JPS5913810A - Wick - Google Patents
WickInfo
- Publication number
- JPS5913810A JPS5913810A JP12255082A JP12255082A JPS5913810A JP S5913810 A JPS5913810 A JP S5913810A JP 12255082 A JP12255082 A JP 12255082A JP 12255082 A JP12255082 A JP 12255082A JP S5913810 A JPS5913810 A JP S5913810A
- Authority
- JP
- Japan
- Prior art keywords
- platinum
- fuel vaporization
- adsorbed
- vaporization section
- wick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000446 fuel Substances 0.000 claims abstract description 42
- 230000008016 vaporization Effects 0.000 claims abstract description 31
- 238000009834 vaporization Methods 0.000 claims abstract description 30
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003054 catalyst Substances 0.000 claims abstract description 18
- 239000000919 ceramic Substances 0.000 claims abstract description 5
- 241000217776 Holocentridae Species 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 18
- 238000009825 accumulation Methods 0.000 abstract description 10
- 238000002485 combustion reaction Methods 0.000 abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 8
- 238000009835 boiling Methods 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 239000003365 glass fiber Substances 0.000 abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract description 2
- -1 hexachloro platinum (IV) Chemical compound 0.000 abstract description 2
- 239000007767 bonding agent Substances 0.000 abstract 2
- 239000002657 fibrous material Substances 0.000 abstract 2
- 229920002125 Sokalan® Polymers 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000004584 polyacrylic acid Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 240000008415 Lactuca sativa Species 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 235000012045 salad Nutrition 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D3/00—Burners using capillary action
- F23D3/02—Wick burners
- F23D3/08—Wick burners characterised by shape, construction, or material, of wick
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は液体燃料用燃焼器に用いられる灯芯に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a wick for use in a liquid fuel combustor.
液体燃料を灯芯の毛細管現象によって吸上げその灯芯の
気化室内に露出している先端部分、即ち燃料気化部の表
面から液体燃料を気化させて燃焼せしめる、いわゆる吸
上げ気化式の燃焼器は、石油ストーブ、石油コンロ等に
広く用いられている。The so-called suction vaporization type combustor sucks up liquid fuel by the capillary action of the lamp wick and vaporizes the liquid fuel from the surface of the fuel vaporization section, which is exposed in the vaporization chamber of the wick, and burns it. Widely used in stoves, oil stoves, etc.
この種の燃焼器では、燃料気化部が高温でかつ酸累の介
在する雰囲気に暴露されているために燃焼中において燃
料気化部に含有される燃料の一部が酸化9重合反応等に
よってタール状物質となり、燃料気化部に蓄積されると
いう現象が容易に生じていた。特に燃料中に微量の高沸
点成分が混入したり(例えば幻油中に機械油、軽油、サ
ラダ油等が混入した場合)、あるいは燃料成分の一部が
変質(例えば灯油を長期間高温あるいは直射1」光下に
保存した時に生ずる酸化物、過酸化物、樹脂等)してい
る場合等には、前記タール状物質の生成。In this type of combustor, the fuel vaporization section is exposed to a high temperature and an atmosphere containing acid accumulation, so during combustion, part of the fuel contained in the fuel vaporization section becomes tar-like due to oxidation and polymerization reactions. The phenomenon of easily becoming a substance and accumulating in the fuel vaporization section occurred. In particular, if trace amounts of high-boiling components are mixed into the fuel (for example, when machine oil, light oil, salad oil, etc. are mixed into phantom oil), or some of the fuel components are altered (for example, when kerosene is heated for a long period of time or exposed to direct heat, ``Oxides, peroxides, resins, etc. generated when stored under light), the formation of tar-like substances.
蓄積は著しく増大する。Accumulation increases significantly.
このタール状物質が燃料気化部に蓄積した時、燃料気化
部の表面あるいは内部の毛細管が閉塞され、燃料の吸上
げや気化が阻害される。このため燃←1気化量が異常に
低下し、燃焼室における空燃比を崩して臭気、ススや有
毒な一酸化炭素を多発する様な不具合を生じていた。ま
た点火時には上記タール状物質によって燃料気化部の速
かなる温度上肩、燃料気化量の増加が妨げられ、安定燃
焼に至るに著しく長時間を有し、その間不安定過渡燃焼
による臭気、スス、−酸化炭素等の発生を増大せしめて
いた。更にタール状物質が灯芯とこれを支持する金属部
とを固着させ、灯芯の機械的動作を不可能ならしめ、灯
芯を下げての消火操作を不能とする様な危険な状態もあ
った。When this tar-like substance accumulates in the fuel vaporization section, the capillary tubes on the surface or inside the fuel vaporization section are blocked, thereby inhibiting fuel suction and vaporization. As a result, the amount of fuel ←1 vaporized is abnormally reduced, causing problems such as the air-fuel ratio in the combustion chamber being disrupted and the generation of odor, soot, and toxic carbon monoxide. In addition, at the time of ignition, the tar-like substance quickly raises the temperature of the fuel vaporization part and prevents an increase in the amount of fuel vaporization, resulting in a significantly long period of time for stable combustion to occur. - Increased generation of carbon oxide, etc. In addition, the tar-like substance caused the wick to stick to the metal part that supported it, making it impossible for the wick to operate mechanically, making it impossible to extinguish the fire by lowering the wick.
本発明はこのような従来の欠点を解消するために、ター
ル状物質の生成蓄積を抑制することを[」的とするもの
である。The present invention aims to suppress the generation and accumulation of tar-like substances in order to eliminate such conventional drawbacks.
この目的を達成するために本発明は、灯芯においてセラ
ミック繊維に少量の結合剤を加えて形成した多孔体の燃
料気化部の少なくとも一部に、白金pt、ロジクムRh
等白金白金族触媒浸、吸着させたものである。In order to achieve this object, the present invention provides platinum PT, logicum rh
Platinum is impregnated with a platinum group catalyst and adsorbed.
この構成によって、タール状物質の生成、蓄積の判たる
要因である高沸点成分や変質成分が、高温状態となって
いる燃料気化部において、白金族触媒、すなわちpto
等の強い触媒作用を受けて、分解され、気化し易くなる
。とのため高沸点成分や変質成分は燃料気化部で長時間
滞留することはなく、重合反応等によるタール状物質へ
の変化は著しく減少し、長期間安定な燃焼を維持し得る
こととなる。With this configuration, high boiling point components and degraded components, which are known factors for the generation and accumulation of tar-like substances, are transferred to the platinum group catalyst, that is, PTO, in the fuel vaporization section which is in a high temperature state.
It is easily decomposed and vaporized by the strong catalytic action of Therefore, high-boiling components and degraded components do not remain in the fuel vaporization section for a long time, and the conversion to tar-like substances due to polymerization reactions and the like is significantly reduced, making it possible to maintain stable combustion for a long period of time.
以下本発明の一実施例を添付図面と共に説明する。An embodiment of the present invention will be described below with reference to the accompanying drawings.
第1図は本発明の一実施例の灯芯の縦断面を示したもの
であり、1は主窓で、シリカ−アルミナ系のセラミック
繊維(シリカ:アルミナ−5o:60、重量比)を結合
剤の一例として用いたポリアクリル酸エステルを加えて
形成したもので、無水ケイ酸を分散、吸着させである。FIG. 1 shows a vertical cross section of a lamp wick according to an embodiment of the present invention. 1 is the main window, and silica-alumina ceramic fiber (silica:alumina-5o:60, weight ratio) is used as a binder. It is formed by adding the polyacrylic ester used as an example, and by dispersing and adsorbing silicic acid anhydride.
2はガラス繊維を主体としだ編組布よりなる補助芯であ
る。3は吸上げ芯上部で、綿を主体とした編組布よりな
る。4u吸上げ芯上部で、ポリプロピレンを主体とした
編組布よりなる。5は主窓1上部に形成した燃料気化部
で、燃焼器に装着した時、燃焼室に露出される部分であ
る。燃料気化部6には、白金族触媒として、ヘキサクロ
ロ白金(IV)酸を還元してつくった白金黒触媒が吸着
させである。6は主窓1、補助芯2の内側面に固着した
円筒状の芯取付部材、7は吸上げ芯上部3.吸上げ芯上
部4の内側面に固着した円筒状の吸上げ芯取付部材であ
る。Reference numeral 2 denotes an auxiliary core made of a braided cloth mainly made of glass fiber. 3 is the upper part of the wick, which is made of a braided cloth mainly made of cotton. The upper part of the 4u wick is made of braided cloth mainly made of polypropylene. Reference numeral 5 denotes a fuel vaporization section formed above the main window 1, which is exposed to the combustion chamber when installed in the combustor. In the fuel vaporization section 6, a platinum black catalyst made by reducing hexachloroplatinic (IV) acid is adsorbed as a platinum group catalyst. 6 is a cylindrical core attachment member fixed to the inner surface of the main window 1 and the auxiliary core 2, and 7 is the upper part of the suction core 3. This is a cylindrical suction core attachment member fixed to the inner surface of the suction core upper part 4.
8は接着テープである。8 is an adhesive tape.
上記構成において、液体燃料は吸上げ芯上部4から吸上
げ芯3を経て、補助芯2.主窓1へと吸上げられ、燃料
気化部6表面から気化する。ここで本実施例の効果を燃
料の流れとともに、従来例と比較して詳述する。In the above configuration, the liquid fuel passes from the suction wick upper part 4 to the suction wick 3, and then to the auxiliary wick 2. The fuel is sucked up to the main window 1 and vaporized from the surface of the fuel vaporization section 6. Here, the effects of this embodiment will be explained in detail along with the flow of fuel in comparison with the conventional example.
第2図は、セラミック繊維からなる主窓1と、ガラス繊
維よりなる補助芯2の燃料気化部6に無水ケイ酸を分散
、吸着させた従来の灯芯の一例で、その燃料気化部6の
断面図を示す。また第3図は、本実施例によるところの
燃料気化部5の断面図で白金黒触媒が吸着させである。Figure 2 shows an example of a conventional lamp wick in which silicic acid anhydride is dispersed and adsorbed in the fuel vaporization part 6 of the main window 1 made of ceramic fiber and the auxiliary wick 2 made of glass fiber, and a cross section of the fuel vaporization part 6. Show the diagram. Further, FIG. 3 is a cross-sectional view of the fuel vaporization section 5 according to this embodiment, in which a platinum black catalyst is adsorbed.
即ち、燃料F(実線矢印)は主窓1や補助芯2内を吸上
げられ、燃料気化部6表面から気化する。That is, the fuel F (solid arrow) is sucked up inside the main window 1 and the auxiliary wick 2, and is vaporized from the surface of the fuel vaporization section 6.
このとき従来例においては第2図に示すように、燃料は
燃料気化部6において、定常燃焼時には。At this time, in the conventional example, as shown in FIG. 2, the fuel is in the fuel vaporization section 6 during steady combustion.
温度(約200°C前後になっている。)や空気の影響
を受けて一部タール状物質になり易くなっている。とく
に、高沸点成分や変質成分(白抜き矢印)等は、温度や
空気の影響を受けて、酸化1重合反応し易くなりタール
状物質Tに変化し、蓄積していた。ところが第3図に示
すように、本実施例に示すところの白金族触媒として、
ヘキサクロロ白金(IV)酸を還元してつくった白金黒
触媒を、シリカ−アルミナ系のセラミック繊維に吸着さ
せた燃料気化部6においては、白金黒触媒は、シリカ。Some parts tend to turn into tar-like substances due to the influence of temperature (approximately 200°C) and air. In particular, high boiling point components and altered components (white arrows) were susceptible to oxidation and monopolymerization reactions under the influence of temperature and air, and were converted into tar-like substances T and accumulated. However, as shown in FIG. 3, as the platinum group catalyst shown in this example,
In the fuel vaporization section 6 in which a platinum black catalyst made by reducing hexachloroplatinic (IV) acid is adsorbed on silica-alumina ceramic fibers, the platinum black catalyst is silica.
アルミナの表面に吸着して、その触媒作用を十分発揮す
ることや、燃料気化部6の温度(約200°C前後)が
、白金黒触媒が高沸点成分や変質成分を、分解して気化
し易い物質に変化させるのに適していること等によって
、従来のようにタール状物質等の生成、蓄積は著しく減
少する。The platinum black catalyst is adsorbed onto the surface of alumina and fully exerts its catalytic action, and the temperature of the fuel vaporization section 6 (approximately 200°C) is such that the platinum black catalyst decomposes and vaporizes high-boiling components and altered components. Because it is suitable for converting into substances that are easy to change, the generation and accumulation of tar-like substances, etc., as in the past, is significantly reduced.
ちなみに吸上げ気化方式の石油燃焼器を用いて燃焼させ
たときの結果を示すと第4図のようになる。燃料は白灯
油にサラダ油を0.1容量%混合させたものを用い、タ
ール状物質が生成、蓄積することによる発熱量の低下に
与える影響を比較すると、白金黒触媒を燃料気化部6に
吸着させた本実施例によるところの灯芯は、従来例より
も、発熱量の維持特性が著しく良く、タール状物質の生
成。Incidentally, the results of combustion using a suction vaporization type oil combustor are shown in Figure 4. The fuel used was a mixture of white kerosene and salad oil at 0.1% by volume, and when comparing the effect on the reduction in calorific value due to the generation and accumulation of tar-like substances, it was found that the platinum black catalyst was adsorbed in the fuel vaporization section 6. The lamp wick according to this embodiment has significantly better heat generation retention characteristics than the conventional example, and has a tendency to reduce the generation of tar-like substances.
蓄積が著しく少ないことがわかる。It can be seen that the accumulation is extremely low.
以上の様に本発明の灯芯は、セラミック繊維に少量の結
合剤を加えて形成した多孔体の燃料気化部の少なくとも
一部に白金Pt、ロジウムRh等の白金族触媒を含浸、
吸着させることによって、タール状物質の生成、蓄積を
抑え、長101間にわたる安定燃焼を提供し得るもので
、実用的に大きな効果を有するものである。As described above, the lamp wick of the present invention includes a porous body formed by adding a small amount of a binder to ceramic fibers, and at least a portion of the fuel vaporizing portion thereof is impregnated with a platinum group catalyst such as platinum Pt or rhodium Rh.
By adsorbing it, the generation and accumulation of tar-like substances can be suppressed and stable combustion can be provided over a long period of time, which has a great practical effect.
第1図は本発明の一実施例にがかる灯芯の部分断面図、
第2図、第3図は灯芯の作用説明図、第4図はその特性
図である。
1・・・・・・主窓、2・・・・・・補助芯、5・・・
・・・燃料気化部。
代理人の氏名 弁理士 中 尾 赦 男 ほか1名第2
図
第3図
第4図
癲
痺
燃焼F18間(b超r)FIG. 1 is a partial sectional view of a lamp wick according to an embodiment of the present invention;
FIG. 2 and FIG. 3 are explanatory diagrams of the operation of the lamp wick, and FIG. 4 is a characteristic diagram thereof. 1...Main window, 2...Auxiliary core, 5...
...Fuel vaporization section. Name of agent: Patent attorney Masao Nakao and 1 other person 2nd
Figure 3 Figure 4 Paralysis combustion between F18 (b over r)
Claims (1)
の燃料気化部の少なくとも一部に、白金pt、ロジクム
Rh等白金白金族触媒浸、吸着させた灯芯。A lamp wick in which at least a part of the fuel vaporization part of a porous body formed by adding a small amount of a binder to ceramic fibers is impregnated with and adsorbed with a platinum group catalyst such as platinum PT or Logicum Rh.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12255082A JPS5913810A (en) | 1982-07-14 | 1982-07-14 | Wick |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12255082A JPS5913810A (en) | 1982-07-14 | 1982-07-14 | Wick |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5913810A true JPS5913810A (en) | 1984-01-24 |
Family
ID=14838644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12255082A Pending JPS5913810A (en) | 1982-07-14 | 1982-07-14 | Wick |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5913810A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56146907A (en) * | 1980-04-17 | 1981-11-14 | Matsushita Electric Ind Co Ltd | Liquid fuel combustion wick |
-
1982
- 1982-07-14 JP JP12255082A patent/JPS5913810A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56146907A (en) * | 1980-04-17 | 1981-11-14 | Matsushita Electric Ind Co Ltd | Liquid fuel combustion wick |
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