JPH02117996A - Liquid cleaning agent composition - Google Patents
Liquid cleaning agent compositionInfo
- Publication number
- JPH02117996A JPH02117996A JP27254488A JP27254488A JPH02117996A JP H02117996 A JPH02117996 A JP H02117996A JP 27254488 A JP27254488 A JP 27254488A JP 27254488 A JP27254488 A JP 27254488A JP H02117996 A JPH02117996 A JP H02117996A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- jetanolamide
- fatty acids
- temperature stability
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 239000007788 liquid Substances 0.000 title claims description 5
- 239000012459 cleaning agent Substances 0.000 title description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 54
- 239000000194 fatty acid Substances 0.000 claims abstract description 54
- 229930195729 fatty acid Natural products 0.000 claims abstract description 54
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 52
- 235000003441 saturated fatty acids Nutrition 0.000 claims abstract description 8
- 238000004140 cleaning Methods 0.000 claims abstract description 7
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- -1 12C saturated fatty acid Chemical class 0.000 abstract description 13
- 238000005187 foaming Methods 0.000 abstract description 13
- 230000008719 thickening Effects 0.000 abstract description 12
- 150000004671 saturated fatty acids Chemical class 0.000 abstract description 5
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract description 5
- 150000001408 amides Chemical class 0.000 abstract 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- 229940043237 diethanolamine Drugs 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000003599 detergent Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000012847 fine chemical Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- GWEBEJYKXBMRJL-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO.CCCCCCCCCCCCOCCCCCCCCCCCC GWEBEJYKXBMRJL-UHFFFAOYSA-N 0.000 description 1
- UNWFFCPRJXMCNV-UHFFFAOYSA-N 3-[dodecanoyl(methyl)amino]propanoic acid Chemical compound CCCCCCCCCCCC(=O)N(C)CCC(O)=O UNWFFCPRJXMCNV-UHFFFAOYSA-N 0.000 description 1
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 1
- DWIYFHPNCGKDJM-UHFFFAOYSA-N CN(C)CC(=O)O.C(CCCCCCCCCCC)(=O)O Chemical compound CN(C)CC(=O)O.C(CCCCCCCCCCC)(=O)O DWIYFHPNCGKDJM-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 229960000458 allantoin Drugs 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 1
- LTVJJSFLSYSCEF-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S([O-])(=O)=O)CC([O-])=O LTVJJSFLSYSCEF-UHFFFAOYSA-L 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940074774 glycyrrhizinate Drugs 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- CAVXVRQDZKMZDB-UHFFFAOYSA-M sodium;2-[dodecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O CAVXVRQDZKMZDB-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は洗浄剤組成物に関し、さらに詳しくは特定の脂
肪酸組成を有する脂肪酸ジェタノールアミドを含むこと
を特徴とする増粘性、起泡性、洗浄力および低温安定性
に優れた洗浄剤組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a detergent composition, and more particularly, to a detergent composition having thickening properties, foaming properties, and detergency characterized by containing a fatty acid jetanolamide having a specific fatty acid composition. The present invention also relates to a cleaning composition having excellent low-temperature stability.
微速ｃｌ＞ｎｍ
従来、台所洗剤やシャンプーなどの主成分として、アル
キルサルフェート、α−オレフィンスルホネート、直鎖
アルキルベンゼンスルホン酸などの界面活性剤が用いら
れており、さらにこれらの主成分を補助する目的で脂肪
酸ジェタノールアミドが広く使用されている。Very slow cl>nm Conventionally, surfactants such as alkyl sulfates, α-olefin sulfonates, and linear alkylbenzene sulfonic acids have been used as the main ingredients of kitchen detergents and shampoos, and surfactants such as alkyl sulfates, α-olefin sulfonates, and linear alkylbenzene sulfonic acids have been used to supplement these main ingredients. Fatty acid jetanolamide is widely used.
脂肪酸ジェタノールアミドを構成する脂肪酸としては、
天然のヤシ油がら得られるヤシ油脂肪酸が最も多く用い
られている。The fatty acids that make up fatty acid jetanolamide are:
Coconut oil fatty acids obtained from natural coconut oil are the most commonly used.
ヤシ油脂肪酸ジェタノールアミドは、起泡力、洗浄力お
よび低温安定性は優れているが、がならずしも増粘性が
充分ではなく、希望する粘度を有する製品を得るのが難
しい場合がある。そこで、当業界ではヤシ油脂肪酸や牛
脂脂肪酸を分別し、それぞれ炭素数１２．１４．１６．
１８を主留分とする脂肪酸を得て、これらの分別脂肪酸
がらのジェタノールアミドを利用するなどしているが、
前記の全ての条件を満たすことはできない。Coconut oil fatty acid jetanolamide has excellent foaming power, detergency, and low-temperature stability, but its thickening properties are not sufficient, and it may be difficult to obtain a product with the desired viscosity. . Therefore, in the industry, coconut oil fatty acids and beef tallow fatty acids are separated, each having a carbon number of 12, 14, and 16.
We obtain fatty acids with 18 as the main fraction and use jetanolamide from these fractionated fatty acids.
It is not possible to satisfy all of the above conditions.
すなわち、炭素数１２の脂肪酸を主留とする脂肪酸ジェ
タノールアミドは、起泡力および洗浄力が優れるが低温
安定性が充分でない。炭素数１４以上の脂肪酸を主留と
する脂肪酸ジェタノールアミドは、増粘作用は強いが、
起泡力、洗浄力、低温安定性が悪くなる。That is, fatty acid jetanolamide containing a fatty acid having 12 carbon atoms as its main residue has excellent foaming power and detergency, but does not have sufficient low-temperature stability. Fatty acid jetanolamide, whose main residue is a fatty acid with 14 or more carbon atoms, has a strong thickening effect, but
Foaming power, detergency, and low temperature stability deteriorate.
また、増粘させる手段として、無機塩や高分子化合物な
どの添加剤を加える方法も提案されているが、低温安定
性が悪くなったり、尋泡力が劣ったりする欠点がある。In addition, methods of adding additives such as inorganic salts and polymer compounds have been proposed as a means of increasing viscosity, but these have drawbacks such as poor low-temperature stability and poor foaming power.
九朋圀５進じようとす１１】よび制」
本発明の目的は、増粘性、起泡性、洗浄力および低温安
定性に優れた脂肪酸ジェタノールアミドを含有する洗浄
剤組成物を提供することである。An object of the present invention is to provide a cleaning composition containing a fatty acid jetanolamide that has excellent thickening properties, foaming properties, detergency, and low-temperature stability. That's true.
課題を解４（す」卜々ｙ入凶」−以一
上記課題を解決するため、本発明者等が鋭意研究した結
果、ある特定範囲の脂肪酸組成を有する脂肪酸ジェタノ
ールアミドのみが上記課題解決に有効であることを見い
だし、本発明を完成するに至った。Solving the Problem 4 - First, in order to solve the above problem, the present inventors conducted intensive research, and as a result, only fatty acid jetanolamide having a fatty acid composition within a certain range solved the above problem. The present invention has been completed based on the discovery that the present invention is effective.
すなわち、本発明は、脂肪酸ジェタノールアミドを構成
する脂肪酸として、
・炭素数１２未満の飽和脂肪酸：１５％以下・炭素数１
２の飽和脂肪酸 ：４５〜５５％・炭素数１４の飽和
脂肪酸 ：１２〜１７％・炭素数１８の不飽和脂肪酸
（不飽和数：ｌ ：１２〜１７％から成る
脂肪酸ジェタノールアミドを含有することを特徴とする
洗浄剤組成物に関するものである。That is, the present invention provides the following fatty acids constituting fatty acid jetanolamide: - Saturated fatty acids with less than 12 carbon atoms: 15% or less - 1 carbon number
2 saturated fatty acids: 45-55%, saturated fatty acids with 14 carbon atoms: 12-17%, unsaturated fatty acids with 18 carbon atoms (contains fatty acid jetanolamide consisting of 12-17% of unsaturated fatty acids) The present invention relates to a cleaning composition characterized by:
本発明における脂肪酸ジェタノールアミドの脂肪酸組成
は、上記割合の混合脂肪酸系のものを用いることが好ま
しく、この範囲を外れると以下のように不都合が生じる
。As for the fatty acid composition of the fatty acid jetanolamide in the present invention, it is preferable to use a mixed fatty acid composition having the above-mentioned proportions, and if it deviates from this range, the following disadvantages will occur.
すなわち、炭素数１２未満の脂肪酸が１５％を超えると
増粘性が悪くなり、炭素数１２の飽和脂肪酸が４５％未
満では増粘性が劣り、５５％を超えると低温安定性が低
下してしまう。炭素数１４の飽和脂肪酸が１２％未満で
は増粘性が劣り、１７％を超えると低温安定性が悪くな
り、炭素数１８の不飽和脂肪酸が１２％未満では増粘作
用が劣り、１７％以上になると低温安定性が悪くなる。That is, if the content of fatty acids having less than 12 carbon atoms exceeds 15%, the thickening properties will be poor, if the content of saturated fatty acids having 12 carbon atoms is less than 45%, the thickening properties will be poor, and if the content exceeds 55%, the low temperature stability will decrease. If the saturated fatty acid with a carbon number of 14 is less than 12%, the thickening effect will be poor, if it exceeds 17%, the low temperature stability will be poor, if the unsaturated fatty acid with a carbon number of 18 is less than 12%, the thickening effect will be poor, and if the content is more than 17%, the thickening effect will be poor. If this happens, the low temperature stability will deteriorate.
本発明に用いられる脂肪酸ジェタノールアミドを製造す
るには油や脂肪酸からの直接反応法、あるいは脂肪酸の
低級アルコールエステル法等、どのような方法であって
もよい。The fatty acid jetanolamide used in the present invention may be produced by any method, such as a direct reaction method from oil or fatty acid, or a lower alcohol ester method of fatty acid.
脂肪酸組成の調整は、単一の脂肪酸を本発、明の範囲に
混合してもよく、また天然の油を用いてこの範囲内にし
てもよい。また、脂肪酸とジェタノールアミンの反応モ
ル比は１：１または１：２のいずれでもよい。The fatty acid composition may be adjusted by mixing a single fatty acid within the range specified in the present invention, or by using a natural oil within this range. Further, the reaction molar ratio of fatty acid and jetanolamine may be either 1:1 or 1:2.
本発明の洗浄剤組成物には使用目的に応じて、慣用され
ているアニオン界面活性剤、非イオン界面活性剤、両性
界面活性剤などの各種界面活性剤、エタノール、尿素、
多価アルコール類、トルエンスルホン酸ナトリウムなど
の可溶化剤、ＥＤＴＡなとのキレート剤、クエン酸、リ
ンゴ酸などのｐＨ１１ｕ剤、香料、着色剤などを用いる
ことができ、またシャンプーなどに使用する場合は、グ
リコール類、アミノ酸類、動植物エキスなどの保湿剤、
アラントイン、グリチルリチン酸塩などの抗炎症剤、殺
菌剤、防腐剤などを配合することができる。Depending on the purpose of use, the cleaning composition of the present invention may contain various surfactants such as commonly used anionic surfactants, nonionic surfactants, amphoteric surfactants, ethanol, urea, etc.
Polyhydric alcohols, solubilizing agents such as sodium toluenesulfonate, chelating agents such as EDTA, pH 11u agents such as citric acid and malic acid, fragrances, coloring agents, etc. can be used, and when used in shampoos etc. moisturizers such as glycols, amino acids, animal and plant extracts,
Anti-inflammatory agents such as allantoin and glycyrrhizinate, bactericides, preservatives, etc. can be added.
火瀞例１〜３、比較例１〜Ｌ％
第１表に示される炭素数の脂肪酸とジェタノールアミン
から合成した脂肪酸ジ・エタノールアミド（脂肪酸とジ
ェタノールアミンの反応モル比は、１．１）のそれぞれ
を以下に示す試験処方で台所用液体洗浄剤を調製し、そ
の起泡力、洗浄力、粘度、低温安定性を測定した。結果
は第１表中に示した。なお、各試験方法は以下の方法を
採用した。Hidori Examples 1 to 3, Comparative Examples 1 to L% Fatty acid diethanolamide synthesized from a fatty acid with a carbon number shown in Table 1 and jetanolamine (the reaction molar ratio of fatty acid and jetanolamine is 1.1 ) were prepared as kitchen liquid detergents using the test formulations shown below, and their foaming power, detergency, viscosity, and low-temperature stability were measured. The results are shown in Table 1. The following methods were used for each test.
・起泡力 ロスマイルス法 濃度０．２５％、−１Ｏ°Ｃ・洗浄力 ローナツツ法 ＪＩＳ Ｋ３３７０ 濃度０．０３％、３０’Ｃ ・粘度 Ｂ型粘度計 ２５°Ｃ ・低温安定性 一５°Ｃに７日間放置し、判定した。・Foaming power Ross Miles method concentration 0.25%, -1O°C, cleaning power Lonatz method JIS K3370 Concentration 0.03%, 30'C ·viscosity B type viscometer 25°C ・Low temperature stability It was left at -5°C for 7 days and evaluated.
Ｏ・・・ 均一透明
△ ・・・ 少し白濁
× ・・・ 白濁または分離
民１４九 ％・直鎖
アルキルベンゼンスルホン酸
ナトリウム １６・脂肪
酸ジェタノールアミド ４・クエン酸
ｐＨ・７．０とする量水
残（以下余白）
第１表の結果から、実施例１〜３の各液体洗剤は、増粘
性、起泡力、洗浄力、低温安定性のいずれにも優れたも
のであるがわかる。O... Uniform transparency △... Slightly cloudy ×... White cloudy or isolated 149% Sodium linear alkylbenzene sulfonate 16 Fatty acid jetanolamide 4 Citric acid
Amount of water to adjust pH to 7.0
Remainder (hereinafter referred to as margin) From the results in Table 1, it can be seen that each of the liquid detergents of Examples 1 to 3 was excellent in thickening ability, foaming power, detergency, and low-temperature stability.
実施例４
下記の処方で台所洗剤を調製した。なお、処方中の脂肪
酸ジェタノールアミドは実施例３の脂肪酸組成と同一の
脂肪酸を用いて合成した。Example 4 A kitchen detergent was prepared according to the following formulation. The fatty acid jetanolamide in the formulation was synthesized using the same fatty acid composition as in Example 3.
（Ａ）
・α−オレフィンスルホン酸ナトリウム １４％・脂肪
酸ジェタノールアミド（１：１型） ６・尿素
２・コハク酸
ｐＨ＝６．５とする量・水
残
（Ｂ） ％・ポリオキシ
エチレン（３）ラウリル
エーテル硫酸ナトリウム ６・直鎖ア
ルキルベンゼンスルホン酸
ナトリウム ６・脂肪
酸ジェタノールアミド（１：１型）１０・エチルアルコ
ール ２・リンゴ酸
ｐＨ・７とする量・水
残（Ｃ）
％・ポリオキシエチレン（３）ラウリル
エーテル硫酸ナトリウム ６・直鎖
アルキルベンゼンスルホン酸
ナトリウム ６・ラウ
ロイル−Ｎ−メチル−β−
アラニンナトリウム（３０％”） ” Ｌ ２
・ソジウムココイルイセチオネート ６・ラウ
リルジメチルアミンオキシド ２・ラウリン酸
アミドプロビルジメチル
アミノ酢酸ベタイン（３０％）２′１０・脂肪酸ジェタ
ノールアミド（１：１型） ５・ｐ−トルエンスル
ホン酸ナトリウム ３香料
０．１・色素
微量・クエン酸 ｐＨ
＝７．５とする量−ＥＤＴＡ ・ ２Ｎａ
Ｏ，１・水
残
（Ｄ）
α−オレフィンスルホン酸ナトリウム １０・ポリオ
キシエチレンく５）ラウリル
エーテル ５ポリオキ
シエチレン（５）ヤシ油脂肪酸モノエタノールアミド６
３′５
・ソジウムアルカンスルホネート ５・脂肪
酸ジェタノールアミド（１１型） ７・酒石酸
ｐＨ・８．０とする量・香料
０．２・色素
微量・水
残実流側４の（Ａ）〜（Ｄ）の各台所洗剤は
、起泡力、洗浄力および低温安定性に優れ、手荒れも少
なかった。(A) - Sodium α-olefin sulfonate 14% - Fatty acid jetanolamide (1:1 type) 6 - Urea
2. Succinic acid
Amount/water to adjust pH to 6.5
Remaining (B) % Polyoxyethylene (3) Sodium lauryl ether sulfate 6 Sodium linear alkylbenzene sulfonate 6 Fatty acid jetanolamide (1:1 type) 10 Ethyl alcohol 2 Malic acid
Amount/water to adjust pH to 7
Remainder (C)
%・Polyoxyethylene (3) Sodium lauryl ether sulfate 6・Sodium linear alkylbenzene sulfonate 6・Sodium lauroyl-N-methyl-β-alanine (30%)” L 2
・Sodium cocoyl isethionate 6.Lauryl dimethylamine oxide 2.Amidoprobyl dimethylaminoacetate laurate betaine (30%) 2'10.Fatty acid jetanolamide (1:1 type) 5.Sodium p-toluenesulfonate 3 fragrances
0.1・Pigment
Trace amount/citric acid pH
Amount to make =7.5 - EDTA・2Na
O,1・Water
Remainder (D) Sodium α-olefin sulfonate 10. Polyoxyethylene 5) Lauryl ether 5 Polyoxyethylene (5) Coconut oil fatty acid monoethanolamide 6
3'5 - Sodium alkanesulfonate 5 - Fatty acid jetanolamide (type 11) 7 - Tartaric acid
Amount and fragrance to adjust pH to 8.0
0.2・Pigment
Trace amount/water
Each of the kitchen detergents (A) to (D) on the residue flow side 4 had excellent foaming power, detergent power, and low-temperature stability, and caused less roughness on hands.
（注）
＊１・商品名「アラノンＡＬＥＪ 、用研ファインケミ
カル■製使用
＊２；商品名「ソフタゾリンＬＰＢ」、用研ファインケ
ミカル■製使用
＊３：商品名「アミゼット５Ｃ」、用研ファインケミカ
ル■製使用
実施例５
下記の処方により各種液体洗浄剤を調製した。(Note) *1.Product name "Alanone ALEJ", manufactured by Yoken Fine Chemical *2; Product name "Softazoline LPB", manufactured by Yoken Fine Chemical *3: Product name "Amizet 5C", manufactured by Yoken Fine Chemical *3. Example 5 Various liquid cleaning agents were prepared according to the following formulations.
（Ａ）ヘアーシャンプー ％・ポリ
オキシエチレン（３）ラウリル
エーテル硫酸トリエタノールアミン ６・ラウロ
イル−Ｎ−メチル−β−
アラニンナトリウム（３０％） ５・ラウ
ロイルメチルタウリンナトリウム ２・脂肪酸ジェ
タノールアミド（１：１型）４，５・Ｎ−ヤシ油脂肪酸
アシル−Ｌ−グルタミン酸トリエタノールアミン（３０
％）”’１．０・加水分解コラーゲン
０，５、ＥＤＴＡ・２Ｎａ
０．トメチルパラベン ０．
１・クエン酸 ｐＨ＝６．５とす
る量・水 残
（Ｂ）へよニーシャンプー ％・２
−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエ
チルイミダゾリウム
ベタイン（３０％）５２４０
・ラウロイル−Ｎ−メチル−β−アラ
ニントリエタノールアミン（３０％）１０・脂肪酸ジェ
タノールアミド（１：１） ３・グリセリン
３・カルボキシメチルキチン
０．３・メチルパラベン
０，１−ＥＤＴＡ−２Ｎａ
Ｏ，トクエン酸 ｐＨ
・６．５にする量・水
残（Ｃ）ボディーシャンＡ１ ％・ラ
ウロイルサルコシンナトリウム
（３０％）−６１２０
・ラウリン酸アミドプロピルジメチル
酢酸ベタイン（３０％）２４
・ラウリルスルホサクシネート
ジナトリウム ３・脂肪
酸ジェタノールアミド（１：１型） ２・混合アミノ
酸１７）ト
メチルパラベン ０． トプロ
ビルパラベン ０． トクエン酸
０，６・香料
０． トヒアルロン酸
０．０トアロエエキス
０．０５・水
残
臭流側５のシャンプー類は、洗浄力、起泡力、低温安定
性が優れており、使用感も良好で刺激も少ないことが認
められた。(A) Hair shampoo % Polyoxyethylene (3) Lauryl ether sulfate triethanolamine 6 Lauroyl-N-methyl-β-sodium alanine (30%) 5 Sodium lauroyl methyl taurate 2 Fatty acid jetanolamide (1: Type 1) 4,5-N-coco fatty acid acyl-L-glutamic acid triethanolamine (30
%)"'1.0・Hydrolyzed collagen
0,5, EDTA・2Na
0. Tomethylparaben 0.
1. Citric acid amount to make pH = 6.5 ・Water remainder (B) Hair knee shampoo % ・2
-Alkyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine (30%) 5240 ・Lauroyl-N-methyl-β-alanine triethanolamine (30%) 10 ・Fatty acid jetanolamide (1:1) 3. glycerin
3.Carboxymethylchitin 0.3.Methylparaben
0,1-EDTA-2Na
O, tocitric acid pH
・Amount to make 6.5 ・Water
Remaining (C) Bodyshan A1%・Sodium lauroylsarcosinate (30%)-6120・Betaine amidopropyldimethylacetate laurate (30%) 24・Disodium lauryl sulfosuccinate 3・Fatty acid jetanolamide (1:1 type) 2. Mixed amino acids 17) Tomethylparaben 0. Toprovirparaben 0. Tocitric acid 0,6/Fragrance
0. Tohyaluronic acid
0.0 toaloe extract
0.05・Wednesday
The shampoos on the residual odor flow side 5 were found to have excellent detergency, foaming power, and low-temperature stability, and were also found to have a good feeling of use and little irritation.
（注）
＊５：商品名「ソフタゾリンＣＨ」、用研ファインケミ
カル■製使用
＊６・商品名「ソイボンＳＬＥ」、用研ファインケミカ
ル＠製使用
＊７．商品名［プロデュウ１００Ｊ、味の素■製使用
Ｏへ蝮迷−
本発明の脂肪酸組成が特定の脂肪酸ジェタノールアミド
を用いることにより、増粘性、起泡性、洗浄力および低
温安定性に優れた洗浄剤組成物を得ることができる。(Note) *5: Product name "Softazolin CH", manufactured by Yoken Fine Chemical *6. Product name "Soibon SLE", manufactured by Yoken Fine Chemical @ *7. Product Name: [Prodew 100J, manufactured by Ajinomoto ■] A detergent with excellent thickening properties, foaming properties, detergency, and low-temperature stability due to the fatty acid composition of the present invention using specific fatty acid jetanolamide A composition can be obtained.
Claims (1)
、 ・炭素数１２未満の飽和脂肪酸：１５％以下 ・炭素数１２の飽和脂肪酸：４５〜５５％ ・炭素数１４の飽和脂肪酸：１２〜１７％ ・炭素数１８の不飽和脂肪酸 （不飽和数：１）：１２〜１７％ から成る脂肪酸ジエタノールアミドを含有することを特
徴とする液体洗浄剤組成物。[Claims] 1. As fatty acids constituting fatty acid diethanolamide: - Saturated fatty acids with less than 12 carbon atoms: 15% or less - Saturated fatty acids with 12 carbon atoms: 45 to 55% - Saturated fatty acids with 14 carbon atoms: 12 -17% - Unsaturated fatty acid having 18 carbon atoms (number of unsaturations: 1): 12-17% A liquid cleaning composition characterized by containing fatty acid diethanolamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63272544A JP2567277B2 (en) | 1988-10-27 | 1988-10-27 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63272544A JP2567277B2 (en) | 1988-10-27 | 1988-10-27 | Liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02117996A true JPH02117996A (en) | 1990-05-02 |
| JP2567277B2 JP2567277B2 (en) | 1996-12-25 |
Family
ID=17515381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63272544A Expired - Fee Related JP2567277B2 (en) | 1988-10-27 | 1988-10-27 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2567277B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02212600A (en) * | 1988-12-12 | 1990-08-23 | Unilever Nv | Detergent composition containing betaine and ether sulfate |
| EP0708199A1 (en) * | 1994-10-20 | 1996-04-24 | Kao Corporation | Deinking composition |
| US5562848A (en) * | 1992-09-21 | 1996-10-08 | Wofford; James A. | Viscosity-stabilized amide composition, methods of preparing and using same |
| DE10257984A1 (en) * | 2002-12-12 | 2004-06-24 | Beiersdorf Ag | Cosmetic or dermatological skin cleansing agent e.g. for reducing skin roughness, comprises fatty acid salt surfactants |
| JP2008127490A (en) * | 2006-11-22 | 2008-06-05 | Diversey Ip Internatl Bv | Neutral liquid cleanser composition for automatic tableware washer |
| JP2014074114A (en) * | 2012-10-04 | 2014-04-24 | Kawaken Fine Chemicals Co Ltd | Thickener composition and liquid detergent composition |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5343708A (en) * | 1976-10-01 | 1978-04-20 | Kao Corp | Liquid and light-duty detergent composition |
| JPS5396007A (en) * | 1977-02-02 | 1978-08-22 | Kawaken Fine Chem Co Ltd | Luquid detergent composition |
| JPS5978297A (en) * | 1982-10-27 | 1984-05-07 | 旭電化工業株式会社 | Detergent composition |
| JPS5980643A (en) * | 1982-10-29 | 1984-05-10 | Lion Corp | Preparation of alkanolamide having low cloud point |
| JPS62257988A (en) * | 1986-05-01 | 1987-11-10 | 花王株式会社 | Detergent composition |
| JPS6396161A (en) * | 1986-10-14 | 1988-04-27 | Lion Corp | Production of fatty acid alkanolamide |
-
1988
- 1988-10-27 JP JP63272544A patent/JP2567277B2/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5343708A (en) * | 1976-10-01 | 1978-04-20 | Kao Corp | Liquid and light-duty detergent composition |
| JPS5396007A (en) * | 1977-02-02 | 1978-08-22 | Kawaken Fine Chem Co Ltd | Luquid detergent composition |
| JPS5978297A (en) * | 1982-10-27 | 1984-05-07 | 旭電化工業株式会社 | Detergent composition |
| JPS5980643A (en) * | 1982-10-29 | 1984-05-10 | Lion Corp | Preparation of alkanolamide having low cloud point |
| JPS62257988A (en) * | 1986-05-01 | 1987-11-10 | 花王株式会社 | Detergent composition |
| JPS6396161A (en) * | 1986-10-14 | 1988-04-27 | Lion Corp | Production of fatty acid alkanolamide |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02212600A (en) * | 1988-12-12 | 1990-08-23 | Unilever Nv | Detergent composition containing betaine and ether sulfate |
| US5562848A (en) * | 1992-09-21 | 1996-10-08 | Wofford; James A. | Viscosity-stabilized amide composition, methods of preparing and using same |
| EP0708199A1 (en) * | 1994-10-20 | 1996-04-24 | Kao Corporation | Deinking composition |
| DE10257984A1 (en) * | 2002-12-12 | 2004-06-24 | Beiersdorf Ag | Cosmetic or dermatological skin cleansing agent e.g. for reducing skin roughness, comprises fatty acid salt surfactants |
| JP2008127490A (en) * | 2006-11-22 | 2008-06-05 | Diversey Ip Internatl Bv | Neutral liquid cleanser composition for automatic tableware washer |
| JP2014074114A (en) * | 2012-10-04 | 2014-04-24 | Kawaken Fine Chemicals Co Ltd | Thickener composition and liquid detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2567277B2 (en) | 1996-12-25 |
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