JPS5947333A - Production of high-tension cold-rolled steel sheet having good drawability and aging resistance - Google Patents

Production of high-tension cold-rolled steel sheet having good drawability and aging resistance

Info

Publication number
JPS5947333A
JPS5947333A JP15737682A JP15737682A JPS5947333A JP S5947333 A JPS5947333 A JP S5947333A JP 15737682 A JP15737682 A JP 15737682A JP 15737682 A JP15737682 A JP 15737682A JP S5947333 A JPS5947333 A JP S5947333A
Authority
JP
Japan
Prior art keywords
temperature
rolled
cold
aging resistance
hot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP15737682A
Other languages
Japanese (ja)
Other versions
JPS6112007B2 (en
Inventor
Takashi Sakata
敬 坂田
Takashi Obara
隆史 小原
Minoru Nishida
稔 西田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP15737682A priority Critical patent/JPS5947333A/en
Publication of JPS5947333A publication Critical patent/JPS5947333A/en
Publication of JPS6112007B2 publication Critical patent/JPS6112007B2/ja
Granted legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

PURPOSE:To obtain a high-tension cold-rolled steel sheet having good drawability and aging resistance, by hot-rolling a steel slab having the specific compsn. contg. C at an extra low rate and having regulated B/N under specific temp. conditions then subjecting the slab to cold rolling and continuous annealing. CONSTITUTION:The steel slab contg. <=0.0040wt% C, <=0.60% Si, <=0.80% Mn, 0.035-0.15% P, 0.008-0.090% SolAl, 0.0005-0.0050% B, 0.0010-0.0050% N, 0.2-1.0 B/N, and the balance Fe and unavoidable impurities, and contg. 0.002- 0.02 total of >=1 kinds among Ti, Nb, V, Zr according to need is heated to <=1180 deg.C. The heated slab is hot-rolled at 680-830 deg.C finishing temp. and <=650 deg.C coiling temp., and is then subjected to cold rolling followed by continuous annealing. The high-tension cold-rolled steel sheet having excellent drawability and aging resistance is effectively produced by above-mentioned method even if the finishing temp. for hot rolling is the Ar3 transformation point or below.

Description

【発明の詳細な説明】 本発明は絞り性、耐時効性の良好な高張力冷延m板の製
造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a high-tensile cold-rolled m-plate having good drawability and aging resistance.

絞り性の良好方晶張力鋼板に従来箱焼鈍法により製造さ
れているが,箱焼鈍法でνま処理日数に数日ケ要するの
み力らず,コイル状態の1−!t.熱処理されるためコ
イルの半径方向で加熱,冷却速)8.が異なり,コイル
全体に亘って均等な材質ゲイけることが困難であった。
Conventional box annealing is used to manufacture square tensile steel sheets with good drawability, but the box annealing process requires several days for the process, and the coil state is 1-! t. 8. Heating and cooling speed in the radial direction of the coil due to heat treatment. This makes it difficult to maintain a uniform material gain over the entire coil.

連続焼鈍法によh.ば、箱焼鈍法(/(よふ上記の欠点
ケ!+’(消−Jることが01能であるが、一方急速加
熱、急速冷に11処叩含−伴々うため。
By continuous annealing method h. For example, the box annealing method has the disadvantages of the above-mentioned drawbacks. However, it is possible to perform the box annealing method, but on the other hand, it involves rapid heating and rapid cooling.

結晶粒の成長性が悪く、また世中4C固浴しているCの
析出が不十分のため硬りtLであって高張力鋼イIvと
して要求j il、る35にり/nJ以−]−の引張強
1貞)−は比較的容易に達成pノ1.るものの目的とす
る絞iノ性、耐時効性において箱焼鈍法VCよる成品に
比し劣るのが通常であった、 連続焼鈍法による上記欠点ケ屓消1−るlこめに従来と
も神々の対策が開示されている。例えはCMが0.01
〜()1取量%のアルミキルドR)K強化元素としてP
、Mn、Si等ケ中独もしくけ相合わぜて615加した
鋼を用い、熱間Lト帆時高温−(゛合11Xることによ
り絞り性に有利な方位の結晶粒の成長を促進はせ、力)
つ連続焼鈍中!6!、司冷却後訛−300〜5()0℃
の渦電範囲で数秒乃至数分間過時効処理ケ行なうことに
より、未析υ1の固溶C(7)析11.’+を促進させ
耐時効性全改善する方法が開示ζ力、ているが、この方
法による熱延時の、1−11?品巻J8!は、当然の結
果としで酸洗性の低下全招き、また絞り性および耐時効
性においても従来の箱焼鈍材には未だ及ばない。
Due to poor growth of crystal grains and insufficient precipitation of C, which is present in the 4C solid bath, the hardness is tL, which is required for high tensile strength steel IV. The tensile strength of -1) is relatively easily achieved. Although it is usually inferior to products made by box annealing method VC in terms of drawing properties and aging resistance, the continuous annealing method eliminates the above drawbacks. Countermeasures have been disclosed. For example, CM is 0.01
~() 1% aluminum kill R) P as K reinforcing element
, Mn, Si, etc. are added to the steel at 615°C, and during hot rolling, the growth of crystal grains in an orientation favorable to drawability is promoted. power)
Continuous annealing in progress! 6! , Tsukasa after cooling -300~5()0℃
By carrying out over-aging treatment in the eddy electric range for several seconds to several minutes, the undeposited solid solution C(7) 11. 1-11? A method for promoting ζ-strength and completely improving aging resistance has been disclosed, but 1-11? Shinamaki J8! As a natural result, this results in a complete decline in pickling properties, and the drawability and aging resistance are still inferior to conventional box annealed materials.

また、連続焼鈍狗の耐時効性を悪化はせている主原因は
周界C量が多いことから、C含有m全0、0050%以
下に低減した極低炭素鋼を素4Aどじで用贋耐時効性を
向上芒ゼる方法も1是案略オ]、ている。しかし絞り性
鋼板の製造には一般に熱延仕上ケAr、変態点以上の温
度で終了をせることが必須と芒れており、上記の如き極
低炭素4$■では耐時効性については有利であるが+ 
A r B変態点を上昇芒せるので熱延仕上時にAr、
変態点以上のγ域で圧娘仕上ケ終了させるためVCは、
必然的[素ロスラブの加熱温度の上昇を伴ない、そのた
め熱延の圧下スケジュールの変更全余儀なくされ、省エ
ネルギーの面より大きなマイナスとhる。
In addition, since the main reason for the deterioration of the aging resistance of continuously annealed steel is the large amount of peripheral C, ultra-low carbon steel with a C content reduced to less than 0.0050% is used in plain 4A etc. There are also ways to improve aging resistance. However, in the production of drawable steel sheets, it is generally necessary to finish the hot rolling at a temperature above the transformation point, and the ultra-low carbon 4$■ mentioned above is not advantageous in terms of aging resistance. Yes, but +
Since the A r B transformation point can be raised, Ar,
In order to complete the indentation finish in the γ range above the transformation point, VC is
This inevitably involves an increase in the heating temperature of the bare slab, which necessitates a complete change in the hot rolling reduction schedule, which is a bigger disadvantage than the energy saving aspect.

連続焼鈍拐の耐時効性を悪化芒せている他の原因は鋼中
に固溶しているNである。同浴Nケ低減する方法として
は、アルミギルド鋼片を熱延仕上温度取りしAハとして
固定する方法、もしくは高温巻取による酸洗性の悪化を
避けるためアルミギルドfA IF、 2 Q 〜5 
(1ppnl(7) [3y 添加し2、)3 Nとし
7 Nを固定し1へ温巻取lせずV(これと同質の耐時
効性を得る方法も知ら)′1.ている。
Another cause of deterioration in the aging resistance of continuous annealing is N dissolved in the steel. As a method to reduce the number of baths, aluminum guild steel slabs can be hot-rolled to a finishing temperature and fixed as A, or aluminum guild fA IF, 2 Q to 5 can be used to avoid deterioration of pickling properties due to high-temperature winding.
(1 ppnl (7) [3y added 2,) 3 N, 7 fixed N, hot winding to 1 V (I also know of a method to obtain the same quality of aging resistance)'1. ing.

かくの如く、固?i′(C,N[jる耐時効性の改善お
よび絞り性、延性の同一1ニケ目的と[7て、アルミキ
ルド鋼の高温巻取、また品温巻取によらないB添加、ア
ルミキルド鋼のCを(1,(11%以下の極低炭素鋼と
し、こオしらの鋼のスラフ加熱温度ふ・よび熱延条件を
適当に組合わせる数多くの方法が開示芒れているが、絞
り性、耐時効性ともすぐf′シた高張力冷延鋼板のル′
I造力法としてt:l熱々J〔仕上温珪りが著しく高温
である等未だZi JA−t−べき方法であるとは断じ
難い現状である。
Like this, solid? i′(C,N [j) Improving aging resistance and improving drawability and ductility. C is (1, A high-strength cold-rolled steel sheet with excellent aging resistance.
At present, it is difficult to conclude that the t:l hot J[finishing temperature is extremely high temperature] method as an I force-building method.

不発明の目的は、上記従来技術の欠点を克服し熱延仕上
温度がAr3変態点以−1・であっても、イノ[来のA
r、変!π点以上の仕−に温1)にて製1告これたτl
t%張力鋼板と同程度もしくはそノL以七ゲ)すぐね5
だ絞り性と面1時効性ケ併せ有する高張力冷延鋼板の効
果的な?!造方法を提供するにある。
The purpose of the invention is to overcome the drawbacks of the above-mentioned prior art, and to provide an inno [next A
r, weird! τl manufactured at temperature 1) above the π point
Same level as t% tensile steel plate or more than that L) Immediately 5
What is the effectiveness of high-strength cold-rolled steel sheets that have both drawability and surface aging properties? ! to provide a method of construction.

本発明のこの目的はF記扱旨σ)2発明によって達成ネ
7する。
This object of the present invention is achieved by the F-2 invention.

第1発明の要旨とするところは次の如くである、すなわ
ち2重量比にてC: 0. (1040%匂、下、 S
i: 0. (i 0%以下、Mn:0.80%以下、
P : (+、(135〜0.15%、  5o7A/
’、 : 0.008〜O,(+ 9 (1%、B:0
.0005〜0.0050%、N:O1](110〜0
.0(150%を含み、かつB/N = 0.2〜12
であり、残部けFeおよび不可避的不純物より成る儒ス
ラブffi 1801:以下の温度に加熱した後、熱延
仕上温度金680〜830℃、巻取温度全650℃以下
とする熱間圧延ケ行ない1次いで該熱延宿根を冷間圧延
した後連続焼鈍を施すこと全特徴とする絞り性、耐時効
性の良好な高張力冷延鋼板の製造方法、である。
The gist of the first invention is as follows: C: 0.2 at a weight ratio of 2. (1040% odor, bottom, S
i: 0. (i 0% or less, Mn: 0.80% or less,
P: (+, (135~0.15%, 5o7A/
', : 0.008~O,(+9 (1%, B:0
.. 0005-0.0050%, N:O1](110-0
.. 0 (including 150% and B/N = 0.2-12
1801: After heating to the following temperature, hot rolling is carried out at a finishing temperature of 680 to 830°C and a total coiling temperature of 650°C or less. This is a method for producing a high-strength cold-rolled steel sheet with good drawability and aging resistance, which is characterized in that the hot-rolled stud is then cold-rolled and then subjected to continuous annealing.

第2発明の要旨とするところは次の如くである。The gist of the second invention is as follows.

すhわち、上記第1発明と同一基本組成のほかK。That is, in addition to having the same basic composition as the first invention, K.

更KTTi 、 Nb、 V、Z「のいずれか1種もし
くは2棟以上ケ合計附で0.002〜002%を含有し
、カッB/N = 0.2〜1. Ofあり、残?f1
5 if Feおよび不UT)Iit的不純物より成る
鋼スラブe*x】発明と同−条件6Cてρ〜延、冷〃I
Lおよび連k(1,た゛εεクンltHすことfX−’
?!+徴とする絞り性、釦時効件σ)良好に高張力冷÷
1Σ鋼板の製で1方法、である。
Contains 0.002 to 002% in total of any one or two or more of KTTi, Nb, V, and Z, and has B/N = 0.2 to 1. Of, remaining?f1
5 If Fe and Iit impurities e *
L and k(1, εεkunltH and fX-'
? ! + Signs of drawability, button aging condition σ) Good high tension cooling ÷
It is made of 1Σ steel plate and has 1 method.

本発明者らは数多くの′p!:験々・Φ;1〕だ結果I
C113、Nの成分範囲ケ規制し1.史にイ′;ソり性
、耐時効性ケ劣化ζせること庁く強を埃を向上心−b2
:、元素とし千PおよびSiを添加(、た極低炭素アル
ミキルド鍔上ロケ用い、スラブ加熱温)Wと熱妙崇件ケ
楢正νこ州合わすことVこより、熱延時Ar、4態点J
−ノ下の低温仕上、低温巻取でも連Hモ!”Li屯υr
よって絞り性オ?よひ耐時効性とも良好力高飛力冷延犯
板が侑らjすることを見出し、木):Jlt明l・完成
−するに至ったものである。
The inventors have obtained a large number of ′p! :Experience・Φ;1〕Result I
Regulating the component range of C113 and N1. Historically, there is no possibility of deterioration of warpage resistance and aging resistance.
: Adding 1,000 P and Si as elements (Using ultra-low carbon aluminum killed tsuba top location, slab heating temperature) W and Netsumyosu matter Naramasa ν Koshu combining V, Ar during hot rolling, 4 states J
Low-temperature finishing at the bottom, continuous H even during low-temperature winding! “Li tun υr
So, is it a squeeze? It was discovered that the cold-rolled steel plate had good aging resistance and good strength, and was completed on Thursday.

本ざi−明の詳イIIIならひ(ζ限定理由ケ不5I〕
明省らが行なつグこ実験結果に基いて記載する。
Honzai-Mei details III Narahi (ζ limited reason 5I)
The following description is based on the results of an experiment conducted by Meisho et al.

木発明者′鴇の行った各実験は、C,Aノ)、N、13
等の一含有扇をそれぞれゲ・SυC[7,かつPヶ()
07〜0()8%の範囲で添加L f(小型61F1塊
全実1倹室的に製作し1分塊圧延で30燗厚6)スラブ
とし、各スラブの加熱源;Wと熱延仕上温度ケ斐fヒ芒
止で2.8門σ)熱延板とし、直ちに530℃に加熱り
、た炉に装入し、2時間保持後炉中で徐冷する熱延板の
巻取ンミュレートゲ行った。次いで酸洗後0.8 vm
に冷間圧延し、更に800℃の流動層式熱処理炉に各供
試料を装入し、加熱速度約50℃/’ sec Vcて
板温が800’Cに到達後15秒保持し、その後冷却速
朋約2 (1℃/ seeにて急冷する連続焼鈍を行っ
た後1.0%σ)既刊圧延を施した冷延U’ I’rつ
いて1宵を1凋査1−る方法ケ採った。
The experiments conducted by the wood inventor 'Toki are C, A, N, 13.
Each one containing fan such as ge・SυC [7, and P ()
Addition of Lf in the range of 07 to 0()8% (one small 61F block made in one room and rolled in one block to a thickness of 30 mm), heating source for each slab; W and hot rolling finish. Temperature scale: 2.8 mm (σ) at 530° C.) A hot-rolled sheet is heated immediately to 530°C, charged into a furnace, held for 2 hours, and then slowly cooled in the furnace. went. Then after pickling 0.8 vm
After cold rolling, each sample was charged into a fluidized bed heat treatment furnace at 800°C, heating rate was approximately 50°C/'sec Vc, and after the plate temperature reached 800'C, it was held for 15 seconds, and then cooled. Approximately 2 (1.0%σ after continuous annealing with rapid cooling at 1℃/see) Ta.

実験 I rl’(’−fN’、比にてC: (1,0024%、
I\in : 0.46%。
Experiment I rl'('-fN', C in ratio: (1,0024%,
I\in: 0.46%.

Si:Q、21%、)’:O,(171%、S:0.0
11%、At: 0.040%ケ基準組成とし、こil
−にN:()、 OOI D〜O,(+ (+ 8 (
1%、L(:0.0(103〜0、0080%の範囲で
変化させた鋼塊を実り検案的に溶製し、上記の如(30
thnn厚のスラブとし、スラブ加熱温度を1100℃
、熱延仕上温度を760℃、巻取相当温度530℃の条
件で熱延を終了し、その後上記工程により冷延、連続焼
鈍[、また供試材について材質特性を調泥した。第1図
にBとNの変化Uζ伴なう時効指数(以1・−八、1.
と称する)の変化ン・示11.第2図に13とNσ)p
、化に伴々う7値の変化を71マし、いずハも図中の6
字にそれぞjl−A 。
Si: Q, 21%, )': O, (171%, S: 0.0
11%, At: 0.040% standard composition, coil
- to N: (), OOI D~O, (+ (+ 8 (
1%, L(: 0.0
The slab is thnn thick and the slab heating temperature is 1100℃.
Hot rolling was completed under the conditions of a finishing hot rolling temperature of 760°C and a coiling equivalent temperature of 530°C, followed by cold rolling and continuous annealing according to the above steps [and the material properties of the test materials were adjusted. Figure 1 shows the aging index (hereafter 1.-8, 1.
11. Figure 2 shows 13 and Nσ)p
, the change in 7 values due to the
The letters are jl-A.

1、およびフイHr−rの61.115?値であZ、。1, and 61.115 of Hui Hr-r? The value is Z.

庁ふ〜、こ引、らの・11(試イAの引張強1i1: 
Ilゴすべで38〜42にり/−の範囲内であった。
Agency Fu~, Kohiki, Lano・11 (Tensile strength of test A 1i1:
It was within the range of 38 to 42 yen/- for Il gobe.

に記の如く、絞りイテ1゛オ、・よひ而Iu、7′イh
性の尺I現としてそ)1ぞt1〜7仙およ()・ノ\、
14.・用いたが、A、I。
As stated in
As the scale of sex, it is) 1, t1 to 7, and (), ノ\,
14.・I used A, I.

H−7,5%の予企みケ与えyt th I (+ (
1℃−c :J、 (1分の促jイ(時効ケ行々い1降
伏応力の」1昇[11ケもって示したものであり、A、
1.  ≦31・り/ J VなオLは耐萌タノl性r
1箱焼鈍拐と同等であって、室温での時効はほとんど無
視でき、A、1.≦、41(り/−のi!f+、囲でも
第tλI、での[Il1効の進み方0」遅く、′−51
刃l11一時幼性は間h1[1とならないので不実験で
i・;t A、 t、≦4にり/−ケ基j、I、qどし
た。、また毅りり1ト會示すτ11r:’、 r、を従
来の荀焼911でイ4すられる絞り用in+t Il、
’?効性商張カて白4JV!と同等の拐賀として7値≧
1.3を柚亭と1.た。
H-7.5% of the plan is given yt th I (+ (
1℃-c: J, (1 minute increase of 1 yield stress [11 points), A,
1. ≦31・ri/J V O L is Moetano L resistance r
It is equivalent to one box annealing and the aging at room temperature can be almost ignored.A.1. ≦, 41(ri/- i!f+, also in the tλI, [Il1 effect progresses 0''slow,'-51
Since the blade l11 temporary immensity does not become h1[1, i・;t A, t, ≦4, /-ke groups j, I, q were set without experiment. , and τ11r:', r, which shows the resolute 1-ton meeting, is the in+t Il for drawing which is made by the conventional Shun ware 911,
'? Effective trading power white 4JV! 7 value ≧ as equivalent to
1.3 with Yuttei and 1. Ta.

第1図、第2図において、い1″J1もΔ、I3.C。In Figures 1 and 2, I1''J1 is also Δ, I3.C.

1)、Eで囲才れた範IJjl l[ソノ’1.(’ 
ft A、 I、 ≦41<g /−1〒≧1.3の耐
時効性、絞り性の良好な範囲である。而して第1図、第
2図に、l、−いて、いず力、もW 紳A B id 
T3 / N = 0.2 k 示L 、 +i’j 
糾1.) E Id B /N = 1.0を示し、B
の下限を示すC点は[3=0、0 (l O5%、Bの
上限ケ示すE点は13=Q、旧)50%であるのでIl
 H’ O,(1(105〜0゜0 (150%の61
1)囲に限定すべきであることが判明した。
1), E range IJjl [Sono'1. ('
ft A, I, ≦41<g/-1〒≧1.3, which is a good range of aging resistance and drawability. So, in Figures 1 and 2, l, -te, Izu force, also W gent A B id
T3 / N = 0.2 k Indication L, +i'j
Conclusion 1. ) indicates E Id B /N = 1.0, and B
Point C, which indicates the lower limit of
H' O, (1 (105 ~ 0゜0 (61 of 150%)
1) It was found that the following should be limited.

寸た。こノ1.て対応するNの下限はC,I)点の0.
0010%であり、上限にA、14点の0.(1050
%であるのでNの含有財ケ0.0010〜0.0 (1
50%π限χピすべきであることが判明し7た。なお、
現在のl’M M4技術の点よりもへの下限&、I’ 
0.0010%であり、才だ第2図より明らかなとおり
、Nの菖”有田が0.0(150%ケ越えて多くなると
、焼鈍時の結晶粒の成長ケ著しく抑制御/ r値が13
未満と万り絞り性?著しく低下させるのでNの含有柘”
vlこの理由から0.0 (l ] (1〜f)、 0
050%の範囲に限定すべきであり、絞り性の一層の向
上のためには好ましくはNは(1,0040%以下が望
寸しい。
Dimensions. This 1. The corresponding lower limit of N is 0.
0010%, A at the upper limit, 0.0 at 14 points. (1050
%, so the N content is 0.0010~0.0 (1
It was found that 50% π limit χ pi should be used7. In addition,
Lower bound to &,I' than the current l'M M4 technology point
As is clear from Figure 2, when the N content exceeds 0.0 (150%), the growth of crystal grains during annealing is significantly inhibited. 13
Is it less than a million yen? Because it significantly reduces the
vl For this reason 0.0 (l ] (1~f), 0
In order to further improve the drawability, N should be limited to a range of 1,0040% or less.

また上記13景については、)3添加の効果ケ出ζぜる
には最低(1,00(15%の添加全必要々する。
Regarding the above 13 scenes, the total addition of (1,00 (15%) is required at least) to achieve the effect of adding (3).

rI 1r−t 〕% Ujff焼鈍ロノ而1[面S効
性IF イi ’;Q )i N k 固定1. 。
rI 1r-t ]% Ujff Annealing Ronoji 1 [Surface S effectiveness IF i';Q ) i N k Fixed 1. .

用π形成智れたザヴ化物σ)1.3 Nが・j情神1時
の結晶粒度J5七C)抑制力が咋めて小さいことにより
校りゼ1:の11v7(πも効果がt)るものと考えr
−)i’+る。この焼σ屯11斤の結晶粒成長のflf
fゴIf; K 4)Iノ果Q)あるH fN hiに
も適iE「1・れ囲が存在し、Bが0. (1(15(
1%を越λ−るが、叶fr、に、t 13 / Nカ1
.0 kLL’li、Rl) 13 IN i jvr
1固i’ffLTいる++が増加い尭鈍萌の結晶4)7
. I、1li−+ぐにがえってイ〒′frとなり良好
な材ノt1がイ・Iられない。寸た[3 /へが過小と
なって02よりIJ(くなるとイ1効なオJ”+出物7
)テ極>’:RI’こ少なくな2・のて絞り性」、・よ
ひ面1時効4′1゛の向ヒに効果がないので、木)1′
1、門で&j: I(/’ Nを(1,2−10の+7
・ぺ囲に限5iシた。
The crystal grain size J57C) when π formation is known for 1.3N is 11v7 (π is also effective) because the suppressing force is very small. t)
-)i'+ru. flf of grain growth of this baked σtun 11 catties
f Go If;
Although it exceeds 1%, t 13 / N 1
.. 0 kLL'li, Rl) 13 IN i jvr
1 solid i'ffLT ++ increases 孭 dull moe crystal 4) 7
.. I, 1li-+ becomes stiff and becomes 〒'fr, and the good material t1 cannot be removed. Dimension [3 / becomes too small and IJ from 02 (when it becomes I1 effect OJ" + appearance 7
) Te pole>': RI' is small 2. It has no effect on the direction of 4'1' aging, so wood) 1'
1, &j at the gate: I(/' N(1, +7 of 2-10
・5i was limited to Pekai.

なお、スラブ加熱時詮−13と化合せずに残ったNは、
スラブ加熱時おまひと(間ハ帆時υこA/−と結t(し
てA7Nと12で析出するσ)で1nlj’ H4Hク
ツ1性にとってなんら有害となら々い。
In addition, the N that remained without combining with So-13 when heating the slab was
When heating the slab, there is no harm to the properties of 1nlj' H4H shoes due to the difference between υko A/- and t (and σ precipitated by A7N and 12).

上記本発明におけるU、Nおよびl−3、/ Nの限定
理由を本発明者らの実1も・・I結果にAζ−いて説明
したが。
The reason for limiting U, N, and l-3, /N in the present invention was explained by referring to Aζ- in the present inventors' actual results.

その他の成分についても本発明者らの実験結果に基いて
、その限定理由を説明する。
Regarding other components, the reasons for their limitations will be explained based on the experimental results of the present inventors.

5otAt : AtはBにより固定されなかったNを固定するために少
くとも0.008%ケ必要とする。(2かし。
5otAt: At requires at least 0.008% to fix N that was not fixed by B. (2 but.

A7’(14過剰bτ添加すると固溶状態で存在するA
tが増加し、焼鈍時の結晶粒成長が著しく13目害キi
L絞り性全劣化づせるので、その上限i 0.090%
にし0.0 (18〜0. (190%に限定した。
A7' (14 When excess bτ is added, A that exists in a solid solution state
t increases, and grain growth during annealing becomes significant.
The upper limit i is 0.090% since it completely deteriorates the L drawability.
It was limited to 0.0 (18 to 0. (190%).

C: Cは伺・咽の強度を向上させるのに有効な元素であるが
、多量に含まれると絞り性に有利な方位の結晶粒の成長
を抑制するばかりでなくh鋼中に固溶して耐時効性ケ著
しく劣化させるので少いほどよく、そノil!R’z 
(1,0040’/、 、!: シフjカ、 art 
1.イ範囲一(1,00・3()%以下である。
C: C is an effective element for improving the strength of the steel, but if it is included in large amounts, it not only suppresses the growth of crystal grains in orientations that are advantageous for drawability, but also forms a solid solution in the steel. Aging resistance deteriorates significantly, so the less the better! R'z
(1,0040'/, ,!: Shifujka, art
1. A range of 1 (1,00.3()% or less).

Mn : Mnも岨の強度を増加するに有効な元素であるが。Mn: Mn is also an effective element for increasing the strength of the core.

0、80%を越して過多となると絞り性な・劣化坏せる
ので、その上限全0.80%とした。
If the amount exceeds 0.80%, the drawability will deteriorate, so the upper limit was set at 0.80%.

Pは一ヒ記実験Iから明らか庁とおり、絞り性を劣化ジ
せることなく強度を一ヒ昇略せるに最も不動な元素であ
る。従って本発明の目的とする3 5 kp/−以上の
引張強きケイ4Iるために少くとも0035%を必要と
する。しかl−過剰の添加は溶接性の劣化をもたらすの
でその上限1−0.15%とした。かくの如くかなり大
附のPヶ添加→4しめたことが本発明の特徴の一つであ
ってP (r fl、035〜015%の範囲内で調節
することにより35〜5 (l l<7 / yaの引
張強fil f有ぜしめて、なおかつ絞り性、耐時効性
の良好な高張力m根を製造fることができる。
As is clear from Experiment I, P is the most stable element that allows the strength to be increased without deteriorating the drawability. Therefore, in order to achieve a tensile strength of 35 kp/- or more, which is the objective of the present invention, at least 0.035% is required. However, since excessive addition of 1- causes deterioration of weldability, the upper limit was set at 1-0.15%. One of the features of the present invention is that a considerably large amount of P can be added →4. It is possible to produce a high tensile strength root having a tensile strength of /ya and having good drawability and aging resistance.

Sl: Siは八−Inと同様に鋼の強t+slの十ケIVcイ
A効な元素であるが、(1,60%2.− d:+lJ
すと絞りllh ’r劣化せしめるのでo、6oLA以
下に限シピした。
Sl: Like In, Si is an element that is effective at increasing the strength of steel, t+sl, but (1,60%2.-d:+lJ
Since it causes deterioration of the aperture, I limited it to o, 6 o LA or less.

S : Sの含イ= M: Kついてtj特に限定しないが1曲
常の製徊工程で不可避的Vこ残留する範囲の8:0、 
C12(1%以下であilは本発明の目的連成に悪影響
を及ばずものではない。
S: Contains S = M: K and Tj are not particularly limited, but it is 8:0 in the range where V remains unavoidable in the usual washing process,
C12 (il at 1% or less does not adversely affect the objective coupling of the present invention.

上記本発明の目的とする引張ヴ)1度35〜5 (l 
kg/−全確保した上で絞り性、耐時効性のすぐ力、た
高張力冷延鋼板を得る鋼の基本組成の限定理由について
説明【−だが、これらの限定成分に効果を発揮させるた
めには以下説明する鋼スラブの加熱温度、仕」二圧延温
度および巻取温度の影響するところが犬であり、特に極
低炭素鋼スラブのN、IJの有効材については上記熱延
条件が適正であって初めて効果が発揮これるものである
ので、以下これらの熱延2y件について説明する。
The above-mentioned tensile force as the object of the present invention) 1 degree 35~5 (l
Explanation of the reasons for limiting the basic composition of steel to obtain high tensile strength cold-rolled steel sheets with drawability, aging resistance, and instant strength after ensuring all kg/- [-However, in order to make these limited components effective, The heating temperature, final rolling temperature, and coiling temperature of the steel slab, which will be explained below, have a significant influence on the heating temperature, and the above hot rolling conditions are particularly appropriate for N and IJ effective materials of ultra-low carbon steel slabs. Since the effect can only be achieved when hot rolling is carried out, these 2y hot rolling cases will be explained below.

先すスラブの加熱温間について&、t、;σ↓′畠σ)
スラブ加熱温度である1250〜13011 ’Cより
低い1180 ℃以下であることが必要である。その理
由はこの1品度範囲ではB Nの溶解が起らず、13は
全量BNとして固定烙れでいると考えらil7.こσ)
状態が焼鈍時の結晶粒の成長に好捷しい影響を与え、か
つB Nとして固定された残部のN =i Atにより
AtNとして固定するためにも必蛯な温IW範囲である
からである。スラブ加熱温度のト限に!1ケに限定し2
2いが、圧延性σ)点グハ’]95 (1℃以上が望・
1F、〈1本発明の[]]的jヤ成Vロ1(100〜1
160℃の加熱温度がt1″+鏑である。
Regarding the warm heating of the first slab &,t,;σ↓′Hatakeσ)
It is necessary that the heating temperature be 1180°C or lower, which is lower than the slab heating temperature of 1250 to 13011'C. The reason for this is that BN does not dissolve in this one grade range, and 13 is considered to have a fixed heat with the total amount of BN. koσ)
This is because the temperature IW range has a favorable influence on the growth of crystal grains during annealing, and is also necessary for fixing as AtN due to the remaining N = i At fixed as BN. To the limit of slab heating temperature! Limited to 1 piece 2
2, but the rolling property σ) point is 95 (desired to be 1°C or higher).
1F, <1 of the present invention []]
The heating temperature of 160° C. is t1″+kabura.

D、Vpy〜延什−F、 +7+M W k 68 (
1〜83 (1℃]範囲vr限M L、た理由について
説、明する。
D, Vpy ~ extension - F, +7 + M W k 68 (
1 to 83 (1°C) range vr limit M L, the reason will be explained and explained.

従来、絞り用値板の11.゛ノ造6τli;、m +=
 −r i、i、箱焼鈍法および連続焼鈍法のいずれに
よる場合も熱延什上輻度fAr3変軸点以上の渦層、す
なわち全3−ステナイトJ′Fj)、(γ相)で熱延ゲ
終了するのが望ましいとされていf(つこハ、a熱机終
了温度がAr、変態「、%以下のフェライト(α相)−
1−オーステナイト(γ相)の2相域もし、5くけα域
でrン・ζ帆ケ終rすると絞り性に不利な(J 1 (
1)および(] On )方位が板面に平行に発達(7
,・焼鈍時に政り性に有利h(111)方位全板面に平
行に発作をせるのを阻害すると智れていたことによるも
のである。
Conventionally, the aperture value plate 11.゛nozo6τli;, m +=
-r i, i, hot rolling in both the box annealing method and the continuous annealing method, with a vortex layer above the hot rolling radiance fAr3 inflection point, that is, all 3-stenite J'Fj), (γ phase) It is said that it is desirable that the heating end temperature is Ar, and the transformation is less than % ferrite (α phase).
In the two-phase region of 1-austenite (γ phase), if the 5-phase α region is r-n and the ζ-layer end-r is used, it will be disadvantageous for drawability (J 1 (
1) and (] On ) orientation develops parallel to the plate surface (7
This is because it was known that during annealing, the h(111) direction, which is advantageous for politics, inhibits the formation of heat parallel to the entire plate surface.

こ#1. &で対し本発明者らは以−トVrc循明する
実験Hにより上記本発明による特定Hg11成、の創1
板にお(へ)る焼鈍時の結晶粒の成長性、的にAFi而
に平行に(111)方位ゲ発述智−bるKけ熱机什−]
二温度が680〜830 ℃の温度範囲であることがき
わめて有効であることを見出した。
This #1. In contrast, the present inventors conducted experiments H that circulated since Vrc to create the specific Hg11 formation according to the present invention.
The growth of crystal grains during annealing in the plate, the (111) orientation is parallel to AFi.
It has been found that a temperature range of 680 to 830 DEG C. is extremely effective.

実;倹 ■ C: 0. O(116%、Mn:Q、41%、  S
i : 0.48%、t’:o、o76%、S’0.0
16%、A/−:0、 (121%、N:0.0037
%、B:0.0(129%、B/N=0.78の組成ケ
有する小型価塊を溶製し、実験Iと同様に30埴厚のス
ラブとシ2.スラブ加熱温度1120℃に加熱後仕上温
度ヲ650〜930℃として28門厚の熱延板とし、的
らに530℃の炉に装入し2時間保持後炉中で冷却する
ことにより熱延板の低温巻取に相当する処理1行なった
。才た一部の供試劇について幻比較のため仕上熱延後6
80℃の炉中に装入し2時間保持後炉中冷却する熱延板
の高温巻取相当処理を行った。酸洗以後の工程は前に記
載した本発明者らの7般実験工程と同様にして連続焼鈍
による冷廷相を製造した。結果に第3図(A)、(13
1に示すとおりである。第3図(5)、(B)において
○印は530 ℃の低温巻取全行ったものであり、×印
Vi680℃の高?L?1巻取4・行ツタもので;h 
Zl。;7)、 3図(A)、(Ill 、1:り明し
)か力とおり、t!シ延仕にj晶度ケ68()〜83 
(1℃で終了した場・43に〒領)λきわめて良q「例
なることか判明した。この事実は絞りI’1.O’l 
&の11・4造には一般V?熱延仕上17Ar、変態点
以にσす1、!t jB:で終了す2・ことが必〕Jど
されていた従来の′l’i’+ 識ケ破る本発明の大き
な効果である。
Real; frugal ■ C: 0. O (116%, Mn:Q, 41%, S
i: 0.48%, t': o, o76%, S'0.0
16%, A/-: 0, (121%, N: 0.0037
%, B: 0.0 (129%, B/N = 0.78) A small lump having a composition of After heating, the finishing temperature was set to 650 to 930°C to form a hot rolled sheet with a thickness of 28 gates, which was then charged into a furnace at 530°C, held for 2 hours, and then cooled in the furnace, which corresponds to low-temperature winding of a hot rolled sheet. One treatment was carried out for some of the test pieces.After finishing hot rolling for visual comparison,
A hot-rolled sheet was charged into a furnace at 80° C., held for 2 hours, and then cooled in the furnace, which was equivalent to high-temperature winding. The steps after pickling were the same as the seven general experimental steps of the present inventors described above to produce a cold phase by continuous annealing. The results are shown in Figure 3 (A) and (13
As shown in 1. In Fig. 3 (5) and (B), the ○ mark indicates that all winding was performed at a low temperature of 530 °C, and the × mark indicates a high temperature winding of 680 °C. L? 1 roll 4 rows of ivy; h
Zl. ;7), Figure 3 (A), (Ill, 1: Reveal), t! Crystallinity 68 () ~ 83
(If it ends at 1℃, 43 degrees) λ Very good q ``It turns out that this is an example.
General V for &'s 11.4 building? Hot-rolled finish 17Ar, σ1 above the transformation point! This is a great effect of the present invention, as it breaks through the conventional 'l'i'+ convention, which required that it end with tjB:2.

若干低下するが、高張力付’l A5v ltl pν
氷心れZ、 35 kり/−以上ゲ+り〕満足している
のて本発明においては熱延仕」:温1現を680〜83
 (1℃の範囲に1(JJ定した。
Slightly lower, but with high tension 'l A5v ltl pν
[Ice core Z, 35 kri/- or more] Satisfied, in the present invention, hot rolling process: 680 to 83
(JJ was determined in the range of 1°C.

かくのan < lrg定の低6情イl’ L nln
 出−IFj’1.囲T I’ 1的がJt−7加する
理由Vこついては明らかで(、Jないが、熱延仕−ヒは
時にAr、変態点以1・の低llI、Xl仕Lすπより
、熱延什には時に専入坏り、7こ加上作・みの−・LI
、lXが、そσ)まま常温になった後も・閉持σノ上、
かつスラフ加熱温度ケ1180℃以下と従来」、り低温
にすることにより、r3N、Aハ庁どの4ノ1出物が1
−)1人化1−るため、これらの相乗効果により絞り性
1/rイT利なj(4合組織が発達することによるもの
と考えらり、 z−、。
This an < lrg fixed low 6 information l' L nln
Out-IFj'1. The reason for the addition of Jt-7 to T I'1 is obvious (although it is not J, hot rolling is sometimes carried out using Ar, low llI, Xl below the transformation point, There are also 7 works, Mino, and LI.
, lX remains unchanged σ) even after it reaches room temperature,
In addition, by lowering the slough heating temperature to 1180°C or lower, which is lower than the conventional method, the 4-1 outputs of r3N, A, etc.
-) Since it is made into one person, the synergistic effect of these increases the squeezeability by 1/r.

次に熱延券取温度については、530℃で巻取った場合
と、680℃で巻取つ女湯合手−比較すると、後者tま
引張強プにおいて若干劣化の項向かあり、1斤T値にお
いては700℃ので嗅延(1十温度の基)合にやや−に
デ1.,8(10℃の−1へ延仕に1靜1仄の場合v1
やや劣化傾向な′示すも680〜83011?、の熱延
仕上温度範囲では変化なしと考えらil、る。一方高温
巻取材&′i位洸時の脱スケールコストの−に91を1
f−なう。これに対(7本発明ではAr、変態点」υ、
下の低i晶における77+、、延仕−ヒを行′/2:り
ことVでより低温で巻取っても高温巻取材と同等もしく
に引’jRJClj 8においては却って向−に傾向が
あり、かつ酸洗コストヶ低減できる効果があるので熱延
巻取渦1埃の上限を65 (1℃に限定し7た。
Next, regarding the hot-rolling temperature, when we compare the case of rolling at 530℃ and the case of rolling at 680℃, there is a slight deterioration in the tensile strength of the latter. The T value is 700 degrees Celsius, so if the temperature is 700 degrees Celsius, it will be slightly -1. , 8 (v1 in the case of 1 still 1 in extension to -1 of 10℃
680-83011 which shows a slight tendency to deteriorate? It is thought that there is no change in the hot rolling finishing temperature range of . On the other hand, the descaling cost during high-temperature winding and transportation is 91 to 1.
f-Now. In contrast to this (7 In the present invention, Ar is the transformation point υ,
77+ in the lower i-crystal, 2/2: Even if it is rolled at a lower temperature with the riko and V, it is the same as the high-temperature rolled material, but in RJClj 8, there is a tendency in the opposite direction. The upper limit of the amount of dust per hot-rolling vortex was set at 65°C (1°C) because it has the effect of reducing pickling costs.

次に本発明による前記カ一本組成のほかに’j’i 。Next, in addition to the above-mentioned composition according to the present invention, 'j'i.

Nb、V、Zrのうちからス゛べばtしたいずオLか1
オ中もり、 <は2棹以上を合計Fl”l’で0.00
2〜(102%ケ含有し、かつ1.3/N = 0.2
〜1.0であZ) job合、その他の熱延要件を11
1記と同−Ii’<’ −t Z、、こと匠より本発明
の効47+−ケより−J1’ (’Il[Lイ(するこ
と1本;I7.町名らの実!’r’Q Illによって
確r、Cす2・ことができたのでこ九πついて説、明す
る。
If you switch from among Nb, V, and Zr, it will be Zuo L or 1.
Ochumori, < is 0.00 for 2 or more sticks in total Fl"l'
2 to (contains 102% and 1.3/N = 0.2
~1.0 and Z) job matching and other hot rolling requirements to 11
Same as Section 1 -Ii'<' -t Z,, From Kotakumi, the effect of the present invention 47+-ke -J1'('Il[Lii (one thing to do; I7. Town name fruit!'r' Since I was able to confirm r and C2 by Q Ill, I will explain and explain this 9π.

″二11・(111 実1’;ti’ lの一ヶ基本組成とL 、・′色1表
に示す如くこ]1ffTi、N13.V、lrのp、 
lBj、 f添加[た叱ケ!℃空溶解Vこて実11.Q
室的に小型1「l塊ケ庁置’j’! L/ 、前記と同
様17rシて30問)早のスラブとした。このスラフケ
加熱渦度11 (10℃の加熱区δ、、+5 il、仕
上温度ゲ78 (1℃トLテ2.8 rrml、+熱I
#、4i(トシ、13jチK 5301〕の炉に装入し
2時間保持後傾+1胃1)却″1イ、ことにより熱延也
の低温巻取和尚処j」1′会行った。酸洗以?麦の工程
は実験I、■と同一てJ)る。かくの9]1くし−〔!
j丁曝造した連糸元焼1屯V(よるIlr帆、(″うの
r1直およびA、 1.(lcjは第2表に示1とおり
である。
``211・(111 Real 1';ti'l's basic composition and L, ・'Color 1 As shown in table] 1ffTi, N13.V, lr's p,
lBj, f addition [Tasuke! ℃ air melting V trowel 11. Q
In a small room, the slab was made into a small 1 "l block office location 'j'! L/, same as above, 17 r, 30 questions). , finishing temperature 78 (1℃, 2.8 rrml, + heat I
#, 4i (Toshi, 13j Chik 5301) was charged into a furnace and held for 2 hours with backward tilt + 1 stomach 1). After pickling? The process for wheat is the same as in Experiment I, ■J). 9] 1 comb - [!
1.(lcj is as shown in Table 2).

r、J’+ 1表、第2表より明らかンλ如く供試相馬
3の如きTi : 0.002 ’A kr テCト(
/’)Ik1子比’l’i /C=021のよりに倣L
4の炭化物形成元τ、の添加により〒呟がほとんど変化
し力いがA、1.値のみ低下第  21・で して卦り、更に時効性の良り、rな4:゛肩板を゛製造
する上で好ましい材質が得らノすることを示している。
r, J'+ It is clear from Tables 1 and 2 that Ti like the sample Soma 3 as shown in λ: 0.002 'A kr TeC (
/') Ik1 ratio 'l'i /C=021 L
The addition of the carbide forming element τ in A and 1. This shows that only the value decreases in No. 21, and that it is possible to obtain a material that has good aging properties and is suitable for manufacturing shoulder plates.

また供試材扁2の?lJ < ’l’i : O,(l
 o 1%含有のj勘合r値、およびA、1.質が(j
′IJ、’ht元素を含1ない本発明による基本組成の
供試(4]が1と♀く1川−で′I゛1の添加効果が見
られ々いが、こil id i’iけ不可−JE的不?
lI物と化合することIlrよりCと結合せず、A、I
Also, what about the sample material 2? lJ <'l'i : O, (l
o j fitting r value of 1% content, and A, 1. The quality is (j
Test sample (4) of the basic composition according to the present invention that does not contain ``IJ, ``ht element'' is ♀1, and the effect of addition of ``I゛1'' cannot be observed in 1 river. Not possible - JE's not possible?
It does not combine with C than Ilr, and A, I
.

値の低下fイ1効に働ハ・なかったことに−よるものと
考えられる。この傾向はTiのみならずその他の炭化物
形成元素であるNb、V、Zrにおいても認められた。
It is thought that the decrease in value was due to the fact that the effect of F was not working. This tendency was observed not only in Ti but also in other carbide-forming elements such as Nb, V, and Zr.

従ってTi 、 Nb、 V、 Zrのうちより1共ば
れた1種または2種以上の添加ijA、1.値の低減に
効果があるが、 0.002%未d111ではその効果
がないので下限y□、(1(12%とすべきであること
が判明(また。こf]、らの炭化物形成元素Ti 、 
Nl)。
Therefore, if one or more of Ti, Nb, V, and Zr are added together, ijA, 1. However, it is found that the lower limit y□, (1 (12%) should be set (also, Ti,
Nl).

V%Zrの上限ケ0.02%としたのは、これ(Y−越
す添/Jl+によっても効果が飽和心力、て無駄である
ことが判明したからである。
The reason why the upper limit of V%Zr was set at 0.02% is because it was found that even this (Y-over-addition/Jl+) had no effect because it saturated the mind and was useless.

かくの如く先VCかかげた基本組成の41かに1゛l。Like this, the basic composition of VC was 41 crabs.

1〜l〕、V、Zrのうちより3宍はれた11重またt
ユ2オ屯以上を0.0 (12〜(102%の範囲で含
イイし、かつB/N = 0.2〜1..0であり、残
部fJ、 Fc オよヒ小可避的不純物より成る鋼スラ
ブを使用L 、同一の加熱温度、熱延仕上温度1巻取温
既条件で熱延した熱延−板を同一条件で冷延し7た後連
続焼鋪ケ施すことにより1本発明の効果音一層発揮【フ
イ々することが明らかとなった。
1~l], V, Zr, 11 folds and t
Contains 0.0 (12 to 102%) or more of U2Oton, and B/N = 0.2 to 1.0, and the remainder is fJ, FcO, and small unavoidable impurities. A hot-rolled steel slab consisting of L, hot-rolled at the same heating temperature and hot-rolling finishing temperature of 1 coiling temperature is cold-rolled under the same conditions and then subjected to continuous annealing. It has become clear that the sound effects of the invention are even more effective.

連続焼鈍条YPとしてtj鋼板の最高到達温度が再結晶
温度以上であることVま当然と12で、その他の加:”
、1L1jlヱI!〔、冷却仙度貫たd過11.’ll
グツのイ1ζ、懐&でつい−Ctr、j−’1.′fK
限ボクー鮫(7庁い。
As a continuous annealing strip YP, the maximum temperature of the steel plate must be higher than the recrystallization temperature, and other additions:
,1L1jlヱI! [11. 'll
Gutsu no i1ζ, pocket & detsui-Ctr, j-'1. 'fK
Limited Boku Shark (7 offices.

実施ff11 す・r(炉出世後20分間1ull脱カス処哩ゲ施すこ
とにより第3表に示す如き成分の昇なる5’4’q(6
カの洲、・4を溶製し、連続1pj造により板厚2 (
l fl門のスラブとした。こil、らの供試:壮1を
本イI′、明V(よる118(1’c以下の104 (
1〜112(1℃の11、^Bに60分保持した後、熱
間F7’ bi T l〜IJ 、7j: (Ff) 
[jil ff) 6Hfl 〜83()℃の温度範囲
で仕上り圧4+l;ケ11°−丁17.65 (1’C
Cヒトτ黒度の53(+ 1?:で巻j19.す、1j
えI’7:(,2m門の一1机コイルとした。
Implementation ff11 S・R (5'4'q (6
KANOSU, ・4 is melted, and plate thickness 2 (
It was used as a slab for the l fl gate. Koil, et al.'s test: 118 (104 below 1'c)
1 to 112 (11, ^B at 1°C for 60 minutes, then hot F7' bi T l to IJ, 7j: (Ff)
[jil ff) Finishing pressure 4+l in the temperature range of 6Hfl to 83()℃; ke 11°-17.65 (1'C
C human τ black degree 53 (+ 1?: Volume j19.su, 1j
EI'7: (, 11 coils with 2m gate.

次に比較のため供試gti444のスラフケそtしぞれ
加熱温度] 25 (1’Cと本発明駆足外とし770
 ℃で仕上JE延を終了した試別と* 7Jl %温度
1 ]、 3. (1℃とし、熱延仕上温度ケ限定夕t
の920℃とした試料ゲ作成し比較例と(7た。第3表
匠卦いてアンダーラインした数値は本発明1/r j 
A ltj:定外売件である。かくして得斤熱に11価
1栓p、才べ一テ1讐柑−Y11,4四の53 (1℃
&τて巻取った後、同一・条件で酸拐、後08門に冷間
圧延I7.引井:〒、き;1]4耘6 )、r4神を施
した。連続焼鈍の条件1ri加力へ1Σ口賃が約211
 ’C: / Sec 、均熱は8 (l fl ℃で
20秒間(41: ’I”I’ * (t;力旨11j
’−i1約5 +1 ℃/secである。ぞ0)後06
%の+8’Al ’I’(ハ二M、 k /7illL
、 ft。
Next, for comparison, the heating temperature of the sample GTI 444 was set at 25 (1'C and 770
*7 Jl % Temperature 1], 3. (1°C, limited to hot rolling finishing temperature)
Samples were prepared at 920°C and compared with the comparative example (7.
Altj: This is an unspecified sale. Thus, Tokuko fever has 11 valent 1 stopper p, 1 valence of 1 and 1 enemy - Y11, 44 of 53 (1℃
After winding with &τ, it was acid-absorbed under the same conditions and then cold rolled I7. Hikii: 〒、ki;1】4耘6)、r4 God was given. Continuous annealing conditions: 1ri force to 1Σ mouth is approximately 211
'C: / Sec, soaking is 8 (l fl ℃ for 20 seconds (41: 'I"I' * (t; power fact 11j
'-i1 is approximately 5 +1 °C/sec. 0) 06
% +8'Al 'I' (HaniM, k /7illL
, ft.

かくしで得た?′l)机5叛Cτついてそノ1そi l
−Ji5j械的性′I′1  お よ び T 値 、
  、へ、  ■。 イ1白 イl−’  11川 5
ピ し /こ牟、′i ;、: fま 貴t 4 Yモ
(((示すとおりである。
Did you get it from hiding? 'l) The 5th Rebellion Cτ Part 1 Part 1
-Ji5j Mechanical property 'I'1 and T value,
, to ■. I1 White Il-' 11 River 5
Pi shi /komu,'i ;,: fma t 4 Ymo(((As shown.

第 4−( pa 4表より四重かな如く5本発明に上り製造された
供試fHA1,2.3,4.5はすべて引張強度35 
kf / +IIA以上の高張力冷延鋼板であると同時
に絞り性を示す?値は常に164以上と区好で、かつ耐
時効性ゲ示すA、1.値は供試m篇1〜4は4kp /
−以下の遅時効性、扁5は3に7/−以下の非時効性を
示すのに対し、本発明の1要件のみ満足しなかった供試
鉗A 4 ’およびA4″の比較鋼は7値tit 1.
3以下で悪(’、A、I、値も4にり/π4を越す値を
示しており5本発明のすべての及件ケ満足する場合にお
いて始めて絞り性、耐時効性のすぐれた冷延鋼板ケ得る
ことができることケ示している。
No. 4-(pa From Table 4, it can be seen that the sample fHA1, 2.3, and 4.5 manufactured according to the present invention all have a tensile strength of 35
Is it a high tensile strength cold rolled steel sheet with kf/+IIA or higher and at the same time exhibits drawability? The value is always 164 or higher, and A, 1. The value is 4kp for sample m editions 1 to 4.
-The comparative steels of test forceps A4' and A4'', which did not satisfy only one requirement of the present invention, showed a slow aging property of 7/- or less, and flat 5 showed a non-aging property of 3 to 7/- or less. Value tit 1.
If it is less than or equal to 3, it is bad (', A, I, and the value also exceeds 4/π4, and 5 cold rolling with excellent drawability and aging resistance is achieved only when all the requirements of the present invention are satisfied. It shows that you can get steel plate.

なお、上記本発明による供試材AI、2,3,4゜5に
ついて2%予否を与えた後、170℃に2()分間保持
の焼付塗装相当処理ケ施した処、加工硬化計を含まず3
〜5 ky / yaJの降伏点の一ヒ昇が認めらiま
た。これは焼料硬化能(B1(性)も著しくすぐれてい
ることを示すものである。
In addition, after giving a 2% tolerance to the above-mentioned sample material AI according to the present invention, 2, 3, and 4°5, the work hardening meter was measured after applying a treatment equivalent to baking paint at 170°C for 2 () minutes. Not including 3
A significant increase in the yield point of ~5 ky/yaJ was also observed. This shows that the sinter hardening ability (B1 (quality)) is also extremely excellent.

−上記実施例より明らかなとおり、本発明ハ鋼の成分を
限定し Il’biに13.NおよびB / Nケ規j
Iiす[7、かつスラブ加熱温度を1180℃以下の低
γ1冨に抑11tll t、 、仕上圧延温度全68(
)〜83 (1℃、巻取温度を650℃以−トに規制す
る一゛・1間圧ii1: f行カつた後1通常の冷間圧
帆奮施し、(、かる後急速冷却の連に〕1−1焼鈍ケ行
なうことにより、引張強へに−おいて35〜50にり/
 Vaであり、かつf値が1.3以上、A、1.値が常
温で3kf/−以下の非時効性1も(−くは4に9/−
以下の遅)11を動性l示す絞り性および耐時効性に共
にすぐれた高り1、力冷砥g4板を(47ることができ
、各種プレス用高張力冷勉り;:♂板としてすぐitた
効果が期侍芒り、る。
- As is clear from the above examples, the composition of the steel of the present invention is limited to 13. N and B/N rules
Ii[7, and suppress the slab heating temperature to 1180℃ or less, low γ1 richness11tllt, , finish rolling temperature total 68 (
) ~ 83 (1℃, the winding temperature is regulated to 650℃ or higher 1゛・1 pressure ii 1: After the f row is completed, 1 normal cold pressure is applied, (, after that, a series of rapid cooling is applied. By performing 1-1 annealing, the tensile strength increased to 35 to 50/
Va, and the f value is 1.3 or more, A, 1. Non-aging 1 with a value of 3kf/- or less at room temperature (- or 4 to 9/-
The following high tensile strength cold grinding g4 plate (47), which exhibits dynamic l and excellent drawability and aging resistance, can be used as a high tensile cold grinding plate for various presses. The immediate effect was felt by the samurai.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明な・イ()る基本実1”、4!、jにて
イiIた時効指数(A、I、値)に及Iヨす鋼中の’*
 N’Drイ」量および13 / Nの影響を示1−線
図、ゐ)72図!c、t +−ii+!+置−及はず鋼
中の[3,Nおよび13 / Nの影゛汁4・示す線図
、第3図(A>、 (I3)は熱延仕上渦1仄と、そル
そ゛ノ1.引ツJX強心(i’ S )おまひ〒値との
関係を示すFOIIIZIである。 代理人 中 路 弐 n(= 第1図 B(%) 第2図 Y イ直 B(%) 11に3  図 熱灸1イ士上シ昌L   (’C) 手続補正書(方式゛) 昭和57年−12月10日 特許庁長官 若 杉 和 夫 殿 」、事件の表示 +1fJfU 57 年  特許&1vJ157 J 
7’ 6 号2、発ゆJの名称 絞シ性、耐時効性の良好な高張力冷延鋼板の製造方法 3、 補止をする者 事件との関係 特許出願人 住 所 兵庫県神戸市中央区北本町通−丁目1査28号
名称 (125)川崎製鉄株式会ネ」 代表者 八 木 哨 7告 4、代理人〒187 昭和57年11月12日 (発送日 昭和57年11月
30日)6、 補正により増加する発明の数 6、補正の対象 図面 7、補正の内容 別紙第3図(5)、の)訂正図面のとおり。 以上
Figure 1 shows the aging index (A, I, value) of the present invention.
1-diagram showing the amount of N'Dr I and the influence of 13/N, ii) 72-diagram! c, t +-ii+! Figure 3 (A>, (I3) shows the influence of [3,N and 13/N in the steel). .This is FOIIIZI which shows the relationship between the JX cardiopulmonary (i' S) and the paralysis value. Proxy Nakaji 2 n (= Figure 1 B (%) Figure 2 Y Directional B (%) 11. 3 Diagram Heat Moxibustion 1 Ishijo Shijo L ('C) Procedural Amendment (Method ゛) 1981 - December 10, 1982, Commissioner of the Japan Patent Office, Mr. Kazuo Wakasugi, Incident Indication + 1fJfU 1957 Patent & 1vJ157J
7' 6 No. 2, Name of Hatsuyu J Method for producing high-strength cold-rolled steel sheets with good drawing resistance and aging resistance 3, Relationship with the supplementary case Patent applicant address Chuo, Kobe City, Hyogo Prefecture 28, Kitahonmachi-dori-chome, Ward Name (125) Kawasaki Steel Co., Ltd. Representative: No. 7 Yagi No. 4, Agent Address: 187 November 12, 1980 (Shipping date: November 30, 1988) ) 6. Number of inventions increased by amendment 6. Drawing subject to amendment 7. Contents of amendment as shown in Attachment Figure 3 (5). that's all

Claims (2)

【特許請求の範囲】[Claims] (1)  重量比にてC! 0.0 (14(1%以下
、Sl;(1,60%以下、Mn : 0.B □%以
T’、 P : 0.035〜0.15%、sat A
t : o、 (1(18〜Oo 9 (l z、B 
: 0.0005〜(1,0050(X;、 N : 
(Ill 01 (1〜(1,0050%を含み、かつ
137N = (1,2〜1.()であり、残部はFe
および不E’1−uiY的不純物より成る鋼ヌラブ’(
z1180℃以下の温1隻に加熱した後、熱延仕上温度
を680〜830℃、巻取温度全650℃以下とする熱
間圧延な行ない1次いで該熱延鋼板を冷間圧延した後連
続焼鈍分施すこと全特徴とする絞り性、耐時効性の良好
な高張力冷延m板の製造方法。
(1) C in weight ratio! 0.0 (14 (1% or less, Sl; (1,60% or less, Mn: 0.B □% or more T', P: 0.035-0.15%, sat A
t: o, (1(18~Oo 9 (l z, B
: 0.0005~(1,0050(X;, N:
(Ill 01 (1~(1,0050% included, and 137N = (1,2~1.(), the remainder is Fe
and steel nulab' (
After heating to a temperature of 1180°C or lower, hot rolling is carried out with a hot rolling finishing temperature of 680 to 830°C and a total coiling temperature of 650°C or lower.1st, the hot rolled steel sheet is cold rolled and then continuously annealed. A method for producing high-tensile cold-rolled m-plates with good drawability and aging resistance.
(2)  重量比にてC: 0. (1(14+1%以
下、Sl:060%以下、 Mn : 0.8 (1%
以丁 11 : o、035〜0.15%、  5o7
At: 0.008−0.090%、B:0.0005
〜0.0050%、  N  :  0.0(110〜
00050%を含み、 fK ’I’i 、  Nb 
、  V、 Zrのいず第1か1種もしくは2種以上を
合計計で0、On2〜002%ケ含有し、かつB/N 
= 0.2〜1.0であり、残部はFeおよび不可避的
不純物より成る鋼スラブを]、 ] 8 (1℃以下の
温)及に加熱した後、熱延仕上温度′(i−680〜8
3(Ic、巻取温度を65 (1℃以下とする熱間圧砥
全行ない1次いで一該熱延n1通板を冷間圧延しに後連
続焼鈍ケ施すことff−特、徴とする絞り性、耐時効性
の良好な高張力冷延m板の製造方法。
(2) C by weight ratio: 0. (1 (14+1% or less, Sl: 060% or less, Mn: 0.8 (1%
Itcho 11: o, 035-0.15%, 5o7
At: 0.008-0.090%, B: 0.0005
~0.0050%, N: 0.0 (110~
00050%, fK 'I'i, Nb
, V, Zr at a total content of 0, On2 to 002%, and B/N
= 0.2 to 1.0, and the remainder consists of Fe and unavoidable impurities. After heating the steel slab to ], ] 8 (temperature of 1°C or less), the hot rolling finishing temperature '(i-680 to 8
3 (Ic, complete hot rolling with a coiling temperature of 65 (1°C or less) 1) Then, the hot rolled n1 sheet is subjected to continuous annealing after cold rolling. A method for producing a high-tensile cold-rolled m-plate with good strength and aging resistance.
JP15737682A 1982-09-09 1982-09-09 Production of high-tension cold-rolled steel sheet having good drawability and aging resistance Granted JPS5947333A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15737682A JPS5947333A (en) 1982-09-09 1982-09-09 Production of high-tension cold-rolled steel sheet having good drawability and aging resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15737682A JPS5947333A (en) 1982-09-09 1982-09-09 Production of high-tension cold-rolled steel sheet having good drawability and aging resistance

Publications (2)

Publication Number Publication Date
JPS5947333A true JPS5947333A (en) 1984-03-17
JPS6112007B2 JPS6112007B2 (en) 1986-04-05

Family

ID=15648301

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15737682A Granted JPS5947333A (en) 1982-09-09 1982-09-09 Production of high-tension cold-rolled steel sheet having good drawability and aging resistance

Country Status (1)

Country Link
JP (1) JPS5947333A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112359285A (en) * 2020-11-09 2021-02-12 山东钢铁集团日照有限公司 Ageing-resistant cold-rolled continuously annealed steel strip and manufacturing method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02300605A (en) * 1989-05-16 1990-12-12 Fuji Electric Co Ltd Infrared thickness thickness gage for blow film

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112359285A (en) * 2020-11-09 2021-02-12 山东钢铁集团日照有限公司 Ageing-resistant cold-rolled continuously annealed steel strip and manufacturing method thereof

Also Published As

Publication number Publication date
JPS6112007B2 (en) 1986-04-05

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