JPS59193811A - Solid preparation - Google Patents
Solid preparationInfo
- Publication number
- JPS59193811A JPS59193811A JP6636984A JP6636984A JPS59193811A JP S59193811 A JPS59193811 A JP S59193811A JP 6636984 A JP6636984 A JP 6636984A JP 6636984 A JP6636984 A JP 6636984A JP S59193811 A JPS59193811 A JP S59193811A
- Authority
- JP
- Japan
- Prior art keywords
- solid
- methyl
- pirimiphos
- component
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
木発19Jは、ピリミホスメチルと配合系忌の固形!成
分とヒリミホヌメfルとを組合せた固形製剤に閃する。[Detailed Description of the Invention] Kibatsu 19J is a solid compound containing pirimiphos methyl! It is a solid preparation that combines the ingredients and hirimihonumefl.
を1(々の作用、佐賀を有するl物質が他方間でいろん
な目U!tでイ史用されており、単独であるいは相(々
のt11合せ、混合、配合でよシ有効に用いられている
。これら物質を椋々の組合せで1配合した場合V乙配合
するとIF’d時にあるいは徐々に変化たとえば化学的
変仕、理学的変化、薬理学的変化などが生じ、使用時拠
不4jiX、e−まだは不便な状Jルになることがあり
、配合禁忌と称されている。このような物質を2種以上
配合した場合に生ずる配合禁忌は、農薬、医薬を始め種
々の技術分野において、物質のたとえばよシ有効なある
いは省力的な利用の障壁となっている。たとえば、現在
特長のある農園芸用殺虫剤、殺菌剤が多数開発され、各
々の特長を活かして、各種の混合製剤が数多く実用化さ
れ、同時防除を可S1gKL防除作業の省力化に大いに
貢献している。しかし、非常に有用な特長を有し乍ら2
種以上の成分を配合すると、化学的に著しく不安定圧な
9、本来有する優れた防除効果が失われ、実用に供され
ない互に配合禁忌の成分が多くめシ、今だに2梗以上の
配合禁忌の成分を含有する農園芸用固型製剤は市販され
ていない。1. Substances with different effects and effects have been used in various ways in history, and can be used effectively alone or in combination, mixtures, and combinations. When these substances are combined in one combination, chemical changes, physical changes, pharmacological changes, etc. occur during IF'd, and when these substances are combined, chemical, physical, and pharmacological changes occur, However, this may result in an inconvenient condition, which is called a combination contraindication.The combination contraindication that occurs when two or more of these substances are combined is used in various technical fields, including agricultural chemicals and medicine. For example, many agricultural and horticultural insecticides and fungicides with special characteristics have been developed, and various mixed preparations have been developed by taking advantage of the characteristics of each. A number of S1gKL control systems have been put into practical use, and they can perform simultaneous control, greatly contributing to labor savings in control work.However, although they have very useful features,
If more than one ingredient is combined, it will be chemically extremely unstable (9), the original excellent control effect will be lost, and there will be many ingredients that are contraindicated in combination, making it unsuitable for practical use. Solid preparations for agriculture and horticulture containing contraindicated ingredients are not commercially available.
本発明者らは、かかる事情に鑑み柚々夕を究の結果、ビ
リミホスメチルと配合禁忌を示す固形成分とビリミホス
メチルとの組合せにおいて、固型成分を常温で固状の水
溶性ワックスで溶融コーティングすると、練合コーティ
ングで得られる知見に比べ予想外の特異的な安定化効果
を示すと同時に、各成分の卓越した有用な効果、たとえ
ば防除効果−prを7J<ずことを知見し、これらに拙
ういて本発明を完成し/こ。In view of the above circumstances, the present inventors have investigated Yuzuyu and found that in a combination of virimiphos-methyl and a solid component that is contraindicated for combination with virimiphos-methyl, when the solid component is melt-coated with a water-soluble wax that is solid at room temperature, At the same time, we discovered that each component had an unexpectedly specific stabilizing effect compared to the knowledge obtained with kneaded coatings, and at the same time found that each component had an outstanding and useful effect, such as a pest control effect of 7J<7. and completed the present invention.
即ら、不発明は、
■ビリミホスメチルと配合禁忌の固形成分を常温で1面
状の水溶性ワックスで溶融被覆したものと■ヒリミホス
メチルとを
含有することを特徴とする固形製庁]に関する。That is, the invention relates to (1) a solid component that is incompatible with virimiphos-methyl and is melt-coated with a one-sided water-soluble wax at room temperature; and (2) a solid product containing hirimiphos-methyl.
本発明におけるピリミホヌメチルと配合禁忌の成分は固
ル成分である。−合祭忌の固形成分は、■柚まだは2棟
以上である。このような固形成分としては、常温(15
〜a o ’c、 )で固形として用いられる(「融点
35℃以上好ましくは37〜95℃の)物質たとえば固
形の農薬あるいはその固形の添加物等でビリミホヌメチ
ルとKid合禁忌を示すものが用いられる。ピリミホス
メチルと配合禁忌を示す固形成分とビリミホスメチルと
の組合せの具体例としては、たとえばカルタップとピリ
ミホスメチル、カルタップとメソミルとビリミホヌメチ
ル、メソミルとピリミホスメチルなどの組合せが本発明
において用いられる。かくのごとき組合せにおける成分
個々の含有量は、用途、固形成分及び剤形等によシ異な
るも一般に固形製剤全量の0.2〜75重量%好址しく
け0.5〜50瓜量%である。また、成分全部の含有量
は、固形製剤の1〜99重量%好ましくは2〜70重量
%である。In the present invention, ingredients that are incompatible with pirimihonumethyl are solid ingredients. -The solid component of the consecration is ■Yuzumada is 2 or more buildings. Such a solid component is prepared at room temperature (15
Substances (with a melting point of 35°C or higher, preferably 37 to 95°C) that are used in solid form in ~ao'c, Specific examples of combinations of virimiphos-methyl and solid components that are contraindicated for incorporation with pirimiphos-methyl include combinations of cartap and pirimiphos-methyl, cartap, methomyl, and virimifos-methyl, and methomyl and pirimiphos-methyl, etc. Ingredients in such combinations Although the individual content varies depending on the use, solid components, dosage form, etc., it is generally 0.2 to 75% by weight of the total amount of the solid preparation, and 0.5 to 50% by weight. The content of the solid preparation is 1 to 99% by weight, preferably 2 to 70% by weight.
具体的には、たとえばカルタップ、メソミルなどの殺虫
剤の各々は固形製剤全体に対して通常1〜90重量%好
ましくは1〜50重量%含有せしめる。そして、成分全
量が農薬用固形製剤の2〜80重量%好ましくは2〜6
0重量%になるように含有せしめる。Specifically, each of the insecticides, such as cartap and methomyl, is usually contained in an amount of 1 to 90% by weight, preferably 1 to 50% by weight, based on the entire solid preparation. The total amount of the ingredients is preferably 2 to 80% by weight of the solid preparation for agricultural chemicals, preferably 2 to 6%.
The content is 0% by weight.
本発明では、ピリミホヌメチルと配合禁忌の固形成分を
溶融被覆するために、常温で固状の水溶性ワックスが用
いられる。常温で固状とは、常温で固形状のことであっ
て、具体的には融点a5’C−以上好ましくは37〜9
5℃を持つ水溶性ワックスが用いられる。このような水
溶性フックスとしては、水100gに対して0.5g以
上好ましくは51以上溶けるワツク7で、たとえばポリ
エチレン−グリコ−/I/類(たとえばPEG−400
0。In the present invention, a water-soluble wax that is solid at room temperature is used to melt and coat solid components that are incompatible with pirimihonumethyl. Solid at room temperature means solid at room temperature, and specifically has a melting point of a5'C or higher, preferably 37 to 9
A water-soluble wax having a temperature of 5°C is used. Such water-soluble fuchs has a melting capacity of 0.5 g or more, preferably 51 g or more, per 100 g of water, such as polyethylene glycol/I/types (e.g. PEG-400
0.
PEG−6000,PEG−10000,PEG−20
000寺)、ポリエチレンポリプロピレングリコール類
(たとえばニューボールP E −68**
、同’ys 、同108*等)、ポリエチレンノニル
フェノールエーテル類(たとえばノニボール400*、
同500*、同800”、同862*専)、ポリオキン
エチレン高級アルコール頑(だとえばエマルミンL−8
80*等)券が用いられる(*三洋化成KKf[)。こ
れらは必要に応じて単品の′−!(であるいは任惹に混
合して用いてもよい。PEG-6000, PEG-10000, PEG-20
000 Temple), polyethylene polypropylene glycols (for example, New Ball PE-68**, New Ball PE-68**, New Ball PE-68**, New Ball PE-68**, New Ball PE-68**, New Ball PE-68*, New Ball PE-68*, etc.), polyethylene nonylphenol ethers (such as Noni Ball 400*,
500*, 800", 862*), polyethylene ethylene higher alcohols (for example, Emulmin L-8)
80*, etc.) tickets are used (*Sanyo Chemical KKf[). These can be purchased separately as needed! (You may also use them in any combination.
なかでも、たとえばPEG (ポリエチレングリコール
)−2000、PEG−4000、pp:a−6000
などのPEG−2000〜6000のポリエチレンダリ
コー/I/類、ニューボー/l/ P E −68、ニ
ューポー/I/PE−78のポリエチレン・ポリプロピ
レングリコ−/L/川、ノニポー/し400などのポリ
エチレンノニルフェノールエーテル類またはそれらの混
合物等が好−ましい水溶性フックスである。このような
水溶性ワックスの使用量は、少な過ぎては自己合禁忌を
示してしまい多過ぎては使用時不都合であシ、通常溶融
被覆される固形成分に対して0,5〜5倍好ましくは0
.5〜3倍(重量比)用いる。また、得られる固形製剤
に適度な水溶性を持たせてたとえば水利剤辱として用い
る場合には、水溶性ワックスの使用量が多過ぎると水溶
性が悪くなる点に注意して適度の水溶性ワックスを用い
る必要があシ、そのためには溶融被りされる固形成分に
対して0.5〜2.5倍(重量比)用いるのが望ましい
(特に0.7〜2倍用いると好結果が得られる)。この
ような水溶性ワックスに、ピリミホスメチルと配合禁忌
の固形成分の安定性を助長する物質たとえばリン酸、修
酸、PAP(イソグロビルアシドホス7エ−)IAl少
i(水溶性ワックス1重量部に対して0.1〜1重量部
好ましくは0.2〜o、 8 M*filS )添加す
ることもでき、また粉砕助剤兼固結防止剤としてたとえ
ばケイソウ土、粉末硅酸などのシリカ類、たとえばベン
トナイト、酸性白土などのクレイ類、更には粉末状界面
活性剤等を適宜配合することも出来る。Among them, for example, PEG (polyethylene glycol)-2000, PEG-4000, pp:a-6000
Polyethylene such as PEG-2000 to 6000 polyethylene Daliko/I/Class, Newbo/L/PE-68, Newpo/I/PE-78 polyethylene/polypropylene glyco/L/Kawa, Nonipou/Shi 400, etc. Nonylphenol ethers or mixtures thereof are preferred water-soluble hooks. The amount of such water-soluble wax to be used is preferably 0.5 to 5 times the solid component to be melt-coated, because if it is too small, self-coating will be contraindicated, and if it is too large, it will be inconvenient during use. is 0
.. Use 5 to 3 times (weight ratio). In addition, if the resulting solid preparation has appropriate water solubility and is to be used as an irrigation agent, use an appropriate amount of water-soluble wax, paying attention to the fact that if too much water-soluble wax is used, the water-solubility will deteriorate. For this purpose, it is desirable to use 0.5 to 2.5 times (weight ratio) to the solid component to be melted and coated (particularly good results can be obtained by using 0.7 to 2 times). ). Substances that promote the stability of solid components that are incompatible with pirimiphos-methyl are added to such water-soluble waxes, such as phosphoric acid, oxalic acid, PAP (isoglobil acid phos-7a), and IAl (1 part by weight of water-soluble wax). 0.1 to 1 part by weight, preferably 0.2 to 8M For example, clays such as bentonite and acid clay, powdered surfactants, and the like may be appropriately blended.
本発明の固形製剤では、含有されてるピリミホスメチル
と配合禁忌の固形成分が常温で固状の水+8性ワックス
で〆融被憶されている。たとえばビリミホヌメチルと配
合禁忌を示す2椋以」二の161形IJ史分とビリミホ
スメチルとのDt台にあっては前者の目vlの固形成分
のみをあるいは2棟以上の浩1形成分全部を別々にある
いは一緒に適宜溶融被覆してもよい。溶融湿度は、水溶
性ワックスの融点以上でかつビリミホスメチルと配合余
忌の固形成分の融点以−「であり、一般に40−100
’C望ましくは50〜85℃である。他の溶融被覆の条
件、方法等は公知の手段に従って行なうことができる。In the solid preparation of the present invention, pirimiphos-methyl and solid components that are incompatible with each other are fused with water and 8-based wax that are solid at room temperature. For example, in the Dt series of 161 type IJ history and virimiphos methyl, which is contraindicated for combination with virimifos-methyl, only the solid component of the former's 1-vl or all of the 1-form component of 2 or more buildings are separately added. Alternatively, they may be appropriately melt-coated together. The melting humidity is higher than the melting point of the water-soluble wax and higher than the melting point of the solid components to be mixed with virimiphos-methyl, and is generally 40-100%.
'C is desirably 50-85°C. Other melt coating conditions, methods, etc. can be carried out according to known means.
本発明のlr’=I形御剤は、ビリミホヌメチルとIQ
!合祭忌の固形成分を常温で固状の水溶性ワックスで沿
fAm被榎したものと、ビリミホスメチルとをそのまま
常法に従ってthI形製剤として用いてもよく、または
適当な固体担体(たとえば希釈剤、増量剤など)と混合
するがあるいはこれに吸着させ、さらにはこれにたとえ
ば浸透剤、湿潤剤、粘漿剤。The lr'=I type control agent of the present invention comprises virimihonumethyl and IQ
! The solid components of the Apocalypse treated with a water-soluble wax that is solid at room temperature and virimiphos-methyl may be used as they are as a thI-form preparation according to a conventional method, or they may be combined with a suitable solid carrier (for example, a diluent, (filling agents, etc.) or adsorbed thereto, and furthermore, penetrants, wetting agents, mucilage agents, etc.
安定剤などを添加し、常法に従ってたとえば水利剤、粉
剤2粒剤、m粒剤1錠剤などの適宜の固形の剤形として
使用してもよい。By adding a stabilizer and the like, it may be used in a suitable solid dosage form, such as an aqueous solution, two powder tablets, one m-granule tablet, etc., according to a conventional method.
本発明の固形製剤を製造する場合には、たとえば希釈剤
、増量剤などの固体担体としては、たとえば植物性粉末
(たとえば、米糠、大豆粉、タバコ粉、小麦粉、木粉な
ど)、に物性粉末(たとえば、カオリン、ベントナイト
、リン酸カルシウム、酸性白土などのクレー類、滑石粉
、ロウ石粉などのタルク頻、硅藻土、雲母粉などのシリ
カ類など)、さらにアルミナ、硫黄粉末、活性炭なども
用いられ、これらは−棟または二種以上を(製剤中に5
〜90%好ましくは10〜80%)混合して使用しうる
。また、必要に応じてたとえば石けん頬、高級アルコー
ルの硫酸エステル、アルキルスルホン酸、ア!レキルア
リールヌρホン酸、第4級アンモニウム塩、オキシアル
キルアミン、脂肪酸エステル、ポリアルキレンオキサイ
ド系、アンヒドロソルビトール系などの界面活性剤を、
一般に製剤中に0.2〜10%程度、含有させることも
できる。さらに、必要に応じ、カゼイン、ゼラチン、殿
粉、アルギン酸、寒天、CMC、ポリビニルアルコール
、ベントナイト、クレゾール石けんなどを用いてもよい
。また、必要に応じ他柚の殺菌剤(たとえば有機塩素系
殺菌剤、有機リン糸殺菌剤、ベンズイミダゾ−μ系殺菌
剤、鋼系殺菌剤、有蒙イオウ系殺菌剤、フェノール系殺
菌剤、抗生物質など)、殺虫剤(天然殺虫剤、カーバメ
ート糸殺虫剤、有機すン系殺虫剤など)、その他殺ダニ
剤、殺線虫剤、除草剤、植物生長ii1+d節剤、安定
剤、共方剤、誘り1剤、忌避剤、香料、植物栄養剤、肥
料、各種アミノ酸、低分子ないし商分子のリン酸塩用な
どを適宜、たとえばビリミホヌメチルと=a混合忌の固
形成分を水溶性ワックスで溶融被覆する際にあるいは溶
融破缶後の固形d /lllとする際等に混合してもよ
く、ま/こ、効力増強の目的でもって金i’4塩頚を加
えてもよい。なお、たとえば水イ11/ilJなど・製
造する場合には、溶−被覆した固形成分を一般的な方法
により粉砕した後に、ピリミホスメチル、担体を加える
1各して製してもよいっかくして得られるli’J形製
AIJは、(リビリミホスメチルと配合禁忌の固形成分
と(リビリミホスメチルとを含有しているにもかかわら
ず、通常の保存条件下では長期同極めて安定であり、固
形成分の従来よシの使用方法に従って用いることによシ
成分個々の用途に十分用いることができる。具体例とし
て、たとえば殺虫剤のピリミホスメチルと殺菌剤の組合
せからなる殺虫殺菌固形製剤の場合は、たとえば水稲、
そ菜および果樹害虫など広範囲の害虫に対して育苗箱処
カ1(1作物の茎葉散布、幼成虫の虫体散布、水田の水
中施用あるいは土壌処理などにおいて卓越しだ殺虫効果
を発揮し、しかも本発明の殺虫殺菌固形製剤は害虫と同
f¥fK広範囲の植物病原菌、特に斜(類に対して、強
い抗菌力を有しており、例えば水田用殺菌剤として適用
した場合、単に稲熱病菌を殺滅するばかりでなく、同時
に紋枯病菌、小球菌核病菌、胡麻葉枯病菌などに対して
も強い併殺的殺滅力を有する。さらに稲の病原菌のみな
らず、賊菜類など多くの作物に病害を惹き起す病原菌に
も強い抗菌力を有する。例えば、胡瓜灰色疫病菌、菜豆
菌核病菌9位灰色懐(病菌などに対して抗菌力を有する
。また、本発明の枚虫殺菌向ノβ製剤は既に罹病してい
る植物体に処理して、その伸展を阻止する治庶的能力を
有するはかりでなく、未罹病の植物体に処理することV
CJニジ、病原菌の感染を防fJ二し、植物体を保護す
る予防的能力をも併有する。さらに処理法として、通常
の植物体茎葉への散布処理のみならず、植物体根部へ処
理することによってもその強力な浸透的性質により、植
物体内へ吸収され、体内を移行しで広く分布し、偏物体
保護に必要なa度を保つ能カケ有する。従って、このよ
うな殺虫殺菌固形製剤は、例えは農業および園芸用有用
4iU物体をIllしやく加害する鱗翅目害虫たとえは
ハヌ七ンヨトウ(5podoptera 1ittur
a、 ) 、コブノメイガ(CnaphFLlocr
ocis medinalis ) mイネットムシ(
Parna、ra guttata ) 、コナガ(P
luttellam+cuH,penni+3) 、モ
ンシロチョワ(Pierisrapa、e cruci
vora ) 、ニカメイガ(Chil、。When producing the solid preparation of the present invention, solid carriers such as diluents and fillers may be, for example, vegetable powders (e.g., rice bran, soybean flour, tobacco powder, wheat flour, wood flour, etc.), physical powders, etc. (For example, clays such as kaolin, bentonite, calcium phosphate, and acid clay, talc powders such as talcum powder and waxite powder, and silicas such as diatomaceous earth and mica powder) In addition, alumina, sulfur powder, and activated carbon are also used. , these contain one or more types (5 or more in the formulation).
~90%, preferably 10-80%) may be used in combination. In addition, if necessary, for example, soap cheeks, sulfuric esters of higher alcohols, alkyl sulfonic acids, etc. Surfactants such as lekylarylnuphonic acid, quaternary ammonium salts, oxyalkylamines, fatty acid esters, polyalkylene oxides, anhydrosorbitol, etc.
In general, it can be contained in the formulation in an amount of about 0.2 to 10%. Furthermore, if necessary, casein, gelatin, starch, alginic acid, agar, CMC, polyvinyl alcohol, bentonite, cresol soap, etc. may be used. In addition, other fungicides (e.g., organochlorine fungicides, organic phosphorous thread fungicides, benzimidazole-μ fungicides, steel fungicides, monosulfur fungicides, phenolic fungicides, antibiotics, etc.) may be used as needed. substances, etc.), insecticides (natural insecticides, carbamate thread insecticides, organosun insecticides, etc.), other acaricides, nematicides, herbicides, plant growth II1+D moderation agents, stabilizers, synergistic agents , attractants, repellents, fragrances, plant nutrients, fertilizers, various amino acids, low molecular or commercial molecule phosphates, etc., as appropriate.For example, solid components of virimihonumethyl and =a mixed repellent are melted with water-soluble wax. It may be mixed when coating or when forming a solid d/ll after melting and breaking the can, and gold i'4 salt neck may be added for the purpose of enhancing the potency. For example, when producing water-coated solid components, the melt-coated solid component may be pulverized by a general method, and then pirimiphos-methyl and a carrier may be added. li'J type AIJ is extremely stable for long periods of time under normal storage conditions, even though it contains a solid component that is contraindicated for combination with (livirimiphos-methyl). By using the ingredients according to their conventional usage methods, the ingredients can be used satisfactorily for their respective purposes.As a specific example, in the case of an insecticidal and sterilizing solid preparation consisting of a combination of the insecticide pirimiphos-methyl and a fungicide, for example, Paddy rice,
Seedling box treatment has an outstanding insecticidal effect against a wide range of pests such as vegetable and fruit tree pests (spraying on foliage of one crop, spraying the body of young adult insects, applying in water to rice fields, or treating soil). The insecticidal and sterilizing solid formulation of the invention has strong antibacterial activity against a wide range of plant pathogenic bacteria, especially the phytopathogens, such as insect pests. For example, when applied as a bactericide for rice fields, it simply kills rice fever pathogens. It not only kills, but also has a strong double-killing power against bacteria causing sheath blight, micrococcal rot, and sesame leaf blight.In addition, it not only kills pathogenic bacteria of rice, but also many other pathogens such as vegetable crops. It has strong antibacterial activity against pathogenic bacteria that cause diseases in crops.For example, it has antibacterial activity against pathogenic bacteria such as cucumber Gray Phytophthora and rapeseed Phytophthora 9th place. No.beta preparations should be applied to plants that are already diseased and have the curative ability to prevent their spread, but should be applied to uninfected plants.
CJ Niji also has the preventive ability to prevent infection with pathogenic bacteria and protect the plant body. Furthermore, as a treatment method, not only the usual spraying treatment on the stems and leaves of the plant body, but also the treatment on the roots of the plant body. Due to its strong osmotic properties, it is absorbed into the plant body, moves through the body, and is widely distributed. It has the ability to maintain the a degree necessary to protect uneven objects. Therefore, such insecticidal and sterilizing solid preparations are suitable for use against lepidopteran pests, such as the five-podhoptera 1ittur, which easily damage agricultural and horticultural useful objects.
a, ), CnaphFLlocr
ocis medinalis)
Parna, ra guttata), diamondback moth (P
luttelam+cuH, penni+3), Pierisrapa, e cruci
vora), Chil.
puppreq8FLlie ) 、タバコガ(Be’
J、1coverpa。puppreq8FLlie), tobacco moth (Be'
J, 1coverpa.
assu]、ta) +アワヨトウ(Leucania
5eparata)jヨトウガ(Momestra
brasFIicae) 、コカクモンハマキ(Ado
xophyes orana) 、キンモンホソガ(L
ithocclletis ringonialla)
sワタツメイガ(Cnaphalocrocis m
edinalis ) +ジャガイモガ(Phthor
imaea operculella )などの幼虫、
鞘翅目害虫たとえばニジュウヤホシテントウムシ(Ep
ilachna vigintioctopuncta
ta) 、ウリハムシ(Au1acophora fe
moralis) 、キスジノミハムシ(Phyllo
treta 5tiolata、) 、イネミズゾウム
シ(Li5sorhoptrus oryzaphil
us) 。assu], ta) + fall armyworm (Leucania)
5eparata)j Armyworm (Momestra)
brasFIicae), Kokakumon Hamaki (Ado
xophyes orana), Kinmonhosoga (L
ithocclletis ringonialla)
Cnaphalocrocis m
edinalis) + potato moth (Phthor
imaea operculella) and other larvae,
Coleoptera pests such as the lady beetle (Ep.
ilachna vigintioctopuncta
ta), Au1acophora fe
moralis), phyllomorph beetle (Phyllo
treta 5tiolata,), rice water weevil (Li5sorhoptrus oryzaphil)
us).
イネゾウムシ(Echinocnemus squam
eus) sイネクロカメムシ(Oulema ory
zae )などの幼成虫、直列目害虫たとえばトノサマ
バッタ(Locυ−5ta migratoria)な
どの幼成虫、半翅目害虫たとえばイネクロカメムシ(8
cotinophara 1uri−da)、ナシグン
バイ(5tophanitis nashi) 。Rice weevil (Echinocnemus squam)
eus) s Rice black stink bug (Oulema ory
zae); young adult insects such as Serial order pests such as the locust locust (Locυ-5ta migratoria); and Hemiptera pests such as the rice black stink bug (Locυ-5ta migratoria).
cotinophara 1uri-da), Nasigunbai (5tophanitis nashi).
ヒメトビウンカ(Laodel、phax 5tiat
ellus ) 。Laodel, phax 5tiat
ellus).
トビイロウンカ(Ni1oparuata lugen
sl、ツマグロヨコバイ(Nephotettix c
incticeps) 、ヤノネカイガラムシ(Una
epis yannoneneis) +ダイズアブラ
ムシ(Aphis glycineB) jワタアブラ
ムシ(Aphi日gOθ5ypii)などの幼成虫、ハ
クニ9護たとえはナミハダニ(Tetra、ycbus
urti−eae ) *ミカンハダニ(Panon
gchus citri) 。Japanese brown planthopper (Ni1oparuata lugen)
sl, Nephotettix c
incticeps), Una
epis yannoneneis) + soybean aphid (Aphis glycineB) j Young adult insects such as the cotton aphid (Aphis yannoneneis), and two-spotted spider mites (Tetra, ycbus)
urti-eae) *Orange spider mite (Panon
gchus citri).
リンゴハダ= (Fanonychus ulmi )
などの幼成虫、植物体の根部に寄生する線虫類たとえば
キタネコプセンチュウ(Meloidogyne ha
pla )などの農園芸害虫、穀物を食筈するコクゾウ
(5ito−phj、lu8 zeamais) sコ
クヌストモドキ(Tri −bolum castan
eum )などの貯穀害虫、羊毛、皮革1紙などを食害
するイガ(’l’1nea pellione −11
a ) *ヒメカツォグシムシ(Attagenus
piceus)、ヤマトンミ(Ctenolepism
a villosa)などの家庭害虫9人基に直接間接
に危害を与えるアカイエカ(Cu1ex pipien
s ) 、ニッポンヤマブユ(Simulium na
cojapi ) *イエバエ(Muscado+ne
stica) rキンバエ(Lucil、ia cae
sar) yクロゴキブリ(Periplaneta
fuiigjnosa) 、チャバネゴキブリ(Bla
ttala germanica) sヤマトマグニ(
Ixodes japonensis )などの衛生0
家斎再虫に卓効を示す。その上温血動物に対して壽性が
低く、魚壽性などの環境に及ぼす影響も少なく損物体に
も薬害性を全く示さない。さらに、既存の多くの殺虫剤
に抵抗性を示す昆虫、ダニ類にも同様に有効である。Applefin = (Fanonychus ulmi)
nematodes that parasitize the roots of plants, such as Meloidogyne ha
Pla) and other agricultural and horticultural pests, and grain-eating insect pests such as Tri-bolum castan (5ito-phj, lu8 zeamais) and Tri-bolum castan (Tri-bolum castan).
eum), as well as bur moths ('l'nea pellione-11) that feed on wool, leather, paper, etc.
a) *Attagenus
piceus), Yamatonmi (Ctenolepism)
Culex pipien, which directly and indirectly harms domestic pests such as A villosa
s), Nippon Yamabuyu (Simulium na
cojapi) *Housefly (Muscado+ne
stica) Lucil,ia cae
sar) y black cockroach (Periplaneta)
fuiigjnosa), German cockroach (Bla
ttala germanica) s Yamato Magni (
Hygiene 0 such as Ixodes japonensis)
It is highly effective against insects in the house. Moreover, it has low susceptibility to warm-blooded animals, has little impact on the environment such as susceptibility to fish, and shows no toxicity to damaged animals. Furthermore, it is equally effective against insects and mites that are resistant to many existing insecticides.
上記の本発明殺虫殺菌固形製剤の施用は、たとえば対象
植物の生育段階、生育状況、疾病の種類、発病の状態、
薬剤の施用時期あるいは施用方法などの諸条件によって
異なるが、一般に個々の有効成分が10アール当たり、
lO〜3001程度となるように調整すればよい。また
、固形製剤が水利剤の場合には使用濃度としては、個々
の有効成分が10〜1000 ppmの範囲となるよう
に希釈して使用すればよく、また、使用方法としては、
作物に散布、散粉、潅注あるいは種子粉衣してもよく、
作物に安全かつ有効に使用されるならば、それがどのよ
うな使用量、使用濃度あるいは使用方法であろうと本発
明になんらの制限を加えるものではない。The application of the above-mentioned insecticidal and sterilizing solid preparation of the present invention can be carried out based on, for example, the growth stage of the target plant, the growth situation, the type of disease, the state of disease onset,
Although it varies depending on various conditions such as the time of application or the method of application, in general, the amount of each active ingredient per 10 ares,
It may be adjusted to about 10 to 3001. In addition, if the solid preparation is an aquarium, it may be diluted so that the concentration of each active ingredient is in the range of 10 to 1000 ppm, and the method of use is as follows:
The crop may be sprayed, dusted, irrigated or seed coated;
As long as it is used safely and effectively on crops, no limitations are imposed on the present invention, regardless of the amount, concentration, or method of use.
本発明の殺虫殺菌固形製剤(とシわけ水利剤)は副作用
がきわめて少なく安全で、簡易、安価。The insecticidal and sterilizing solid preparation (toshiwake irrigation agent) of the present invention is safe, simple, and inexpensive with very few side effects.
かつ長Al1間の医存後においても適確にすぐれた作用
、効果を契しうるから当業界における有用性はきわめて
大きい。Moreover, it is extremely useful in the art because it can accurately exhibit excellent actions and effects even after long-term medical treatment.
以下実施例kDげて本発明の方法および効果を詳細に説
明する。The method and effects of the present invention will be explained in detail with reference to Examples below.
なお実施例中の部及び%はすべて重量部及び重h(%を
示す。Note that all parts and % in the examples indicate parts by weight and weight h (%).
実施例1゜
カルタップ3都にPEG−200001,5部及びリン
酸0.01都を混合し80℃に溶融し、冷却し、粉砕し
、ビリミホスメチル3都及びクレイ95都を加え均一に
混合して侮られる粉剤。Example 1 1.5 parts of PEG-20000 and 0.01 part of phosphoric acid were mixed with 3 parts of Cartap, melted at 80°C, cooled and pulverized, and 3 parts of virimiphos-methyl and 95 parts of clay were added and mixed uniformly. A powder that is despised.
灰飾IN2゜
カルタラ110都にニューボーlL/P E −682
5部及びリン酸0.05部を混合し70°Cに溶融し、
冷却し、粉砕し、メソミル5都とビリミホスメチル2都
を加え均一に混合して得られる水利剤。Hyakikari IN2゜Kalutara 110 Miyako ni New Ball lL/P E-682
5 parts and 0.05 part of phosphoric acid were mixed and melted at 70°C,
An irrigation agent obtained by cooling, pulverizing, adding 5 methomils and 2 virimiphos methyl and mixing uniformly.
実施例8゜
メソミル10都にノニボール40071Sを加え60℃
に溶融し、冷却し、粉砕し、ビリミナスメチル3部及び
クレイ10都を加え均一混合して得られる水利剤。Example 8 Add Noniball 40071S to Methomil 10 and heat at 60°C.
An irrigation agent obtained by melting, cooling, pulverizing, adding 3 parts of biliminus methyl and 10 parts of clay, and uniformly mixing.
突験例1. (有効成分の安定性試験)実施例1〜3
に示した本発明による改良された農園芸用固彫製剤をア
ルミ箔袋に包装し、40℃恒温器中で60日間保管した
後、有効成分含量の残存率を測定しかつ外観の経日変化
を測定し、その結果を表−12表−2に示した。Accidental example 1. (Stability test of active ingredients) Examples 1 to 3
The improved agricultural and horticultural hard-carving formulation according to the present invention shown in Figure 1 was packaged in an aluminum foil bag and stored in a 40°C thermostat for 60 days, after which the residual rate of active ingredient content was measured and changes in appearance over time were measured. was measured and the results are shown in Table 12 and Table 2.
本発明に属さない対照製剤は以下に示す。Control formulations that do not belong to the invention are shown below.
対照製剤:
カルタッグ3部にビリミナスメチル3部及びクレイ95
都を加え、均一に混合して得られる粉剤。Control formulation: 3 parts Caltag, 3 parts Viliminous Methyl and Clay 95
Powder obtained by adding Miyako and mixing uniformly.
表−1有効成分の残存率 表−2製剤の外貌変化 8Table-1 Residual rate of active ingredients Table-2 Changes in appearance of preparations 8
Claims (1)
′湿でIrkl状の水活性ワックスで溶融被伽したもの
と(〃ビリミホヌメチルとを 含]jすることを特徴とする同形製AIJ。[Scope of Claims] (L) It is characterized by comprising (contains virimihonumethyl) a single-forming molecule 'crystal' that is incompatible with virimihonumethyl and is melted and coated with an Irkl-like water-activated wax when wet. Same shape AIJ.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6636984A JPS59193811A (en) | 1984-04-02 | 1984-04-02 | Solid preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6636984A JPS59193811A (en) | 1984-04-02 | 1984-04-02 | Solid preparation |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4392783A Division JPS59170002A (en) | 1983-03-16 | 1983-03-16 | Solid pharmaceutical preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS59193811A true JPS59193811A (en) | 1984-11-02 |
Family
ID=13313853
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6636984A Pending JPS59193811A (en) | 1984-04-02 | 1984-04-02 | Solid preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59193811A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4797275A (en) * | 1985-09-26 | 1989-01-10 | Eli Lilly And Company | Nicarbazin feed premix |
FR2645709A1 (en) * | 1989-04-18 | 1990-10-19 | Sumitomo Chemical Co | EMULSIFIABLE SOLID PESTICIDE COMPOSITIONS |
-
1984
- 1984-04-02 JP JP6636984A patent/JPS59193811A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4797275A (en) * | 1985-09-26 | 1989-01-10 | Eli Lilly And Company | Nicarbazin feed premix |
FR2645709A1 (en) * | 1989-04-18 | 1990-10-19 | Sumitomo Chemical Co | EMULSIFIABLE SOLID PESTICIDE COMPOSITIONS |
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