JPS5978297A - Detergent composition - Google Patents

Detergent composition

Info

Publication number
JPS5978297A
JPS5978297A JP18877882A JP18877882A JPS5978297A JP S5978297 A JPS5978297 A JP S5978297A JP 18877882 A JP18877882 A JP 18877882A JP 18877882 A JP18877882 A JP 18877882A JP S5978297 A JPS5978297 A JP S5978297A
Authority
JP
Japan
Prior art keywords
formula
group
liquid
agent
detergent composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP18877882A
Other languages
Japanese (ja)
Other versions
JPH0363600B2 (en
Inventor
民次 鎌倉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adeka Corp
Original Assignee
Asahi Denka Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Denka Kogyo KK filed Critical Asahi Denka Kogyo KK
Priority to JP18877882A priority Critical patent/JPS5978297A/en
Publication of JPS5978297A publication Critical patent/JPS5978297A/en
Publication of JPH0363600B2 publication Critical patent/JPH0363600B2/ja
Granted legal-status Critical Current

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  • Detergent Compositions (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 木を)+1門は液体洗浄剤組成物にIl’IL、詳t−
,< rJ、主[・−分活(’l゛剤のすべてが非イオ
ン活性剤から[,1;。
DETAILED DESCRIPTION OF THE INVENTION Wood)+1 contains Il'IL in a liquid cleaning composition.
, < rJ, main [・-separation activity ('l゛ agent is all from non-ionic active agent [,1;

2)、台所用等の液体洗浄剤組成物に閂J7]もの−t
’ :P、る。
2) For liquid cleaning compositions for kitchen use, etc.
' :P, Ru.

i忙来、r′N#’l’用液体洗剤と1.−ic tJ
:、■、A 5IRAS、高級アルコールツルフェート
又C」、高をンノ′ルコール:c −チルザルフェート
等ノアニオンγ占件剤を主成分としたものが一般的で才
)つたOl、かじ、これらアニオン活性剤kl二その大
小&、lあるものの、いずれも蛋白変性作用がある為、
使用者の皮層障害が発生し易いものであった。この為、
標準(c!:用6“)度に希釈しての使用やゴム手袋等
の使用を推奨しているが、現実にe、J−素手で原液を
スポンジに直接伺けて使用されている例が圧到的に多い
。一方、手荒れの少い151′、剤にし、て、シヨ糖脂
肪β′?エステル、ソルビタン脂肪酸ニスデルエトキシ
レート等の非イオン活性剤を主成分とする台所用洗剤が
知られているo 1.−かしこれらは、(くL能が劣り
、l持に油汚i7−の多い食器等の洗浄は困Jjljで
あシ、保乳ビン、野ご(4等の洗浄に使用可能な程度の
ものである。又、ヤシ油脂肪うマ等の石けん?1ウー独
及びこの石けんにアルキロールアマイド、ショ糖脂肪酸
エステル等の活性剤をカルシウム石けん分散剤として添
加した台所洗剤も公知であるが、これもまた、被洗物の
すすぎ時に汚れが再付着する等の間j、IGが有り、児
全に満足できる性能とは貰い難いものである。又、石け
んの性質上%pHはアルカリ性とせざるを得す、その為
の手荒れの問題も有る。
Liquid detergent for r'N#'l' and 1. -ic tJ
:, ■, A 5IRAS, higher alcohol sulfate or C', high alcohol: C-tylsulfate, etc. are commonly used as main ingredients of non-anionic γ-occupants. Although there are two types of agents, both large and small, they all have protein denaturing effects.
Users were more likely to experience skin damage. For this reason,
Although it is recommended to dilute to a standard (c!: 6") degree and use rubber gloves, in reality, it is used by directly applying the undiluted solution to a sponge with bare hands. On the other hand, there are kitchen detergents whose main ingredients are nonionic active agents such as sucrose fat β'? ester and sorbitan fatty acid nisdel ethoxylate, which are less rough on hands. Known o 1.-However, these are difficult to clean, such as tableware, etc., which are inferior in L ability and have a lot of oil stains. In addition, soaps such as coconut oil and fat horse? 1 Woo Germany and kitchen detergents made by adding active agents such as alkylolamides and sucrose fatty acid esters to these soaps as calcium soap dispersants. is also known, but this also has problems such as re-attachment of dirt when rinsing the items to be washed, and it is difficult to obtain a performance that satisfies all children.Also, due to the nature of the soap, % pH has to be alkaline, which causes the problem of rough hands.

本発明渚f′行1:、上記理由から、蛋白変性作用を有
スz)−リルフエート、スルフオネー・ト則のア;−千
ン活性剤を使用ぜず、かつそノ1.らを使用j7カーも
のと同1′)の性能を有する洗浄剤をl:’l ’t”
11すべく伺意栓n・11〜だ結果、B’l<べき車に
、アマイド型非イオン活性剤2 filNとアミンオキ
サイドを特定IL率で配合する事によって、所期の[]
的を、1゛6しフイ!)る事を3−5い出し、本発明を
なすに、tlつだ。
The present invention's row 1: For the above-mentioned reasons, no active agent is used, and no activating agent is used. Use a cleaning agent with the same performance as the one used in the J7 car.
As a result, the desired [
Hit the target by 1 or 6! ) It takes 3 to 5 things to accomplish this invention.

・ト:発明の油体洗浄剤組成物tよ必須の成分と17て
、下記の(汽)〜(c)を含有する。
・T: The oil body cleansing composition of the invention contains the following essential components (17) to (c).

(n、)  式(1)でimpわされるアマイドエトキ
シレート5〜20市11;チ () Ra、−h+n (cn 2an、、o )nH(+)
0式(1)中n、は炭素数9〜17好寸しくtよ?〜1
3の直イj11゛アルキル基、n &J、平均で4〜2
「〕好オしくO」8〜12) (ト) 式(2)で4トキわされるアルキロールアマイ
ドう 〜 1 0 市 Ill、  タロ(式(2)中
R2は炭素数5〜17好寸しく i’f 9〜13の1
r〒4!’jアルギル県) (C)  式(3)で5′テわされる6級アミンオギザ
イド0.5〜5爪);(1% RI+ 5 0式(3)中R5は炭素数6〜18好丑しく′は10〜
14のii7ぐl’lアルギル基、R及びR6(・よメ
チI ル基、エヂル轄又はヒドロキシエチル基好ましくけメチ
ル基) 上記各成分の各々それ自体は公知であり、各種の方法で
得ることができる。
(n,) Amide ethoxylates 5 to 20 impeded by formula (1) 11;
0 In formula (1), n means 9 to 17 carbon atoms, and t? ~1
3 straight ij11゛alkyl group, n & J, 4-2 on average
8-12) (G) Alkylolamide that is converted to 4 in formula (2) ~ 10 City Ill, Taro (R2 in formula (2) has 5 to 17 carbon atoms) Shikuku i'f 9-13 1
r〒4! (C) 6-class amine ogizide 0.5-5 to be 5'-terminated in formula (3); (1% RI+ 5 0 R5 in formula (3) preferably has 6 to 18 carbon atoms) Shiku' is 10~
14-ii7Gl'l Argyl group, R and R6 (-methyl group, ethyl group, or hydroxyethyl group, preferably methyl group) Each of the above components is known per se, and can be obtained by various methods. I can do it.

」二記各成分の一般式中R1,R2,R,で示されるア
ルギル基としてはヤシ油又はパーム核油に由来する脂肪
酸から肋導されるアルキル基が好ましい。
The argyl groups represented by R1, R2, and R in the general formulas of the respective components listed above are preferably alkyl groups derived from fatty acids derived from coconut oil or palm kernel oil.

本発明の組成物は上記必須成分を水に添加温台才、ろこ
とにより得られるが、上記必須成分σ)他に本発明の目
的の範囲内で通常液体洗7′、′テ剤に加えt−r t
l、、 Z>ものを含んでいてもよく、たノえばiYV
 ;:、: >iL性の向−にの為にエタノール、プロ
ピlノングリコール簀の溶剤、尿釆等、或t1.粘川二
;i「l ili′t−σ)RE 芒Tit’i 1.
N 1ilN 等ノ無PR塩等、 −、t< iJ、K
Z rN n’l 各Mを含有することもできる。又、
他の成分とし2で界面活性能の矛)る化合物を含有する
ことは本発明の目的を逸脱しない範囲ならば可能であZ
〕が、ザルフェート系やスルフオネー1−系のものC」
、W′:’jh 3 、+r< :i’li係迄にとど
めた方がよい0又、本発明め洗浄剤111成物ij必須
成分がすべで非・イオン活性剤である事から、Tl1−
Tの?I;!I限を受けA:いが、皮膚や眼に対する刺
τ;;r件の面から4jt、iIT? (’I:或C1
を中性が望才しい。
The composition of the present invention can be obtained by adding the above-mentioned essential ingredients to water and filtering, but in addition to the above-mentioned essential ingredients σ), the above-mentioned essential ingredients σ) can be added to the usual liquid washing agent within the scope of the present invention. t-r t
l,, Z> may also be included, for example iYV
;:,: > For iL properties, use ethanol, propyl non-glycol solvent, urine broth, etc., or t1. Mukawaji;i ``l ili't-σ)RE 芒Tit'i 1.
N 1ilN etc. no PR salt etc., −, t< iJ, K
Z rN n'l can also contain each M. or,
It is possible to contain compounds that have surface active properties as other components, as long as they do not depart from the purpose of the present invention.
] is a sulfate-type or sulfone-1-type C.
, W': 'jh 3 , +r<:i'li It is better to limit the value to −
T's? I;! A: However, it may sting to the skin or eyes; 4jt, iIT? ('I: or C1
A neutral person is desirable.

以下、実7Kli例により本発明を更に詳細に1i(J
、 l1llするが、本発明はこれらの実施例に限21
″、へ;1.、Z、も(7) f il、ない。尚、例
中の部p、+、7Tj )1j: 、J+% f’/(
チオ、Zl。
Hereinafter, the present invention will be explained in more detail with reference to actual 7Kli examples.
However, the present invention is limited to these examples.
'', to; 1., Z, also (7) f il, none. In addition, the part in the example p, +, 7Tj )1j: , J+% f'/(
Thio, Zl.

′、I!、 、il’li例 、1嬶1に示゛J配合組成を有する名神n〜、浄剤の名
’Fit zt浄力、ン(す立ち2手荒れ性を以下に示
す方法によりn゛「価した。結、−i:を岩1に示す。
', I! , , il'li Example, 1. The name of the cleaning agent having the composition shown in 1. .Conclusion, -i: is shown in rock 1.

く評価方法〉 0 洗浄力(シェル変法) 汚垢としてマーガリン100部、オレイン酸4部、小ノ
ε粉104部を配合したものを、直径21c1nの皿に
直径15cmの円状に1■11枚につき3fぬり利は一
夜放置したものを被洗物とした。’?5’Q液rj洗浄
剤1.5苫Cを水1tに溶解したものをワ1.い桶に入
れその上部45a1+の所から、別の水1tを滴下し洗
液を泡立たせたものを使用した。この洗液中に前記皿を
入れ、タワシで左右10回づつこすり、洗液の泡が汚れ
の為に消失し、液面の50係となる咬でに洗浄した皿の
枚数で評価した。なお、水tよ58 CaC0,ppm
の水道水を使用、況7J’7 t、i25℃に調整した
Evaluation method> 0 Cleaning power (Modified shell method) A mixture of 100 parts of margarine, 4 parts of oleic acid, and 104 parts of small epsilon powder was poured into a 15 cm circle in a 21 c1n diameter dish. Each sheet was coated with 3 f glue and was left overnight to be washed. '? 5'Q liquid rj cleaning agent 1.5 C dissolved in 1 t of water. Another 1 ton of water was added dropwise from the upper part 45a1+ of the washing liquid to foam the washing liquid. The dishes were placed in this washing liquid and rubbed 10 times on each side with a scrub brush. The bubbles in the washing liquid disappeared due to dirt, and the number of dishes washed was evaluated by the number of plates washed when the liquid level reached 50 parts. In addition, water 58 CaC0, ppm
Tap water was used, and the temperature was adjusted to 25°C.

○ 洗浄力(スポンジ洗い法) 中華ナベにマーガリン151を入れ、カッ色になるまで
加熱後冷却し、水100mgを入れ7)Qこれ番・C−
所定量の洗浄剤を入れ、??+: r(す1)スポンジ
で左右10回づつこすり、このIH;7.の泡、油清イ
’:l 4’+! I”り、油の乳化状Qjiを観察す
Z)。1iIJ41へIC状<1t1c’: /l Z
) + −CK 必要f(51t 浄剤1rE−c洗r
T+剤’7) ?il−: Q+力4’、、 FiF価
した。
○ Cleaning power (sponge washing method) Put margarine 151 in a wok pan, heat it until it turns brown, cool it, then add 100 mg of water 7) Q This number/C-
Pour in the specified amount of cleaning agent and ? ? +: R (S1) Rub with a sponge 10 times on each side, this IH; 7. Foam, oil cleansing':l 4'+! Observe the emulsified oil Qji.1iIJ41 IC<1t1c': /l Z
) + -CK Required f(51t Cleaning agent 1rE-c cleaning r
T+ agent '7)? il-: Q+force 4', FiF value.

o1ゴ  汚  染 直径’)1nnの1111に直径15mの円状にマR・
す、−ズ5F4−ぬり伺けだもの20枚をj+7:洗物
とl−、、+1 、5 rm X 7 rm X 3 
eynの洗浄用スポンジにi/、l゛。
o1 contamination diameter') 1nn in a circle with a diameter of 15 m.
-s 5F4- 20 pieces of colored objects j + 7: washing and l-,, +1 , 5 rm x 7 rm x 3
i/, l゛ for eyn's cleaning sponge.

?’fl剤5y全5yたもので洗浄j〜だ。洗浄後のI
ll i/よ水を張った洗い桶にt1′tけ、3分後、
水道71りで汁、水ず一1′ぎをし乾燥後の油の伺着状
ηi11を傅牝(l−1全く残ってい女いものを−、油
(・I’ ;?′fイハF、−小なもの→−9少し多い
ものを1千、程度の<’bといも(7)を−1→千とし
た。
? 'Wash with 5y of fl agent in total. I after washing
ll i/Put it in a washing tub filled with water, and after 3 minutes,
Rinse the juice and water at the tap 71, and after drying, remove the oil (11) from the oil (l-1). , -Small → -9 A little more than 1,000, and <'b and potato (7) of about 1,000.

0 手荒ノ1,11・(験0 Rough Hands 1, 11・(Experience)

Claims (1)

【特許請求の範囲】 1 下11(コの(n)〜(C・)を必須成分として含
有するととを!1゛v徴とする液体洗浄剤組成物(a)
  式(1)てコ゛ミわ込れるアマイドエトギシレー]
・ 5〜20甫;、1:係 RlC−No(an2aH2o)nn     (1)
(式(+) 111R1i’、]、炭=(ζ数9〜17
の直((1アルキル基、n)よ平均で4〜20) (b)  式(2)で表わされるアルギロールアマイド
5 〜1 0 重 1.1 係 6式(2)中R2&J、炭素数5〜17の直鎖アルギル
基) (c)  式(勺で表わさJする3級アミンオキ′リー
イド[〕、5〜 !j j!’t’、 44係P+1 ■ 5 (式(6)中R5−”炭素数6〜18の直、(、+9”
rルヤル;r:’j、R,、及びR9はメチル基、エチ
ル井只v1、ヒドロキシエチル基) 2(n)〜(C)の各成分がいずれもヤシ油又t、(、
パー、/% 4!j油を原木トと1〜て得られるもので
オ〕る11..7γ[請求の範囲第1頂記+j+’4の
液体ね)、υ剤組酸物
[Scope of Claims] 1. A liquid detergent composition (a) containing (n) to (C.) as essential components.
Amide Etogishire incorporated by formula (1)]
・5~20甫;, 1:RlC-No(an2aH2o)nn (1)
(Formula (+) 111R1i', ], Charcoal = (ζ number 9 to 17
Direct ((1 alkyl group, n) is 4 to 20 on average) (b) Argyrolamide represented by formula (2) 5 to 10 weight 1.1 Coefficient 6 R2 & J in formula (2), carbon number 5 ~17 straight chain argyl group) (c) Formula (tertiary amine oxy-reide [], 5 ~ !j j!'t', 44 P+1 ■ 5 (R5- in formula (6)) Direct carbon number 6-18, (,+9"
r: 'j, R, and R9 are methyl group, ethyl Idada v1, hydroxyethyl group) Each of the components of 2(n) to (C) is coconut oil or t, (,
Par, /% 4! 11.It is obtained by mixing oil with raw wood.11. .. 7γ [the liquid in the first claim +j+'4], υ agent group acid
JP18877882A 1982-10-27 1982-10-27 Detergent composition Granted JPS5978297A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18877882A JPS5978297A (en) 1982-10-27 1982-10-27 Detergent composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18877882A JPS5978297A (en) 1982-10-27 1982-10-27 Detergent composition

Publications (2)

Publication Number Publication Date
JPS5978297A true JPS5978297A (en) 1984-05-07
JPH0363600B2 JPH0363600B2 (en) 1991-10-01

Family

ID=16229620

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18877882A Granted JPS5978297A (en) 1982-10-27 1982-10-27 Detergent composition

Country Status (1)

Country Link
JP (1) JPS5978297A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02117996A (en) * 1988-10-27 1990-05-02 Kawaken Fine Chem Co Ltd Liquid cleaning agent composition
EP0552032A2 (en) * 1992-01-16 1993-07-21 Unilever Plc Surfactant amides and cosmetic or cleaning compositions comprising the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4994701A (en) * 1972-09-11 1974-09-09

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4994701A (en) * 1972-09-11 1974-09-09

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02117996A (en) * 1988-10-27 1990-05-02 Kawaken Fine Chem Co Ltd Liquid cleaning agent composition
EP0552032A2 (en) * 1992-01-16 1993-07-21 Unilever Plc Surfactant amides and cosmetic or cleaning compositions comprising the same
EP0552032A3 (en) * 1992-01-16 1996-05-29 Unilever Plc Surfactant amides and cosmetic or cleaning compositions comprising the same

Also Published As

Publication number Publication date
JPH0363600B2 (en) 1991-10-01

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