JPS60114338A - 水銀吸着材としてのカーボン類およびカーボンモレキュラーシーブ類 - Google Patents
水銀吸着材としてのカーボン類およびカーボンモレキュラーシーブ類Info
- Publication number
- JPS60114338A JPS60114338A JP59230449A JP23044984A JPS60114338A JP S60114338 A JPS60114338 A JP S60114338A JP 59230449 A JP59230449 A JP 59230449A JP 23044984 A JP23044984 A JP 23044984A JP S60114338 A JPS60114338 A JP S60114338A
- Authority
- JP
- Japan
- Prior art keywords
- mercury
- impregnated
- carbon
- sulfur
- mercury vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 100
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims description 96
- 229910052799 carbon Inorganic materials 0.000 title claims description 70
- 239000002808 molecular sieve Substances 0.000 title claims description 43
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims description 43
- 229910052753 mercury Inorganic materials 0.000 title claims description 22
- 239000003463 adsorbent Substances 0.000 title description 28
- 239000007789 gas Substances 0.000 claims description 53
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 47
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 34
- 229910052717 sulfur Inorganic materials 0.000 claims description 33
- 239000011593 sulfur Substances 0.000 claims description 33
- 238000009792 diffusion process Methods 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 21
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 12
- 229920006395 saturated elastomer Polymers 0.000 claims description 12
- 239000010457 zeolite Substances 0.000 claims description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 239000003245 coal Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 20
- 239000001301 oxygen Substances 0.000 description 20
- 229910052760 oxygen Inorganic materials 0.000 description 20
- 238000011068 loading method Methods 0.000 description 19
- 235000013162 Cocos nucifera Nutrition 0.000 description 17
- 244000060011 Cocos nucifera Species 0.000 description 17
- 229910001868 water Inorganic materials 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000001179 sorption measurement Methods 0.000 description 8
- 235000014643 Orbignya martiana Nutrition 0.000 description 7
- 244000021150 Orbignya martiana Species 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- DKNPRRRKHAEUMW-UHFFFAOYSA-N Iodine aqueous Chemical compound [K+].I[I-]I DKNPRRRKHAEUMW-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229940020414 potassium triiodide Drugs 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- 101100172886 Caenorhabditis elegans sec-6 gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- NVDORESINSWXKC-UHFFFAOYSA-N [Ca].O=C=O Chemical compound [Ca].O=C=O NVDORESINSWXKC-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000036619 pore blockages Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54847183A | 1983-11-03 | 1983-11-03 | |
| US548472 | 1983-11-03 | ||
| US548471 | 1990-07-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60114338A true JPS60114338A (ja) | 1985-06-20 |
| JPH0233416B2 JPH0233416B2 (enrdf_load_stackoverflow) | 1990-07-27 |
Family
ID=24188983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59230449A Granted JPS60114338A (ja) | 1983-11-03 | 1984-11-02 | 水銀吸着材としてのカーボン類およびカーボンモレキュラーシーブ類 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60114338A (enrdf_load_stackoverflow) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10216476A (ja) * | 1997-01-31 | 1998-08-18 | Kawasaki Heavy Ind Ltd | 排ガス処理方法及び装置 |
| JP2005521731A (ja) * | 2002-04-03 | 2005-07-21 | サビック ハイドロカーボンズ ビー．ブイ． | 吸着剤を用いて炭化水素流からアルシンを除去する方法 |
| JP2008238009A (ja) * | 2007-03-26 | 2008-10-09 | Central Res Inst Of Electric Power Ind | 水銀除去装置 |
| WO2008146773A1 (ja) * | 2007-05-29 | 2008-12-04 | Kuraray Chemical Co., Ltd. | 水銀吸着材およびその製造方法 |
| US8696931B2 (en) | 2010-10-22 | 2014-04-15 | Futamura Kagaku Kabushiki Kaisha | Method of production of activated carbon for removal of mercury gas |
| JP2015515924A (ja) * | 2012-05-01 | 2015-06-04 | フューエル テック インコーポレーテッド | 水銀、硫黄酸化物およびＨＣｌを低減するためのドライ方法、装置、組成物およびシステム |
| CN109971521A (zh) * | 2019-04-04 | 2019-07-05 | 煤炭科学技术研究院有限公司 | 一种低浓度煤层气中甲烷浓缩分离的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4953595U (enrdf_load_stackoverflow) * | 1972-08-11 | 1974-05-11 | ||
| JPS5978915A (ja) * | 1982-10-25 | 1984-05-08 | Takeda Chem Ind Ltd | 硫黄担持活性炭の製造法 |
-
1984
- 1984-11-02 JP JP59230449A patent/JPS60114338A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4953595U (enrdf_load_stackoverflow) * | 1972-08-11 | 1974-05-11 | ||
| JPS5978915A (ja) * | 1982-10-25 | 1984-05-08 | Takeda Chem Ind Ltd | 硫黄担持活性炭の製造法 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10216476A (ja) * | 1997-01-31 | 1998-08-18 | Kawasaki Heavy Ind Ltd | 排ガス処理方法及び装置 |
| JP2005521731A (ja) * | 2002-04-03 | 2005-07-21 | サビック ハイドロカーボンズ ビー．ブイ． | 吸着剤を用いて炭化水素流からアルシンを除去する方法 |
| JP2008238009A (ja) * | 2007-03-26 | 2008-10-09 | Central Res Inst Of Electric Power Ind | 水銀除去装置 |
| WO2008146773A1 (ja) * | 2007-05-29 | 2008-12-04 | Kuraray Chemical Co., Ltd. | 水銀吸着材およびその製造方法 |
| JPWO2008146773A1 (ja) * | 2007-05-29 | 2010-08-19 | クラレケミカル株式会社 | 水銀吸着材およびその製造方法 |
| US8696931B2 (en) | 2010-10-22 | 2014-04-15 | Futamura Kagaku Kabushiki Kaisha | Method of production of activated carbon for removal of mercury gas |
| JP2015515924A (ja) * | 2012-05-01 | 2015-06-04 | フューエル テック インコーポレーテッド | 水銀、硫黄酸化物およびＨＣｌを低減するためのドライ方法、装置、組成物およびシステム |
| CN109971521A (zh) * | 2019-04-04 | 2019-07-05 | 煤炭科学技术研究院有限公司 | 一种低浓度煤层气中甲烷浓缩分离的方法 |
| CN109971521B (zh) * | 2019-04-04 | 2020-12-11 | 煤炭科学技术研究院有限公司 | 一种低浓度煤层气中甲烷浓缩分离的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0233416B2 (enrdf_load_stackoverflow) | 1990-07-27 |
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