JPS59132876A - Preservation of food - Google Patents
Preservation of foodInfo
- Publication number
- JPS59132876A JPS59132876A JP767083A JP767083A JPS59132876A JP S59132876 A JPS59132876 A JP S59132876A JP 767083 A JP767083 A JP 767083A JP 767083 A JP767083 A JP 767083A JP S59132876 A JPS59132876 A JP S59132876A
- Authority
- JP
- Japan
- Prior art keywords
- food
- ethyl alcohol
- oil
- mixture
- essential oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、食品の保存方法に関するものであり主として
微生物の増殖により、腐敗あるいは劣化する食品の保存
性を向上させる保存方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for preserving food, and primarily to a method for improving the preservation of food that rots or deteriorates due to the growth of microorganisms.
従来、食品の保゛存のために種々の食品添加剤が使用さ
れており、これらの添加剤は、食品の製造時または収獲
時等に、混合、塗布等により直接食品に添加する方法が
最も多(用いられている。Conventionally, various food additives have been used to preserve food, and the best way to add these additives is to add them directly to food by mixing or coating it during food production or harvesting. Many (used.
しかしながら、これらの添加剤を直接食品へ添加する方
法は、近年の社会情勢から使用を自粛するようになって
来ており、使用量や使用対象の食品が限定されて、−律
に使用できるものではなく、また食品本来の味や色や風
味等が変化しゃずいという欠点があった。However, due to the social situation in recent years, the use of these additives directly into food has been discouraged, and the amount of use and the foods to which they can be used are limited. Moreover, there was a drawback that the original taste, color, flavor, etc. of the food were not changed.
またこの直接添加する方法は、製造時や収獲時等に添加
しなげればならないため、使用方法が限定され、適用で
きる対象食品も限られたものであった。In addition, this direct addition method requires addition at the time of manufacturing or harvesting, so the methods of use are limited and the food products to which it can be applied are also limited.
最近では、エチルアルコールの殺菌乃至は静菌効果を利
用して、エチルアルコールを担持させたシリカゲル等の
担体な食品とともに容器内に収納し、担体より発散する
エチルアルコール蒸気により、黴の発生を防ぐ試みもな
されているが、食品のように栄養価の高いものに発生す
る酵母、細菌類に対し充分な増殖抑制効果を得るために
は、多量のエチルアルコール蒸気が必要であり、従って
エチルアルコール特有のいわゆるアルコール臭力強く、
食品の風味、臭いを著るしく変化させるため、使用量が
限定され、多(の微生物に対しては実用的に充分満足で
きるものではなかった。Recently, taking advantage of the bactericidal or bacteriostatic effect of ethyl alcohol, it is stored in a container together with food carriers such as silica gel carrying ethyl alcohol, and the ethyl alcohol vapor emitted from the carrier prevents the generation of mold. Although some attempts have been made, a large amount of ethyl alcohol vapor is required to sufficiently suppress the growth of yeast and bacteria that occur in highly nutritious foods such as food. The so-called alcohol smell is strong,
Because it significantly changes the flavor and odor of foods, the amount used is limited, and it has not been practically satisfactory against many microorganisms.
一方、精油あるいは香辛料もしくはその成分(以下精油
等と称す)に、微生物の増殖抑制効果があることは、古
(から知られている。しかしながら精油等には、特有の
強い臭気があり、微生物、抑制効果を有する濃度では臭
気が強すぎるため、「カラン漬け」等の特殊な食品にの
み利用されるだけであった。このよウニエチルアルコー
ルのみ、または精油等のみにより食品を保存しようとす
る場合は、食品の変敗原因となる多くの微生物に対し充
分な効果を得るには比較的高い濃度となるため、アルコ
−)し臭、あるいは精油等に特有の臭気が強く、実際的
には、極めて限定された食品にしか適用できないもので
あった。また近年、これらの欠点を改良しようとして、
数種類の精油等の混合物やエチルアルコールと精油等の
混合物や有機酸等を食品に混合する試みがなされて(・
るが、これとても食品への直接添加であり、使用方法、
適用食品が限定され、食品の風味へ与える影響も無視で
きないという欠点があった。On the other hand, it has been known since ancient times that essential oils, spices, or their components (hereinafter referred to as essential oils, etc.) have the effect of inhibiting the growth of microorganisms. At concentrations that have a suppressive effect, the odor is too strong, so it was only used for special foods such as pickled vegetables.In this way, when trying to preserve foods only with sea urchin alcohol or essential oils, etc. Since it has a relatively high concentration to be sufficiently effective against many microorganisms that cause spoilage of food, it has a strong alcohol odor or odor characteristic of essential oils, and in practical terms, It could only be applied to very limited foods. In recent years, attempts have been made to improve these shortcomings,
Attempts have been made to mix mixtures of several types of essential oils, mixtures of ethyl alcohol and essential oils, organic acids, etc. into foods.
However, this is a direct addition to food, and how to use it,
The disadvantages are that the applicable foods are limited and the effect on the flavor of the food cannot be ignored.
また有機酸、特に酢酸蒸気を発する担体を食品とともに
容器内に別添する方法も検討されて(・るが、これも食
品に酸味を与えることはまぬがれないうえ包装開封時、
包装内に充満した酢酸蒸気により、酢酸臭を感じること
が多く、食欲を減退させることすらあった。また該方法
を利用できる食品としては、シュウマイやギョウザなど
若干の酢酸臭があっても影響が比較的少ない食品に限ら
れていた。In addition, a method of attaching a carrier that emits organic acids, especially acetic acid vapor, to the food container is also being considered.
Due to the acetic acid vapor that filled the packaging, the smell of acetic acid was often felt, and it even decreased appetite. Furthermore, the foods to which this method can be applied are limited to foods such as shumai and dumplings, which have relatively little effect even if they have a slight acetic acid odor.
本発明は、かかる従来法の欠点を解決しようとするもの
であり、食品の風味、臭い、テクスチャーなどにほとん
ど影響を与えることなく、長期間食品、を保存しようと
するもので、エチルアルコールおよび精油等との混合物
を直接食品と接触することなく、包装容器内に収納する
ことによりエチルアルコールおよび精油等の微生物の増
殖抑制に対する相乗効果で多種の食品の保存効果を高め
るものである。The present invention attempts to solve the drawbacks of such conventional methods, and aims to preserve food for a long period of time without substantially affecting the flavor, odor, texture, etc. of the food. By storing a mixture of ethyl alcohol and essential oils in a packaging container without coming into direct contact with foods, the synergistic effect of ethyl alcohol and essential oils on inhibiting the growth of microorganisms enhances the preservation effect of various foods.
本発明の詳細な説明すれば、保存しようとする食品に応
じて選択された担体、または小袋にエチルアルコールお
よび精油等の混合物を担持または充填し、該食品が収納
された包装容器中にエチルアルコールおよび精油等が液
状で、直接食品に接触しないように配置し、包装容器を
封止してなる食品の保存方法である。To explain the present invention in detail, a carrier or a sachet selected according to the food to be preserved is supported or filled with a mixture of ethyl alcohol and essential oil, and the ethyl alcohol is placed in a packaging container containing the food. This is a food preservation method in which essential oils and the like are placed in liquid form so as not to come into direct contact with the food, and the packaging container is sealed.
担体としては、該混合物が容易に浸透、吸着により担持
される物質、具体的には、紙、不織布やゼオライト、二
酸化ケイ素、ケイ酸アルミニウム、メルク、殿粉、砂糖
、食塩等の粉末等、種々の物質が用いられるが食品衛生
上無害なものが好ましく′1゜
また小袋としては、該混合物が液状で容易に流出せず、
かつ小袋を通して混合物の各成分が徐々に蒸散する材質
構成の包装材料が適当であり具体的には、ポリエチレン
またはポリプロレレン製微多孔シートや、紙、有孔ポリ
エチレン等からなる& 層材料や、ポリビニルアルコー
ル、エチレン−酢酸ビニル共重合体、三酢酸セルロース
等の単体フィルムあるいはこれらの複合材料からなる。Examples of carriers include materials that allow the mixture to easily permeate and be supported by adsorption, such as paper, nonwoven fabric, zeolite, silicon dioxide, aluminum silicate, Merck powder, starch, sugar, salt, and other powders. The following substances are used, but those that are harmless from a food hygiene perspective are preferred.
In addition, packaging materials with a material composition that allows each component of the mixture to gradually evaporate through the pouch are suitable, and specifically, microporous sheets made of polyethylene or polyprorelene, paper, layered materials made of perforated polyethylene, etc., and polyvinyl alcohol. , ethylene-vinyl acetate copolymer, cellulose triacetate, etc., or a composite material thereof.
本発明でいうエチルアルコールとは、エチルアルコール
およびエチルアルコール水溶液中のエチルアルコール成
分を意味し、また、精油等とは、植物の枝葉、根茎、木
皮果実、つぼみ、樹脂等から蒸留、圧搾、抽出等の方法
で得た天然物または該天然物の主成分、あるいは該成分
の化学的合成物であり、精油、精油成分香辛料、香摩料
成分、・香料等である。In the present invention, ethyl alcohol refers to ethyl alcohol and the ethyl alcohol component in an aqueous ethyl alcohol solution, and essential oils are distilled, pressed, extracted from plant branches and leaves, rhizomes, bark fruits, buds, resins, etc. It is a natural product obtained by a method such as the above, or the main component of the natural product, or a chemical composition of the component, such as essential oil, essential oil component spice, fragrance component, fragrance, etc.
具体的にはローズマリー油、シン油、クローブ、タイム
、アリル辛子油等があるが、中でもアリル辛子油(イソ
チアン酸アリルCH2−CHCH2NC8)およびシリ
油は効果が高い。Specifically, there are rosemary oil, coconut oil, clove, thyme, allyl mustard oil, etc. Among them, allyl mustard oil (allyl isothioanate CH2-CHCH2NC8) and silica oil are highly effective.
本発明においてエチルアルコールと精油等との混合物蒸
気が吸着物質または小袋より、徐々に放出され、包装容
器中に拡散することにより、食品表面を覆い、食品の種
類によっては食品内部にまで浸透する。該混合物蒸気の
殺菌な(化は静菌作用により食品の微生物の増殖を抑止
し、食品の賞味期間の延長や黴の防止をするととができ
るものである。In the present invention, the vapor of a mixture of ethyl alcohol, essential oil, etc. is gradually released from the adsorbent or the pouch and diffuses into the packaging container, thereby covering the surface of the food and, depending on the type of food, penetrating into the interior of the food. The sterilization of the vapor mixture inhibits the growth of microorganisms in foods due to its bacteriostatic action, thereby extending the shelf life of foods and preventing mold.
エチルアルコールまたは精油それぞれの微生物抑制効果
は既に知られており、精油、特にアIJ )し辛子油の
ダラム陰性菌に対する優れた効果はよく知られるところ
である。The microbial inhibitory effects of ethyl alcohol and essential oils are already known, and the excellent effects of essential oils, especially AJ) and mustard oil against Durham-negative bacteria, are well known.
本発明により、エチルアルコールおよび精油混合物蒸気
を包装系内に拡散させろことにより、エチルアルコール
のみ、または精油のみの使用よりも、食品の風味、臭い
、テクスチャーなどに与える影響が少なく、かつ高い保
存効果が得られろ。By diffusing the ethyl alcohol and essential oil mixture vapor into the packaging system, the present invention has less influence on the flavor, odor, texture, etc. of food and has a higher preservation effect than using only ethyl alcohol or only essential oil. You can get it.
本発明により長期保存可能な食品は、ノくン、スポンジ
ケーキ、カステラ、和菓子等の加工食品、魚肉加工品、
獣肉加工品、穀類、野菜等極めて多(の腐敗性食品に適
用可能である。Foods that can be stored for a long time according to the present invention include processed foods such as nokun, sponge cake, castella, and Japanese sweets, processed fish products,
It can be applied to an extremely large number of perishable foods such as processed meat products, grains, and vegetables.
本発明における包装容器の封止は、一般的な熱圧着法や
、結束法等の一般的封正方法が利用でき、熱圧着により
完全密封を行なう場合は、炭酸ガス、窒素ガス等のガス
充填包装や真空包装または脱酸素剤や鮮度保持剤との併
用包装が可能であり、相乗効果をあげることができる。For sealing the packaging container in the present invention, general sealing methods such as a general thermocompression bonding method and a binding method can be used. When complete sealing is performed by thermocompression bonding, gas filling such as carbon dioxide gas or nitrogen gas can be used. Packaging, vacuum packaging, or combined packaging with oxygen absorbers and freshness-preserving agents is possible, and a synergistic effect can be achieved.
このように本発明では完全密封が好ましいが必ずしも完
全密封されている必要はなく、逸散した混合蒸気はさら
に吸着体または小袋より放散され、包装内には一定濃度
以上の混合蒸気を有する雰囲気が保てる。In this way, in the present invention, complete sealing is preferred, but it is not necessarily necessary to be completely sealed, and the escaping mixed vapor is further dissipated from the adsorbent or the pouch, and an atmosphere containing the mixed vapor above a certain concentration is created within the package. I can keep it.
また、食品自体の水素イオン濃度(p H) や水分
活性をあらかじめ調整することによりさらに優れた効果
が得られる。Moreover, even better effects can be obtained by adjusting the hydrogen ion concentration (pH) and water activity of the food itself in advance.
次に実施例により本発明の詳細な説明する。Next, the present invention will be explained in detail with reference to Examples.
〈実施例1〉
グリセリンにより水分活性を090に調整したポテトデ
キストロース寒天培地に、水分活性0.90の食品より
分離した酵母6株を植菌したものと表−1のテスト区の
薬剤を5 y、 7 cmの口紙(東洋力紙・届2)に
担持させた担体とを該培地609に接触しないよう、ポ
リプロピレンおよびポリエチレンからなる積層フィルム
中に配置密封し、25°Cにて保存し該培地上の酵母集
落発生状況、の肉眼観察および包装袋内気体の臭気の官
能検査を経時的に行なったところ表−2の結果を得た。<Example 1> A potato dextrose agar medium whose water activity was adjusted to 0.90 with glycerin was inoculated with 6 strains of yeast isolated from foods with a water activity of 0.90, and 5 y of the drug from the test group shown in Table 1 was inoculated. The carrier supported on a 7 cm paper (Toyo Rikishi, Notification 2) was placed and sealed in a laminated film made of polypropylene and polyethylene so as not to come into contact with the culture medium 609, and stored at 25°C. Visual observation of the occurrence of yeast colonies on the culture medium and sensory test of the odor of the gas inside the packaging bag were conducted over time, and the results shown in Table 2 were obtained.
表1 テスト区
表2 結果
A:肉眼により集落観察
m:はとんど認められないか1株のみ
+:2株以上が容易に認められる
什:著しく増殖
世:特に著しく増殖
B:官能検査による臭気
○:微弱なアルコール臭のみ
×:強いアルコール臭および/またはアリル辛子油臭△
:微弱なアリル辛子油臭
〔備考〕
エチルアルコールは、試薬1級を用い、アリル辛子油は
高砂香料製マスタードオイルに−7811を用いた。ま
た、両者の混合物はあらかじめ混合し7た後に、2紙に
担持させた。Table 1 Test area Table 2 Results A: Observation of colonies with the naked eye M: Hardly observed or only one plant +: Two or more plants are easily observed T: Significant growth: Particularly significant growth B: Sensory test Odor ○: Only weak alcohol odor ×: Strong alcohol odor and/or allyl mustard oil odor △
: Weak allyl mustard oil odor [Note] For ethyl alcohol, a first class reagent was used, and for allyl mustard oil, mustard oil -7811 manufactured by Takasago Co., Ltd. was used. Moreover, both mixtures were mixed in advance and then supported on two pieces of paper.
表−2から明らかなように本発明のエチルアルコールお
よびアリル辛子油混合物を使用した区である1および2
は、エチルアルコールのみ使用した区に比べ、少量のエ
チルアルコールであっても多量のエチルアルコールを用
いた場合と同等の酵母の増殖抑制効果があり、臭気も少
ない。またアリル辛子油のみを使用した区に比べても、
臭気が少なく、かつ優れた効果が認められた。As is clear from Table 2, areas 1 and 2 using the ethyl alcohol and allyl mustard oil mixture of the present invention
Compared to the group using only ethyl alcohol, even a small amount of ethyl alcohol has the same effect on yeast growth as using a large amount of ethyl alcohol, and has less odor. Also, compared to the area using only allyl mustard oil,
Low odor and excellent effects were observed.
〈実施例2〉
エチルアルコール100部とアリル辛子油01部の混合
物中にシリカゲルを浸漬し、′2D分後に取り出し、そ
の2gを厚さ10μのポリエチレン薄膜で覆い、魚肉ね
り製品(市販かまぼと)100gとともにポリエチレン
製シール容器内に配置し、蓋をした後、25°C恒温室
内に保存したところ、内容の魚肉ねり製品は、5日間変
化がなかったのに対し、対照の該浸透シリカゲルを使用
しない魚肉ねり製品は25日後て不快臭を生じた。<Example 2> Silica gel was immersed in a mixture of 100 parts of ethyl alcohol and 0.1 part of allyl mustard oil, taken out after 2D minutes, and 2g of it was covered with a 10 μm thick polyethylene film to form a fish paste product (commercially available kamabo and kamabo). ) was placed in a sealed polyethylene container with 100 g, covered with a lid, and stored in a constant temperature room at 25°C. The contents of the fish paste product remained unchanged for 5 days, whereas the permeated silica gel as a control did not change. The unused fish paste product developed an unpleasant odor after 25 days.
また、エチルアルコールのろ、に浸漬したシリカゲルを
同様にして使用した場合は3日後に不快臭を感じた。Furthermore, when silica gel soaked in ethyl alcohol was used in the same manner, an unpleasant odor was felt after 3 days.
〈実施例6〉
食塩を10%添加により水分活性を調整したポテトデキ
ストロース寒天培地を大気中K 1.5時間暴路した後
、そのシャーレの蓋を閉じ、下記テスト区薬剤をいれた
通気度約i oooo秒/ 1o 。<Example 6> Potato dextrose agar medium whose water activity was adjusted by adding 10% salt was exposed to air K for 1.5 hours, the lid of the petri dish was closed, and the following test chemicals were added to the air permeability: ioooo seconds/1o.
mlの上質紙および有孔ポリエチレンから成る袋ととも
に、塩化ビニリチンをコートしたポリプロピレンフィル
ム(20μ)とポリエチレンフィルム(60μ)とから
なる包装袋にそれぞれ寒天培地と共に密封した。ml of high-quality paper and a bag made of perforated polyethylene, and the agar medium was sealed in a packaging bag made of polypropylene film (20μ) and polyethylene film (60μ) coated with vinylitin chloride.
表6 テスト区
シソ油ニシンのエーテル抽出液
包装袋の外部より肉眼観察により、空中落下真菌の発育
状況を観察したところ、薬剤を添加しない対照区(11
)では、真菌、%□にカビのコロニーが多く生じたのに
対し、シソ油とエチルアルコール用いた本発明のテスト
区(8)では、真菌のコロニーは生じないか、生じても
数個であり、コロニーの生育度合も弱いものであった。Table 6 Test group Perilla oil herring ether extract The growth status of airborne fungi was visually observed from the outside of the packaging bag, and the control group (11
), many mold colonies were formed in the fungus and %□, whereas in the test group (8) of the present invention using perilla oil and ethyl alcohol, no or only a few fungal colonies formed. The colony growth rate was also weak.
また、シソ油の水懸濁液を用いたテスト区00)では対
照区とほぼ同程度の多くのコロニーが発育した。エチル
アルコールのみを用いたテスト区(9)て゛はテスト区
(10)に比ベコロニー数はやや少なかったが、本発明
のテスト区(8)よりも多く、生育度合も旺盛であった
。Furthermore, in the test plot 00) using a water suspension of perilla oil, approximately the same number of colonies grew as in the control plot. Although the number of colonies in the test plot (9) using only ethyl alcohol was slightly lower than that in the test plot (10), it was larger than in the test plot (8) of the present invention, and the growth rate was also vigorous.
以上のように空中落下真菌に対し、シソ油およびエチル
アルコールの併用による増殖抑制効果が認められた。As described above, the combination of perilla oil and ethyl alcohol was found to have an inhibitory effect on the growth of airborne fungi.
特許出願人 凸版印制株式会社patent applicant Toppan Printing Co., Ltd.
Claims (3)
香辛料あるいは香辛料成分との混合物担持させた担体を
直接食品と接触することなく食品と共に非通気性材料で
密封包装してなる食品の保存力法。(1) A food preservative method in which a carrier carrying a mixture of ethyl alcohol and essential oil or essential oil components, spices, or spice components is sealed and packaged together with the food in an air-impermeable material without direct contact with the food.
ル辛子油を主成分とする精油あるいはアリル辛子油であ
る特許請求の範囲第1項記載の食品の保存方法。(2) The method for preserving food according to claim 1, wherein the mixture supported on the carrier is an essential oil or allyl mustard oil whose main components are ethyl alcohol and allyl mustard oil.
油を主成分とする精油あるいはシソ油である特許請求の
範囲第1項記載の食品の保存方法。(3) The method for preserving food according to claim 1, wherein the mixture supported on the carrier is an essential oil or perilla oil whose main components are ethyl alcohol and perilla oil.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP767083A JPS59132876A (en) | 1983-01-20 | 1983-01-20 | Preservation of food |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP767083A JPS59132876A (en) | 1983-01-20 | 1983-01-20 | Preservation of food |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS59132876A true JPS59132876A (en) | 1984-07-31 |
Family
ID=11672231
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP767083A Pending JPS59132876A (en) | 1983-01-20 | 1983-01-20 | Preservation of food |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59132876A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003028451A2 (en) * | 2001-10-04 | 2003-04-10 | State Of Israel, Ministry Of Agriculture, Volcani Center | Microbiocidal formulation comprising essential oils or their derivatives |
WO2006006745A1 (en) * | 2004-07-08 | 2006-01-19 | Mi-Young Hwang | Commodity freshness preserving composition by using natural extract |
WO2008149232A2 (en) * | 2007-06-06 | 2008-12-11 | Post Harvest Solutions Limited | Active materials incorporating micro-porous solids and essential oils |
-
1983
- 1983-01-20 JP JP767083A patent/JPS59132876A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003028451A2 (en) * | 2001-10-04 | 2003-04-10 | State Of Israel, Ministry Of Agriculture, Volcani Center | Microbiocidal formulation comprising essential oils or their derivatives |
WO2003028451A3 (en) * | 2001-10-04 | 2004-03-18 | Israel State | Microbiocidal formulation comprising essential oils or their derivatives |
US7465469B2 (en) | 2001-10-04 | 2008-12-16 | State Of Israel, Ministry Of Agriculture & Rural Development Agricultural Research Organization, The Volcani Center | Microbiocidal formulation comprising essentials oils or their derivatives |
WO2006006745A1 (en) * | 2004-07-08 | 2006-01-19 | Mi-Young Hwang | Commodity freshness preserving composition by using natural extract |
WO2008149232A2 (en) * | 2007-06-06 | 2008-12-11 | Post Harvest Solutions Limited | Active materials incorporating micro-porous solids and essential oils |
WO2008149232A3 (en) * | 2007-06-06 | 2009-01-29 | Post Harvest Solutions Ltd | Active materials incorporating micro-porous solids and essential oils |
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