JPS6011528A - Substituted polyphenylenevinylene and highly electroconductive composition - Google Patents

Substituted polyphenylenevinylene and highly electroconductive composition

Info

Publication number
JPS6011528A
JPS6011528A JP11712383A JP11712383A JPS6011528A JP S6011528 A JPS6011528 A JP S6011528A JP 11712383 A JP11712383 A JP 11712383A JP 11712383 A JP11712383 A JP 11712383A JP S6011528 A JPS6011528 A JP S6011528A
Authority
JP
Japan
Prior art keywords
sulfonium salt
obtained
nucleus
alkoxy substituted
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11712383A
Other versions
JPH0415813B2 (en
Inventor
Kazumoto Murase
Masanobu Noguchi
Toshihiro Onishi
Original Assignee
Agency Of Ind Science & Technol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency Of Ind Science & Technol filed Critical Agency Of Ind Science & Technol
Priority to JP58117123A priority Critical patent/JPH0415813B2/ja
Priority claimed from US06/602,534 external-priority patent/US4528118A/en
Publication of JPS6011528A publication Critical patent/JPS6011528A/en
Publication of JPH0415813B2 publication Critical patent/JPH0415813B2/ja
Anticipated expiration legal-status Critical
Application status is Expired - Lifetime legal-status Critical

Links

Abstract

PURPOSE: To obtain a substituted polyphenylenevinylene which can be processed into any desired shape and give a high electric conductivity by doping, by eliminating a sulfonium salt group from a specified polymeric sulfonium salt.
CONSTITUTION: Poly(nucleus-alkoxy substituted p-phenylenevinylene) is obtained by eliminating a sulfonium salt group from a polymeric sulfonium salt of the formula (wherein R is a 1W6C alkyl, R2 and R3 are each a 1W10C hydrocarbon group, X is a counter ion, n is an integer ≥2, and m is 1W2). The obtained polymer can be doped with an electron acceptor or donor to acquire a markedly high electric conductivity. The polymeric sulfonium salt can be obtained by, for example, polycondensing a nucleus-alkoxy substituted p-xylylenedisulfonium salt, obtained by reacting a nucleus-alkoxy substituted p-xylene dihalide with a dialkyl sulfide, in the presence or absence of water or a water-soluble organic solvent with the aid of an alkali.
COPYRIGHT: (C)1985,JPO&Japio
JP58117123A 1983-06-30 1983-06-30 Expired - Lifetime JPH0415813B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58117123A JPH0415813B2 (en) 1983-06-30 1983-06-30

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP58117123A JPH0415813B2 (en) 1983-06-30 1983-06-30
US06/602,534 US4528118A (en) 1983-04-28 1984-04-20 Highly electroconductive conjugated polymer composition and process for producing the same

Publications (2)

Publication Number Publication Date
JPS6011528A true JPS6011528A (en) 1985-01-21
JPH0415813B2 JPH0415813B2 (en) 1992-03-19

Family

ID=14703998

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58117123A Expired - Lifetime JPH0415813B2 (en) 1983-06-30 1983-06-30

Country Status (1)

Country Link
JP (1) JPH0415813B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61258832A (en) * 1985-05-10 1986-11-17 Nitto Electric Ind Co Ltd Electrically conductive organic polymer and production thereof
JPS63178138A (en) * 1986-09-18 1988-07-22 Agency Of Ind Science & Technol Production of conjugated high-molecular stretched molding
JPH01234418A (en) * 1988-03-14 1989-09-19 Sumitomo Chem Co Ltd Novel polymer, production thereof, production of conjugated polymer therefrom and highly electrically conductive composition comprising said conjugated polymer
JPH01254734A (en) * 1988-04-04 1989-10-11 Agency Of Ind Science & Technol Poly-p-phenylenevinylene nucleus-substituted with long-chain alkoxy group, its production, precursor thereof and highly electrically conductive composition containing the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992203A (en) * 1975-04-18 1976-11-16 Veb Pentacon Dresden Polyphenylenevinylene photoconductor composition sensitized with a 1,4-bis (styryl) benzene derivative

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992203A (en) * 1975-04-18 1976-11-16 Veb Pentacon Dresden Polyphenylenevinylene photoconductor composition sensitized with a 1,4-bis (styryl) benzene derivative

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61258832A (en) * 1985-05-10 1986-11-17 Nitto Electric Ind Co Ltd Electrically conductive organic polymer and production thereof
JPS63178138A (en) * 1986-09-18 1988-07-22 Agency Of Ind Science & Technol Production of conjugated high-molecular stretched molding
JPH0588853B2 (en) * 1986-09-18 1993-12-24 Kogyo Gijutsuin
JPH01234418A (en) * 1988-03-14 1989-09-19 Sumitomo Chem Co Ltd Novel polymer, production thereof, production of conjugated polymer therefrom and highly electrically conductive composition comprising said conjugated polymer
JPH01254734A (en) * 1988-04-04 1989-10-11 Agency Of Ind Science & Technol Poly-p-phenylenevinylene nucleus-substituted with long-chain alkoxy group, its production, precursor thereof and highly electrically conductive composition containing the same

Also Published As

Publication number Publication date
JPH0415813B2 (en) 1992-03-19

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