JPS59196454A - Combustion state detecting method - Google Patents
Combustion state detecting methodInfo
- Publication number
- JPS59196454A JPS59196454A JP22498782A JP22498782A JPS59196454A JP S59196454 A JPS59196454 A JP S59196454A JP 22498782 A JP22498782 A JP 22498782A JP 22498782 A JP22498782 A JP 22498782A JP S59196454 A JPS59196454 A JP S59196454A
- Authority
- JP
- Japan
- Prior art keywords
- exhaust gas
- combustion state
- metal oxide
- air
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、ガスあるいは石油ストーブ、自動車エンジン
等の、炭化水素を主成分とする燃料を大気と混合して燃
やす燃焼器の燃焼状態を検出する方法に関する。Detailed Description of the Invention (Industrial Application Field) The present invention detects the combustion state of a combustor such as a gas or oil stove, or a car engine, which burns a fuel mainly composed of hydrocarbons mixed with the atmosphere. Regarding how to.
(従来例の構成とその問題点)
一般に、SnOr ZnO+ Tie2+ Fe2O3
+ Coo等の金属酸化物半導体の電気抵抗値が、雰囲
気中のガス組成により変化することは広く知られており
、この現象を利用した内燃機関、バーナ等の燃焼状態の
検出に用いる賦与がなされている。すなわち排気ガス中
の特定成分、多くは酸素、あるいはNOx等の酸化性ガ
ス濃度の増減を検知し空燃比(以下A/’Fと記す)を
制御することで、省燃料化、を図ろうとするものである
。(Conventional structure and its problems) Generally, SnOr ZnO+ Tie2+ Fe2O3
+ It is widely known that the electrical resistance value of metal oxide semiconductors such as Coo changes depending on the gas composition in the atmosphere, and this phenomenon has been used to detect the combustion state of internal combustion engines, burners, etc. ing. In other words, it attempts to save fuel by detecting increases and decreases in the concentration of specific components in exhaust gas, mostly oxygen or oxidizing gases such as NOx, and controlling the air-fuel ratio (hereinafter referred to as A/'F). It is something.
しかしながら、必ずしも排気ガス成分組成が、燃焼状態
に対応する形で得られることはなく、自動車エンノンを
例にとれば、同−p、/F値であっても、エンジン回転
数、点火時期、負荷等が変化すると排気ガス組成も大き
く変化することから、現在はA/F f細かく制御する
ことはむずかしく、省燃料化をはかるには、A/Fが1
4.7より大きくなるところでのA/Fの制御が必要と
されるにもかかわらず、排気ガス組成が極端に変化する
理想空燃比(A/F″=14.7)のみによる燃焼状態
の制御しかできない欠点があった。However, the exhaust gas component composition cannot always be obtained in a form that corresponds to the combustion state. Taking an automobile engine as an example, even if the -p, /F value is the same, the engine speed, ignition timing, load, etc. As the exhaust gas composition changes greatly when the
Controlling the combustion state using only the ideal air-fuel ratio (A/F'' = 14.7) where the exhaust gas composition changes drastically, even though it is necessary to control the A/F at a point where it becomes greater than 4.7. There was a drawback that could only be done.
(発明の目的)
本発明は、従来のこのような欠点をなくシ、A/Fを理
想空燃比だけでなく、A4値を幅広い範囲で制御するた
めの燃焼状態の検知方法を提供することを目的とする。(Objective of the Invention) The present invention eliminates these conventional drawbacks and provides a combustion state detection method for controlling the A/F not only at the ideal air-fuel ratio but also at the A4 value over a wide range. purpose.
(発明の構成)
本発明は、燃焼状態の検知を、排気力゛ス中での金属酸
化物の電気抵抗の変化と排気ガス温度を同時に検出する
ことで行なおうとするものでおる。(Structure of the Invention) The present invention attempts to detect the combustion state by simultaneously detecting the change in electrical resistance of the metal oxide in the exhaust gas and the temperature of the exhaust gas.
すなわち、排気ガスは、高温で燃焼器から排出されるの
であるが、この排気ガスのガス成分中には、高温下(例
えば、300〜600℃)ではお互いに化学反応を起こ
す成分、No 、 No 、 Co、02゜■20等
が含まれており、これらガス成分の濃度は、お互いの濃
度と排気ガス温度によシ規定されてぃ比
NOとNO2とH2O2間には3NO2+H2O−+
2HNO3+NOのように互いに複雑にからみ合ってお
り 、K l +K ’2 + K 3は、各反応
の平衡定数であり、主に温度により決定されるため、排
気ガス温度は、排気ガス中の成分組成を決定している重
要な因子であることがわかる。また、一方、代表的な燃
焼器として自動車エンジンを例にとれば、排気ガス温度
は、一般に、負荷が大きい程、エンジン回転数が大きい
程高くなり、同一負荷、回転数では、A/Fにあまシ依
存しない(A7F = 14〜19の間で±20℃程度
の変動)ことが知られている。That is, exhaust gas is discharged from the combustor at high temperature, and the gas components of this exhaust gas include components that cause chemical reactions with each other at high temperatures (for example, 300 to 600 degrees Celsius). , Co, 02゜■20, etc., and the concentrations of these gas components are determined by their respective concentrations and exhaust gas temperature.The ratio between NO, NO2, and H2O2 is 3NO2 + H2O-+.
They are intricately entangled with each other like 2HNO3 + NO, and K l + K'2 + K3 is the equilibrium constant of each reaction and is mainly determined by temperature, so the exhaust gas temperature depends on the component composition in the exhaust gas. It can be seen that this is an important factor determining the On the other hand, if we take an automobile engine as a typical combustor, the exhaust gas temperature generally increases as the load and engine speed increase; It is known that it is not dependent on sweetness (variation of approximately ±20°C between A7F = 14 and 19).
本発明は、以上のような、燃焼器の本来の特性に着目し
て創意されたもので、空燃比以外の燃焼状態を規定する
因子、例えば回転数とか負荷等による排気ガス状態の変
動分を、排気ガス温度を同時に検出することにより有効
に取り除くことができ、これを金属酸化物半導体の電気
抵抗の変化の検出と組み合せることで理想空燃比以外で
も八Aを制御することができ、省燃料化をはかる際の有
効な方法となるものである。The present invention was devised by focusing on the inherent characteristics of the combustor as described above, and is designed to compensate for fluctuations in the exhaust gas state due to factors that define the combustion state other than the air-fuel ratio, such as rotation speed and load. , can be effectively removed by simultaneously detecting the exhaust gas temperature, and by combining this with detecting changes in the electrical resistance of metal oxide semiconductors, it is possible to control 8A even at non-ideal air-fuel ratios, resulting in savings. This is an effective method for turning it into fuel.
(実施例の説明)
第1図は、本発明の効果をみるために用いた金属酸化物
半導体をガス感応体としたガス検知器の外観を示す図、
第2図は、第1図に示したガス検知器10の部分拡大図
で、11はガス検知部、12はガス感応体であシ、金属
錫を蒸発源とするスパンクリング法で形成した厚さ50
00Xの酸化錫(5nO2)金属酸化物半導体の膜であ
る。13は導電性の白金ベーストを印刷焼き付けること
で得たガス感応体2の電気抵抗の変化を外部信号として
取り出すための電極である。14は直径9てφ、厚さ0
.5朝のアルミナ基板、15は排気ガス温度を検知する
だめのCA線(クロメル−アルメル線)より成る熱電対
である。(Description of Examples) FIG. 1 is a diagram showing the appearance of a gas detector using a metal oxide semiconductor as a gas sensitive material, which was used to examine the effects of the present invention.
FIG. 2 is a partially enlarged view of the gas detector 10 shown in FIG. Sa 50
00X tin oxide (5nO2) metal oxide semiconductor film. Reference numeral 13 denotes an electrode for extracting a change in electrical resistance of the gas sensitive body 2 obtained by printing and baking a conductive platinum base as an external signal. 14 has a diameter of 9φ and a thickness of 0
.. 5 is an alumina substrate, and 15 is a thermocouple made of a CA wire (chromel-alumel wire) for detecting the exhaust gas temperature.
次に、本発明を自動車エンジンに適用した場合について
説明する。第3図において、30は自動車エンジンの排
気管20に取り付けた前述のガス検知器10からの電気
抵抗と温度の信号を受けて、燃料噴射量制御装置40に
信号を送り出すだめのデータ処理装置である。Next, a case where the present invention is applied to an automobile engine will be described. In FIG. 3, 30 is a data processing device that receives electrical resistance and temperature signals from the aforementioned gas detector 10 attached to the exhaust pipe 20 of the automobile engine and sends the signals to the fuel injection amount control device 40. be.
用いた自動車エンジンの仕様は、以下の通りである。The specifications of the automobile engine used are as follows.
種 類;水冷単筒4サイクルガソリンエンジ
ンボア×ストロークニア4.0X750聾排 気
量:322.6cc
圧 縮 比=871
最高軸出カニ 12.1 / 5500 ps/ rp
m最高軸トルク:2.1/2000 kg・m/rp
m最大平均有効圧: 8.0/2000 kg/c
m2/ rpmエンジンを通常の自動車の運転状態をほ
ぼ満足する回転数1500 rpm〜3000rpm、
点火角20°〜40°、負荷1/4負荷〜全負荷 の範
囲で、空燃比を13〜16.5の範囲で運転したときの
、ガス検知器の電気抵抗と、排気ガス温度の関係を示し
たのが第4図である。この図から明らかなように、回転
数、負荷1点火角に依らず、本発明に従いガス検知器の
電気抵抗と排気ガス温度を同時に検知することで諺が一
義的に精度良く決定され、燃焼状態の検知が有効になさ
れることが解る。Type: Water-cooled single-cylinder 4-stroke gasoline engine Bore x stroke near 4.0 x 750 deaf exhaust
Volume: 322.6cc Compression ratio = 871 Maximum shaft output 12.1 / 5500 ps/ rp
m maximum shaft torque: 2.1/2000 kg・m/rp
m Maximum average effective pressure: 8.0/2000 kg/c
m2/rpm The engine has a rotational speed of 1500 rpm to 3000 rpm, which almost satisfies the driving conditions of a normal car.
The relationship between the electrical resistance of the gas detector and the exhaust gas temperature when operating at an ignition angle of 20° to 40°, a load of 1/4 to full load, and an air-fuel ratio of 13 to 16.5. This is shown in Figure 4. As is clear from this figure, by simultaneously detecting the electrical resistance of the gas detector and the exhaust gas temperature according to the present invention, regardless of the rotational speed or load/ignition angle, the combustion state can be determined uniquely and accurately. It can be seen that the detection can be performed effectively.
比較のために、ガス検知器の電気抵抗の変化をA/Fに
対してゾロントしたのが第5図であるが、ガス検知器の
電気抵抗のみではA/F値は精度良く一義的に決まり難
いことが解る。For comparison, Figure 5 shows the change in the electrical resistance of the gas detector compared to the A/F, but the A/F value can be determined accurately and uniquely by the electrical resistance of the gas detector alone. I understand difficult things.
このことから、いかに本発明の検知方法が優れているか
が理解されよう。From this, it will be understood how superior the detection method of the present invention is.
なお、本発明の実施例では、燃焼器として自動車エンノ
ンを例にとって示したが、その他の燃焼器、例えばガス
ストーブ、石油ストーブ等においても本発明の効果が有
効に作用するものであり、また、金属酸化物半導体とし
て、酸化錫を一例として挙げたが、酸化錫以外の金属酸
化物半導体、例えばT ’、 O、ZnO、Fe2O3
、CoOを用いても本発明の効果を有効に得られるのは
言う壕でもないことである。In the embodiments of the present invention, an automobile ennon was used as an example of a combustor, but the effects of the present invention can be effectively applied to other combustors, such as gas stoves and kerosene stoves. Although tin oxide is mentioned as an example of the metal oxide semiconductor, metal oxide semiconductors other than tin oxide, such as T', O, ZnO, Fe2O3
It is no secret that the effects of the present invention can be effectively obtained even if CoO is used.
(発明の効果)
以上説明したように本発明は、燃焼器の排気ガス中での
金属酸化物半導体の電気抵抗と、燃焼器の排気ガス酷度
から燃焼器の空燃比を検出するようにしたので、A/F
以外の燃焼状態を規定する因子を有効に取り除くことが
できる。したがって本発明の燃焼状態検知方法によれば
、A/F値を理想空燃比だけでなく、幅広い範囲で制御
することが可能となる。(Effects of the Invention) As explained above, the present invention detects the air-fuel ratio of the combustor from the electrical resistance of the metal oxide semiconductor in the exhaust gas of the combustor and the severity of the exhaust gas of the combustor. Therefore, A/F
It is possible to effectively eliminate factors that determine the combustion state other than the above. Therefore, according to the combustion state detection method of the present invention, it is possible to control the A/F value not only at the ideal air-fuel ratio but also over a wide range.
第1図は本発明に用いられるガス検知器の外観図、第2
図(A)は第1図に示したガス検知器の部分拡大平面図
、第2図(B)は同じく部分拡大断面図、第3図は本発
明を自動車エンジンに適用した場合の説明図、第4図は
本発明の詳細な説明するための、排気ガス温度と、ガス
検知器の電気抵抗と、空燃比の関係を示す図、第5図は
ガス検知器の電気抵抗と空燃比の関係を示す図である。
io・・・ガス検知器、1トガス検知部、12 ・アル
きy港夷(
ガス感応体、13 電極、14・・蜘寺→、20・・排
気管、30・・データ処理装置、40・燃料噴射量制御
装置。
第1図 第2図
(81
2
b
第3図
第4図
200 300 400 500
600琲襖5力゛又垢戻 (6C)Figure 1 is an external view of the gas detector used in the present invention, Figure 2 is an external view of the gas detector used in the present invention.
Figure (A) is a partially enlarged plan view of the gas detector shown in Figure 1, Figure 2 (B) is a partially enlarged sectional view, and Figure 3 is an explanatory diagram when the present invention is applied to an automobile engine. Fig. 4 is a diagram showing the relationship between exhaust gas temperature, electrical resistance of a gas detector, and air-fuel ratio for detailed explanation of the present invention, and Fig. 5 is a diagram showing the relationship between electrical resistance of a gas detector and air-fuel ratio. FIG. io...Gas detector, 1 Gas detection unit, 12 Gas sensitive body, 13 Electrode, 14...Kumeda →, 20...Exhaust pipe, 30...Data processing device, 40... Fuel injection amount control device. Fig. 1 Fig. 2 (81 2 b Fig. 3 Fig. 4 200 300 400 500
600 琲 Fusuma 5 Power゛Mata return (6C)
Claims (1)
、燃焼器の排気ガス温度とから燃焼器の空燃比を検出す
ることを特徴とする燃焼状態検知方法。A combustion state detection method comprising detecting an air-fuel ratio of a combustor from the electrical resistance of a metal oxide semiconductor in the exhaust gas of the combustor and the temperature of the exhaust gas of the combustor.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22498782A JPS59196454A (en) | 1982-12-23 | 1982-12-23 | Combustion state detecting method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22498782A JPS59196454A (en) | 1982-12-23 | 1982-12-23 | Combustion state detecting method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59196454A true JPS59196454A (en) | 1984-11-07 |
JPH0514226B2 JPH0514226B2 (en) | 1993-02-24 |
Family
ID=16822319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22498782A Granted JPS59196454A (en) | 1982-12-23 | 1982-12-23 | Combustion state detecting method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59196454A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6398407B2 (en) * | 2000-06-07 | 2002-06-04 | Mitsubishi Denki Kabushiki Kaisha | Temperature detector for exhaust gas sensor |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55122143A (en) * | 1979-03-15 | 1980-09-19 | Nippon Soken Inc | Gas detector |
JPS5739341A (en) * | 1980-08-22 | 1982-03-04 | Toyota Motor Corp | Oxygen sensor |
-
1982
- 1982-12-23 JP JP22498782A patent/JPS59196454A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55122143A (en) * | 1979-03-15 | 1980-09-19 | Nippon Soken Inc | Gas detector |
JPS5739341A (en) * | 1980-08-22 | 1982-03-04 | Toyota Motor Corp | Oxygen sensor |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6398407B2 (en) * | 2000-06-07 | 2002-06-04 | Mitsubishi Denki Kabushiki Kaisha | Temperature detector for exhaust gas sensor |
Also Published As
Publication number | Publication date |
---|---|
JPH0514226B2 (en) | 1993-02-24 |
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