JPS59120639A - Rubber composition - Google Patents

Rubber composition

Info

Publication number
JPS59120639A
JPS59120639A JP22713282A JP22713282A JPS59120639A JP S59120639 A JPS59120639 A JP S59120639A JP 22713282 A JP22713282 A JP 22713282A JP 22713282 A JP22713282 A JP 22713282A JP S59120639 A JPS59120639 A JP S59120639A
Authority
JP
Japan
Prior art keywords
vulcanization
carbon black
rubber composition
rubber
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22713282A
Other languages
Japanese (ja)
Inventor
Yoshitaka Udagawa
好隆 宇田川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yokohama Rubber Co Ltd
Original Assignee
Yokohama Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yokohama Rubber Co Ltd filed Critical Yokohama Rubber Co Ltd
Priority to JP22713282A priority Critical patent/JPS59120639A/en
Publication of JPS59120639A publication Critical patent/JPS59120639A/en
Pending legal-status Critical Current

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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

PURPOSE:A low-rolling resistance tire rubber composition of a markedly lowered loss tangent having a high vulcanization rate and, shows a high hardness and a high modulus after vulcanization, prepared by compounding a stock rubber with a specified amount of CS2. CONSTITUTION:Carbon black containing absorbed CS2 is prepared by adding under agitation 1-10pts.wt. CS2 in which a vulcanizing agent (e.g., S) in an amount to be added per 100pts.wt. stock rubber is dissolved to 50pts.wt. carbon black. A stock rubber is compounded with the above-produced carbon black, an antioxidant, an extender oil, a vulcanization aid, etc., and the mixture is mixed in a paint mill, and heat-treated under the same conditions of temperature and time as those for vulcanization.

Description

【発明の詳細な説明】 本発明【5Lコjム絹成物に関し、詳しくは原オ′」ゴ
ムに一用売化Ijl崇を特定量重含りることによって、
加硫を速め、かつ加硫後の硬度、モジ」、ラスを向上さ
UるとJ(にI11失正接(+’allδ)を11℃下
させたゴム組成物に関づる。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the 5L comb silk composition, specifically, by heavily containing a specific amount of 5L comb silk in raw comb silk,
The present invention relates to a rubber composition that accelerates vulcanization and improves hardness, modulus, and lath after vulcanization, and lowers I11 loss tangent (+'all δ) by 11°C.

従来のゴム組成物にJ9いて、原着ゴl\に直1i二硫
化炭指を配合しlこ例はな(、ゴム組成物を加l111
[りる際1(−、:11: M+化炭素を発生づる1−
リヂオカ□−ボネ=1〜Jiステル写の化合j勿を配合
する、例え1′J:特り7n昭47−’I 2850月
等の例があるのみである。
In this example, a conventional rubber composition is mixed with J9 disulfide carbon, and a rubber composition is added directly to the undyed rubber.
[1(-, :11: 1- to generate M+ carbon)
There are only examples such as 1'J: Particularly 7n 1973-'I 2850 month, which incorporates the combination of Rijioka□-Bone=1~Ji stealth copy.

このような加橘中に二硫化炭素を発生−4名化合物を配
合した゛ゴム組成物におし′XCは、化合物の配合によ
ン(加硫後の硬度、モジ−lラスか向11]たり」al
l  δが低下するというようなこと(,1,生じなか
つ lこ 。
Carbon disulfide is generated in the vulcanized orange. ] Tari'al
Something like l δ decreases (,1, does not occur and l this).

本発明は加岡速痕が速く、加硫後に高硬度、高モジ1.
ラスを有しかつ損失正接(FITδ)を大幅に11(下
させたゴム組成物を1T供りることを[I的とし、特に
叡転勤抵抗タイへ・用に利用される。
The present invention has fast Kaoka markings, high hardness and high modulus after vulcanization.
It is desirable to provide 1T of a rubber composition having a lath and a loss tangent (FIT δ) significantly lower than 11, and is particularly used for transfer resistance ties.

本発明のこの目的はゴム組成物に特定量の二硫化炭素を
配合することに、上って達成される。
This object of the present invention is achieved in particular by incorporating a specific amount of carbon disulfide into the rubber composition.

すなわら本発明は原料ゴl\100重早部に幻しU 、
rq−硫化炭素を1へ・16*邑部配香したことを特1
放とづるゴム組成物にある。
In other words, the present invention is based on the raw material concentration of 100 parts.
rq-carbon sulfide to 1/16*Obube special feature 1
It is in a rubber composition that releases.

本発明にJ9”いて配合される二硫化炭素は原オ゛ヨ1
ゴム100重i部に対して1・〜′10東吊部である。
The carbon disulfide compounded in the present invention is
It is 1.~'10 east hanging part for 100 weight i parts of rubber.

二硫化炭素の配合量が11吊部未満Cは、配合効果が(
Jどんどなく加硫後に高硬度、11”♂1ジ1ラス □
や tall  5の□大幅な低F′は期□待できず、
・一方10重早部を越えて配合してもそれほどの配合効
果は1じない。     □ 本発明においC1原IIIゴムに二1流化炭素を配合じ
 (小1 合 r3’  yf、)1J 4人 と (
7(は 以 1・ に ;)’<  (j−IJij 
 合 lJ’  ?人”Jかある。。
When the blending amount of carbon disulfide is less than 11 parts, the blending effect is (
J High hardness after vulcanization, 11”♂1ji1rus □
□Significantly low F′ of □ tall 5 cannot be expected.
-On the other hand, even if more than 10 parts are blended, the blending effect will not be that great. □ In the present invention, C1 raw III rubber is blended with carbon 21 fluid (1st grade r3' yf,) 1J 4 people and (
7 (hereinafter 1. ;)'< (j-IJij
Combined lJ'? There's a person called J.

ン昆 菖 1’j i人 (I ) taxi fL r、す素・6 )ノ、411代物の配
合剤であるカーホシノノツ′ノ(ニ)段イ゛jさせる1
53人(−d9す、麿1木的(こ11[・記(、lj:
 jl f〕)人1..X、上−)で41さl′iろ。
1'j i person (I) taxi fL r, Sono 6), 411th grade combination agent, carhoshinonotsu'no(2) step 1
53 people (-d9su, Maro 1 tree (ko11 [・ki (, lj:
jl f]) person 1. .. X, top -) and 41 l'iro.

IA) ノ、+−ホンノンッノノj〕0申早部をvf器
(、二と番〕、(二」ロー1頓11−1ムl 00中早
部1.lりij l)(配合【Jへき早の加Iiに1i
il(イ、1つ)を溶か(、た−(IにiWt、に素1
0小ii1部’a1+11 ;li、 li71丁!f
ii合りる。次(、:このン昆合1カを1吸引乾ナヘQ
l−r余′Jンのニー屋1化1、に素を除去し、1[(
,1化り多J崇44所定q)配合11)と1する。、(
2)バー小シーツ)・y′lbOΦ;一部を容器(lど
り、c  IL  1.−’Q  11  ’−11x
  1 0  ()  申’l’、’  部1、−、、
  RJ  Lノー’−(配Q  ”I)\N所定ri
jの加!+:(i i’i’l ((Aつ)を加λ撹拌
況合−はる1、次に、+、I ’((’6.− 、’、
’i’、 r!a化j、jJ木溶液が存右−りる容器中
(こ19]又しill;閉じC夕f:Xt化炭72 /
、、配、Qすl\さli w> I+! 、Li2る。
IA) ノ, +-honnon-no-no j] 0 Mon early part vf device (, 2 and number), (2' low 1 ton 11-1 ml 00 middle early part 1.l ij l) (combination [to J Haya no Ka Ii to 1i
Melt il (I, 1) (, ta-(iWt in I, 1 element in I)
0 small ii 1 part'a1+11; li, li71 ton! f
ii fits. Next (,: 1 suction of 1 kongo)
l-r Yu'Jn's knee shop 1 conversion 1, remove the element to 1 [(
, 1 Converter J Takashi 44 Predetermined q) Combination 11) and 1. ,(
2) Bar small sheet)・y'lbOΦ; Part of it is a container (l, c IL 1.-'Q 11'-11x
1 0 () shin'l',' part 1, -,,
RJ L No'-(Distribution Q "I)\N specified ri
J's addition! +:(i i'i'l ((A) added λ stirring condition - Haru 1, then +, I'(('6.- ,',
'i', r! A, jJ wood solution is present in the container (this 19) and ill; closed C: Xt carbonized charcoal 72 /
,,Ai, Qsl\Sali w> I+! , Li2ru.

この3J、)(5伺1 fL iグ木4吸1■シた)J
−・j(ンf−)ッノノを171’l −’l izに
配合−4る。
This 3J,) (5 visit 1 fL igu tree 4 suck 1■shita) J
-・j(nf-)ccnono is blended into 171'l-'liz-4.

< rfN a 1ノ法 II  ) 1〔[オニに丁)8、カー小シブラ・ツク、1叫す爪ハ
リ4(;♀い!、二((!!の配合剤を独\゛!(こ已
合し熱墾1’l! Fiイ)1.(\二でいう他の配合
剤と(−1,酸化i1j j4j、ス−i’ 7”、、
Jン酌、老化防止剤、仲1g曲、Jll’l Miii
)り等をいう。これらのNL Q t’l’l ” 所
定’、) 配r> m + ill j;’HLJ、次
(−0−1Iヲヘイン1−ミルを用い7]混合しC1す
、1j[1舗条(′1と同1.調川、+1”I 1ij
l Cり、:′!惜埋りる。
< rfN a 1 method II) 1 1. (with other compounding agents referred to in \2) (-1, oxidation i1j j4j, su-i'7",,
J'un, Anti-aging agent, Naka 1g song, Jll'l Miii
)ri etc. These NL Q t'l'l ``predetermined',) Arrangement r> m + ill j;'HLJ, then (7 using -0-1I washin 1-mil) mix C1, 1j [1 column ( Same as '1 1. Togawa, +1"I 1ij
lCri, :'! I regret it.

イ(ブf ljf’lυ(ψ用する原料−fノ、(61
特に1111限がイしく、pilバー(5E人′(1:
 jノ\\ゝ)ボリノタシ[ン1)\、ポリrソノ゛ 
し′ ニア  −f  l、 、  ス f しノ ン
 −ブ ′J シ  1 ン ](重 合 1本  f
 )1.1、たけ、:L4IC−)σ目昆合物簀のシ■
ン糸[ムか々f)内(に1・力用される、。
(61
The 1111 limit is especially good, and the pil bar (5E people' (1:
\\\ゝ)borinotashi[n1)\, polyrsono゛
[1] (Polymerization 1 line f
) 1.1, Take, :L4IC-) σ-order insect cage ■
The thread is used within the thread.

まI、二、本光明の−fl\絹成物(こあ−)−(は、
前記した二賄Its吹んl= IIuえて通1A)ゴム
組成1カ(ご配合さ1えるカー小ンf−)・・I′、)
、醇化叶11)、−47う′リン酸、11+ 17ご油
、と、化p/ノ11削、(j(1碕促進^(1、(」パ
ノ等σ)自11合剤か適宜J fl!配合される。7 1゛4十、実施例43よび比較例(51阜−5ε〜本ず
i: liIfを1,11体的(5二il!l!’!I
しJる1、なお、第1表中の配合数的は(jl\l J
il i;’1部ζ(0イ)、。
I, 2, Honkomyo's -fl\silk product (koa-) - (ha,
The above-mentioned two parts are blown l = II u ettsu 1A) Rubber composition 1 part (mixture 1 car small f-)...I',)
, -47 U' phosphoric acid, 11 + 17 sesame oil, and chemical p/no 11 reduction, (j (1 碕 promotion ^ (1, (''Pano etc. σ) self 11 mixture or J as appropriate fl! is blended. 7 1゛40, Example 43 and Comparative Example (51㎜-5ε~honzu i: liIf is 1,11 body (52il!l!'!I
In addition, the number of combinations in Table 1 is (jl\l J
il i;'1 part ζ (0i),.

yHII虻1jylj−j −−4咥↓t−1’lj較
Jしし二二第1(l〈に小−!J配合(−1ム絹成物を
調製し!51.こ0) −i l、Ill成物の調t%
jグJ >A L;L、比較M i 、 3 a’r 
J: 0!”i −−−/’ 1.Li山7’jのil
P Dノ))人、^I−イ1わら、1紅j V”l−i
ムと配合i’ill (1lll i1/li f′j
す6.除く)をハンハリーミ1リ−C3)5)間混合i
す、IJ(1硫剤’= Jilt 、i (2分[11
し尺八(,7、さ’31ご11−1しく゛ン1を白り・
テ)、二ど(5,1、すijjlい、比中21(す2d
31−び/′4は前記(−5/ご1昆合方法■を用いて
1.卯?”11゛ ]、と 、 べ r シ 1− ミ
 几7 C)[ル 合 と(1鴇 1甲 し、5 〕、
二 西e 会 凸り をハシI\1J−ミl 1−1′
、:lブ)間ン昆合し5、カー小シフノ・y′ノ、11
11 ’Ai i’i!I A−、’li1え(2分間
混合し、さらに[i−ル・ 、F昌Th  ii  <
:l  L、  u  t、E  、J、 リ b  
な −) だ 。  ま jこ 、  ゛ノ、h色 I
も111.13上(>S)は、前記り、、、 /、混合
/)f人I4−用い(原(81−Il、、ど配合剤(]
]J−小シl−ノック1111 ilA剤、二線ftl
 i、’iζ:、メi1土’、 ) ”: !\ンハリ
ーミキリー C3分間!(〜合 1,2  、  カ 
− ホ シ・  ) ノ ・・I  ′ノ 、  l1
il  5%t  剤 、   −−1iii  jヒ
 kリ 累 をIl(1λ (? ブン 間)1コ  
合 し−1、il I−)(ご 11−− ル Cン昆
 ご リ る (−1、l:−二、、、J、す、1ム絹
成物4調シ1し7k。1さらに、実廁19’l  2 
 お 上 (す 11(よ !I I:  含 ノ°ノ
 )人 [お 、J、1す li  を 引 合 4つ
 [県 C、原寸)置j’ lxど、ベイシトミル(−
混合熱I7j、j +11. L配合〜1をバンハリー
−ミ%−jl−−(’ 3分間j[シ合じ、ツノ−・1
(ツノラック、1j11随剤、ニー硫化rap号r ’
01111え(:2ブ)間Ifi a L、c ラI9
1 t−t  I’v C混r’r 4 ;i> コ+
’ tJ J、0.11Xキ[1成物を調製しlご。
yHII 1jylj-j --4 mouth↓t-1'lj comparison J Shishi 22 1st (l〈small-!J combination (-1 mu silk composition prepared!51.ko0) -i I, Ill composition preparation t%
j gu J > A L; L, comparison M i , 3 a'r
J: 0! "i ---/' 1. il of Li mountain 7'j
P Dノ))人, ^I-i 1 straw, 1 red j V”l-i
Combined with mu and i'ill (1llll i1/li f'j
6. (except for), mixed between Hanharimi1li-C3)5) i
S, IJ (1 sulfur agent' = Jilt, i (2 minutes [11
Shakuhachi
te), 2nd (5,1, sijjl, hichu 21(s2d)
31-bi/'4 is the above (-5/go1 combination method ■) 1. rabbit?"11゛], and be rshi 1-mi 几7C) A, 5],
2 West e meeting convexity Hashi I\1J-mil 1-1'
, :lbu) between kongoshi 5, car small shift no y'no, 11
11 'Ai i'i! I A-, 'li1e (mix for 2 minutes, then [i-le, F-Cho Th ii <
:l L, ut, E, J, Ri b
Na-). Ma jko, ゛ノ, h color I
111.13 Above (>S) is as above, /, Mixed /)
] J-Small-Knock 1111 ILA agent, two-line FTL
i, 'iζ:, May i1 Sat', ) ”: !\n Harry Mikili C3 minutes!
- Hoshi・)ノ・・I′ノ、l1
Il 5%t agent, --1iii jhikli cumulative Il (1λ (?bun interval) 1 piece)
Combined -1,il I-) , Actual 19'l 2
11 people (including ノ°ノ) [O, J, 1s li] 4 [Prefecture C, original size] Place j' lx, Basitomil (-
Mixing heat I7j,j +11. L combination ~ 1 Banhari-mi%-jl--(' 3 minutes j [shi combination, horn-1
(Tunorac, 1j11 adjunct, knee sulfide rap No.r'
01111e(:2b) Ifi a L, c La I9
1 t-t I'v C mixed r'r 4 ;i> Ko+
'tJJ, 0.11X [1] Prepare the product.

この、1、−)(二L(i:’;らIIたf Is @
lliカをl A 51:、1−ルク 5)巳)(・l
 9!+ ) IJ−、にでる5口、−q) 1.’1
間カミ1(1全し、(−1111] IIQ L2/ご
際のIll l硫速匪、11【ひL−1ill M、冒
イ沖ハ、川 S(l1il島、 [ジー1−) スおよ
び t a II”  δを1llll定1−(N、、
+、 T 4第 1 表 (ご 、7’<  −tl 
 、  %  お 、 J、リ ii:  3  ン入
 は F  IF−、r  の 1山 ’−,)  ”
(、’  il’+ろ。
This, 1, -) (2L(i:'; et IIta f Is @
llika wo l A 51:, 1-luku 5) Sn) (・l
9! +) IJ-, 5 mouths to appear, -q) 1. '1
Interval 1 (1 complete, (-1111) IIQ L2/Ill 1 sulfur speed, 11 [hi L-1ill M, attack off the coast, river S (l1il island, [G1-) Su and t a II” δ is 1lllll constant 1-(N,,
+, T 4 Table 1 (Go, 7'< -tl
, % O, J, Lin ii: 3 lin is 1 pile of F IF-, r '-,)''
(, 'il' + ro.

すII  1tli  il  l:’ゴ σ)、叫 
定 は し・ 」  メ −′ノ −(、’  Wt 
 )\ j−ル ′ノ のIl) !50゜、のトル′
ノに達−4るま℃の口1間(+9.’i)(分)で 訂
′ (曲 15 k 、1  。L  l、−1)II
  Ml  lリ の 、11リ 定 (よ 、  :
’−1’  l−z  ?I目戊 1勾をシ・−1・1
人とL、1iii記のく二と(Ill碕じで、ZS  
J<r ’Jンヘ/し411+z i! li史@ ?
r 3111 ’ig シ/、二、、 tl、L 5 
C) 冑)、100%、20096.300OR14C
)096の各しシ!’、/ ス1JIVI jy ”C
1,i J IS −K −630’l M ’S’ 
lk’jして測定を(+イτつた。さらIJ、  t 
a II  δt、t 20 ’CとG O”Cの測定
子(1(行4「)/こ。
sII 1tli il l:'go σ), shout
Determined Hashi・"Me -'ノ-(,' Wt
) Tor' of 50°
Reached -4 degrees Celsius in 1 minute (+9.'i) (minutes) (Tune 15 k, 1. L l, -1) II
Mlli's, 11li fixed (Yo,:
'-1' l-z? I eye 1 degree shi-1・1
Man and L, 1iii.
J<r 'Jnhe/shi411+z i! li history @ ?
r 3111 'ig shi/, two,, tl, L 5
C) helmet), 100%, 20096.300OR14C
) 096 each! ', / s1JIVI jy "C
1,i J IS -K -630'l M 'S'
lk'j and measure (+Iτt. Also IJ, t
a II δt, t 20 'C and G O''C measuring element (1 (row 4'')/ko.

第1イ1ミに7I々されることく、二硫化炭素を配合し
!、:実流1!l!l i −=−/Iは二硫化炭素を
未配合の比較例1・・・−4に比較()4、加lii!
1時間が短り、1空度おJ、びモジlラスが向」、!J
るど」(に 【旧1 δが低下しくいるのり(1〕か6
9゜ 比較1!”I !、)・−・7 Ll、 、T」が(化
がJ免供与体eある1〜リヂAカーネオ−1へ上ステル
の配合効果を調べたもの−で゛あるが、1−リ’fAカ
ーボネートコニステルづるにt;Lっで、加硫時間(よ
やや短縮されるものの、1i1 1>( d) 、”、
びLジ1ンスlt 4;E 、!:んど向.にI!f、
−15+an  j51;I高くなっζしまい好ましい
結果はIBgられ4rい,。
Contains carbon disulfide to prevent 7I from being added to the 1st and 1st! , :Actual flow 1! l! l i -=-/I is compared to Comparative Example 1...-4 in which carbon disulfide is not added ()4, addition lii!
1 hour is shortened, 1 hour is shortened, 1 hour is shortened, 1 hour is shortened, and 1 hour is shortened. J
"Nori" (Ni [Old 1 δ is decreasing (1) or 6
9° comparison 1! ``I!,)...7 Ll, , T'' is (an investigation of the effect of blending upper stell with 1-LigiA carneo-1, which has a J donor e), but 1-Li 'fA carbonate conistert; vulcanization time (although it is somewhat shortened, 1i1 1>(d),'',
4;E,! :Ndo direction. niI! f,
−15+an j51; I becomes high ζ and the favorable result is IBg 4r.

以]−説明しlj J、うに、原1′+1ゴl\に特定
早の二硫化炭素を配合しlこ本発明のゴム組成物ト1加
Vli速度が速,−1、す、7111 kMi ’L’
j l!l: 、 ’I−!jに硬麿やモジコラスが向
上し、しかも(all  δが低下することから、高硬
麿の低qゾ1動(1(抗タイX7川として好適に使用さ
れる。
-Explanation: When the rubber composition of the present invention is blended with carbon disulfide at a specific rate, the rubber composition of the present invention has a Vli rate of -1, 7111 kmi. 'L'
j l! l: , 'I-! It is suitable for use as a low qzo 1 movement (1 (anti-tie

Claims (1)

【特許請求の範囲】[Claims] 原:l’l −r l\100 K、n 部品に対t、
 r 二1ift化炭素を1〜101ffi部配合した
ことを特徴どするゴム組成物。
Original: l'l -r l\100 K, n for parts, t,
A rubber composition characterized in that it contains 1 to 101 parts of carbon diift.
JP22713282A 1982-12-27 1982-12-27 Rubber composition Pending JPS59120639A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22713282A JPS59120639A (en) 1982-12-27 1982-12-27 Rubber composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22713282A JPS59120639A (en) 1982-12-27 1982-12-27 Rubber composition

Publications (1)

Publication Number Publication Date
JPS59120639A true JPS59120639A (en) 1984-07-12

Family

ID=16855973

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22713282A Pending JPS59120639A (en) 1982-12-27 1982-12-27 Rubber composition

Country Status (1)

Country Link
JP (1) JPS59120639A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6247512B1 (en) * 1996-09-03 2001-06-19 Michelin Recherche Et Technique S.A. Tire having tread portion with rubber to control wear

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6247512B1 (en) * 1996-09-03 2001-06-19 Michelin Recherche Et Technique S.A. Tire having tread portion with rubber to control wear

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