JPS5924798A - Foamable hard surface detergent composition - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention is a two-part foaming hard surface cleaning product that can effectively remove stains from hard surfaces such as plastin, ceramics, tiles, joints, and the inside of drain pipes. The present invention relates to a drug composition.

Conventionally, as detergents for household plastics, Fil III appliances, and tiles, liquid detergents containing alkali as the main ingredients have been known, and powder detergents containing abrasives have been used as detergents for joints. Or known as liquid detergent. However, all of these detergents still had insufficient cleaning power.

In recent years, food waste and excrement have been deposited inside drain pipes, traps, and filter pipes in kitchens, bathrooms, and toilets due to the Western style of general housing, the small cross sections of high-rise housing complexes, and the Western style of eating habits. Dirt such as hair, mud, and bathroom grime often clogs or adheres to the inner wall of the pipe, obstructing the flow of water within the pipe. Such dirt inside drain pipes is one of the most difficult to remove among hard surface dirt in gardens, partly because it is difficult to reach the dirty parts.

Conventionally, methods for removing dirt from traps, filter tubes, etc. include a method of dissolution and emulsification using a chlorinated hydrocarbon and an activator (U.S. Pat. No. 55B, No. T4A); Method of decomposing dirt using enzymes and microorganisms (Tokuko Sho 3)
8-26464), a method using sodium percarbonate and an activator (Japanese Patent Application Laid-Open No. 52-152406), a method using a t'l agent and an alkaline carbonate (Japanese Patent Application Laid-open No. 53-5020).
7), a method using an oxidizing agent such as an acid agent, an alkaline carbonate, and sodium percarbonate (Japanese Patent Laid-Open No. 53-51120)
No. 8) and the like have been reported, and none of these have sufficient cleaning power.

US Pat. Kei, American watch specification section 3.53 & 0
No. 08 Mei*++i* has 11,80. .

IC! t, llN0. , Is there a method to introduce strong enemies such as O/L/Torin rR and sulfamine If and silica sol? This method is also extremely dangerous.
Moreover, H4 feeding habits are large.

On the other hand, is TJ completely refined using aerosol injection pressure? ``It is also known to pass M84+, but this method is almost ineffective against dirt that has accumulated on the wall.Is it possible to increase the number of times when cleaning the inside of the drain pipe physically is time-consuming? It is difficult to do it easily at home.

The present invention has been made to solve the problems of the prior art as described above, and can easily remove stains from hard surfaces such as plastics, ceramics, tiles, joints, bathtubs, and the inside of drain pipes.
It is an object of the present invention to provide a two-component foaming hard surface cleaning composition that can effectively remove the problem.

That is, the two-part foaming hard surface cleaning composition of the present invention has the following components A and B. The two are brought into contact or mixed during use, and water is added if necessary.

(1) Agent A: Inorganic 3! j4# An oxygen-based oxide composition containing an I compound and having an effective oxygen value of 0.25 to 25%, or an ice-melting solution of this composition.

(2) B location 1]: Contains hypochlorite and the amount of available chlorine is 0
．． 25 to 60% of the mounded fiber oxide composition in the armpit or a water bath solution of this composition.

The present invention will be briefly described below.

Part A has an oxygen-unoxidized composition containing an inorganic peroxide.

or its aqueous solution, and the inorganic peroxide wax in Part A is 0.5 to 10% in the case of a liquid, and 10% in the case of a solid.
It is preferable to have ~1 o o ft excellent, and more cleverly, respectively 1~B 5wt chi and 30~gnw *
%. And, the effective acid index in agent A is 0.25 to 2
5 inches, preferably 0.5 to 20 inches. If the effective oxygen cap is less than 0.25 liters, sufficient cleaning power cannot be obtained, while if it exceeds 25%, storage stability deteriorates and it is also dangerous to handle after household use, which is not preferable.

Here, the effective oxygen cap is the ratio (% by weight) of oxygen t(,O)Q-)Q-)λ which is effective for morning sun etc. contained in Agent A. This can be measured by a conventional method using potassium permanganate or the like.

Any inorganic peroxide that can be used as agent A can be used as long as it reacts with hypochlorite and decomposes, or preferably hydrogen peroxide and sodium percarbonate (Na, C
It is a hydrogen peroxide adduct represented by o, .nHlo + typical -kitn:=)). Other specific examples include sodium perborate, a hydrogen peroxide adduct of sodium hydroxide, a hydrogen peroxide adduct of sodium silicate, and a hydrogen peroxide adduct of sodium orthophosphate. Among the above, particularly preferred are hydrogen peroxide and sodium percarbonate.

Agent B is a chlorine-based oxide composition containing hypochlorite or an aqueous solution thereof, and the concentration of hypochlorite in Agent B is 0.25 to 40% by weight when it is liquid. 1 to 1 for powder
Preferably, the content is 1 to 15 wt%, and more preferably 1 to 15 wt%, and 10 to 90 wt%, respectively. The amount of available chlorine in agent B is 0.25 to 60%, preferably 1 to 15%. The amount of available chlorine is 0.
If it is less than 25 yen, sufficient cleaning power cannot be obtained;
If the temperature exceeds 1, the storage stability will be markedly deteriorated, and it will be dangerous to handle on a slope.

Here, the effective chlorine paper is the ratio of chlorine yt (ctt) contained in the B agent to the entire B agent.

Examples of the flexible salt of Agent B include sodium hypochlorite, AM potassium hypochlorite, and high-strength salinity powder, with hypochlorite being particularly preferred.

The properties of agents A and 13 are either liquid (#liquid) or solid (normally
powder) may also be used. Among the combinations of agents A and B, particularly clever combinations are as follows.

(1) Liquid/M type type A agent: 1.0 to 35 wt% hydrogen peroxide bath liquid Agent B: 1.0 to 15 wt≠ sodium hypochlorite bath liquid (2) Powder/Kai [this type Part A: Powder composition containing 10 to 100 wt% of sodium percarbonate Part B: 0.5 to 15 wt%) sub-ntm oxide (3) Adult/powder Tyzo A-Kura IJ: 1.0 ~35W1≠ hydrogen peroxide water bath solution B agent: Powder composition (4) containing 2.0 to 100 wt% of bleaching powder 8 pieces/powder type A agent: Powder containing in to l (10 wt%) of soda percarbonate Composition B agent: Powder composition containing 2.0 to 100 wt of bleaching powder.
fi+JU) The surface oil agent can be cooled on either side or both sides. As will be explained in detail later, the external surfactant primarily contributes to the stability of foaming. Therefore, if it has such an effect, then
B can also be used, and it is preferable to store it together with the A ingredient or the B agent ingredient. As surfactant firmness, anionic surfactants, non-ionic surfactants, ion-resistant and anti-ionic surfactants, and amphoteric surfactants can be used.
Particularly preferred are ionic surfactants and nonionic surfactants. Specific examples of such surfactants include the following.

(1) Anion world "self-activating agent fatty acid salt with carbon number 10-20 carbon IKIO-18 alkyl sulfate carbon tli
xo~18 alkylbenzene sulfonate ash number 8~
18 (1g-olefin sulfonate carbon number 8-18
Polyoxyethylene alkyl ether sulfonate with an average added mole number of ethylene oxide (EO) EOp of 1 to 10 moles Polyoxyethylene alkyl phenyl ether sulfonate with a carbon number of 6 to 12 and Eop = a to 20 (2) Nonionic surfactant Alcohol EO adduct with carbon chain 10-20 (Eop=6
~20) Alkyl group υ) Alkylphenol EO adduct with alkyl group having 6 to 12 carbon atoms (Eop=a~20) Sorbitan alkyl ether EO adduct with alkyl group having 12 to 18 carbon atoms (
EoP=a~30) Carbon 6112~18 ノJJIfatr
REO adduct (EoP=5-50) (3) Cationic surfactant Quaternary ammonium base imidazolinium 4-dimer (4) Ampholytic surfactant betaine amino salt imidazolinium of the above surfactants Among them, it is particularly superior in terms of foaming properties,
are alkyl sulfates with an average carbon number of 12,
Anionic surfactants such as alkylbenzene sulfonates whose alkyl groups have an average carbon number of 12 or 12, carbon atoms 12 to 18 (1)*-olefin sulfonates, polyoxyenalene nonylphenyl ether (GOP=8 to 111), lauri/l /7 /l/2r-l KO adduct (go
Examples include nonionic surfactants such as P=a to t o) and nonylphenyl ether Eo adducts (EoP=a to 1o).

In terms of stability during storage, alkyl sulfates with an average carbon number of 12, polyoxyethylene nonylphenyl ether (HOP''8-10), lauryl alcohol E (
) adduct (Eop = s ~ 10), nonylphenyl ether IO adduct (EoF = a ~ in), etc.
I'm l. Examples of products that are excellent in promoting penetration into dirt include alkyl sulfates with an average carbon content of 12, alkylbenzene sulfonates with an alkyl group having an average carbon number of 12, and carbon atoms with 12 to 180 Ja-
Examples include anionic surfactants such as olefin sulfonate and -lyoxyethylene nonylphenyl ether (bop=s~10).

Kai Katsu Suminaka 1 is A agent or B agent d 0.1 to 20 or 1 n.
% 'I hope this will be added so that I can become better,
The thickness is preferably 0.5 to 1 OjlIIJL. If this company exceeds 0.1% IC (tNj), there must be sufficient foaming power or the city stable company will cry out. (1) Decreased poison purifying potency.

Next, the method for using the surface cleaning agent composition of the present invention and the method for using it will be explained.

Parts A and B are stored separately and each is applied separately onto the hard surface soil at the time of use.

The order of application may be either first or at the time of opening. For liquid/powder type and powder 7g type,
It is practical to spread the powder first and then pour the liquid. Also, for the powder/powder type, add an appropriate amount of water after spraying both. The liquid/liquid type is easy to handle and is convenient for applying the desired phosphor to any hard surface, especially hard surfaces such as hard to reach places or vertical surfaces. From this point of view, hydrogen peroxide and sodium hypochlorite, which can be stably stored even in liquid form, are advantageous.

When Agent A and Agent B come into contact with each other on hard surface dirt and react, the dirt is decomposed by the generated oxygen. Cough cords are generated by both the decomposition of impurities and compounds and the decomposition of hypochlorite, which act synergistically to decompose dirt. In particular, hypochlorite IA has a strong bactericidal effect, so it also works as a fungicide and as a fungicide.

As mentioned above, the large amount of air bubbles produced by the reaction removes dirt using physical force. Therefore, it can be effectively removed even in hard-to-reach areas, and it can also be removed without scrubbing or other operations on the outer surface. Furthermore, due to the generation of air bubbles, the fk# agent can be spread even to places where the cleaning agent is difficult to reach, such as recesses, due to the filling force of the air bubbles, and anti-f* can be efficiently carried out. In addition, foaming makes it easier for cleaning agents to adhere to hard surfaces.
If you have enough time to clean even sloped and vertical surfaces, it will be possible.

Furthermore, the force of removing dirt can be reduced by the heat of reaction between the manual removal and the B agent.

As described above, the cleaning composition of the present invention contains peroxide and ? : Due to the decomposition of subsalt wood and salt.

(1) Disinfecting and sterilizing power (2) Physical external force on the dirt due to foaming, light intensity of the disinfectant, and adhesion or stagnation of the cleaning agent (3) Synergistic effect of heat of reaction It provides superior cleaning power that could not be imagined with conventional cleaning agents.

It is very common for the hard surfaces to be cleaned to have slopes or surfaces that are difficult to clean, such as recesses or corners. Therefore, foaming power or foam stability is an important factor. For example, consider the drain pipe for a sink used for salmon. This drain pipe descends almost straight down, and one of the crooked side walls is a snake! Many have a structure. A predetermined flow channel is formed within the pipe, and when water is allowed to flow, the water does not flow uniformly within the pipe, but flows along the flow channel. Even if a cleaning agent is poured into such a drain pipe, the cleaning agent only comes into contact with specific parts, and it quickly flows down, making it impossible to clean efficiently. JP-A-52-152406 and JP-A-53-502 already mentioned
Powdered foaming compositions have also been reported in Publication No. 07 and No. 53-50208, but these have insufficient foaming amount and foaming power, and cannot be foamed when used in the above-mentioned drain pipe. It flows down quickly.

On the other hand, when using agent A and agent B of the present invention,
The foam 11" has a strong foaming power, and it fills the entire inside of the drain, applying physical force to the dirt, and slowly descends inside the drain pipe to remove the dirt for a sufficient amount of time. contact over a period of time.

In particular, when at least one of the A and B agents contains a surfactant, the foaming power increases and the generated bubbles become stable, further enhancing the foaming effect described above.

As is clear from the above explanation, the two-component foaming cleaning composition of the present invention is effective for cleaning all hard surfaces, such as moldy surfaces, slanted surfaces, and vertical surfaces. ) Particularly effective for areas that are prone to flow, or areas that are difficult to clean, such as corners, corners, and inside areas. Specifically, it is particularly effective as a toilet cleaner, a mold remover, a sardine stain remover, and a drain pipe cleaner.

a: The cleaning composition of the present invention further contains Glauber's salt, Tanban soda, Hekkan, sodium triphosphate, sodium diphosphate, tripolyphosphate, pylocaliphosphate, etc. in the agent A and/or the agent B. Bulking agents, colorants, fragrances, disinfectants, chelating agents, activators, alkalis, or other additives commonly added to cleaning agents can be added.

These additives are preferably added so as not to impair the stability or function of Part A and Part B. For example, it is preferable to add a chelating agent or an activator to Part A.

Example 1 Each sample shown in Table 1 was prepared and evaluated for its ability to remove urine scale. In addition, the numerical value represents weight %.

Evaluation method 10 rIfIII-] tiles and cyclized vinyl were immersed in human urine, taken out, dried and turned over to form urine stains (0.5f/10 Gel) used as re#f stains.

Invention Q] Samples 1 to 4 (2-component type) are % of agent A and agent B.
201F was mixed at the time of use to treat urine 4 (2,s x 6 bacteria), and after rinsing with water, the dirt removal rate was evaluated by visual judgment. In addition, a comparative example (one-liquid type) was the same except that 40F was used, and the same was used for eel.

Evaluation criteria: O: 95 or more chips removed ○: 80 to 95 chips removed Δ: Approximately 50 chips removed (blank below) Table 1 *) Nb2-D: /IJ, txyethylene nonylphenyl ether Sulfonate (HOP=10) **) Softano/L/90: 2d Flucol B□ adduct (you=9) Example 2 Each sample shown in Table 2 was prepared, and mold-removed ska rice was evaluated.

Evaluation method A joint board (10 x 10011) was prepared in advance, and mold (CIadapo
ri+++n, Aureobasidum %
) If the surface was uniformly contaminated with black after culturing, it was used as an evaluation stain.

The test of the present invention yF+/% 8 to 11 contains 4 parts A and B part.
The mixture was mixed at the time of use, treated with Mekapi (IXI OLM) for 10 minutes, and the removal rate was evaluated by visual judgment. The specific yield example was the same except that the wave phase was 8f.

Criteria for evaluation: ◎...More than 95 inches removed ○...80-95 inches removed △...50% extreme removal Table 2 Example 3 Each sample shown in Table 3 was prepared and tested The dirt removal effect was evaluated.

Evaluation method An evaluation stain was created as follows.

(1) Kitchen grime 20kg of hard water at 50°Dll and 200f of powdered soap.

Add 10 lj' of tempura oil, 50 f of soluble starch, 20 f of gelatin, and 40 f of inorganic dirt (clay minerals) and mix well.
It was circulated through a transparent vinyl chloride hose. 20~
After 24 hours of circulation, model dirt accumulates on the entire inner wall of the vinyl chloride, which can hardly be removed by washing with water alone. This hose was cut to an appropriate length and used as an evaluation stain.

(2) Bathroom dirt 5001) If 20kg of hard water and 200f of powdered soap.

Fatty acid (oleic acid/stearin 9 = 60/40) 1
A hose was prepared in the same manner as for kitchen dirt, except that 00R, gelatin 50F, and inorganic dirt (Kanto loam pigeon topsoil) 50F were added and mixed.

The cleaning effect was tested by attaching the above Q) hose to the drain of a sink at home.

/1614-16, A agent and B agent were separately injected into the drainage port, mixed, and left to stand for 2 minutes, then water was flushed away.

For /%17, carefully spray 50 f of agent A around the bend in the drain, pour 50 tons of agent B into the bottom of the 2h agent, soak it into the hose with a small amount of water, and after leaving it for 2 hours, drain the water and close the pipe. child.

418.19, spray 50f of Part A and Part B around the bend of the drain, pour 100ml of water into the area, and
I poured water on Shun who was left unattended for u8.

/16211, 21 dumped 100 tons of wood, poured water into it for several hours, and poured water over it.

A22.23 should be sprayed around the drain outlet, and then filled with water.
DOmt was flushed, and after standing for 2 hours, water was flushed again.

The removal rate was evaluated by visual judgment.

Criteria for evaluation of music: 2 〇... 60-100 chi Removal ○... 30-60 chi removed Δ... lO ~ 30q6 removed ×... 10 chi or less Example insects Each sample shown in Table 4 was prepared. The stain removal effect of the ventilation silk cleaner was evaluated.

Evaluation method A ventilated sardine with oil stains was used as the evaluation stain.For the product of the present invention, 5f each of agent A and agent B were mixed on the stain (40 csi), left for 10 minutes, and then gently rubbed with a dry towel. The removal rate of wiping dirt was visually judged. 10F was treated and evaluated in the same manner.

Review 1 LIlI quality: ◎...90-100 chips removed O...
・80-90% removal 0-Δ...Approximately 50-80% removal (white space below) Table 4 Procedural Amendments November 1982 2. 1. Mr. Kazuo Wakasugi, Commissioner of the Patent Office, 2. Title of the invention: Foaming hard surface cleaning composition 3. Relationship to the case of the person making the amendment. Patent applicant: 1-3-7 Honjo, Matota-ku, Tokyo (676) Lion Co., Ltd. Representative Atsushi Kobayashi 4, Agent 5, Compilation of "Detailed Description of the Invention" of the specification to be amended Contents of the amendment + IJ Ming MB 8g5fN 2 4'6KrN
AtCOa-nlitOJ is replaced with “Na1CO1・
Correct with nH2O,J.

(2) The 18th member sample JK 40A agent in Table 1 which says [92.5J in the water camphor tree] is corrected to IO2.54.

(3) The water column for agent A in Table 3 for coffin 2317 is corrected as follows.

that's all

Claims (1)

[Claims] 1. Contains an inorganic peroxide and has an effective oxygen amount of 0.25 to 25
The oxygen-based oxidizing agent composition or its aqueous solution of H is used as a λ agent,
A chlorine-based oxidizing agent composition containing hypochlorite rR salt and having an effective chlorine cap of 0.25 to 60-2
A foaming hard surface cleaning composition in dosage form. 2. The foaming hard surface cleaning composition according to claim 1, wherein at least one of the A and B agents contains a surfactant.