.5 sides. The ratio of pongee medicine to mountain bark varies depending on the type of pongee medicine used and the various fiber components mixed into the dispersion, but the dry weight ratio of pongee medicine to mountain bark is approximately 0.01 to 500. , preferably about 0.1 to 100 kHz, more preferably about 0.1 to 5 MB.

紬薬は、たとえば蝿枠棒やボールミルなどの通常、公3
句の方法によって山皮の水分散液中に分散させる。
Tsumugi medicine is usually made using a common method such as a fly frame stick or a ball mill.
Disperse it in an aqueous dispersion of mountain bark using the method described in the article.

ついで、この分散液を紙状になるまで適宜の方法(例、
自然炉週,減圧炉過など)によって脱水する。このよう
にして得られた紙は必要に応じて乾燥してもよい。本発
明では、このようにして得られた紬薬紙を陶磁器原料の
成形時もしくは成形後にその主体面に付着させる。
Next, this dispersion is processed in an appropriate manner (e.g., until it becomes paper-like).
Dehydrate by natural furnace heating, vacuum furnace filtration, etc.). The paper thus obtained may be dried if necessary. In the present invention, the pongee medicine paper thus obtained is attached to the main surface of the ceramic raw material during or after molding.

陶磁器原料としては、たとえば磁器洋食器,陶器質洋食
器,衛生陶器,磁器玩具,置物,硝子,碍管,点火栓碍
子、高周波絶縁材料,誘電体材料,理化学用磁器,耐酸
磁器,耐酸レンガ,タイル,テラコツタ・クリンカーレ
ンガ,舗道レンガ,赤レンガ,粘土瓦などの製造に用い
られる陶磁器用素地材料があげられる。陶磁器原料の成
形法としては、たとえば銭込成形,ろくろ成形,押型成
形,型おこし成形,プレス成形,押出成形法などがあげ
られるが、特に金型や木型内に陶磁器原料を充填し、圧
縮成形機で圧縮して成形する方法(プレス成形法)が好
ましい。
Ceramic raw materials include, for example, porcelain Western tableware, ceramic Western tableware, sanitary ware, porcelain toys, ornaments, glass, insulators, spark plug insulators, high frequency insulating materials, dielectric materials, porcelain for physics and chemistry, acid-resistant porcelain, acid-resistant bricks, and tiles. , terracotta clinker bricks, pavement bricks, red bricks, clay tiles, etc. are used as base materials for ceramics. Examples of molding methods for ceramic raw materials include coin molding, potter's wheel molding, extrusion molding, mold raising molding, press molding, and extrusion molding. A method of compressing and molding using a molding machine (press molding method) is preferred.

このように成形された陶磁器原料の主体面に柚薬紙を付
着させる。
Citrus paper is attached to the main surface of the ceramic raw material thus formed.

陶磁器原料は、陶磁器士を練り固め、これを一定の形状
に成形したものでもよい。また、この成形品を適宜の温
度(例、約700〜900℃)で秦鱗きしたものでもよ
い。このように本発明では、陶磁器原料の主体面は湿っ
たものでもよく、乾燥したものあるいは素焼きしたもの
でもよい。陶磁器原料の成形時に紬薬紙を付着させる場
合には、たとえば(i}士練り機から出てきた湿った練
り土に袖薬紙をはりつけながら成形する方法、(ii)
士練り機から出てきた土を切断成形し、この湿った成形
物上に直接、紬薬紙をはりつける方法、(iiiーあら
かじめ、セッコウの鋳型にはりつけた紬薬紙の上に解こ
う剤で解こうした流動性のある陶磁器士泥を流し込み、
セツコウで吸水した後、残った泥を流し出して銭込成形
と同時に施紬する方法、『W柚薬紙上にやわらかい練り
土を押しつけて凹み成形と同時に施紬する方法などがあ
げられる。純薬紙を陶磁器原料の主体面に付着させる場
合、水を使って主体面に付着させてもよく、また、公知
の接着剤などを用いてはりつけてもよい。
The ceramic raw material may be one obtained by kneading and hardening the ceramic material and molding it into a certain shape. Alternatively, this molded product may be scaled at an appropriate temperature (eg, about 700 to 900°C). Thus, in the present invention, the main surface of the ceramic raw material may be wet, dry, or unglazed. When attaching pongee paper to ceramic raw materials during molding, for example, (i) a method of molding while pasting pongee paper onto the moist kneaded clay that comes out of the shikneading machine, (ii)
A method is to cut and shape the soil that comes out of the gypsum mold, and then paste pongee paper directly onto the wet molded material. Pour this fluid ceramic clay,
After absorbing the water with a sedge, the remaining mud is poured out and the pongee is tied at the same time as the coin is formed, and another method is to press soft kneaded soil onto the double yuzu paper and tie the pongee at the same time as the dents are formed. When attaching pure medicinal paper to the main surface of a ceramic raw material, it may be attached to the main surface using water, or it may be attached using a known adhesive or the like.

このような接着剤としては、紬薬の種類や陶磁器原料の
主体面への影響もあって一概にはいえないが、たとえば
澱粉のり、CMC、ゴムラテツクス、フ/IJなどの天
然または合成の接着剤、松やに、ろう、合成樹脂などの
樹脂類、水ガラス、珪酸ゾル、アルミナゾル、リン酸ア
ルミなどの無機接着剤などを用いてもよい。また、紬薬
紙を陶磁器原料の主体面に付着させる場合、(iー紬薬
紙を細かく切り、これを水あるいは接着剤を用いてふり
かける、あるいは吹き付ける、(ii)紬薬紙をはりつ
けた後、ロール圧着,プレス圧着,遠心圧着,減圧操作
などをして付着させてもよい。
Although it is difficult to generalize about such adhesives due to the type of pongee and the influence on the main surface of the ceramic raw material, for example, natural or synthetic adhesives such as starch paste, CMC, rubber latex, and F/IJ are available. , pine resin, wax, resins such as synthetic resins, water glass, silicic acid sol, alumina sol, inorganic adhesives such as aluminum phosphate, etc. may be used. In addition, when attaching pongee medicine paper to the main surface of ceramic raw materials, (i) cut the pongee medicine paper into small pieces and sprinkle or spray it with water or adhesive, (ii) after pasting the pongee medicine paper , roll crimping, press crimping, centrifugal crimping, vacuum operation, etc. may be used for attachment.

紬薬紙を二枚以上重ねて用いることもできる。It is also possible to use two or more layers of pongee medicine paper.

この場合、重ねることにより種々の模様をつけることが
できる。同じ種類の袖薬紙を重ねた場合は優がけの効果
が現われる。異種の紬薬紙を重ねることによって二重が
けの手間を省くことができる。たとえば、白萩柚紙と鉄
紬紙とを重ねばりすることによって、信楽で有名ななま
こ紬が得られる。顔料を含有する紙と本発明の紬薬紙を
重ねてもよい。炭酸鋼を含有する紙と前述の織部柚から
酸化鋼を除いた柚薬を用いて得られる紙を重ねることに
よって、緑の濃淡や部分的に緑のある織部.柚ができる
。また、紬薬紙をたとえば切り紙細工,折紙,いまりな
どの細工を施し、これに色の異なった紬薬紙を重ねるこ
とによって独特の模様を作ることもできる。さらには、
複数の袖薬成分をそれぞれ紙状にして、これらを重ねて
焼成することによって紬薬成分を反応させて施紬するこ
ともできる。
In this case, various patterns can be created by overlapping them. When layers of the same type of medicinal paper are stacked on top of each other, a superior effect appears. By layering different types of pongee paper, you can eliminate the need for double layering. For example, Shigaraki's famous sea cucumber pongee can be obtained by layering Shirohagiyuzu paper and Tetsutsumugi paper. The pigment-containing paper and the pongee paper of the present invention may be overlapped. By layering paper containing carbonated steel and paper obtained using the above-mentioned Oribe yuzu with the oxidized steel removed, Oribe produces shades of green and partially green. You can make yuzu. It is also possible to create unique patterns by applying techniques such as kirigami, origami, and imari to pongee paper, and layering pongee paper of different colors on top of this. Furthermore,
It is also possible to create a pongee by making a plurality of sodeyaku ingredients into paper shapes and stacking them and firing them to react with the pongee medicine ingredients.

特に結晶柚の場合には、このような方法が有効である。
紬薬成分として金属を用いた紙は、焼成時に酸素を要す
るため、酸素雰囲気下でも還元された純薬の色を出すこ
とができる。また、袖薬紙と通常の柚薬を組み合わせて
用いてもよい。まず、最初に柚薬紙を用い、つぎに通常
の柚薬を流しがけ、吹き付けがけ、つけがけなどの方法
で紬がけしてもよいし、あらかじめ紬薬がけの済んでい
るものに柚薬紙をふりかけ、吹きつけ、庄着、はりつけ
てもよい。本発明の施紬方法は、■特別の施柚装置や手
段が不要である,■従釆法と比べて色むらの少ないもの
が得られる,■袖薬紙を製造する工程では粉塵や純薬な
どの飛散がなく、公害発生の恐れが全くない,■模様紬
薬紙を用いることにより陶磁器原料の主体面に多種類の
模様顕出が可能である,■特に、陶磁器原料を圧縮成型
機で圧縮して成形する場合、金型や木型内に充填された
陶磁器原料の主体面(例、上面.下面.側面など)に単
に紬薬紙を付着させることによって成形と同時に施袖が
できる。
This method is particularly effective in the case of crystalline yuzu.
Paper that uses metal as a pongee medicine component requires oxygen during firing, so it can produce the color of the reduced pure medicine even in an oxygen atmosphere. Also, a combination of sleeve medicine paper and regular yuzu medicine may be used. First, you can apply pongee by using yuyaku paper first, then pouring regular yuyaku on it, spraying it, dipping it, etc., or use yuyaku paper on the item that has already been coated with pongee. You can also sprinkle, spray, apply, or paste. The pongee making method of the present invention does not require any special pongeeing equipment or means, ■ produces products with less uneven color than the conventional pongee method, and ■ eliminates dust and pure chemicals in the process of manufacturing cuff paper. ■ There is no risk of pollution due to the scattering of materials, ■ By using patterned pongee paper, it is possible to express various patterns on the main surface of ceramic raw materials. ■ In particular, ceramic raw materials can be molded using a compression molding machine. When molding by compression, sleeves can be applied at the same time as molding by simply attaching pongee paper to the main surface (e.g., top, bottom, side, etc.) of the ceramic raw material filled in a metal mold or wooden mold.

などの利点を有する。つぎに実施例をあげて本発明を具
体的に説明する。
It has the following advantages. Next, the present invention will be specifically explained with reference to Examples.

実施例 1 夫目紬からマグネサィトを除いた組成物1鷺rを0.5
%の山皮分散液600泌に加えて家庭用ミキサーでよく
蝿拝し6肌×2肌の紬薬紙に抄く。
Example 1 Composition 1 obtained by removing magnesite from Fuume Tsumugi 0.5
In addition to 600% mountain bark dispersion, mix well with a household mixer and make into 6 skin x 2 skin pongee paper.

白萩紬からタルクを除いた組成物1舷rを0.5%の山
皮分散液600の‘に加えて家庭用ミキサーでよく燈拝
した後、6肌×2肌の柚薬紙に抄く。
After removing talc from Shirohagi Tsumugi, add 1 shipload of the composition to 600ml of 0.5% mountain bark dispersion, mix thoroughly with a household mixer, and then print on 6 skins x 2 skins of citrus paper. .

一方士練機より、練り出された連続したL型のタイル素
地(厚さ1肌、Lの外側6弧)の一方の面に白萩紬の紙
を、他の一面に夫目紬の紙を連続的にロ−ルで圧着する
と二色が施柚されたL型の長いタイル素地ができる。こ
れをL型榛に垂直に10伽毎に糸切りし、立てて乾燥し
た後、立てたま)で1250qoにまで徐々に加熱する
とL型のタイルができる。紬薬のたれは生じなかった。
通常の方法では、土練機よりL型素地が出てくるのを1
0伽毎に切り、これを天日で乾燥した後、素焼きする。
L型の一方の面を紙で覆った後、白萩紬をスプレーし、
乾燥する。白萩袖をはがさないように再び紙で覆った後
、他の面に夫目袖をスプレーし、乾燥する。柚薬のむら
のない方を縦にし、むら面を横にして、徐々に炉内で加
熱し1250ooにするので乾燥工程が2つ、紙で覆う
工程が2つ、この工程毎に置き換える手間が省ける。実
施例 2 土練機より練り出された直径8肌の円筒状の湿った素地
に実施例1に用いた二種の柚薬を包帯状に、または紙筒
をつくるように交互に巻きこれを直径8弧、長さ30伽
の型に入れて、筒の中心を軸に高速回転させて遠D力で
圧着成型する。
On the other hand, a continuous L-shaped tile base (1 skin thick, 6 arcs outside of L) is kneaded by the Shiren machine, and one side is covered with white Hagi Tsumugi paper, and the other side is covered with Fuume Tsumugi paper. When crimped continuously with a roll, a long L-shaped tile base coated with two colors is created. This is perpendicular to the L-shaped tiles, cut into threads every 10 steps, allowed to dry in an upright position, and then gradually heated to 1250 qo (while still standing) to form an L-shaped tile. No dripping of Tsumugi medicine occurred.
In the normal method, the L-shaped base material comes out from the kneading machine.
Cut into pieces, dry in the sun, and then fire unglazed.
After covering one side of the L shape with paper, spray white Hagi Tsumugi.
dry. After covering the white hagi-sode with paper again so as not to peel it off, spray the other sides with fume-sode and let it dry. The smooth side of the yuzu medicine is held vertically, the uneven side is placed horizontally, and it is gradually heated in the oven to 1250 oo, so there are two drying steps and two steps of covering it with paper, which saves you the trouble of replacing it after each step. . Example 2 The two types of yuzu medicine used in Example 1 were wrapped alternately in a bandage-like manner or as a paper tube on a wet cylindrical base with a diameter of 8 skins that had been kneaded using a clay kneading machine. The tube was placed in a mold with a diameter of 8 arcs and a length of 30 mm, and the tube was rotated at high speed around the center of the tube to press and mold it using a far-D force.

天日でよく乾燥後、1250℃まで焼成すると表面に白
黒のラセン模様のある陶管が得られた。
After drying well in the sun, it was fired to 1250°C to obtain a ceramic tube with a black and white spiral pattern on its surface.

実施例 3実施例1の夫目紬紙を縦に半分に切り、これ
を2枚白萩柚紙に重ねておく。
Example 3 Cut the Fuume Tsumugi paper from Example 1 in half lengthwise, and stack two sheets of Shirohagiyuzu paper on top of each other.

これに厚さ1肌、中6伽の連続的なタイル素地を士練機
より出し、前記柚薬紙を重ねて圧着する。これを10肌
毎に切断して、乾燥後1250qoまで加熱すると、真
中が紙厚だけへこんだなまこ柚、ふちは白色柚のタイル
ができた。紙厚を利用した成形法ができる。
A continuous tile base with a thickness of 1 inch and a medium size of 6 mm is taken out of the tile machine, and the above-mentioned citrus paper is layered and crimped. This was cut into every 10 skins, dried and heated to 1,250 qo, resulting in a sea cucumber tile with a depression in the middle equal to the thickness of the paper and a white yuzu edge. A molding method that takes advantage of paper thickness is possible.

実施例 4 型を円周上に10ケつけた遠心機に漉しよう(水分60
%位のタイル素地泥)を入れ1000回転で回転すると
、水分30%位のL型のタイル素地ができる。
Example 4 Let's strain the mold into a centrifuge with 10 pieces on the circumference (moisture 60
% of tile base mud) and rotated at 1000 revolutions, an L-shaped tile base with a moisture content of about 30% is created.

Claims (1)

【特許請求の範囲】[Claims] 1 釉薬を山皮の水分散液中に分散させ、かかる分散液
を紙状に抄いて得られる釉薬紙を陶磁器原料の成形時も
しくは成形後にその主体面に付着させることを特徴とす
る陶磁器類の施釉方法。
1. A ceramic product characterized in that a glaze is dispersed in an aqueous dispersion of mountain bark, and the dispersion is made into paper, and the resulting glaze paper is attached to the main surface of the ceramic raw material during or after the molding. Glazing method.
JP12993476A 1976-10-27 1976-10-27 How to glaze ceramics Expired JPS6012305B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12993476A JPS6012305B2 (en) 1976-10-27 1976-10-27 How to glaze ceramics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12993476A JPS6012305B2 (en) 1976-10-27 1976-10-27 How to glaze ceramics

Publications (2)

Publication Number Publication Date
JPS5354213A JPS5354213A (en) 1978-05-17
JPS6012305B2 true JPS6012305B2 (en) 1985-04-01

Family

ID=15022028

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12993476A Expired JPS6012305B2 (en) 1976-10-27 1976-10-27 How to glaze ceramics

Country Status (1)

Country Link
JP (1) JPS6012305B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4778526A (en) * 1986-10-14 1988-10-18 National Refractories & Minerals Corporation Gunnable refractory composition

Also Published As

Publication number Publication date
JPS5354213A (en) 1978-05-17

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