JPS5987753A - Organic electrolytic battery - Google Patents
Organic electrolytic batteryInfo
- Publication number
- JPS5987753A JPS5987753A JP57198006A JP19800682A JPS5987753A JP S5987753 A JPS5987753 A JP S5987753A JP 57198006 A JP57198006 A JP 57198006A JP 19800682 A JP19800682 A JP 19800682A JP S5987753 A JPS5987753 A JP S5987753A
- Authority
- JP
- Japan
- Prior art keywords
- positive electrode
- separator
- negative electrode
- layer
- active material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polypropylene Polymers 0.000 claims abstract description 14
- 239000004743 Polypropylene Substances 0.000 claims abstract description 8
- 229920001155 polypropylene Polymers 0.000 claims abstract description 8
- 239000004745 nonwoven fabric Substances 0.000 claims description 9
- 239000011149 active material Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000005486 organic electrolyte Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 abstract description 10
- 239000007774 positive electrode material Substances 0.000 abstract description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052744 lithium Inorganic materials 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- 238000005096 rolling process Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000011511 Diospyros Nutrition 0.000 description 1
- 244000236655 Diospyros kaki Species 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- 241001185311 Lyticum Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/172—Arrangements of electric connectors penetrating the casing
- H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
- H01M50/179—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for cells having curved cross-section, e.g. round or elliptic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/172—Arrangements of electric connectors penetrating the casing
- H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
- H01M50/181—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for button or coin cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/491—Porosity
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cell Separators (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は正極と、軽金ｒｊｉ ′ｆ：活物質とする負極
と、こｎら正９Ｌ極間に介在さｎるセパレータ七を備え
比有機電解質屯池ｒ（ｌＪＡするものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention comprises a positive electrode, a negative electrode using light metal rji'f as an active material, and a separator 7 interposed between these positive electrodes and a specific organic electrolyte. It is something to do.
従来技術
このイ市電池は圧検活物質に金ｈ１の酸５化物、硫化物
或いはハロゲンの炭素化合物などを用い、負極活物質と
してリチウム、ナトリウムなどの怪金属を用い、こγＬ
らＩＦ負極間に介在せるセパレータに有餞宙ｆ！Ｉγ質
を含浸させたものであり、高゛市圧、１１工ネルギー密
度を有し、且つ自己放心が少ないなど＆冬ぐの１０点を
有するものである。Conventional technology This Ichi battery uses gold H1 oxide pentoxide, sulfide, or halogen carbon compound as the active material, and strange metals such as lithium and sodium as the negative electrode active material.
The separator interposed between the IF negative electrode has a special effect on the separator. It is impregnated with Iγ substance, has high market pressure, 11 energy density, and has low self-absorption, etc., and has 10 points.
しかしながら、従来のこのａ１屯池においてにセパレー
タとしてポリプロピレン不織布或いはポリエチレン不織
布全崖独で用いているためｌＸ述の如き問題かあった。However, in this conventional A1 tank, polypropylene non-woven fabric or polyethylene non-woven fabric is used entirely as a separator, so there are problems as described above.
即ち、放電或いは保存時に正極活物質粉末が正極Ｊ：り
遊濡し、不織布製セパレータの孔部を介し文負極表面上
に到達、付着し、その結果と［２て電池内部砥杭の増加
及び自己放電量が大きくｌるこｔである。That is, during discharge or storage, the positive electrode active material powder wets the positive electrode, reaches the surface of the negative electrode through the holes of the nonwoven fabric separator, and adheres to the surface of the negative electrode. The amount of self-discharge is large.
：５凸１−ＩＩＪの目的
本発明は上記問題に４み、セパレータを改良シ正礁より
一！１ｉｌｌｌ、た正極活物質粉末が負柿表聞に到達、
付着するのを抑制することを目的とする。Purpose of 5 Convex 1-IIJ The present invention addresses the above problems and improves the separator. 1llll, the positive electrode active material powder reached the negative persimmon level,
The purpose is to suppress adhesion.
発明の構成
本丸りＩｉｉ上記目的を達成すべくなさγｔ７ｃもので
め、す１２．その蒙「とＴるところμ、正極と、・１φ
蛍キル
ｋＡをン占ｌ勿Ｊ１とする負極と、こｎら也貝向に弁在
さｔＬるセパレークと金（＃＃えるものであってｓ １
４ｊｌａ己セパレータがポリプロピレン或いはポリエチ
レンなどからなる不織布と、耐液性のマイクロポーラス
フィルムとの二Ｍ＞を曽で楕１祝さｎていること金特畝
とする有ｉ、Ａ市１り＃貝ゼ池にある。Structure of the Invention Honmaru III To achieve the above object, γt7c has been developed. 12. Where μ is the positive electrode, ・1φ
The negative electrode with the firefly kill kA and the negative electrode with J1, and the separate lake and gold that are placed in the direction of the shell.
4. The separator is made of a nonwoven fabric made of polypropylene or polyethylene, etc., and a liquid-resistant microporous film. It's in Zeike.
失 １１ら 例
以下本発明の゛夾Ｉ臣例について区間に基づきｒｉｌ’
連する。第１凶に扁半型電池の場合をボし、＋１１１’
Ｊ正極でりって６５ＵＣ〜４．５０’０の温度で愚処ｊ
・１（シた二ｄ化マンガン清物賀に、・祁電剤きしての
ｙセチレンブラック及び黒鉛、結眉剤としてのフッ素＠
ｊＩ ＩＪ寵粉末を８５：’１０：５のｊ＠量比で混む
し７で正極Ｃ１剤を加匝成μｖしたのち、２５０い５０
Ｕ ｒ 、、ｆ＜ｋ逃理しｆＣものであり、止軸缶１
２）の内戚１川に固層した正毬集嘔体１２；にＩｆ俵さ
ｎている。１３１にリチクムｌｆ帆板エクｌる負値であ
って、貝４龜缶ｉ４１の内底間に固層し１ヒ負樵果゛ｌ
Ｊ体（４′）にｔｆ看さｎている。11 et al. Examples The following examples of the present invention are based on intervals.
continue. The first problem is the case of a flat half battery, +111'
The positive electrode is heated at a temperature of 65UC to 4.50'0.
・1 (manganese didide), y-cetylene black and graphite as an electric agent, and fluorine as an eyebrow agent.
After mixing the IJ powder at a ratio of 85:'10:5 and adding the positive electrode C1 agent at step 7,
U r ,,f<k escape fC, and the shaft stopper can 1
2) If the bales are placed in a solid layer of solidified water in the river. 131, the negative value of the lyticum sailboard was found to be solidified between the inner bottom of the 4 shell cans I41, and the result was 1 negative value.
tf looks at J body (4').
而して、（６）は木光男の破ばとするセパレータであっ
て、ポリプロピレン不屈しＣ５よりなる第１のノ曽（６
１と、微細ルを竹するマイクロポーラスフィルムよ！ｌ
Ｉｌる第２の層１７）との二虚屑で構成さｌしている。Therefore, (6) is the separator to be broken by Mitsuo Ki, and the first noso (6) is made of polypropylene and C5.
1. Microporous film that creates fine particles! l
The second layer 17) is composed of two layers.
（８１に＋Ｅ貝ａ６１を隔離する絶縁バンキングである
。(81 is an insulating bank that isolates the +E shell a61.
尚、上記せるマイクロポーラフィルムとはイオン’を透
過しうる値組ｔしを有し、かつ表向が平滑な曲を呈する
ものであり、その−例としてに部品名゛ジュラガード”
「ポリプラスチックス株式会社」がφげらｒＬる。The above-mentioned micropolar film has a value set that allows ions to pass through, and has a smooth curved surface.As an example, the part name "Duraguard" is used.
"Polyplastics Co., Ltd." is φgerarL.
父、第２凶ぼ木冗ＩＪの他の実施例でめる円荊空雨池の
場合をボし、第２凶においてｆｉｌｌに円筒状の１楓で
必りｌＥ悌喘子瀘用の屯油谷器じの内側間に配゛、直さ
ｎている。＋１３１は正極１１１１の中空ｄ１りにポリ
プロピレン不織亜エクなる第１の増ｌｌ６）と、マイク
ロポーラスフィルムエりなる第２０鳩口ηとの二重層で
構成さｎたセパレータ（ｌｉ−弁して配置さγしたリチ
ウム負極である。α４１は負樵果電捧でめって該果鴫棒
を介して負極０３１と、容器蓋１（至）の中Ｉυ化に絶
縁材−を介して向有さγ＋Ｊｔ貝極唱子部祠シＯＪとが
４気埃続さ几ている。Father, in the other examples of the 2nd Kyoboki IJ, I will skip the case of the round yen and the sky rain pond, and in the 2nd Kyo, I will fill the cylindrical one Kaede with the tun oil valley for lE 悌悌子filtration. It is placed between the inside of the container and is straightened. +131 is a separator (with a li-valve) composed of a double layer of a first insulating layer made of polypropylene non-woven fabric and a 20th hole opening η made of microporous film in the hollow d1 of the positive electrode 1111. The lithium negative electrode 031 is connected to the negative electrode 031 through the negative electrode, and the lithium negative electrode 031 is connected to the inside of the container lid 1 through an insulating material. Sa γ + Jt Kaigoku Shokobu Shrine OJ continues for 4 days.
第６図及び第４図は′ｆ；１図に不丁木拍す」電池（５
）と、セパレータとしてポリプロピレン不織布全単独で
用いることを除いて池に第１図と回（兼の従来電池（Ｂ
）との電池特性比較図であり、第６図に温度６０’Ｃ，
湿度９０％のもとて保任した場合の内部抵抗と保存期間
との関係を示す凶でるり、第６図から末完り」電池（Ａ
） ｒＪ：従来電池（Ｂ）に比して内部抵抗の増加が少
なく保存特性にすぐｎでいることがわかる。Figures 6 and 4 are 'f;
) and the conventional battery (B
), and Figure 6 shows a comparison of battery characteristics with
Figure 6 shows the relationship between internal resistance and storage period when stored at 90% humidity.
) rJ: It can be seen that the increase in internal resistance is small compared to the conventional battery (B), and the storage characteristics are close to n.
この坤由汀従来゛電池でに醍ル」間保存すると正極から
遊掲１トシた正極活物質粉末がセパレータｒ弁して負准
表面に到達して付着し、負極の１１効表面積が戚少して
内部抵抗が増加するのに対し、末完１Ｊ電γｍでは正極
から遊離した正極活物質粉末の負極表向への到達、付着
が抑制さγしているためである。As a result, when stored for a long period of time in conventional batteries, the positive electrode active material powder removed from the positive electrode reaches the negative surface of the separator and adheres to it, reducing the effective surface area of the negative electrode. This is because, while the internal resistance increases in the final 1J electric current, the positive electrode active material powder released from the positive electrode is inhibited from reaching and adhering to the surface of the negative electrode.
父、第４図は温度６０゛Ｃで４０日保存した改、負＃１
２にΩ、２０Ｃで放電した時の放′市特性を示し、末完
りｊ電池の初期特性（０）に比べて、水元Ｌｌｌ］嵐池
（Ｎの方が従来電池（Ｂ）より放電容枇が大きく目己放
電量が少ないことがわかる。Father, Figure 4 shows the modified version stored for 40 days at a temperature of 60°C, negative #1.
2 shows the open market characteristics when discharged at Ω and 20C, and compared to the initial characteristics (0) of the recently completed J battery, the discharge characteristics of Mizumoto Lll] Arashiike (N are better than the conventional battery (B)). It can be seen that the capacity is large and the amount of self-discharge is small.
この理由に従来電池では正極、Ｃり遊離し＞’ｃｆ礁活
物質粉末が負極表面上に到達、付着して−７７１３反応
し、自己放電により容量が低下するためである。The reason for this is that in conventional batteries, the active material powder released from the positive electrode reaches and adheres to the surface of the negative electrode, undergoes a -7713 reaction, and the capacity decreases due to self-discharge.
発ｌ夕Ｊの効果
上述したように、未発明軍池によ几は正負）棋聞に介在
するセパレータとしてポリプロピレン、ポリエチレンな
どからなる不織布と、マイクロポーラスフィルムとの二
／１ｆ＋＝で１ｌｆｆｉ ！戊したので゛、マイク【ゴ
ボーラスフイルムによりｌＥ極から遊匿したしＥ桟活物
質粉末が負極表面上に到達、付着することが抑制さｎ５
その結果として電池内部抵抗のノ１７大及び放屯谷凰の
低下が抑制されるものであり、この撞゛電池の特Ｉト１
゜同上にｔモするところ極めて大である０又、二重層レ
バレータ全土負極［＃１Ｊに介在するに際シてマイクロ
ポーラスフィルムを正極側に配置丁ｎば、正極より遊離
した正極活物質粉末が不１伐布よりなるセパレータ内に
入ることも抑制でき、不織布の父買劣イヒを阻出しうる
効果がある。As mentioned above, the effect of the uninvented military pond is positive and negative).The separator used in the game is a nonwoven fabric made of polypropylene, polyethylene, etc., and a microporous film. 2/1f + = 1lffi! Because of this, the microphone was hidden from the IE electrode by the gobolus film, which suppressed the E-beam active material powder from reaching and adhering to the negative electrode surface.
As a result, the internal resistance of the battery is suppressed by 17 degrees and the drop in the temperature drop is suppressed.
゜Contrary to the above, it is extremely large.If the microporous film is placed on the positive electrode side when interposed in the negative electrode [#1J], the positive electrode active material powder released from the positive electrode will be removed. It is also possible to prevent the non-woven fabric from entering the separator, which has the effect of preventing the inferiority of the non-woven fabric.
第１図μ木罎１１１４の一笑力１区例をボす柵十型螺池
の縦断聞区１、第２１凶ば発明り］の池の一大々ｉａ例
金ボす円筒型゛？は油の挟所面図、Ｃ６０凶及び１ｇ４
凶μ本光１）Ｉｌｊ市池ｃＡ）と従来゛１冒池（Ｂ）
（！：の心池特性比軟凶をボし、掲６１メＩＱゴ！ｉｉ
ｕ度６Ｕ−Ｃ，ｉシ１１賛９０倦のもとて保任した場合
の内１３１ｓ ：ｌ戊仇と保存期間との；釧ｆ；％を不
丁図、第４１５゛信ユメ晶匙６０゛Ｃで４０日保存した
後、貝＋ｉ＜ｒ １２にΩ、 ２０’Ｏで放゛屯した時
の放屯特訃因で・ちる。
１１１１１１１・・・正４！Ｉｌｉ、 ｉ２１・・・
１Ｅ袖イｂ、 ＋１２１・・・屯イ也容１台、＋３１
＋＋３１・・・月極、（４）・・・負極缶、勿η・・・
負極）醜子部桐、（６則９・・・セパレータ、ｆｆ１ｌ
！１ｆｉｌ・・・ボリブａピレン不、１哉布エリなる第
１の、１１η、＋７１１１７１・・・マイクロポーラス
フィルハエ９グーる第２の層ＩＡＩ・・・木売り４屯油
１、（Ｂｌ・・・従来゛４池。
第３図
■
２６フー
バー１．？Ｓ期川用（八）
正極冶物鴫月ＩＨ率（’／、）
手 続 補 正 書（方式）
−昭和５８年６月７日
特許庁長官殿
１、事件の表示
昭和５７年特許願第 １９８００６ 刊２、発明の名
称
有機′ｒに解質電池
６、補正をする者
特許出願人
住所 守口市京阪本通２丁目１８番地
名称（１８８）三洋電機株式会社
代表者 井 植 薫
４、代理人
住所 守口市京阪本通２丁目１８番地
５、補正命令の日付
昭和５８年２月・２２日
６、補正の対接
ｆｉｌ リ］細錫全文（す１細書の浄蒔、内容に９更
なし）７、補正の内容
ｆｉｌ 別紙の通り。Fig. 1 Vertical profile of the ten-shaped screwdriver of μ wood 1114 1114 Ichigaku Ia example of the cylindrical shape of the pond 1, the 21st evil invention]? is a view of the oil gap, C60 and 1g4
1) Ilj Ichiike cA) and conventional ゛1 Exploration (B)
(!:'s Shinike characteristic ratio is soft and evil, and the 61-meter IQ is! ii
U degree 6 U-C, 131 s of the case where it is kept under 11 sanction 90 〦: l 戊en and storage period; 釧 f; After 40 days of storage at °C, the shellfish +i<r was exposed to 12Ω and 20°C. 1111111...positive 4! Ili, i21...
1E Sode I b, +121...Tun I Yayo 1 unit, +31
++31...Monthly pole, (4)...Negative electrode can, of course η...
Negative electrode) Ushibe Kiri, (6 rules 9... separator, ff1l
! 1fil...Bolib a pyrene, 1 yenfu Eri first layer, 11η, +711171...Microporous fill fly 9 goo second layer IAI...wood seller 4 ton oil 1, (Bl...・Conventional ゛4 ponds. Figure 3■ 26 Huber 1.?S period river use (8) Positive electrode metallurgy IH rate ('/,) Procedure amendment (method) - June 7, 1982 Mr. Commissioner of the Japan Patent Office 1, Indication of the case Patent Application No. 198006, Publication 2, Name of the invention, Electrolytic battery 6 for organic'r, Person making the amendment Patent applicant's address: 2-18 Keihan Hondori, Moriguchi City Name ( 188) Sanyo Electric Co., Ltd. Representative Kaoru Iue 4, Agent address 2-18-5 Keihan Hondori, Moriguchi City, Date of amendment order February 22, 1981 6, Correspondence for amendment fil] Hososeki Full text (1 detailed copy, no 9th amendment) 7. Contents of amendment fil As shown in the attached sheet.
Claims (1)
極間に介在さｎるセパレータとを備えるものであって、
１ｌｒＪ記セパレータがポリプロピレン或いはポリエチ
レンなどからなる不織布とも耐液性のマイクロポーラス
フィルム亡の二重層でｉｉ’＆成さｎていること（ｉ−
特徴とする有機電解り４市池。 ■ 前記二重層セパレータのうち、マイクロボー ラス
フィルムが正極側に位１ｍする工うに配置６さ几ている
こと全特徴とする特許請求の範囲７〜０項記載の有機電
解質電池。[Claims] ■ A positive electrode, a negative electrode using a light metal as an active material, and a separator interposed between the positive and negative electrodes,
1lrJ The separator is made of a double layer of liquid-resistant microporous film and nonwoven fabric made of polypropylene or polyethylene (i-
Features four organic electrolyte ponds. (2) The organic electrolyte battery according to any one of claims 7 to 0, characterized in that, of the double layer separator, a micro bolus film is disposed 1 m away from the positive electrode side.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57198006A JPS5987753A (en) | 1982-11-10 | 1982-11-10 | Organic electrolytic battery |
| GB08329576A GB2131597B (en) | 1982-11-10 | 1983-11-04 | Organic electrolyte battery |
| DE19833340329 DE3340329A1 (en) | 1982-11-10 | 1983-11-08 | ACCUMULATOR OR BATTERY |
| CH6042/83A CH662212A5 (en) | 1982-11-10 | 1983-11-09 | BATTERY WITH ORGANIC ELECTROLYTE. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57198006A JPS5987753A (en) | 1982-11-10 | 1982-11-10 | Organic electrolytic battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5987753A true JPS5987753A (en) | 1984-05-21 |
Family
ID=16383939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57198006A Pending JPS5987753A (en) | 1982-11-10 | 1982-11-10 | Organic electrolytic battery |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5987753A (en) |
| CH (1) | CH662212A5 (en) |
| DE (1) | DE3340329A1 (en) |
| GB (1) | GB2131597B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019133940A (en) * | 2013-09-02 | 2019-08-08 | 日本ゴア株式会社 | Protective film, and separator and secondary battery using the same |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS618852A (en) * | 1984-06-22 | 1986-01-16 | Sanyo Electric Co Ltd | Nonaqueous electrolyte cell |
| US4794057A (en) * | 1987-07-17 | 1988-12-27 | Duracell Inc. | Separator for electrochemical cells |
| KR0153002B1 (en) * | 1989-06-16 | 1998-11-16 | 와따나베 히로시 | Inorganic nonaqueous electrolytic solution type cell |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1949958C3 (en) * | 1969-10-03 | 1980-09-25 | Robert Bosch Gmbh, 7000 Stuttgart | Separator for maintenance-free accumulators |
| JPS4940716U (en) * | 1972-07-12 | 1974-04-10 | ||
| US4220693A (en) * | 1978-08-23 | 1980-09-02 | P. R. Mallory & Co. Inc. | Composite separator/absorbent |
-
1982
- 1982-11-10 JP JP57198006A patent/JPS5987753A/en active Pending
-
1983
- 1983-11-04 GB GB08329576A patent/GB2131597B/en not_active Expired
- 1983-11-08 DE DE19833340329 patent/DE3340329A1/en not_active Ceased
- 1983-11-09 CH CH6042/83A patent/CH662212A5/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019133940A (en) * | 2013-09-02 | 2019-08-08 | 日本ゴア株式会社 | Protective film, and separator and secondary battery using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2131597A (en) | 1984-06-20 |
| GB8329576D0 (en) | 1983-12-07 |
| DE3340329A1 (en) | 1984-05-10 |
| CH662212A5 (en) | 1987-09-15 |
| GB2131597B (en) | 1986-06-04 |
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