JPS5944590A - Heat accumulating apparatus - Google Patents

Heat accumulating apparatus

Info

Publication number
JPS5944590A
JPS5944590A JP57155571A JP15557182A JPS5944590A JP S5944590 A JPS5944590 A JP S5944590A JP 57155571 A JP57155571 A JP 57155571A JP 15557182 A JP15557182 A JP 15557182A JP S5944590 A JPS5944590 A JP S5944590A
Authority
JP
Japan
Prior art keywords
heat storage
heat
temperature
tank
storage device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57155571A
Other languages
Japanese (ja)
Inventor
Mitsuhiro Harada
原田 光博
Kenji Saida
健二 才田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP57155571A priority Critical patent/JPS5944590A/en
Publication of JPS5944590A publication Critical patent/JPS5944590A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Abstract

PURPOSE:To enable to make a heat accumulating apparatus in a compact structure, by disposing particles of coagulative heat accumulating medium charged hermetically in moisture-impermeable packing material with proper spacing in a tank-shaped container of a heat accumulating apparatus used for hothouse culture. CONSTITUTION:In a tank-shaped container 3 of a heat accumulating apparatus, particles 4 of coagulative heat accumulating medium consisting of Na2SO4. 10H2O or the like having a melting point of about 10-30 deg.C, charged hermetically in a moisture-impermeable packing material such as polyethylene or the like, are disposed with proper spacing from each other. In case of collecting superfluous heat in a hothouse in the daytime, a control section 7 drives a fan 5 for performing heat collecting operation when the temperature in the hothouse detected by a detector 6 becomes higher than a prescribed temperature. On the other hand, when the temperature in the hothouse becomes lower than a prescribed temperature at night, heat releasing operation is performed by driving the fan 5. Thus, it is enabled to obtain a compact, energy-saving heat accumulating apparatus used for hothouse gardening, which has a high efficiency of heat exchange.

Description

【発明の詳細な説明】 本発明は凝固性蓄熱43を用いた蓄熱装置に関する。%
に木ン1へ明は施設園芸用温室の加温、冷房全省エネル
ギーで効果的に行う蓄熱装置に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a heat storage device using coagulable heat storage 43. %
This article relates to a heat storage device that effectively saves energy in heating and cooling greenhouses for greenhouse horticulture.

一般に冬期における作物類のハウス栽培では昼間におけ
る高温全換気などによって抑制する一方、夜間には栽培
作物の育成TrAKを確保するため暖房を必要とする。
Generally, greenhouse cultivation of crops in winter is suppressed by high temperature ventilation during the day, while heating is required at night to ensure the growth TrAK of the cultivated crops.

暖房機としては燃料に石油を用いた暖房機が広く普及し
ているが石油価格の高騰により代替エネルギーによる省
エネルギータイプの暖房方法が開発され一部実用化され
ている。こうした省エネルギータイプの暖房方法の一つ
として太陽熱全利用する方法がある。これは温室を集熱
体とし昼間温室内に到達する太陽熱のうち、換気によっ
て大気中に捨てられていた余剰熱殴を蓄熱し、これを・
夜間の暖房熱源として′A1」用する方法であり地中熱
ダ換方式、氷蓄熱熱交換方式として知られている011
1者は余剰各11・量を温室内地下に埋設した熱交換バ
イブ全通して地中に蓄熱するものであり、後者は熱交換
機により水槽に温水として蓄熱するものである。
Although heating machines that use petroleum as fuel are widely used, as the price of petroleum has soared, energy-saving heating methods using alternative energy have been developed and some of them have been put into practical use. One of these energy-saving heating methods is a method that makes full use of solar heat. This uses the greenhouse as a heat collector to store the excess heat that was thrown into the atmosphere through ventilation out of the solar heat that reaches the greenhouse during the day.
This method uses 'A1' as a heating heat source at night, and is known as the underground heat exchange method and the ice storage heat exchange method.
In the first method, the surplus amount is stored underground through a heat exchanger vibrator buried underground in the greenhouse, and in the latter method, it is stored as hot water in a water tank using a heat exchanger.

しかしながら地中熱交換方式はパイプ熱交換部面積が温
室面積と同程度かそれ以上のパイプ埋設本数が8四であ
り、寸だバイブ全温室内地中に埋設するためバイブ等の
資材、工事費用が膨大に斤る。寸だ温室内の湿度が高く
なり栽培作物の病害の発生が多いなどの問題点がある。
However, in the underground heat exchange method, the area of the pipe heat exchange section is the same as or larger than the area of the greenhouse, and the number of buried pipes is 84, which means that all of the vibrators are buried underground in the greenhouse, so materials such as the vibrator and construction costs are required. A huge amount. However, there are problems such as high humidity in the greenhouse, which increases the incidence of diseases in cultivated crops.

一方、氷蓄熱熱交換方式は水の比熱が小さいため多量の
熱量を蓄熱するためには大型の水槽を温室の内又は外に
置かなくてはいけないという問題点がある。
On the other hand, the ice storage heat exchange method has a problem in that, since the specific heat of water is small, a large water tank must be placed inside or outside the greenhouse in order to store a large amount of heat.

本発明者等はこのような従来の蓄熱方式のもつ間)首点
について種々検討した結果、凝固性蓄熱材を用いこれを
熱交換が良好になるような配置方法および機構を備える
ことによりこれらの点が容易(て解決できること石:知
り本発明全完成した。即ち本発明は空気の導入11・k
よび導出lコな備えた煙状容器、この煙状容器内部に適
度の空間部が保有さiするように配置さf]−、!−4
つTSr’lt’性のない包装材料によって密閉充填さ
り、たび固fI−蓄熱利、外部空気を煙状容器内層1へ
に導入し蓄熱材配置部を通じて熱交換して211出さね
−’6機ii:Q ’g有する送風機、外気温度を測定
表示する温j4.検出器および検出温度と関連させ一〇
送凧B、職をfil ?+11’する制御部から構成さ
れ、る1さ熱射↑ガである。
As a result of various studies on the key points of such conventional heat storage methods, the inventors of the present invention have solved these problems by using a coagulable heat storage material and providing a method and mechanism for arranging it to improve heat exchange. The point is that it can be easily solved.I know that the present invention has been completely completed.That is, the present invention is based on the introduction of air 11.
A smoky container is arranged such that an appropriate space is maintained inside the smoky container f]-, ! -4
It is sealed and filled with a packaging material that does not have TSr'lt' properties, and outside air is introduced into the inner layer 1 of the smoke container, and heat is exchanged through the heat storage material arrangement part to emit 211. ii: Blower with Q 'g, temperature j4. Measures and displays outside air temperature. 10 sending kite B in relation to the detector and the detected temperature? It consists of a control section that increases +11', and is a heat radiation ↑ga.

以下本発明全一実施形態に−示す添]電1図i?i’i
V釦よって説明する。第1図は、本発明に係る蓄熱装置
の構成を示す見取略示図であり/は空気導入口、−2は
空気導出口、3け煙状容器、グは透湿性のない包装材料
によって密閉充填された凝固性蓄熱材、Jは送風機、名
に温度検出器、7は11制御部をそれぞれ示したもので
ある。本蓄熱装置17は外部FP気の書入[]/と導出
[]、2が備えられてbろ煙状容器3と、この煙状容器
3の内部て透湿性のなり包装材料によって密閉冗填され
たQ関固性蓄熱利グが滴!」!の空間部が保有されるよ
うに配置され、でいる7、この際空気の24入[コ/訃
よび;1% j旧」1に関してその位1りおよび個数V
こついてに特に制約さyすることばなく適度に選定する
ことができる。煙状容器31硫第1図に図示したような
箱形であっても良く、又、円筒状(Lこして円形中心部
(C空気導入口(又は導出口)、その周内部に空気導出
口(又は導入[コ)を設けるように構成することもでき
る。l’?々状容器、?の内部ζこ配++iされる凝固
性蓄熱材りは融解時1で液状となる内容物のfノ19洩
全防止すると同時に長期間の使用中の変質を防止するた
めに透湿性のない合成樹脂又は金属の包装材料によって
密閉されている中に一定量苑、充1イへされている1、
この凝固性蓄熱材qの密閉包装物は煙状容器3の内部(
C配置さハ、るため袋状、板状又は管状のものが適当で
ある。このような包装利料として柑−例えばポリエチレ
ン、エヂレンー酢酸ビニル共重合体、ポリ塩化ビニル、
ナイロン、鉄、ステンレス笠が適当である。凝固性蓄熱
材が元板さ相、ている密閉包装物は強制的に送風された
イど気と接触して熱交1欠を行うため包装物表面を空気
との1g触1iji積を太きくし、しか屹余り大きなI
F、力IF失を生じないような配置ハ方法にすることが
必要である。このような配置方法とし7ては例えば内部
に凝固性蓄熱材が充填されている袋状密閉包装物、板状
密閉包装物、棒状密閉包装物ンー棚段状0て配置する方
法、煙状容器3の横断面形状に対応して同心多j((円
状、渦巻状のものを棚段状に’i’y置する方法、長管
状密閉包装物を各市らせん状に配置する方法等、−穴空
間を4V石するように配置する方法が挙りられる。第2
図、第3図にその/例ケ示した。
Hereinafter, all the embodiments of the present invention will be described. i'i
I will explain using the V button. FIG. 1 is a schematic diagram showing the configuration of the heat storage device according to the present invention, where / is an air inlet, -2 is an air outlet, 3 is a smoke-shaped container, and G is a non-moisture permeable packaging material. The hermetically packed coagulable heat storage material, J is a blower, the name is a temperature detector, and 7 is an 11 control unit, respectively. This heat storage device 17 is equipped with an external FP air inlet []/output [], 2, and a smoke-like container 3, and the inside of this smoke-like container 3 is sealed and redundant by a moisture-permeable packaging material. The Q-temperature storage energy drips! ”! It is arranged so that a space of 1 is held, and 7, in this case, 24 volumes of air [ko/deceased; 1%
This can be appropriately selected without any particular restrictions. The smoky container 31 may have a box shape as shown in Figure 1, or may have a cylindrical shape (L) with a circular center (C) air inlet (or outlet), and an air outlet inside the periphery. (or an introduction can also be provided.) The coagulable heat storage material that is inside the ?-shaped container and the ? 19.In order to completely prevent leakage and at the same time to prevent deterioration during long-term use, a certain amount of the product is stored in a container sealed with a non-moisture-permeable synthetic resin or metal packaging material.1.
The hermetically sealed package of the coagulable heat storage material q is inside the smoke container 3 (
A bag-like, plate-like, or tubular shape is suitable for the arrangement. Such packaging materials include polyethylene, ethylene-vinyl acetate copolymer, polyvinyl chloride,
Nylon, iron, and stainless steel hats are suitable. Sealed packages in which the coagulable heat storage material is in the original plate phase come into contact with the forced air and perform heat exchange, so the surface of the package is exposed to 1 g of air and the product is thickened. , but the I is too big
F. It is necessary to use an arrangement method that does not cause loss of force IF. Examples of such arrangement methods include, for example, bag-shaped sealed packages, plate-shaped sealed packages, bar-shaped sealed packages filled with a coagulable heat storage material in a tiered manner, and smoke-shaped containers. Corresponding to the cross-sectional shape of 3, concentric polygons ((a method of arranging circular or spiral-shaped items on shelves, a method of arranging long tubular sealed packages in a spiral shape, etc.) One method is to arrange the hole space like a 4V stone.Second
An example of this is shown in Figure 3.

本発明に使用可能な凝固性蓄熱材は冬期温室内に到達す
る太陽熱のうち換気によって大気中に捨てられている余
剰熱訃?蓄熱材に蓄熱するため済熱材の融解温度が昼間
の温室内温度より高いと蓄熱は出来ずまた融解温度が低
すぎると夜間7、”、;i室温度が低下しても放熱が充
分出来ず栽培作物の育成温1:yが確保出来なくなるた
め融解p101;!rL 10 r2からJOCの範囲
のものが適当である3、まアζK、44B、 4B、i
のシ′−角+il熱に蓄テ5〜量に関係するためノ・−
きフ≧もQ)に、ど定寸しく小さいと蓄熱材のシ、:が
予目に必叩となるのでム;゛!解熱/ jr ral 
/ g以上のものが5代当である。ζうしブζ蓄格利と
してL1例λばNa、SO4* t’ OTl、04た
(、1これにNaol、 KC!、/ブrどう−11−
1’+合1−. lこもの、O’t C1,2・乙馬○
またはこれ(’r二に槙C12・g+■2o、 MgB
r2− gH20などを混合したもの々とがある。これ
ら(は通常、1局冷却防止剤、濃化剤?配合して[小用
される。
The coagulable heat storage material that can be used in the present invention is the surplus heat that is discarded into the atmosphere through ventilation out of the solar heat that reaches the greenhouse during the winter. Because heat is stored in the heat storage material, if the melting temperature of the heat storage material is higher than the temperature inside the greenhouse during the day, heat cannot be stored, and if the melting temperature is too low, heat cannot be radiated sufficiently at night even if the room temperature drops. Since the growing temperature of the cultivated crops (1:y) cannot be secured, a range from melting p101;!rL 10 r2 to JOC is appropriate.3, Maa ζK, 44B, 4B, i
Since it is related to the amount of heat stored in the angle + il of
Q), if the size is too small, the heat storage material will need to be hit in advance, so ゛! fever reduction / jr ral
/g or more is worth 5 generations. ζ Ushibu ζ As an accumulation case, L1 example λ is Na, SO4 * t' OTl, 04 (, 1 plus Naol, KC!, /Brodo-11-
1'+combination 1-. l Komono, O't C1,2・Otoma○
Or this ('r ni Maki C12・g+■2o, MgB
There are also those mixed with r2-gH20, etc. These are usually used in combination with anti-refrigerating agents and thickeners.

tた送風機Sが付設されている外部空気(主とし゛C温
案内空気)全強制的に導入口/から輪状容器3の内部に
矢印に沿って通風1−凝固性蓄熱材の密閉包装物が配置
さ第1.ている空間K[−多一通り導出1コβから再び
外気に排出するようになっている。この際送風機Sの設
置場所については特に制約されることはなく上記空気流
を形成するような機能?有するようにするものであれば
良い。したがって空気導入口/に空気を吹込む形式にす
ることも可能である。(に外気温度(主として温室内温
度)音検出する温度検出器6と検出温度と設定温度との
1■係から送風機Sを起Ili、jIL jこり停止す
る制御部7が設置されている。
A blower S is attached to force all the external air (mainly temperature guiding air) into the annular container 3 from the inlet/inlet along the arrow 1 - The sealed package of coagulable heat storage material is placed. First thing. The air is discharged to the outside air again from the space K [-Multi-way derived 1 co β. At this time, there are no particular restrictions on the installation location of the blower S. It is fine as long as it has. Therefore, it is also possible to blow air into the air inlet. (A temperature detector 6 detects the outside air temperature (mainly the temperature inside the greenhouse) and a control unit 7 that starts and stops the blower S from the detected temperature and the set temperature.

したがって温度検出器乙および?l;II御部7げ恥部
7も白状容器8の(+ili而部に面置する心安はなく
、〕、゛′風′風機動して機能−4−るようにすること
がbJ能である。
Therefore the temperature sensor B and? There is no peace of mind to place the shameful part 7 of the white container 8 on the (+ili but part) of the white container 8, and it is bJ's function to move it in the wind and make it function. .

例えば本発明の蓄熱装フイで[−1中習、宗1/1の余
剰熱;せゲ集熱する場合、温室内の温度全温度検出器(
乙)で検出し集熱設定温度以」二(例えば、2 s−C
)に達すると送風機(,5)ゲ動かして集熱運転ケし、
それ以下になると送風機が停止する。また夜間に放熱中
15場合、暖房設定温度(例えば10r)以下Vr、温
室内の温度が低下すると送風機(,5)が動き出し放熱
運転ケし、そ力以上になると送風機が停止する機能をイ
1する制御部(7)の杆″七千i’;にこなっている。
For example, when using the heat storage device of the present invention to collect surplus heat of -1, 1/1, the total temperature inside the greenhouse (
B) detects the heat collection set temperature or higher (e.g., 2 s-C).
), move the blower (5) to operate the heat collection.
If the temperature drops below that, the blower will stop. In addition, when heat is being dissipated at night, when Vr is below the heating set temperature (for example, 10R) and the temperature in the greenhouse drops, the blower (,5) will start operating and dissipate heat, and when the temperature exceeds that temperature, the blower will stop. The control section (7) is in control of the rod ``7,000''.

このように本発明の蓄熱装置は水に比較し相当大きな蓄
熱itケ有するんf同性蓄熱材全使用しているため水蓄
熱熱交換力式の様な大型の水槽(蓄熱(・1々)を必要
とぜず蓄熱装置の小R1化が可f、にであり園芸Lイξ
設内外を有効に使うことが可能で力)る。才fr、私゛
熱材全充jfii l、た容B:÷の形状、配置n方法
(Cより空気上の接触面積が広くなること及び本発明の
動力#tj送風機のみであり、それを効率的な制御方式
で集熱、かr熱jp転することが出来/)ため/」ヅリ
で舛、交擁−率の良い省エネルギータイプの施設回芸用
蓄熱袈i〆、′が0伸jに提供できることにある。
As described above, the heat storage device of the present invention has a considerably larger amount of heat storage than water.Since it uses homogeneous heat storage materials, it is possible to use a large water tank (heat storage) like a water heat storage heat exchange type. It is possible to reduce the R1 of the heat storage device without needing it, and it is possible to reduce the R1 of the heat storage device.
It is possible to use the inside and outside of the facility effectively. The shape of B: ÷, the arrangement of N method (the contact area on the air is wider than C, and the power of the present invention is only the blower, and it is efficient It is possible to collect heat and transfer heat using a control method that allows heat to be collected and transferred. The goal lies in the fact that it can be provided to

り、1゛ノ1の簡単なH9明 +!(+ニア図は本発明に係る蓄熱装置の/実施形態の
見取り略示図、第2図、第3図は透湿性のない包装材料
によって活閉充填さfした凝固性蓄熱材の櫓状容器内部
への配置例を示したものであり、/汀空気導入口、2は
空気導出口1.7 Fll状状容器qは密閉充填された
凝固性蓄熱材、Jに送風機、2は温度検出器、7け制1
i11部ケ/jTす。
1-1 easy H9 Akira +! (The nearer figure is a schematic diagram of an embodiment of the heat storage device according to the present invention, and FIGS. 2 and 3 are turret-shaped containers of coagulable heat storage material filled with a non-moisture-permeable packaging material. The figure shows an example of the internal arrangement, 2 is air inlet, 2 is air outlet 1.7, Fl-shaped container q is hermetically filled coagulable heat storage material, J is a blower, and 2 is a temperature detector. , 7-card system 1
i11 part ke/jTsu.

Claims (1)

【特許請求の範囲】 /)空気、の21′I入口:I′、−よび導出口を備え
た槽状容Yz、この槽状容器内部に適度の空間部が保有
されるよう(C配置され目一つ透湿性のない包装置料に
よって密閉充填された凝固性蓄熱材、伺部窄気を槽状容
器内部に導入し蓄熱材配置部を通じて熱父換し、て導出
口より導出される41!HPを有する送風機、例気搗度
を測定表示する温度検出器および検出温度と関連させて
送風機を制御子る制御部より構成されることを特徴とす
る蓄熱装置 、2)・f湿性のない包装材料が合成樹脂捷たは金属で
あり、こ:)t rこよって密閉充填された形状が袋゛
IJS1)lll状状管状である!;シ杵請求の範囲第
1r口記・「(−〇腎べ各装置 、?)71;f固件蓄熱目が融点が10〜30C1融解
;り1−が/ j Ca1./g以−ヒのものである特
許請求の範囲第7項記載の蓄熱装置 ゲ)透湿性のない包装材料によって密閉充填されている
凝固性蓄熱材が、棚段状、らせん状に配ろ1された特許
請求の範囲第1項記載の蓄熱装置 3 ) fltli御部が一定温度以一ヒのときまたは
/および一定潟度」ン、下のとき送風機全作動させる機
能をイイする特許請求の範囲第1項記載の蓄熱装置 乙)施設置Aq芸用温室内の空気全導入し、同室内に導
出する特許請求の範囲第7項記載の蓄熱装置
[Scope of Claims] /) A tank-like volume Yz provided with 21'I inlet: I', - and outlet of air, (C arranged so that an appropriate space is maintained inside this tank-like container) The coagulable heat storage material hermetically filled with a non-moisture-permeable packaging material, with air trapped inside the tank, is introduced into the tank-like container, heat is exchanged through the heat storage material arrangement section, and then led out from the outlet 41 !A heat storage device characterized by comprising a blower having HP, a temperature detector that measures and displays the temperature of the air, and a control unit that controls the blower in relation to the detected temperature, 2)・f Humidity-free The packaging material is synthetic resin or metal, and the shape of the hermetically sealed bag is tubular! Scope of Claims No. 1r Statement: ``(-〇Kidney device, ?) 71;f Solid heat storage eye has a melting point of 10 to 30C1; The heat storage device according to claim 7, wherein the coagulable heat storage material hermetically filled with a non-moisture permeable packaging material is arranged in a tiered or spiral shape. Heat storage device according to claim 1 3) The heat storage device according to claim 1, which has a function of fully operating the blower when the temperature of the fltli control section is above a certain level and/or when the temperature is below a certain level. Device B) Facility location Aq Heat storage device according to claim 7, which introduces all the air in the greenhouse and brings it out into the same room.
JP57155571A 1982-09-07 1982-09-07 Heat accumulating apparatus Pending JPS5944590A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57155571A JPS5944590A (en) 1982-09-07 1982-09-07 Heat accumulating apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57155571A JPS5944590A (en) 1982-09-07 1982-09-07 Heat accumulating apparatus

Publications (1)

Publication Number Publication Date
JPS5944590A true JPS5944590A (en) 1984-03-13

Family

ID=15608948

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57155571A Pending JPS5944590A (en) 1982-09-07 1982-09-07 Heat accumulating apparatus

Country Status (1)

Country Link
JP (1) JPS5944590A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5341837A (en) * 1976-09-24 1978-04-15 Laing Nikolaus Green house heat accumulator

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5341837A (en) * 1976-09-24 1978-04-15 Laing Nikolaus Green house heat accumulator

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