JPS5985834A - Beam of jet pump - Google Patents

Beam of jet pump

Info

Publication number
JPS5985834A
JPS5985834A JP57194649A JP19464982A JPS5985834A JP S5985834 A JPS5985834 A JP S5985834A JP 57194649 A JP57194649 A JP 57194649A JP 19464982 A JP19464982 A JP 19464982A JP S5985834 A JPS5985834 A JP S5985834A
Authority
JP
Japan
Prior art keywords
jet pump
corrosion cracking
stress corrosion
less
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57194649A
Other languages
Japanese (ja)
Other versions
JPH0353376B2 (en
Inventor
Nobuyuki Takeda
竹田 信之
Shuichi Komatsu
小松 周一
Mitsuo Kawai
光雄 河合
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP57194649A priority Critical patent/JPS5985834A/en
Publication of JPS5985834A publication Critical patent/JPS5985834A/en
Publication of JPH0353376B2 publication Critical patent/JPH0353376B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/30Nuclear fission reactors

Abstract

PURPOSE:To obtain a beam of a jet pump having superior stress corrosion cracking resistance and causing no microcracking by specifying the composition of an Ni alloy consisting of C, Si, Mn, Cr, Fe, Ti, Al, Nb, Mo, Mg and Ni. CONSTITUTION:A beam of a jet pump suitable for use in the environment of pure water at high temp. and pressure in a nuclear power plant is made of an Ni alloy consisting of, by weight, <=0.08% C, <=0.5% Si, <=1.0% Mn, 14.0-17.0% Cr, 5.0-10.0% Fe, 2.25-2.75% Ti, 0.40-1.00% Al, 0.7-1.20% Nb, 2.0-8.0% Mo, 0.003-0.06% Mg and the balance Ni. Mo added to the Ni alloy reduces remarkably the sensitivity of the alloy to stress corrosion cracking, and Mg improves the plastic workability and prevents microcracking.

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は高温高圧の純水中で使用するジェットポンプビ
ームに関する1、 〔発明の技術的背景とその問題点〕 原子炉炉内のジェットポンプビームとして高弾性率と高
温強度を有する析出硬化型N1基合金であるインコネル
X −750が従来よシ使用されている。X −750
は所望の副食性を得るに必要な量のCr、析出硬化に必
要なNb、A−e、Tjを貧む析出硬化型Ni基合金で
ある。
[Detailed Description of the Invention] [Technical Field of the Invention] The present invention relates to a jet pump beam used in high-temperature and high-pressure pure water. Conventionally, Inconel X-750
is a precipitation hardening type Ni-based alloy that lacks the amount of Cr necessary to obtain the desired side-eating properties, and the amount of Nb, Ae, and Tj necessary for precipitation hardening.

ところでジェットポンプビーム゛には常に高応力が作用
するとともに、高温、高圧の純水にさらされてお、す、
同時に他の部材と近接し隙間を形成している。そのため
ジェットポンプビームは、高温高圧の純水によって腐食
されるとともに、隙間並びに高応力によって応力腐食割
れが生じる可能性がある。
By the way, the jet pump beam is constantly subjected to high stress and is exposed to high temperature and high pressure pure water.
At the same time, it is close to other members and forms a gap. Therefore, the jet pump beam is corroded by high-temperature, high-pressure pure water, and stress corrosion cracking may occur due to the gaps and high stress.

この応力腐食割れは引張応力の存在、使用積項条件、お
よび材料自体の特性の3因子が揃ったときに発生するも
のであシ、この応力腐食割れを防止するには斜材自体の
特性を改善し、応力腐食割れ感受性を低くすることが最
善の方法である。
This stress corrosion cracking occurs when three factors are met: the presence of tensile stress, the product term conditions used, and the properties of the material itself.To prevent this stress corrosion cracking, the properties of the diagonal members themselves must be adjusted. The best way to improve this is to reduce stress corrosion cracking susceptibility.

他方ジェットポンプビームな成形する場合には型鍛造に
よっているが、所望の形状に加工する場合加工が困難で
微小き裂が発生する可能性を有する等の欠点があった。
On the other hand, when forming a jet pump beam, die forging is used, but it has drawbacks such as difficulty in processing it into a desired shape and the possibility of generating microcracks.

〔発明の目的〕[Purpose of the invention]

本発明の目的は特に原子カプラントの高温高圧純水環境
下においても耐応力腐食割れ性に優れ、同時に微小き裂
のないジェットポンプビームを提供するにある、 〔発明の概要〕 本発明はX量チでco、os係以下、SiO,5チ以下
、A(n 1.0%以下、Cr 14,0〜17.0 
’Ir、Fe 5.0〜1.0.0 %、Ti2.25
〜2.75チ、l司0,40〜1.00チ、Nb O,
7〜1.20チ、Mo2.0〜8.0チ、Mg0.00
8〜0.06東残部NiよりなるIAツ応力腐食割れ性
に優れた微小き裂のない原子カプラントに適したジェッ
トポンプビームである。
The purpose of the present invention is to provide a jet pump beam that has excellent stress corrosion cracking resistance even in the high-temperature, high-pressure pure water environment of an atomic couplant, and is free from microcracks. Chi, co, os or less, SiO, 5 chi or less, A (n 1.0% or less, Cr 14.0 to 17.0
'Ir, Fe 5.0-1.0.0%, Ti2.25
~2.75chi, 0.40~1.00chi, Nb O,
7-1.20chi, Mo2.0-8.0chi, Mg0.00
This jet pump beam is made of 8-0.06 Ni and is suitable for an atomic couplant with excellent stress corrosion cracking resistance and no microcracks.

つまシネ発明は、応力腐食割れ感受性及び塑性加工性に
影響を及ばすNl基合金の成分元素について種々検討し
た結果、特にMoを添加することによって応力腐食割れ
感受性が著しく低下すること及びMgを添加することに
よシ、塑性加工性が向上することを見い出し、これによ
シ、応力腐食割れ感受性が七しく小さく、また微小き裂
のない原子カプラントに遍したジェットポンプビームな
提供するものである。
As a result of various studies on the component elements of Nl-based alloys that affect stress corrosion cracking susceptibility and plastic workability, the Tsumashine invention found that the stress corrosion cracking susceptibility is significantly reduced by adding Mo and that the addition of Mg. We have found that plastic workability is improved by this method, and this provides a jet pump beam that has significantly lower stress corrosion cracking susceptibility and is free from microcracks. .

次に本発明に係るジェットポンプビームの各組成の限定
理由を説明する Cは強度を高めるために必要な元素で
あシ多量に含有させると耐食性が劣化するとともに靭性
を低め熱間塑性加工も害すのでo、o 8 %以下とす
る。Siは脱酸剤として加えるが、その含有量が0.5
%をこえると加工性が劣化するため0.5チ以下の含有
とする。Mnは8Iと同様に脱酸・脱硫剤として添加す
るものでsb、1.0%以上になると溶製が困難となる
ためその含有量を1.0%以下とする。Crは耐食性を
得るのに重要な元素であり、特に原子炉内で使用される
部材として高温高圧純水に対してその耐食性を確保する
ためには14チ以上の含有が必要であるが、17チをこ
えると加工性が劣化するため14〜17%の含有とする
。 Feは熱間加工性を同上するために必要な元素で、
その量が5チ未満では十分な加工性が得られず、また多
量含有すると耐食性が低下すること、またLa%’el
!相などの有害相を生じることから10%までとした。
Next, the reason for limiting each composition of the jet pump beam according to the present invention will be explained. C is an element necessary to increase strength, and if it is included in a large amount, corrosion resistance will deteriorate, toughness will decrease, and hot plastic working will be impaired. Therefore, o, o should be 8% or less. Si is added as a deoxidizing agent, but its content is 0.5
If the content exceeds 0.5%, the workability deteriorates, so the content should be 0.5% or less. Like 8I, Mn is added as a deoxidizing/desulfurizing agent, and if it exceeds 1.0% of sb, melting becomes difficult, so its content is set to 1.0% or less. Cr is an important element for obtaining corrosion resistance, and in order to ensure corrosion resistance against high-temperature, high-pressure pure water as a member used in a nuclear reactor, it is necessary to contain 14 or more Cr. If the content exceeds 14%, the processability deteriorates, so the content should be 14 to 17%. Fe is an element necessary to improve hot workability.
If the amount is less than 5 inches, sufficient workability cannot be obtained, and if it is contained in a large amount, corrosion resistance will be reduced.
! The amount was set at 10% because harmful phases such as phase were generated.

TiおよびA形は微細なN1との釜属間化合物を形成し
高温強度を高める元素として最も好ましいが、それぞれ
、Ti : 2.25チ未満およびAp : 0.40
チ未満では前記作用に所望の向上効果が得られず、一方
それぞれT r : 2.75チおよびA−I3:1.
00チをこえて含有させてもより一段の改善効果が見ら
れないばかシか、好ましくない粗大な金属間化合物を生
成することからそれぞれTi : 2.25〜2.75
チ、 i 0.40〜1.01の含有とする。Nbは析
出硬化によって高温強度を高めるのに必要な元素であり
0.7チ未満では析出硬化が不十分であり、また1、2
0%をこえて含有してもその効果が飽和するので、0.
7〜1.20%の含有とする。Moは特に耐応力腐食割
れ性を向上させるために添加するものであるが、2.0
チ以上とするのはそれ未満では耐応力腐食割れ性の十分
な向上は見られないためであシ、また1゜チ以下とする
のはそれをこえて添加しても効果が飽和してしまうばか
)か、加゛工性及び熱間鍛造性を劣化させるためである
。Mgは脱酸、脱硫剤として有効であると同時に本発明
において、塑性加工性を向上させるために添加するもの
であり、0.008−未満ではその効果は小さく、また
多線の添加は逆に加工性を低下させるため上限を0.0
6%とする。
Ti and type A are most preferred as elements that form intermetallic compounds with fine N1 and increase high-temperature strength, but Ti: less than 2.25 Ti and Ap: 0.40, respectively.
When T r is less than 2.75 h and A-I3:1.
Ti: 2.25 to 2.75, respectively, because even if more than 0.00 Ti is contained, no further improvement effect will be seen, or because undesirable coarse intermetallic compounds will be produced.
h, i shall be contained in the range of 0.40 to 1.01. Nb is an element necessary to increase high-temperature strength through precipitation hardening, and if it is less than 0.7 mm, precipitation hardening will be insufficient, and if it is less than 0.7 mm, precipitation hardening will be insufficient.
Even if the content exceeds 0%, the effect will be saturated, so 0.
The content should be 7 to 1.20%. Mo is added especially to improve stress corrosion cracking resistance.
The reason why it is set at 1° or more is because the stress corrosion cracking resistance will not be sufficiently improved if it is less than that, and the effect is saturated even if it is added at 1° or less. Either this is because it deteriorates workability and hot forgeability. Mg is effective as a deoxidizing and desulfurizing agent, and at the same time is added to improve plastic workability in the present invention.If it is less than 0.008, the effect is small, and on the contrary, the addition of polycarbonate The upper limit is set to 0.0 to reduce workability.
6%.

〔発明の実施例〕[Embodiments of the invention]

通常の真空高周波誘導炉を使用し、通常の溶解条件にて
それぞれ第1表に示される成分組成をもつ溶湯を調製し
、鋳造してインゴットを得た。引続いてこのインゴット
を温[1150Cに24時間保持し、ソーキングを行な
い試料とした、臥千范0 ついでこれらの試料よF) 11’径711111.長
さ12mmの丸棒試験片を切出し、この試験片を900
Cから25Cづつ間隔をおいて1850Cまで加熱し、
各加熱温度に加熱された試験片に対して一定の歪速度(
10/s e c )で長さ12Mから長さ6關にすえ
込む鍛造試験を行ない前記試験片に鍛造割れが生じる最
低加熱温度を測定した。
Using an ordinary vacuum high-frequency induction furnace and under ordinary melting conditions, molten metals having the respective compositions shown in Table 1 were prepared and cast to obtain ingots. Subsequently, this ingot was kept at a temperature of 1150C for 24 hours and soaked to prepare samples. A round bar test piece with a length of 12 mm was cut out, and this test piece was
Heat to 1850C at intervals of 25C from C,
A constant strain rate (
A forging test was conducted in which the test piece was swaged from length 12M to length 6 at a speed of 10/sec), and the lowest heating temperature at which forging cracks occurred in the test piece was measured.

さらに別途各試料について温度115に’に加熱した状
態で鍛造比4まで熱間鍛造を施して熱延板とした。これ
ら鍛造材に対し均質化処理(885CX24hr)十時
効処理(7041Z’ X 20hr)を施した後、J
I8規格に基づく形状の引張試験用丸棒試験片を作成し
た。これら試験片に対して、溶存酸素濃度92ppm、
塩素イオン濃度lppm以下で、温度290C1圧力1
00 kf/Cdの高温高圧純水中で、ひずみ速IJt
 1.OX 10−’ / secにて低ひずみ速度応
力腐食割れ試験を行なった。
Furthermore, each sample was heated to a temperature of 115' and hot forged to a forging ratio of 4 to obtain a hot rolled plate. After homogenization treatment (885CX24hr) and aging treatment (7041Z'X20hr) for these forged materials, J
A round bar test piece for tensile testing was prepared having a shape based on the I8 standard. For these test pieces, the dissolved oxygen concentration was 92 ppm,
Chlorine ion concentration 1ppm or less, temperature 290C1 pressure 1
In high-temperature, high-pressure pure water at 00 kf/Cd, the strain rate IJt
1. A low strain rate stress corrosion cracking test was conducted at OX 10-'/sec.

上記試験結果および各試料の常温における機械的強度を
合わせて第2表に示す。以千金臼第2表よシ明らかなよ
うに本発明に係るジェットポンプビームは鍛造性が良好
で、微小き裂の発生が少ない。また従来のものに比べて
、その機械的強度に遜色はなく、同時に低ひずみ速度応
力腐食割れ試験において、500時間以上経過しても破
断することがなく、耐応力腐食割れ性の点でも優れてい
ることがわかる。
The above test results and the mechanical strength of each sample at room temperature are shown in Table 2. As is clear from Table 2, the jet pump beam according to the present invention has good forgeability and less occurrence of microcracks. In addition, its mechanical strength is comparable to that of conventional products, and at the same time, it did not break even after more than 500 hours in a low strain rate stress corrosion cracking test, and it has excellent stress corrosion cracking resistance. I know that there is.

以上の如く本発明に係るジェットポンプビームは耐応力
腐食割れ性に優れると同時に微小き裂が少なく原子カプ
ラント用として適したものであシ工業上有用な特性を有
する。
As described above, the jet pump beam according to the present invention has excellent stress corrosion cracking resistance, has few microcracks, and is suitable for use in atomic couplants, and has industrially useful properties.

Claims (1)

【特許請求の範囲】 重1t%でC0,08%以下、 8i 0.5%以下、
 Mn 1.0係以下、 Cr 14.0〜17.0%
、 re 5.0〜10.0%、 Ti2.25〜2.
75%、 Ag O,40〜1.00 %、 Nb O
,7〜1.20%。 Mo 2.0〜8.0 fb、 Mg 0.008〜0
.06 %残部Niからなることを特徴とするジェット
ポンプビーム。
[Claims] C0.08% or less at 1t% weight, 8i 0.5% or less,
Mn 1.0 or less, Cr 14.0-17.0%
, re 5.0-10.0%, Ti2.25-2.
75%, AgO, 40-1.00%, NbO
,7-1.20%. Mo 2.0~8.0 fb, Mg 0.008~0
.. A jet pump beam characterized by comprising 06% balance Ni.
JP57194649A 1982-11-08 1982-11-08 Beam of jet pump Granted JPS5985834A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57194649A JPS5985834A (en) 1982-11-08 1982-11-08 Beam of jet pump

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57194649A JPS5985834A (en) 1982-11-08 1982-11-08 Beam of jet pump

Publications (2)

Publication Number Publication Date
JPS5985834A true JPS5985834A (en) 1984-05-17
JPH0353376B2 JPH0353376B2 (en) 1991-08-14

Family

ID=16328017

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57194649A Granted JPS5985834A (en) 1982-11-08 1982-11-08 Beam of jet pump

Country Status (1)

Country Link
JP (1) JPS5985834A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010138476A (en) * 2008-12-15 2010-06-24 Toshiba Corp Jet pump beam and method for manufacturing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010138476A (en) * 2008-12-15 2010-06-24 Toshiba Corp Jet pump beam and method for manufacturing the same
WO2010071017A1 (en) 2008-12-15 2010-06-24 株式会社東芝 Jet pump beam and manufacturing method therefor
US8879683B2 (en) 2008-12-15 2014-11-04 Kabushiki Kaisha Toshiba Jet pump beam and method for producing the same

Also Published As

Publication number Publication date
JPH0353376B2 (en) 1991-08-14

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