JPS59179294A - Multielectrode submerged arc welding method and welding wire used therein - Google Patents

Multielectrode submerged arc welding method and welding wire used therein

Info

Publication number
JPS59179294A
JPS59179294A JP5738683A JP5738683A JPS59179294A JP S59179294 A JPS59179294 A JP S59179294A JP 5738683 A JP5738683 A JP 5738683A JP 5738683 A JP5738683 A JP 5738683A JP S59179294 A JPS59179294 A JP S59179294A
Authority
JP
Japan
Prior art keywords
slag
welding
submerged arc
electrode
arc welding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5738683A
Other languages
Japanese (ja)
Inventor
Teruhiko Kurimoto
栗本 照彦
Nobuyuki Yamauchi
山内 信幸
Hirotsugu Inaba
稲葉 洋次
Fumio Kashimoto
文雄 樫本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP5738683A priority Critical patent/JPS59179294A/en
Publication of JPS59179294A publication Critical patent/JPS59179294A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials

Abstract

PURPOSE:To assure the fluidity of slag and to suppress generation of welding defects in multielectrode submerged arc welding by using a cored wire contg. a specific amt. of Al and Al-Mg alloy powder as a slag forming agent. CONSTITUTION:A cored wire contg. 0.5-7wt% powder of Al, Al-Mg alloy or a mixture composed thereof as a slag forming agent is used for at least one of welding wires in multielectrode submerged arc welding of a thin walled large diameter pipe, etc. The properties over the entire part of slag are maintained at a high viscosity by using such wire. A thermit reaction is caused in at least a part of a molten pool and the fluidity of slag is assured by utilizing the heat generated by the same, by which the generation of welding defects such as an undercut and slag inclusion is suppressed.

Description

【発明の詳細な説明】 本発明は婢肉大径管の製管溶接等に用いられる多電極潜
弧溶接方法及びこれに用いる溶接ワイヤに関するもので
ある。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a multi-electrode latent arc welding method used for manufacturing and welding thin-walled, large-diameter pipes, and a welding wire used therefor.

多重極潜弧溶接方法は大径溶接ワイヤの使用が可能であ
って、溶語能力が高く、また7ランクスに覆われた状態
下でアークを発生させるのでア−り光、ヒユーム等に対
する対策が不要であって、作業環境の管理に好都合であ
り、特に多電極式のものはタンデムに配した各電極、す
なわち溶込み深さを決めるデイギング機能を備えた所謂
デイギング電極、これに後続し、デイギング機能及びビ
ード表面性状を整えるスムージング機能を併有する電極
、更にこれに後続するスムージング電極に夫々に適した
溶接条件を設定することにより、溶接ビードの溶込み形
状、表面性状等を任意に設定し得る優れた特性を備える
反面、高速溶接時にスラグ巻込み、アンダーカント等の
溶接欠陥が発生し易いという難点がある。
The multipolar submerged arc welding method allows the use of large diameter welding wires, has high welding ability, and generates an arc under conditions covered by 7 ranks, so there are no countermeasures against arc light, fumes, etc. It is not necessary and is convenient for managing the working environment.In particular, multi-electrode types have each electrode arranged in tandem, that is, a so-called degging electrode with a degging function that determines the penetration depth. The penetration shape, surface texture, etc. of the weld bead can be arbitrarily set by setting suitable welding conditions for the electrode, which has a smoothing function that adjusts the bead surface properties, and the subsequent smoothing electrode. Although it has excellent properties, it has the disadvantage that welding defects such as slag entrainment and undercant are likely to occur during high-speed welding.

この対策として従来は溶接速度の低下、或いは電極間隔
、電流、電圧を微調整する方法、或いはフラツクスの粒
度分布を調節する方法等が採用されていた。しかしこの
ような方法はいずれも経験的な方法であって確実性に乏
しく、その効果も満足すべきものではないという欠点が
あった。
Conventionally, countermeasures to this problem include reducing the welding speed, finely adjusting the electrode spacing, current, and voltage, or adjusting the particle size distribution of the flux. However, all of these methods have the disadvantage that they are empirical methods, lack certainty, and have unsatisfactory effects.

本発明@等は多電極潜弧溶接法におけるアンダーカット
、スラブ巻込み等の溶接欠陥と使用スランクスとの関係
につき実験研究を行った結果、高粘性ノスラグ物性を有
するフラツクスを用いるとアンダーカットの発生が少な
いこと、また低融点のフランクス程スラグ巻込みの発生
が少ないことを知見した。これはスラグ物性が高粘性で
あると、溶融金属の流動が抑制されるため、溶融金属の
後退による開先部からの離反がなく、その結果としてア
ンダーカットの発生が防止され、またフラツクスが低融
点であると、溶融池、内でのスラグの流動性が高く、ス
ラグが巻込まれても浮上し易く、その結果としてスラグ
巻込みの発生が防止されることによるものと考えられる
The present invention @ conducted an experimental study on the relationship between welding defects such as undercuts and slab entrainment in multi-electrode submerged arc welding and the flux used, and found that undercuts occur when fluxes with high viscosity Noslag physical properties are used. It was also found that the lower the melting point of Franks, the less slag entrainment occurs. This is because when the slag physical properties are high, the flow of the molten metal is suppressed, so the molten metal does not retreat from the groove, and as a result, the occurrence of undercuts is prevented and the flux is reduced. It is thought that this is because when the melting point is high, the fluidity of the slag in the molten pool is high and the slag easily floats even if it gets caught, and as a result, the occurrence of slag entrainment is prevented.

従って、例えばアンダーカットの防止を目的として高粘
度のスラグ物性を封するフラツクスを用いた場合、スラ
グ巻込を生じ易い溶融池の少なくとも一部についてスラ
グの流動性を高めればスラグ巻込みも防止出来てアンダ
ーカット、スラグ巻込みの両欠陥を共に排除し得ること
となる。
Therefore, for example, when using a flux that seals the physical properties of high-viscosity slag for the purpose of preventing undercuts, it is possible to prevent slag entrainment by increasing the fluidity of the slag in at least a portion of the molten pool where slag entrainment is likely to occur. This makes it possible to eliminate both undercut and slag entrainment defects.

本発明はこのような知見に基づきなされたものであって
、その目的とするところは高粘度のスラグ物性を有する
故イ1i7シツクスを用いる一方、溶接ワイヤの少なく
とも1本をAe、kl−Mg合金。
The present invention was made based on such knowledge, and its purpose is to use the late I1i7 slag having high viscosity physical properties, while at least one of the welding wires is made of Ae, Kl-Mg alloy. .

又はこれらの混合物の粉末をスラブ形成剤として重量比
で0.5〜7%合有するコアードワイヤを用いて、スラ
グ全体の物性を高粘度に維持しつつ溶融池の少なくとも
一部においてはテルミット反応を生せしめ、その発熱を
利用してスラグ温度を高め、スラグの流動性を確保する
こ吉によりアンダーカット、スラグ巻込み等の溶接欠陥
の発生を共に抑制し得るようにした多電極潜弧溶接法及
びこれに用いる沿接ワイヤを提供するにある。
Alternatively, by using a cored wire containing 0.5 to 7% by weight of powder of these mixtures as a slab forming agent, a thermite reaction can be generated in at least a part of the molten pool while maintaining the physical properties of the entire slag at a high viscosity. A multi-electrode submerged arc welding method that utilizes the generated heat to raise the slag temperature and ensure the fluidity of the slag, thereby suppressing the occurrence of welding defects such as undercuts and slag entrainment. The present invention provides a creepage wire used for this purpose.

本発明に係る多電4Ii潜弧溶接法けAJ若しくは、4
4?−J合金又はこれらの混合物の粉末をスラグ形成剤
としては量比で0.5〜7%含むコアードワイヤを少な
くとも1木用いることを特徴とする。
Polyelectric 4Ii submerged arc welding method AJ or 4 according to the present invention
4? It is characterized by using at least one cored wire containing powder of -J alloy or a mixture thereof as a slag forming agent in an amount of 0.5 to 7%.

なおここにAl若しくはAl−Mg合金又はこれらの混
合物の粉末は溶融池内でチルミント反応を生せしめ、溶
融金属及びスラグ温度を高めてこれらの流動性を向上さ
せ、巻込まれたスラグの浮上を促進し、スラグ巻込みの
発生を防止するために用いられるものであり、その含有
量をスラグ形成剤として重量比で0.5〜7%としたの
は0.5%未瀾では溶融池1内での発熱効果が十分でな
く、また7%を越えると沿接作業性が著しく悪化するこ
とによる。
Note that the powder of Al or Al-Mg alloy or a mixture thereof causes a chillmint reaction in the molten pool, increases the temperature of the molten metal and slag, improves their fluidity, and promotes the floating of the slag involved. This is used to prevent the occurrence of slag entrainment, and the content is 0.5 to 7% by weight as a slag forming agent. This is due to the fact that the heat generation effect is not sufficient, and if it exceeds 7%, creeping workability will deteriorate significantly.

以下本発明をその実施状態を示す図面に基いて具体的に
説明する。第1図は本発明方法を零発(7)に係る溶接
ワイヤを用いて実施している状態を示す構成的側面図で
あり、図中Mは管母材、M aはエツジ部、1.;2.
311i:潜弧溶接用の電極、Fは7ラツクスを示して
いる。管母材Mのエツジ部Maは適9Jな開先加工を施
して衝き合せてあり、この衝き合せたエツジ部Ma上に
電極1.2.8を臨ませである。電極1.2.8は白抜
矢符で示す溶接進行方向に対し一列に並べ、且つ単一の
溶融池を形成するよう相互の間隔を定めて、夫々溶接ワ
イヤIa。
The present invention will be specifically explained below based on drawings showing its implementation state. FIG. 1 is a structural side view showing a state in which the method of the present invention is carried out using a welding wire according to Zero Shot (7), in which M is the tube base material, M a is the edge portion, 1. ;2.
311i: Electrode for submerged arc welding, F indicates 7 lux. The edge portion Ma of the tube base material M is abutted with an appropriate 9J beveling process, and the electrode 1.2.8 is placed on the abutted edge portion Ma. The electrodes 1, 2, and 8 are arranged in a line in the direction of welding progress indicated by the open arrow, and are spaced apart from each other so as to form a single molten pool, and are connected to the welding wire Ia, respectively.

2a、3aをフランクスF内に差し入れた状態で配設さ
れている。溶接進行方向の最前部忙位置する先行@極、
即ち第1の電4& 1は主に俗込み深さを決めるディギ
ング機能を、またこれに続く後行の電極である′f;2
の電極2はディギング機能と共にビード表面性状を整え
るスムージング機能を、更に最後行の電極である第3の
電イ玉3はスムージング機能を夫々(fi#えるべく適
正な溶接条件に設定されている。溶接ワイヤIa、2a
、8aのうち、第1、第2の電極1.2から供給される
溶接ワイヤIa。
2a and 3a are inserted into Franks F. Leading pole located at the forefront in the direction of welding progress,
That is, the first electrode 4 & 1 mainly has a digging function that determines the digging depth, and the subsequent electrode 'f; 2
The electrode 2 has a digging function and a smoothing function to adjust the bead surface properties, and the third electrode 3, which is the electrode in the last row, has a smoothing function (fi# is set to the most appropriate welding conditions). Welding wire Ia, 2a
, 8a, the welding wire Ia is supplied from the first and second electrodes 1.2.

2aFiいずれもソリッドワイヤが、まだ第8の電極3
から供給される溶接ワイヤ3aはコアードヮイヤが用い
られている。コアードソイヤはスラグ形成剤としてその
重量比で0.5〜7%のAI!l若しくはAJ−Mg合
金又は両者の混合物を粉末として含有している。コアー
ドヮイヤを最後行の電極から供給することにより最も巻
込みを生じ易い部位においてスラグの浮上が促進される
結果、スラグ巻込の発生を効果的に防止し得ることとな
る。勿論、他の溶接ワイヤIa、2aとしてコアード・
ワイヤヲ用いてよいことけ唐うまでもない。
2aFi both solid wires but still the 8th electrode 3
A cored wire is used as the welding wire 3a supplied from the welding wire 3a. Cored Soyer is a slag forming agent with a weight ratio of 0.5 to 7% AI! 1 or AJ-Mg alloy or a mixture of both as powder. By supplying the core wire from the last row of electrodes, the levitation of the slag is promoted in the region where entrainment is most likely to occur, and as a result, the occurrence of slag entrainment can be effectively prevented. Of course, as other welding wires Ia and 2a, cored
It goes without saying that you can use wire.

7ラツクスFとしてけスラグ物性が高粘度のものであれ
ばよく、市販のものをそのまま用いてよい0 第2図は本発明方法の他の実施状態を示す模式的断面図
であり、管母材M全体を水平線に対し所要角度θ(0〜
2°)だけ傾斜させ、溶接進行方向が斜め下向きとなる
ようにしである。他の構成は前記第1図に示した実施状
態と同じであり、対応する部分には同じ番号を付しであ
る。このように溶接進行方向を斜め下向きとすることに
よって、溶融池における溶融金属の後退、即ち溶接進行
方向に対し後方への流動が抑制されて幅方回への広がり
が助長され、広幅で高さの低いビードか形成されアンダ
ーカントの発生が効果的に防止されることとなる。傾斜
角度θとして0〜2°としだのは0゜を越える状態、即
ちg接進行方向が斜め上向きとすると、自噴のため溶融
金属の後退が促イ(され、左、右への広がりが不足し、
ビードが狭1111+1で高くなりアンダーカントが発
生し易くなると七によるものであり、またθが2°を越
えると、逆に〆融金属の前方への移動が大きくなりオー
バランプビードが発生しスラグ巻き込みが多発する結果
を招くからである。
As long as the slag physical property is high viscosity as 7 lux F, a commercially available slag may be used as is. Figure 2 is a schematic cross-sectional view showing another implementation state of the method of the present invention. The required angle θ (0~
2°) so that the welding direction is diagonally downward. The other configurations are the same as the embodiment shown in FIG. 1, and corresponding parts are given the same numbers. By making the welding direction diagonally downward in this way, the retreat of the molten metal in the molten pool, that is, the flow backward with respect to the welding direction, is suppressed, and the spread in the width direction is promoted, and the weld metal is wide and high. A low bead is formed, and the occurrence of undercant is effectively prevented. If the inclination angle θ is 0 to 2° and the angle exceeds 0°, that is, the direction of g-tangential movement is diagonally upward, the molten metal will be forced to retreat due to self-injection (and its spread to the left and right will be insufficient). death,
If the bead is narrow (1111+1), it becomes high and undercant is likely to occur.If θ exceeds 2 degrees, the forward movement of the molten metal increases, causing an overramp bead and slag entrainment. This is because it results in frequent occurrence of

次に本発明方法の実施例について説明する。Next, examples of the method of the present invention will be described.

供試鋼板としては表1に示すljき成分2組成の5M4
1 Aを素材とする厚さ12m+n、幅200mm。
The test steel sheet was 5M4 with the lj component 2 composition shown in Table 1.
1 Made of A material, thickness 12m+n, width 200mm.

長さ1500mmの鋼板であって、これをビードオンプ
レートにて8電極潜弧溶接法により溶接した。
A steel plate having a length of 1500 mm was welded using an 8-electrode latent arc welding method using a bead-on-plate.

溶接条件け3電礒のうち第1の電極は直流、950A。The first electrode of the three welding voltages was DC, 950A.

36V1第2の電極は交流、800A、42V、、第3
の電極は交流、750A、46V1とし、溶接速度は2
.3Ill/分、電極間間隔は第1〜第2電櫃間: 2
0mm 。
36V1 second electrode is AC, 800A, 42V, third
The electrode was AC, 750A, 46V1, and the welding speed was 2.
.. 3Ill/min, the distance between the electrodes is between the first and second electrodes: 2
0mm.

第2〜第3電極間:20mm、チップ高さ85mmとし
た。
The distance between the second and third electrodes was 20 mm, and the chip height was 85 mm.

使用フラツクスは市販のS 102−Mn0−CaO系
の高粘度スラグ物性を備えたものであって、粒IWけメ
ツシュ28以下である。
The flux used is a commercially available S102-Mn0-CaO system having high viscosity slag physical properties, and has grain IW and mesh size of 28 or less.

コアードワイヤとしては表2に示す如き成分。The components of the cored wire are as shown in Table 2.

組成のものを用いた。なお表2中※印を付したものは本
発明に属しないワイヤであって、参照として用いた。表
2に示す組成は上段にスラグ形成剤としての重量比に)
を、また下段にカッコ書きでコアードワイヤのフープを
含めた一@量比を示した0なおコアードワイヤにおける
フープと7ラツクスとの重量比は85:15としである
が、フープ材の厚さ及び形状により60:40tで変更
することが溶接ワイヤの組合せ及び溶接進行方向の傾斜
並びに結果は表3に示すとおりである。結果は溶接開始
点及びその直後、並び忙タレータ部分を除く、ビード長
60 cmについてX線検査を行って得たものである。
The composition was used. Note that wires marked with * in Table 2 are wires that do not belong to the present invention and were used as a reference. The composition shown in Table 2 is shown in the weight ratio as a slag forming agent in the upper row)
In addition, the weight ratio of the hoop of the cored wire to the 7 lux is shown in parentheses at the bottom.The weight ratio of the hoop to the 7 lux in the cored wire is 85:15, but depending on the thickness and shape of the hoop material. Table 3 shows the combination of welding wires and the inclination of the welding direction that were changed at 60:40t. The results were obtained by performing X-ray inspection on a bead length of 60 cm, excluding the welding start point and immediately after, and the busy turret part.

表8中(LJ、・#Jは溶接欠陥なしの場合を、○印は
同じく小数の場合を、Δ印は普通の場合を×叩は多発の
場合を示している。捷だ表3中※を付したのは本発明方
法の条件に適合していない場合を示している。
In Table 8, (LJ, *#J indicates the case where there is no welding defect, ○ indicates the case where it is also a decimal, Δ indicates the case where it is normal, and × indicates the case where there are many welding defects. In Table 3 * Those marked with ``mark'' indicate cases in which the conditions of the method of the present invention are not met.

表3から男らかな如く、木発り」方法以外の方法(N8
.] 、 8’、10 )に依ったときけ溶接欠陥が多
発しているのに対し、本発明方法(No;2〜7,9)
に依ったさきはアンダーカント、スラグ巻込みの発生が
皆無又は小故に留まっていることが解る。なお溶接進行
方向が下向きに1.2°において、本発明を]れ用した
さきもスラブ巻込みが多発する場合がみられるが、コア
ードワイヤ使用位+?イの変更等により、容易に回献し
得ることが解る。
From Table 3, methods other than the ``Manly, Wood-starting'' method (N8
.. ], 8', 10), whereas crack welding defects frequently occur due to the method of the present invention (Nos. 2 to 7, 9).
It can be seen that the occurrence of undercant and slag entrainment is either non-existent or remains small. In addition, when the welding progress direction is 1.2 degrees downward, slab entrainment may occur frequently when using the present invention, but when using a cored wire, It can be seen that it can be easily redeployed by changing A.

以上の如く本発明方法及び零発り1品にあっては他電極
潜弧溶接において、使用溶接ワイヤの少、tくとも1本
をコアードワイヤとし、且つこのコアードワイヤはスラ
グ形成剤の重量比で0.5〜7%のAl、Af−Mg合
金又は両者の混合物を粉末として添加したスラグ形成剤
を内蔵せしめであるから、溶接過程においてスラグ全体
を高粘性に保持して溶融金属の溶接方向と反対方向への
流動を抑・制し、まだコアードワイヤと対向する部分の
スラグ温度を高めて溶融池内での流動性を向上させアン
ダーカット及びスラグ巻き込み等の溶接欠陥を除去出来
るなど本発明は優れた効果を奏するものである。
As described above, in the method of the present invention and the zero-starting one product, in multi-electrode submerged arc welding, at least one of the welding wires used is a cored wire, and this cored wire has a weight ratio of slag forming agent of 0. .5-7% of Al, Af-Mg alloy, or a mixture of both is added as a powder as a built-in slag forming agent, which keeps the entire slag highly viscous during the welding process, so that it is in the opposite direction to the welding direction of the molten metal. The present invention has excellent effects such as suppressing and controlling the flow in the direction, increasing the slag temperature in the part still facing the cored wire, improving fluidity in the molten pool, and eliminating welding defects such as undercuts and slag entrainment. It is something that plays.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明方法の実施状態を示す模式図、v;2図
は木売り−j方法の他の実施状態を模式図である。 1.2.3・・・電4di  la、2a、3a・−溶
接ツイヤM・・・管母材 F・・・フランクス 特 K「 出 願 人   住友金11”4工業体式会
社代理人 弁理士  河 野 登 犬
FIG. 1 is a schematic diagram showing an implementation state of the method of the present invention, and FIG. 2 is a schematic diagram showing another implementation state of the wood selling method. 1.2.3... Electric 4dila, 2a, 3a - Welding thread M... Pipe base material F... Franks Special K Applicant: Sumitomo Metal 11" 4 Industrial Company Representative Patent Attorney Kawa Wild climbing dog

Claims (1)

【特許請求の範囲】 1、Al若しくはAf−Mg合金又はこれらの混合物の
粉末をスラグ形成剤としてその重数比テ0.5〜7%含
有するコアードワイヤを少くとも1本用いることを特徴
とする多電極潜弧溶接方法。 2、AJ若しくはAl−Mg合金又はこれらの混合物の
粉末をスラグ形成剤としてそのET 量比で0.5〜7
%含むことを特徴とする溶接ワイヤ0
[Claims] 1. At least one cored wire containing powder of Al or Af-Mg alloy or a mixture thereof as a slag forming agent in a weight ratio of 0.5 to 7% is used. Multi-electrode submerged arc welding method. 2. Using AJ or Al-Mg alloy powder or a mixture thereof as a slag forming agent, the ET ratio is 0.5 to 7.
Welding wire characterized by containing 0%
JP5738683A 1983-03-31 1983-03-31 Multielectrode submerged arc welding method and welding wire used therein Pending JPS59179294A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5738683A JPS59179294A (en) 1983-03-31 1983-03-31 Multielectrode submerged arc welding method and welding wire used therein

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5738683A JPS59179294A (en) 1983-03-31 1983-03-31 Multielectrode submerged arc welding method and welding wire used therein

Publications (1)

Publication Number Publication Date
JPS59179294A true JPS59179294A (en) 1984-10-11

Family

ID=13054167

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5738683A Pending JPS59179294A (en) 1983-03-31 1983-03-31 Multielectrode submerged arc welding method and welding wire used therein

Country Status (1)

Country Link
JP (1) JPS59179294A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5525265A (en) * 1990-09-24 1996-06-11 Akzo Nobel N.V. Liquid crystalline and infrared-sensitive liquid-crystalline polyesters
TWI495534B (en) * 2012-05-14 2015-08-11 Nat Univ Chung Hsing Hard submerged arc welding equipment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5525265A (en) * 1990-09-24 1996-06-11 Akzo Nobel N.V. Liquid crystalline and infrared-sensitive liquid-crystalline polyesters
TWI495534B (en) * 2012-05-14 2015-08-11 Nat Univ Chung Hsing Hard submerged arc welding equipment

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