JPS59173946A - Button type alkaline manganese battery - Google Patents

Button type alkaline manganese battery

Info

Publication number
JPS59173946A
JPS59173946A JP58048457A JP4845783A JPS59173946A JP S59173946 A JPS59173946 A JP S59173946A JP 58048457 A JP58048457 A JP 58048457A JP 4845783 A JP4845783 A JP 4845783A JP S59173946 A JPS59173946 A JP S59173946A
Authority
JP
Japan
Prior art keywords
gasket
positive
shaped
backing
negative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58048457A
Other languages
Japanese (ja)
Inventor
Tomohisa Yoshida
友久 吉田
Kazutoshi Takeda
和俊 竹田
Takakazu Fukuchi
高和 福地
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Instruments Inc
Original Assignee
Seiko Instruments Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Instruments Inc filed Critical Seiko Instruments Inc
Priority to JP58048457A priority Critical patent/JPS59173946A/en
Publication of JPS59173946A publication Critical patent/JPS59173946A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/166Lids or covers characterised by the methods of assembling casings with lids
    • H01M50/171Lids or covers characterised by the methods of assembling casings with lids using adhesives or sealing agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

PURPOSE:To increase leakage resistance by forming a gasket in a U-shaped structure. CONSTITUTION:A positive mix 2 comprising manganese dioxide and graphite, a separator 3, and a gasket 4 having a U-shaped cross section are accommodated in a positive can. An electrolyte absorbent material 5 is inserted along the inside of the gasket, then a negative mix 6 comprising amalgamated zinc powder, carboxymethylcellulose, and sodium polyacylate is filled on it. After a negative can 7 is covered, the opening of the positive can 1 is mechanically sealed. Since the U-shaped gasket has a long reversed portion, contact area along the inner side of the negative can is increased and penetration of electrolyte is prevented. However, because a thickness D2 of the inside part of the gasket decreases inner volume of a battery, thinner thickness is preferable.

Description

【発明の詳細な説明】 本発明は、ボタン型アルカリマンガン電池の絶縁封口に
用い−るバツギングに関するもので、従来のバッキング
形状とは異なる8字バッキングを用いる事により、耐漏
液性に優れたボタン型アルカリマンガン電池を提供する
ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to bagging used for insulating sealing of button-type alkaline manganese batteries.By using a figure-eight backing, which is different from the conventional backing shape, the present invention provides a button with excellent leakage resistance. type alkaline manganese battery.

近年の小形電子機器発展に伴って、小形、軽量。With the recent development of small electronic devices, they have become smaller and lighter.

高出力の電源が要求される様になってきたが、この要望
に応じてきたのが、ボタン型酸化銀電池であった。しか
しながら、銀地金価格の高騰による酸化銀電池の価格上
昇から、二酸化マンガンを正極活物質とするボタン型ア
ルカリマンガン電池が見直されて来た。
There was a growing demand for high-output power supplies, and the button-type silver oxide battery met this demand. However, due to the rise in the price of silver oxide batteries due to the rise in the price of silver ingots, button-type alkaline manganese batteries using manganese dioxide as a positive electrode active material have been reconsidered.

このアルカリマンガン電池の構成条件は正極以外は酸化
銀電池とほぼ同一であり、二酸化マンガンは銀地金価格
に対して約’/soo と極めて安価な為、今後は有効
利用が期待されている。したがって、あらゆる小形電子
機器に使用されても対応出来る様な電池品質が必要にな
って米た。しかしながら、酸化銀電池同様、耐漏液性に
関してはまだ不充分であり、従来のL字及びJ字形バッ
キングでは充分な効果が得られないという欠点を有して
いた。本発明はこの欠点を除去するもので、0字構造を
持つバッキングを用いる事で、耐漏液性に優れ1ζボタ
ン型アルカリマンガン電池を提供するものである。
The structural conditions of this alkaline manganese battery are almost the same as those of a silver oxide battery except for the positive electrode, and since manganese dioxide is extremely cheap at about 1/soo compared to the price of silver, it is expected that it will be used effectively in the future. Therefore, there was a need for batteries of a quality that could be used in all kinds of small electronic devices. However, like silver oxide batteries, they still have insufficient leakage resistance, and conventional L-shaped and J-shaped backings have the disadvantage that sufficient effects cannot be obtained. The present invention eliminates this drawback and provides a 1ζ button type alkaline manganese battery that has excellent leakage resistance by using a backing with a zero-shaped structure.

以下、実施例に基づき本発明の詳細な説明する。Hereinafter, the present invention will be described in detail based on Examples.

第1図は本発明電池の断面図である。図中、1は正極缶
で、二酸化マンガン、黒鉛からなる正極合剤2.セパレ
ータ32本発明に係る断面形状8字バッキング4を収納
している。次いで、前記バッキング4の内側に沿って、
電解液含浸材5を挿入し、水化亜鉛粉末、カルボキシメ
チルセルロースおよびポリアクリル酸ソーダからなる負
極合剤6を充填する。最後に、電極缶7を被せて、正極
缶1の開口端部を機掛的にカシメて封口する。
FIG. 1 is a sectional view of the battery of the present invention. In the figure, 1 is a positive electrode can, and 2 is a positive electrode mixture consisting of manganese dioxide and graphite. Separator 32 accommodates a backing 4 having a cross-sectional shape of 8 according to the present invention. Next, along the inside of the backing 4,
An electrolyte-impregnated material 5 is inserted, and a negative electrode mixture 6 consisting of zinc hydrate powder, carboxymethyl cellulose, and sodium polyacrylate is filled. Finally, the electrode can 7 is placed over the positive electrode can 1, and the open end of the positive electrode can 1 is caulked to seal it.

第2図は、本発明に係るU字バッキング断面図である。FIG. 2 is a sectional view of the U-shaped backing according to the present invention.

図中、Dlは外側部肉厚、D2は内側部肉厚を示す。こ
のD2d電池内容積を減じるため、出来る限シ薄い肉厚
としたい。一方、第2図の形状に射出成形するためには
、0.07〜0.15’vanの肉厚が必要である。
In the figure, Dl indicates the outer wall thickness, and D2 indicates the inner wall thickness. In order to reduce the internal volume of this D2d battery, we want to make the wall thickness as thin as possible. On the other hand, in order to injection mold the shape shown in FIG. 2, a wall thickness of 0.07 to 0.15'van is required.

これらのことから、本発明に係る8字バッキングの内側
部の肉ノ阜D2は、0.07〜8.13腸が最適である
For these reasons, the optimum thickness D2 of the inner side of the figure 8 backing according to the present invention is 0.07 to 8.13 mm.

第6図(A)、(B)U、従来のバッキングの断面図で
ある。
FIGS. 6A and 6B are sectional views of conventional backings.

次に、従来使用していfCL字、5字バッキングと、本
発明である8字バッキングを用いた電池を各n=100
個ずつ試作し、高温高湿試験を行ない、漏液の発生率を
調査した。試験条件は60℃。
Next, batteries using conventionally used fCL-shaped and 5-shaped backings and batteries using the 8-shaped backing according to the present invention were each used with n=100 batteries.
We made prototypes one by one, conducted high temperature and high humidity tests, and investigated the incidence of leakage. Test conditions were 60°C.

湿度90〜95係で行ない、試験投入日力・ら20日、
40日目に電池を取シ出し、倍率15の実体顕微鏡を、
使用して漏液の判定を行なった。
The humidity was 90-95, and the test was conducted on the 20th day.
On the 40th day, I took out the battery and used a stereo microscope with a magnification of 15.
was used to determine leakage.

第1表 上記表から明らかな様に、従来バッキングと比較して本
発明バッキングを用いた電池の漏液発生率は、約狛と極
めて低い事が証明さねた。
As is clear from the above table in Table 1, the leakage rate of the battery using the backing of the present invention was proved to be extremely low compared to the conventional backing.

ソノ理由は、従来バッキングの場合、電極缶の底面と接
触する面積が少ない為、どうしても電解液が電極缶とバ
ッキングの間に浸入しゃすぐなり、漏液の防止が困難で
あったのに対し、本発明の8字バッキングは折シ返しが
長い為、電極缶の底面から内側に力・け−この接触面積
が太きぐな9、電解液の浸入を防止する効果が得られた
のである。
The reason for this is that with conventional backings, the contact area with the bottom of the electrode can is small, so the electrolyte tends to seep between the electrode can and the backing, making it difficult to prevent leakage. Since the figure 8 backing of the present invention has a long fold, the contact area of the force and force inward from the bottom of the electrode can is large 9, which has the effect of preventing the infiltration of electrolyte.

以上詳述した様に、バッキングの構造をU字形にする事
により、耐漏液性の優れたボタン型アルカリマンガン電
池を開発する事が出来た。したがって、長期信頼性が必
要な電子腕時計はもちろんの事、電卓及び玩具等その他
の小型電子機器などに使用するのには最適である。
As detailed above, by making the backing structure U-shaped, we were able to develop a button-type alkaline manganese battery with excellent leakage resistance. Therefore, it is ideal for use not only in electronic wristwatches that require long-term reliability, but also in other small electronic devices such as calculators and toys.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(d本発明電池の断面図、第2図は本発明に係る
バッキングの断面図、第3図(A) + (B)  は
従来バッキングの断面図である。 1・・・・・・正極缶    2・・・・・・正極合剤
5・・・・・・セパレータ  4・・・・・・バッキン
グ5・・・・・・電解液含浸材 6・・団・負極合剤7
・・・・・・電極缶    D、・・・外側部肉厚D2
・・・内側部肉厚 以上 出願人 株式会社 第二精工合
Figure 1 (d) is a sectional view of the battery of the present invention, Figure 2 is a sectional view of the backing of the present invention, and Figure 3 (A) + (B) is a sectional view of the conventional backing. - Positive electrode can 2... Positive electrode mixture 5... Separator 4... Backing 5... Electrolyte impregnated material 6... Group negative electrode mixture 7
...Electrode can D, ...Outer wall thickness D2
...More than inner wall thickness Applicant: Daini Seikogo Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] (1)正極と負極の絶縁封口に用いるバッキングの形状
を、U字形にした事’kfFMとするボタン型アルカリ
マンガン電池。
(1) A button-type alkaline manganese battery in which the backing used to insulate the positive and negative electrodes is U-shaped.
(2)  前記断面形状0字バッキングの内側部肉厚D
2が0.07〜0.13謡であることを特徴とする特許
請求の範囲第1項記載のボタン型アルカリマンガン電池
(2) Inner wall thickness D of the 0-shaped cross-sectional backing
2. The button-type alkaline manganese battery according to claim 1, wherein 2 is 0.07 to 0.13.
JP58048457A 1983-03-23 1983-03-23 Button type alkaline manganese battery Pending JPS59173946A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58048457A JPS59173946A (en) 1983-03-23 1983-03-23 Button type alkaline manganese battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58048457A JPS59173946A (en) 1983-03-23 1983-03-23 Button type alkaline manganese battery

Publications (1)

Publication Number Publication Date
JPS59173946A true JPS59173946A (en) 1984-10-02

Family

ID=12803884

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58048457A Pending JPS59173946A (en) 1983-03-23 1983-03-23 Button type alkaline manganese battery

Country Status (1)

Country Link
JP (1) JPS59173946A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023511261A (en) * 2020-07-01 2023-03-17 エルジー エナジー ソリューション リミテッド Button type secondary battery and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023511261A (en) * 2020-07-01 2023-03-17 エルジー エナジー ソリューション リミテッド Button type secondary battery and manufacturing method thereof

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