JPS59156905A - Porous structure made of activated carbon and its manufacture - Google Patents

Porous structure made of activated carbon and its manufacture

Info

Publication number
JPS59156905A
JPS59156905A JP58030572A JP3057283A JPS59156905A JP S59156905 A JPS59156905 A JP S59156905A JP 58030572 A JP58030572 A JP 58030572A JP 3057283 A JP3057283 A JP 3057283A JP S59156905 A JPS59156905 A JP S59156905A
Authority
JP
Japan
Prior art keywords
porous structure
activated carbon
synthetic resin
urethane foam
impregnated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58030572A
Other languages
Japanese (ja)
Inventor
Masuhito Iinuma
飯沼 益人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mahle Filter Systems Japan Corp
Tsuchiya Seisakusho KK
Original Assignee
Mahle Filter Systems Japan Corp
Tsuchiya Seisakusho KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mahle Filter Systems Japan Corp, Tsuchiya Seisakusho KK filed Critical Mahle Filter Systems Japan Corp
Priority to JP58030572A priority Critical patent/JPS59156905A/en
Publication of JPS59156905A publication Critical patent/JPS59156905A/en
Pending legal-status Critical Current

Links

Landscapes

  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

PURPOSE:To manufacture the titled porous structure having superior adsorbing power and usable in an atmosphere at a high temp. by calcining a thermosetting synthetic resin impregnated into urethane foam, and activating the resulting carbide. CONSTITUTION:A thermosetting synthetic resin such as phenol resin is impregnated into a base material made of open cell type urethane foam having a desired void volume. The impregnated base material is calcined by heating to burn off the urethane foam as well as to cure the synthetic resin, and the synthetic resin is further carbonized to form a united porous structure 4. The porous structure (carbide) 4 is activated, and many micropores 5 are produced to obtain a porous structure made of activated carbon.

Description

【発明の詳細な説明】 この発明は活性炭で成り、通気性を持たせた多孔質構造
体に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a porous structure made of activated carbon and provided with air permeability.

従来、気体を通過させて吸着浄化する活性炭を担持した
構造体は、たとえば第1図のように連続気孔のウレタン
フオーム1の多孔表面に活性炭粒2を接着剤3で付着さ
せたものであった。
Conventionally, a structure supporting activated carbon that adsorbs and purifies gas by passing through it has been made by adhering activated carbon particles 2 to the porous surface of a continuous pore urethane foam 1 with an adhesive 3, for example, as shown in Fig. 1. .

このものは基材がウレタンであるため高温ガスを通過さ
せるなど高温雰囲気で使用したり、吸着時に発熱作用が
あるような用途に充当すると、構造体が変形したり崩壊
したりする。また活性炭の微粉が剥離して流失したりす
るおそれもあり、活性炭粒が接着剤1とよって被われる
部分は吸着作用をしない無効部分となってしまうという
欠点がある。
Since the base material of this product is urethane, if it is used in a high-temperature atmosphere, such as by passing a high-temperature gas, or if it is used in an application that generates heat during adsorption, the structure will deform or collapse. Further, there is a risk that the activated carbon fine powder may peel off and be washed away, and there is a drawback that the portion where the activated carbon particles are covered by the adhesive 1 becomes an ineffective portion that does not have an adsorption effect.

この発明は前記のような欠点のない活性炭め多孔質構造
体およびその製造方法を1供するものである。
The present invention provides an activated carbon porous structure and a method for manufacturing the same, which are free from the above-mentioned drawbacks.

すなわち炭化物のみで成る多孔質構造体を形成しその表
面を活性化するものである。
That is, a porous structure made only of carbide is formed and its surface is activated.

実施例によって説明すると第2図おいて連続気孔型の多
孔質組織を有する構造体4はフェノール系などの熱硬化
性合成引晰を炭化させた一体的なものであり、その多孔
表面は微細な吸着孔5を有している。
To explain with an example, the structure 4 having a continuous pore type porous structure in FIG. It has suction holes 5.

このような構造体を製造するには、所望の空隙率を有す
る連続気孔型ウレタンフオームの基材へフェノール系な
どの熱硬化性合成樹脂を含浸させ、次いで加熱焼成する
と、前記合成樹脂が硬化するとともに基材のウレタンフ
オームが焼失し、さらに合成樹脂が炭化し甑−材料でか
つ一体的な多孔質構造体4が得られる。つぎにこの炭化
物の構造体に通常用いられている活性炭製造方法におけ
る賦活工程を加える。するとこの炭化構造体自体に吸着
作用を有する微細孔が与えられて活性化しこの発明の多
孔質構造体を得ることができる。なお賦活工程の調節に
より吸着物質に応じた吸着特性をもたせることができる
To manufacture such a structure, a base material of open-pore urethane foam having a desired porosity is impregnated with a thermosetting synthetic resin such as a phenolic resin, and then heated and baked to harden the synthetic resin. At the same time, the urethane foam of the base material is burnt out, and the synthetic resin is further carbonized, yielding an integral porous structure 4 made of clay material. Next, this carbide structure is subjected to an activation step in a commonly used activated carbon manufacturing method. Then, this carbonized structure itself is provided with micropores having an adsorption effect and activated, thereby making it possible to obtain the porous structure of the present invention. By adjusting the activation process, it is possible to provide adsorption characteristics depending on the adsorbed substance.

この発明による多孔質構造体はm−な材料を炭化させた
一体的なものであるから活性炭粒の接着剥離等による不
具合がない。また接着剤に被われて活性炭の微細孔が無
効化することもなく、活性炭自体が多孔質構造体である
から有効な微細孔を多く持たせ吸着性能を向上させるこ
とができる。さらに空隙率が大となるから通気抵抗を減
少させることができ、炭化物のみで成るから高温ガスの
通過や発熱吸着作用にも十分耐えうるものである。
Since the porous structure according to the present invention is made of an integral carbonized m-material, there are no problems such as adhesion and peeling of activated carbon particles. Further, the micropores of the activated carbon are not disabled by being covered with adhesive, and since the activated carbon itself is a porous structure, it can have many effective micropores and improve its adsorption performance. Furthermore, since the porosity is increased, ventilation resistance can be reduced, and since it is made only of carbide, it can sufficiently withstand the passage of high-temperature gas and the heat-generating adsorption action.

またこの発明の製造方法化よれば基材のウレタンフオー
ムの空隙率と、含浸させる合成樹脂の量を適宜に選ぶこ
とにより、形成される構造体の空隙率と活性炭量を変化
させることができるので、用途に応じて容積当りの通気
抵抗の低いものや吸着性能の高いものを選択して製造す
ることができる。
Furthermore, according to the manufacturing method of the present invention, by appropriately selecting the porosity of the urethane foam of the base material and the amount of the synthetic resin to be impregnated, the porosity and amount of activated carbon of the formed structure can be changed. Depending on the application, a material with low ventilation resistance per volume or a material with high adsorption performance can be selected and manufactured.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の活性炭を担持した構造物を示す図、第2
図は乙の発明の多孔質構造体を示す図である。 1・・・・・・ウレタンフオームで成る基材2・・・・
・活性炭粒
Figure 1 shows a structure supporting conventional activated carbon, Figure 2 shows a structure supporting conventional activated carbon.
The figure shows a porous structure according to the invention of B. 1... Base material made of urethane foam 2...
・Activated carbon grains

Claims (2)

【特許請求の範囲】[Claims] (1)  連続気孔型の組織を有し、活性炭で成る多孔
う質構造体。
(1) A porous carious structure made of activated carbon and having a continuous pore type structure.
(2)  ウレタンの連続気孔型構造体に熱硬化性の合
成樹脂を含浸させ、加熱焼成してウレタンを焼失させる
とともに前記合成樹脂を硬化し炭化させ、次いで前記合
成樹脂の炭化物に賦店工程を加えて活性化する、活性炭
で成る多孔質構造体の製造方法。
(2) A thermosetting synthetic resin is impregnated into a continuous pore structure of urethane, and the urethane is burnt out by heating and baking, and the synthetic resin is hardened and carbonized. Then, the carbide of the synthetic resin is subjected to an immobilizing process. A method for producing a porous structure made of activated carbon, which is additionally activated.
JP58030572A 1983-02-25 1983-02-25 Porous structure made of activated carbon and its manufacture Pending JPS59156905A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58030572A JPS59156905A (en) 1983-02-25 1983-02-25 Porous structure made of activated carbon and its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58030572A JPS59156905A (en) 1983-02-25 1983-02-25 Porous structure made of activated carbon and its manufacture

Publications (1)

Publication Number Publication Date
JPS59156905A true JPS59156905A (en) 1984-09-06

Family

ID=12307556

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58030572A Pending JPS59156905A (en) 1983-02-25 1983-02-25 Porous structure made of activated carbon and its manufacture

Country Status (1)

Country Link
JP (1) JPS59156905A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU606454B1 (en) * 1988-09-07 1991-02-07 Kabushiki Kaisha Sophia Game system
JPH05254816A (en) * 1991-11-21 1993-10-05 Pechiney Rech Group Interet Economique Regie Par Ordonnance Du 23 Septembre 1967 Preparation of metal carbide having large specific surface from activated carbon foam

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU606454B1 (en) * 1988-09-07 1991-02-07 Kabushiki Kaisha Sophia Game system
JPH05254816A (en) * 1991-11-21 1993-10-05 Pechiney Rech Group Interet Economique Regie Par Ordonnance Du 23 Septembre 1967 Preparation of metal carbide having large specific surface from activated carbon foam

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