JPS59217793A - 炭素−金属油を転化する方法 - Google Patents
炭素−金属油を転化する方法Info
- Publication number
- JPS59217793A JPS59217793A JP59069893A JP6989384A JPS59217793A JP S59217793 A JPS59217793 A JP S59217793A JP 59069893 A JP59069893 A JP 59069893A JP 6989384 A JP6989384 A JP 6989384A JP S59217793 A JPS59217793 A JP S59217793A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- weight
- zeolite
- matrix
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims description 450
- 238000006243 chemical reaction Methods 0.000 title claims description 139
- 229910052751 metal Inorganic materials 0.000 title claims description 120
- 239000002184 metal Substances 0.000 title claims description 120
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000010457 zeolite Substances 0.000 claims description 152
- 239000000047 product Substances 0.000 claims description 142
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 141
- 229910021536 Zeolite Inorganic materials 0.000 claims description 138
- 239000003921 oil Substances 0.000 claims description 129
- 239000011159 matrix material Substances 0.000 claims description 117
- 238000000034 method Methods 0.000 claims description 111
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 102
- 239000000571 coke Substances 0.000 claims description 98
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 87
- 239000000463 material Substances 0.000 claims description 84
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 83
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 78
- 229910052799 carbon Inorganic materials 0.000 claims description 78
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 78
- 150000002910 rare earth metals Chemical class 0.000 claims description 75
- 229910001868 water Inorganic materials 0.000 claims description 63
- 239000007789 gas Substances 0.000 claims description 58
- 239000002002 slurry Substances 0.000 claims description 58
- 230000000694 effects Effects 0.000 claims description 53
- 230000002378 acidificating effect Effects 0.000 claims description 52
- 230000008569 process Effects 0.000 claims description 52
- 229910052759 nickel Inorganic materials 0.000 claims description 51
- 238000011069 regeneration method Methods 0.000 claims description 48
- 230000008929 regeneration Effects 0.000 claims description 47
- 239000004927 clay Substances 0.000 claims description 46
- 229930195733 hydrocarbon Natural products 0.000 claims description 44
- 150000002430 hydrocarbons Chemical class 0.000 claims description 44
- 238000002485 combustion reaction Methods 0.000 claims description 36
- 238000009835 boiling Methods 0.000 claims description 33
- 238000005336 cracking Methods 0.000 claims description 32
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 30
- 239000003502 gasoline Substances 0.000 claims description 29
- 229910001385 heavy metal Inorganic materials 0.000 claims description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- 239000004215 Carbon black (E152) Substances 0.000 claims description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- 239000005995 Aluminium silicate Substances 0.000 claims description 25
- 235000012211 aluminium silicate Nutrition 0.000 claims description 25
- 238000000354 decomposition reaction Methods 0.000 claims description 25
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 24
- 229910052746 lanthanum Inorganic materials 0.000 claims description 23
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 23
- 150000002739 metals Chemical class 0.000 claims description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
- 230000036961 partial effect Effects 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 21
- 229910052684 Cerium Inorganic materials 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 238000004458 analytical method Methods 0.000 claims description 16
- 238000009825 accumulation Methods 0.000 claims description 14
- 238000004939 coking Methods 0.000 claims description 14
- 229910052720 vanadium Inorganic materials 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 238000000197 pyrolysis Methods 0.000 claims description 10
- 238000011282 treatment Methods 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 9
- 238000001704 evaporation Methods 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 7
- 230000000670 limiting effect Effects 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 229940037003 alum Drugs 0.000 claims description 6
- 238000004523 catalytic cracking Methods 0.000 claims description 6
- 239000000356 contaminant Substances 0.000 claims description 6
- 230000001172 regenerating effect Effects 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000003546 flue gas Substances 0.000 claims description 5
- 239000012263 liquid product Substances 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 230000000750 progressive effect Effects 0.000 claims description 5
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- 230000009849 deactivation Effects 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 239000011364 vaporized material Substances 0.000 claims description 3
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 108090000790 Enzymes Proteins 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 230000003134 recirculating effect Effects 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 9
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 241000239290 Araneae Species 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 239000007792 gaseous phase Substances 0.000 claims 1
- 238000007790 scraping Methods 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 239000010802 sludge Substances 0.000 claims 1
- 239000011148 porous material Substances 0.000 description 50
- 239000010779 crude oil Substances 0.000 description 42
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 26
- 239000001257 hydrogen Substances 0.000 description 21
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- 239000000243 solution Substances 0.000 description 19
- 239000000499 gel Substances 0.000 description 16
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- 238000009826 distribution Methods 0.000 description 13
- -1 clays Chemical compound 0.000 description 12
- 238000000926 separation method Methods 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 10
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 9
- 238000011161 development Methods 0.000 description 8
- 230000018109 developmental process Effects 0.000 description 8
- 230000002829 reductive effect Effects 0.000 description 8
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000000295 fuel oil Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000011269 tar Substances 0.000 description 5
- 238000004448 titration Methods 0.000 description 5
- 239000010426 asphalt Substances 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 229910052622 kaolinite Inorganic materials 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- SWZDQOUHBYYPJD-UHFFFAOYSA-N tridodecylamine Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC SWZDQOUHBYYPJD-UHFFFAOYSA-N 0.000 description 4
- 238000005292 vacuum distillation Methods 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000017 hydrogel Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 150000002605 large molecules Chemical class 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
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- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
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- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- GGZZISOUXJHYOY-UHFFFAOYSA-N 8-amino-4-hydroxynaphthalene-2-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C2C(N)=CC=CC2=C1O GGZZISOUXJHYOY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
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- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 description 1
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- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
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- 229930014456 matrine Natural products 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000011273 tar residue Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000010518 undesired secondary reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/483,061 US4480047A (en) | 1983-04-07 | 1983-04-07 | High performance catalysts for carbometallic oil conversion and their manufacturing and use |
| US483061 | 1983-04-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59217793A true JPS59217793A (ja) | 1984-12-07 |
| JPS6247920B2 JPS6247920B2 (cg-RX-API-DMAC7.html) | 1987-10-09 |
Family
ID=23918486
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59069893A Granted JPS59217793A (ja) | 1983-04-07 | 1984-04-07 | 炭素−金属油を転化する方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4480047A (cg-RX-API-DMAC7.html) |
| EP (1) | EP0124716A3 (cg-RX-API-DMAC7.html) |
| JP (1) | JPS59217793A (cg-RX-API-DMAC7.html) |
| AU (1) | AU575811B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BR8401619A (cg-RX-API-DMAC7.html) |
| CA (1) | CA1206458A (cg-RX-API-DMAC7.html) |
| ES (2) | ES531382A0 (cg-RX-API-DMAC7.html) |
| MX (1) | MX163299A (cg-RX-API-DMAC7.html) |
| NO (1) | NO168120C (cg-RX-API-DMAC7.html) |
| PT (1) | PT78385B (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA842424B (cg-RX-API-DMAC7.html) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE33728E (en) * | 1981-11-24 | 1991-10-29 | Total Engineering And Research Company | Method for catalytically converting residual oils |
| USH222H (en) | 1982-11-16 | 1987-03-03 | W. R. Grace & Co. | Hydrocarbon conversion catalysts |
| WO1985001225A1 (fr) * | 1983-09-22 | 1985-03-28 | Catalysts & Chemicals Industries Co., Ltd. | Procede de preparation d'une composition de catalyseur destinee a etre utilisee dans le craquage d'hydrocarbures |
| JPS60193543A (ja) * | 1984-03-15 | 1985-10-02 | Shokubai Kasei Kogyo Kk | 炭化水素接触分解用触媒組成物の製造法 |
| US4744886A (en) * | 1984-10-03 | 1988-05-17 | Union Carbide Corporation | Catalytic cracking catalysts for high octane gasoline products |
| US4588496A (en) * | 1985-01-03 | 1986-05-13 | Union Oil Company Of California | Process for the catalytic cracking of metals-containing feedstocks |
| US4900428A (en) * | 1985-07-26 | 1990-02-13 | Union Oil Company Of California | Process for the catalytic cracking of vanadium-containing feedstocks |
| US5037531A (en) * | 1986-08-15 | 1991-08-06 | Mobil Oil Corporation | Catalytic cracking process |
| US4880787A (en) * | 1986-08-15 | 1989-11-14 | Mobil Oil Corporation | Cracking catalyst |
| US4810369A (en) * | 1987-05-07 | 1989-03-07 | Union Oil Company Of California | Process for the catalytic cracking of feedstocks containing high levels of nitrogen |
| US4880521A (en) * | 1987-05-07 | 1989-11-14 | Union Oil Company Of California | Process for the cracking of feedstocks containing high levels of nitrogen |
| US5298153A (en) * | 1987-05-07 | 1994-03-29 | Union Oil Company Of California | Cracking process using an attrition resistant catalyst |
| US4913801A (en) * | 1988-06-17 | 1990-04-03 | Betz Laboratories, Inc. | Passivation of FCC catalysts |
| US5071806A (en) * | 1988-09-30 | 1991-12-10 | Chevron Research And Technology Company | Vanadium tolerant cracking catalyst |
| US5160601A (en) * | 1988-09-30 | 1992-11-03 | Chevron Research Company | Hydrocarbon conversion with octane-enhancing catalysts |
| US5135641A (en) * | 1988-11-23 | 1992-08-04 | Chevron Research Company | Catalytic cracking process employing silica/alumina cogel catalysts |
| FR2673385B1 (fr) * | 1991-03-01 | 1994-07-22 | Inst Francais Du Petrole | Catalyseur de craquage de charges hydrocarbonees riches en composes naphteniques et/ou en paraffines comprenant une zeolithe y et une matrice . |
| US5147836A (en) * | 1991-10-18 | 1992-09-15 | W. R. Grace & Co.-Conn. | Catalytic cracking catalysts |
| US5646082A (en) * | 1993-06-24 | 1997-07-08 | Cosmo Research Institute | Crystalline aluminosilicate, process for producing the same, and catalyst employing the same for catalytic cracking of hydrocarbon oil |
| HU213644B (en) * | 1995-11-22 | 1997-12-29 | Mol Magyar Olaj & Gazipari Rt | Additiv catalyst for cracking petroleum fractions, process for making thereof and cracking process |
| US5688975A (en) * | 1996-04-10 | 1997-11-18 | Uop | Rare earth stabilized Cr/Ti substituted molecular sieves |
| JPH11561A (ja) * | 1997-06-13 | 1999-01-06 | Tonen Corp | 重質油の接触分解用添加触媒 |
| US20020153283A1 (en) * | 1998-12-28 | 2002-10-24 | Arthur W Chester | Gasoline sulfur reduction in fluid catalytic cracking |
| US6846403B2 (en) * | 1998-12-28 | 2005-01-25 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US6974787B2 (en) | 1998-08-31 | 2005-12-13 | Exxonmobil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US7803267B2 (en) * | 1998-12-28 | 2010-09-28 | W. R. Grace & Co.-Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| US7507686B2 (en) * | 2002-12-03 | 2009-03-24 | W. R. Grace & Co. - Conn. | Gasoline sulfur reduction in fluid catalytic cracking |
| CN1311907C (zh) * | 2004-07-29 | 2007-04-25 | 中国石油化工股份有限公司 | 一种石油烃裂化催化剂及其制备方法 |
| RU2287370C1 (ru) * | 2005-11-17 | 2006-11-20 | ООО "Компания Катахим" | Способ получения шарикового катализатора крекинга |
| CA2539231C (en) * | 2006-03-10 | 2013-08-13 | Baojian Shen | Catalyst composition for treating heavy feedstocks |
| JP2009542428A (ja) * | 2006-07-06 | 2009-12-03 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 硫酸アルミニウムで結合された触媒 |
| EP2242572A2 (en) * | 2007-12-20 | 2010-10-27 | W.R. Grace & Co.-Conn. | Process for preparing high attrition resistant inorganic compositions and compositions prepared therefrom |
| US9447332B2 (en) | 2013-02-12 | 2016-09-20 | Saudi Basic Industries Corporation | Conversion of plastics to olefin and aromatic products using temperature control |
| US8895790B2 (en) | 2013-02-12 | 2014-11-25 | Saudi Basic Industries Corporation | Conversion of plastics to olefin and aromatic products |
| US9428695B2 (en) | 2013-02-12 | 2016-08-30 | Saudi Basic Industries Corporation | Conversion of plastics to olefin and aromatic products with product recycle |
| JP7083360B2 (ja) * | 2017-02-22 | 2022-06-10 | 中国石油化工股▲ふん▼有限公司 | 接触分解触媒およびその生成方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2840530A (en) * | 1954-07-20 | 1958-06-24 | Houdry Process Corp | Preparation of porous kaolin catalysts |
| US3816342A (en) * | 1963-05-14 | 1974-06-11 | Mobil Oil Corp | Process for preparing a crystalline aluminosilicate zeolite |
| US3553104A (en) * | 1967-12-26 | 1971-01-05 | Mobil Oil Corp | Catalyst matrix material,composite catalyst,and methods of preparing same |
| US3449265A (en) * | 1968-08-14 | 1969-06-10 | Exxon Research Engineering Co | Cracking catalyst compositions |
| US3556988A (en) * | 1969-01-29 | 1971-01-19 | Mobil Oil Corp | Method of preparing composite catalyst and hydrocarbon conversion therewith |
| US3790471A (en) * | 1969-10-10 | 1974-02-05 | Mobil Oil Corp | Conversion with zsm-5 family of crystalline aluminosilicate zeolites |
| US3717587A (en) * | 1970-04-13 | 1973-02-20 | Mobil Oil Corp | Catalyst and method of preparing the same |
| US3696025A (en) * | 1970-11-09 | 1972-10-03 | Chevron Res | Catalytic cracking by addition of titanium to catalyst |
| US3867310A (en) * | 1972-05-08 | 1975-02-18 | Grace W R & Co | Catalyst compositions |
| US3912619A (en) * | 1972-08-21 | 1975-10-14 | Grace W R & Co | Preparation of cracking catalyst |
| US4144194A (en) * | 1973-04-11 | 1979-03-13 | W. R. Grace & Co. | Zeolite promoted hydrocarbon conversion catalysts |
| US3930987A (en) * | 1973-04-12 | 1976-01-06 | Mobil Oil Corporation | Catalyst and method of preparing same |
| US3867308A (en) * | 1973-12-10 | 1975-02-18 | Grace W R & Co | Process for preparing a petroleum cracking catalyst |
| US4199556A (en) * | 1973-12-13 | 1980-04-22 | Mobil Oil Corporation | Method for producing zeolites |
| US4010116A (en) * | 1974-10-15 | 1977-03-01 | Filtrol Corporation | Fluid cracking catalysts |
| IT1054410B (it) * | 1975-11-21 | 1981-11-10 | Mitsui Petrochemical Ind | Catalizzatori per la polimerizzazione delle alfa olefine |
| US4086187A (en) * | 1976-06-17 | 1978-04-25 | Filtrol Corporation | Attrition resistant zeolitic catalyst |
| US4164465A (en) * | 1976-06-23 | 1979-08-14 | Exxon Research & Engineering Co. | Hydrocarbon cracking with catalyst containing a CO oxidation promoter in ultra-stable zeolite particles |
| US4100108A (en) * | 1976-08-27 | 1978-07-11 | Filtrol Corporation | Zeolitic catalysts and method of producing same |
| US4192778A (en) * | 1976-08-27 | 1980-03-11 | Filtrol Corporation | Rare earth exchange faujasite zeolite catalyst containing same and process for producing same |
| US4085069A (en) * | 1976-08-27 | 1978-04-18 | Filtrol Corporation | Hydrothermally stable catalysts containing ammonium faujasite zeolites |
| US4058484A (en) * | 1976-09-09 | 1977-11-15 | Filtrol Corporation | Ammonium faujasite zeolites |
| US4088605A (en) * | 1976-09-24 | 1978-05-09 | Mobil Oil Corporation | ZSM-5 containing aluminum-free shells on its surface |
| US4203869A (en) * | 1976-09-24 | 1980-05-20 | Mobil Oil Corporation | ZSM-5 Containing aluminum-free shells on its surface |
| US4142995A (en) * | 1977-02-16 | 1979-03-06 | Filtrol Corporation | Method of producing zeolitic catalysts with silica alumina matrix |
| US4310441A (en) * | 1977-02-16 | 1982-01-12 | Filtrol Corporation | Large pore silica-alumina gels and method of producing the same |
| US4198319A (en) * | 1977-02-16 | 1980-04-15 | Filtrol Corporation | Method of producing zeolitic catalysts with silica alumina matrix |
| US4215016A (en) * | 1978-02-03 | 1980-07-29 | Filtrol Corporation | Exchanged faujasite zeolite catalyst containing same and process for producing same |
| US4224188A (en) * | 1978-03-13 | 1980-09-23 | Filtrol Corporation | Aluminum faujasites, catalyst containing same and process of producing same |
| US4253989A (en) * | 1978-04-14 | 1981-03-03 | Filtrol Corporation | Zeolitic catalyst and method of producing same |
| US4219446A (en) * | 1978-04-26 | 1980-08-26 | Mobil Oil Corporation | Zeolite-containing silica-alumina hydrogel catalyst and method of making same |
| US4333857A (en) * | 1979-01-15 | 1982-06-08 | Filtrol Corporation | Attrition resistant zeolite containing catalyst |
| US4206085A (en) * | 1979-01-15 | 1980-06-03 | Filtrol Corporation | Balanced alumina matrix in zeolite containing catalyst |
| US4246138A (en) * | 1979-01-16 | 1981-01-20 | Filtrol Corporation | Crystalline alumino silicate-silica-alumina gel catalysts and processes for producing same |
| US4259210A (en) * | 1979-01-16 | 1981-03-31 | Filtrol Corporation | Crystalline alumino silicate-silica-alumina gel hydrocarbon conversion catalysts and processes for producing same |
| US4237031A (en) * | 1979-02-05 | 1980-12-02 | Filtrol Corporation | Crystallized silica-alumina cogel and catalyst employing the same |
| US4226743A (en) * | 1979-03-12 | 1980-10-07 | W. R. Grace & Co. | Silica-alumina hydrogel catalyst |
| US4309277A (en) * | 1979-05-04 | 1982-01-05 | Uop Inc. | Conversion of hydrocarbons with a catalyst comprising an alumina-zeolite, a group VI-B metallic component and a group VIII metallic component |
| US4239654A (en) * | 1979-05-31 | 1980-12-16 | Exxon Research & Engineering Co. | Hydrocarbon cracking catalyst and process utilizing the same |
| US4234457A (en) * | 1979-06-01 | 1980-11-18 | Filtrol Corporation | Crystallized silica-alumina cogel and catalyst employing the same |
| US4252684A (en) * | 1979-06-01 | 1981-02-24 | Filtrol Corporation | Crystallized silica-alumina cogel and catalyst employing the same |
| US4263174A (en) * | 1979-08-29 | 1981-04-21 | Uop Inc. | Low coke-make FCC catalyst |
| US4228137A (en) * | 1979-10-18 | 1980-10-14 | Filtrol Corporation | Method of producing faujasite zeolites employing seeding techniques |
| US4325845A (en) * | 1979-11-09 | 1982-04-20 | Filtrol Corporation | Zeolite catalysts and method of producing the same |
| US4341624A (en) * | 1979-11-14 | 1982-07-27 | Ashland Oil, Inc. | Carbo-metallic oil conversion |
| US4319983A (en) * | 1980-05-19 | 1982-03-16 | Atlantic Richfield Company | Passivation process |
| US4269815A (en) * | 1980-05-23 | 1981-05-26 | Filtrol Corporation | Method of exchanging sodium zeolite |
| US4325847A (en) * | 1980-06-19 | 1982-04-20 | Filtrol Corporation | Use of additional alumina for extra zeolite stability in FCC catalyst |
| US4339354A (en) * | 1980-10-10 | 1982-07-13 | Exxon Research & Engineering Co. | Hydrocarbon conversion catalysts |
| US4407714A (en) * | 1981-05-13 | 1983-10-04 | Ashland Oil, Inc. | Process for cracking high-boiling hydrocarbons using high pore volume, low density catalyst |
| US4508839A (en) * | 1981-08-27 | 1985-04-02 | Ashland Oil, Inc. | Catalyst for the conversion of carbo-metallic containing oils |
| US4415438A (en) * | 1981-11-24 | 1983-11-15 | Dean Robert R | Method for catalytically converting residual oils |
| US4440868A (en) * | 1981-12-07 | 1984-04-03 | Ashland Oil, Inc. | Carbo-metallic oil conversion catalysts |
| EP0103160A1 (en) * | 1982-09-02 | 1984-03-21 | Ashland Oil, Inc. | Catalytic upgrading of reduced crudes and residual oils with a coke selective catalyst |
| DE3374918D1 (en) * | 1983-01-04 | 1988-01-28 | Ashland Oil Inc | Process for the preparation of an rcc catalyst |
-
1983
- 1983-04-07 US US06/483,061 patent/US4480047A/en not_active Expired - Lifetime
-
1984
- 1984-03-09 EP EP84102541A patent/EP0124716A3/en not_active Withdrawn
- 1984-03-20 CA CA000449991A patent/CA1206458A/en not_active Expired
- 1984-03-27 AU AU26139/84A patent/AU575811B2/en not_active Ceased
- 1984-03-30 ZA ZA842424A patent/ZA842424B/xx unknown
- 1984-04-05 MX MX200922A patent/MX163299A/es unknown
- 1984-04-06 ES ES531382A patent/ES531382A0/es active Granted
- 1984-04-06 PT PT78385A patent/PT78385B/pt not_active IP Right Cessation
- 1984-04-06 BR BR8401619A patent/BR8401619A/pt unknown
- 1984-04-06 NO NO841369A patent/NO168120C/no not_active IP Right Cessation
- 1984-04-07 JP JP59069893A patent/JPS59217793A/ja active Granted
-
1985
- 1985-07-09 ES ES545008A patent/ES545008A0/es active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| ES8603765A1 (es) | 1986-01-01 |
| US4480047A (en) | 1984-10-30 |
| PT78385A (en) | 1984-05-01 |
| EP0124716A3 (en) | 1986-12-10 |
| ES545008A0 (es) | 1986-01-01 |
| AU575811B2 (en) | 1988-08-11 |
| NO168120C (no) | 1992-01-15 |
| BR8401619A (pt) | 1984-11-13 |
| AU2613984A (en) | 1984-10-11 |
| ES8602910A1 (es) | 1985-12-01 |
| MX163299A (es) | 1992-04-13 |
| JPS6247920B2 (cg-RX-API-DMAC7.html) | 1987-10-09 |
| NO168120B (no) | 1991-10-07 |
| ES531382A0 (es) | 1985-12-01 |
| EP0124716A2 (en) | 1984-11-14 |
| PT78385B (en) | 1986-05-28 |
| NO841369L (no) | 1984-10-08 |
| ZA842424B (en) | 1984-11-28 |
| CA1206458A (en) | 1986-06-24 |
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