JPS5919086B2 - insecticide composition - Google Patents
insecticide compositionInfo
- Publication number
- JPS5919086B2 JPS5919086B2 JP8287475A JP8287475A JPS5919086B2 JP S5919086 B2 JPS5919086 B2 JP S5919086B2 JP 8287475 A JP8287475 A JP 8287475A JP 8287475 A JP8287475 A JP 8287475A JP S5919086 B2 JPS5919086 B2 JP S5919086B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- salt
- insecticides
- insecticide composition
- nch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
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- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【発明の詳細な説明】
本発明は、Ｎ−ニトロソ−Ｎ−シクロヘキシルヒドロキ
シルアミン（以後、ＮＣＲと称する）の塩と、塩素系、
有機燐系およびカーバメート系殺虫剤から選ばれる殺虫
剤の一種以上とを混合して、効力の増強された殺虫剤組
成物に関し、人畜には低毒性で、強力な殺虫剤を提供す
ることを目的とする。DETAILED DESCRIPTION OF THE INVENTION The present invention provides a salt of N-nitroso-N-cyclohexylhydroxylamine (hereinafter referred to as NCR), a chlorine-based salt,
The purpose of the present invention is to provide a powerful insecticide with low toxicity to humans and livestock, with respect to an insecticide composition whose efficacy is enhanced by mixing it with one or more insecticides selected from organophosphorus and carbamate insecticides. shall be.
現在、キクイムシ、シンクイムシ、カミキリムシのよう
な木材食害虫および白蟻に対してはクロルデン、スミチ
オン、トリクロルナフタリンなどの殺虫剤が広（賞月さ
れている。Currently, insecticides such as chlordane, sumithion, and trichlornaphthalene are widely used against wood-eating pests such as bark beetles, sink beetles, and longhorn beetles, as well as termites.
しかし、これら殺虫剤の効力増強剤としてはいまだ実用
化されたものはなく、また、殺虫剤単独では害虫に抵抗
性を早く与えてしまう懸念もある。However, no efficacy enhancer for these insecticides has yet been put to practical use, and there is also a concern that insecticides alone may quickly develop resistance to insect pests.
本発明者らは、これら殺虫剤の効力増強剤について鋭意
研究した結果、ＮＣＨの塩を配合することにより人畜に
対する毒性を増すことなく、驚くべき相乗的な効力が発
現することを認め、本発明を完成した。As a result of intensive research into the efficacy enhancers of these insecticides, the present inventors recognized that by incorporating NCH salts, surprising synergistic efficacy was expressed without increasing toxicity to humans and animals, and the present invention was developed. completed.
本発明に用いられるＮＣＨの塩としては、カリウム（以
後、Ｋ塩とする）、カルシウム（以後、Ｃａ塩とする）
、アルミニウム（以後、Ａｌ塩とする）などの塩が用い
られ、塩素系、有機燐系およびカーバメート系殺虫剤と
しては前記したクロルデン、スジチオン、トリクロルナ
フタリンのほかには、マラソン、セビンなどが用いられ
る。The salts of NCH used in the present invention include potassium (hereinafter referred to as K salt), calcium (hereinafter referred to as Ca salt).
Salts such as , aluminum (hereinafter referred to as Al salts) are used, and as chlorine-based, organophosphorus-based and carbamate-based insecticides, in addition to the above-mentioned chlordane, sudithion, and trichlornaphthalene, Marathon, Sevin, etc. are used. .
ＮＣＨの塩の配合量は、効果が得られる範囲内で任意に
選ばれるが、一般に殺虫剤に対して０．１〜１０倍量と
するのが望ましい。The amount of NCH salt to be blended can be arbitrarily selected within a range that provides the desired effect, but it is generally desirable to use an amount of 0.1 to 10 times the amount of the insecticide.
次に、試験例により本発明をさらに説明する。Next, the present invention will be further explained using test examples.
試験例 １
殺蟻試験
■ 方法：クロルデン、スミチオンおよびセビンに対し
、０．１倍量、１倍量および５倍量のＮＣＨのＡｌ塩ま
たはに塩を添加したアセトン溶液を所定の濃度に希釈し
て、直径９ｃｒｒＬの沢紙に１分間浸漬し、室温で風乾
する。Test Example 1 Termicidal Test ■ Method: An acetone solution containing 0.1 times, 1 times and 5 times the amount of NCH Al salt or salt added to chlordane, sumithion and sevin was diluted to the specified concentration. Then, soak it in a 9crrL diameter paper for 1 minute and air dry it at room temperature.
その後、深底シャーレの底に敷き、水１ ｒｕｌでｆ紙
を湿らせ、その上にヤマトシロアリの職蟻１０匹を放ち
、シャーレに蓋をし、温度２８±２℃および相対湿度９
０％以上の条件で飼育し、一定時間毎に死亡虫数な調べ
る。After that, place it on the bottom of a deep petri dish, moisten f paper with 1 ru of water, release 10 worker ants of Yamato termites on it, cover the petri dish, and adjust the temperature to 28±2℃ and relative humidity to 9.
The animals are raised under conditions of 0% or higher, and the number of dead insects is checked at regular intervals.
■結果
試験例 ２
殺虫試験
■ 方法：クロルデン、スミチオンおよびセビンに、こ
れと等量のＮＣＨ−Ａｌ塩を添加したアセトン溶液を所
定濃度に希釈した後、液を５ＣｒｒＬ×５（１１７７１
の３プライの合板の表面に５ｏ？／ｒｎ：の割合で塗布
して室温で乾燥する。■Result test example 2 Insecticidal test■ Method: After diluting an acetone solution of chlordane, sumithion, and Sevin with an equivalent amount of NCH-Al salt added to a predetermined concentration, the solution was mixed with 5 CrrL x 5 (11771
5o on the surface of 3 ply plywood? /rn: and dried at room temperature.
その後、深底シャーレの底に置き、ヒラタキクイムシ成
虫１０匹を放ち、温度２５〜２８℃および相対湿度７５
％以下の条件で飼育し、一定時間後の死亡虫数な調べた
。After that, it was placed on the bottom of a deep-bottomed petri dish, and 10 adult yellowtail beetles were released at a temperature of 25-28℃ and a relative humidity of 75℃.
% or less, and the number of dead insects after a certain period of time was investigated.
■結果
本発明の殺虫剤組成物の調整に際しては、常法により油
剤、乳剤、粉剤、エーロゾルなど任意の剤型をとりうる
。(2) Results When preparing the insecticide composition of the present invention, any desired dosage form such as an oil solution, emulsion, powder, or aerosol can be taken by a conventional method.
なお、有機スズ化合物、クロル化フェノール、ヨード系
化合物、その他任意の殺菌剤の配合も可能である。It is also possible to incorporate organic tin compounds, chlorinated phenols, iodine compounds, and other arbitrary fungicides.
処方例 １
クロルデン２０部、ＮＣＲ−Ａｌ塩１０部、ケロシン７
０部を混合溶解してなる油剤。Prescription example 1 20 parts of chlordane, 10 parts of NCR-Al salt, 7 parts of kerosene
An oil agent made by mixing and dissolving 0 parts.
処方例 ２
スミチオン１０部、クロル１７１０部、ＮＣＨ−ＡＩ塩
５部、非イオン系界面活性剤１５部、キシレン６０部か
らなる乳剤。Formulation Example 2 Emulsion consisting of 10 parts of Sumithion, 1710 parts of Chlor, 5 parts of NCH-AI salt, 15 parts of nonionic surfactant, and 60 parts of xylene.
処方例 ３
セビン０．２部、ＮＣＲ−Ａｌ塩０．１部、キシレン６
．５部、白灯油１０部を混合してエーロゾル容器に入れ
、バルブをシールした後、フレオン８３．４部を加え、
加圧充填してなるエーロゾル。Prescription example 3 Sevin 0.2 part, NCR-Al salt 0.1 part, xylene 6
．． Mix 5 parts of white kerosene and 10 parts of white kerosene, put it in an aerosol container, seal the valve, then add 83.4 parts of Freon.
Aerosol made by pressurized filling.
Claims (1)
ミンの塩と、塩素系、有機燐系およびカーバメート系殺
虫剤から選ばれる殺虫剤の一種以上とを混合してなる殺
虫剤組成物。1. An insecticide composition comprising a salt of N-nitroso-N-cyclohexylhydroxylamine and one or more insecticides selected from chlorine-based, organophosphorus-based and carbamate-based insecticides.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8287475A JPS5919086B2 (en) | 1975-07-04 | 1975-07-04 | insecticide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8287475A JPS5919086B2 (en) | 1975-07-04 | 1975-07-04 | insecticide composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS527429A JPS527429A (en) | 1977-01-20 |
| JPS5919086B2 true JPS5919086B2 (en) | 1984-05-02 |
Family
ID=13786430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8287475A Expired JPS5919086B2 (en) | 1975-07-04 | 1975-07-04 | insecticide composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5919086B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5228909A (en) * | 1975-08-27 | 1977-03-04 | Shinto Paint Co Ltd | Composition of controlling insects for woods |
| JPS5956923A (en) * | 1982-09-27 | 1984-04-02 | Anritsu Corp | Square bar bending correcting machine |
-
1975
- 1975-07-04 JP JP8287475A patent/JPS5919086B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS527429A (en) | 1977-01-20 |
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