JPS59120639A - Rubber composition - Google Patents
Rubber compositionInfo
- Publication number
- JPS59120639A JPS59120639A JP22713282A JP22713282A JPS59120639A JP S59120639 A JPS59120639 A JP S59120639A JP 22713282 A JP22713282 A JP 22713282A JP 22713282 A JP22713282 A JP 22713282A JP S59120639 A JPS59120639 A JP S59120639A
- Authority
- JP
- Japan
- Prior art keywords
- vulcanization
- carbon black
- rubber composition
- rubber
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
本発明【5Lコjム絹成物に関し、詳しくは原オ′」ゴ
ムに一用売化Ijl崇を特定量重含りることによって、
加硫を速め、かつ加硫後の硬度、モジ」、ラスを向上さ
UるとJ(にI11失正接(+’allδ)を11℃下
させたゴム組成物に関づる。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the 5L comb silk composition, specifically, by heavily containing a specific amount of 5L comb silk in raw comb silk,
The present invention relates to a rubber composition that accelerates vulcanization and improves hardness, modulus, and lath after vulcanization, and lowers I11 loss tangent (+'all δ) by 11°C.
従来のゴム組成物にJ9いて、原着ゴl\に直1i二硫
化炭指を配合しlこ例はな(、ゴム組成物を加l111
[りる際1(−、:11: M+化炭素を発生づる1−
リヂオカ□−ボネ=1〜Jiステル写の化合j勿を配合
する、例え1′J:特り7n昭47−’I 2850月
等の例があるのみである。In this example, a conventional rubber composition is mixed with J9 disulfide carbon, and a rubber composition is added directly to the undyed rubber.
[1(-, :11: 1- to generate M+ carbon)
There are only examples such as 1'J: Particularly 7n 1973-'I 2850 month, which incorporates the combination of Rijioka□-Bone=1~Ji stealth copy.
このような加橘中に二硫化炭素を発生−4名化合物を配
合した゛ゴム組成物におし′XCは、化合物の配合によ
ン(加硫後の硬度、モジ−lラスか向11]たり」al
l δが低下するというようなこと(,1,生じなか
つ lこ 。Carbon disulfide is generated in the vulcanized orange. ] Tari'al
Something like l δ decreases (,1, does not occur and l this).
本発明は加岡速痕が速く、加硫後に高硬度、高モジ1.
ラスを有しかつ損失正接(FITδ)を大幅に11(下
させたゴム組成物を1T供りることを[I的とし、特に
叡転勤抵抗タイへ・用に利用される。The present invention has fast Kaoka markings, high hardness and high modulus after vulcanization.
It is desirable to provide 1T of a rubber composition having a lath and a loss tangent (FIT δ) significantly lower than 11, and is particularly used for transfer resistance ties.
本発明のこの目的はゴム組成物に特定量の二硫化炭素を
配合することに、上って達成される。This object of the present invention is achieved in particular by incorporating a specific amount of carbon disulfide into the rubber composition.
すなわら本発明は原料ゴl\100重早部に幻しU 、
rq−硫化炭素を1へ・16*邑部配香したことを特1
放とづるゴム組成物にある。In other words, the present invention is based on the raw material concentration of 100 parts.
rq-carbon sulfide to 1/16*Obube special feature 1
It is in a rubber composition that releases.
本発明にJ9”いて配合される二硫化炭素は原オ゛ヨ1
ゴム100重i部に対して1・〜′10東吊部である。The carbon disulfide compounded in the present invention is
It is 1.~'10 east hanging part for 100 weight i parts of rubber.
二硫化炭素の配合量が11吊部未満Cは、配合効果が(
Jどんどなく加硫後に高硬度、11”♂1ジ1ラス □
や tall 5の□大幅な低F′は期□待できず、
・一方10重早部を越えて配合してもそれほどの配合効
果は1じない。 □
本発明においC1原IIIゴムに二1流化炭素を配合じ
(小1 合 r3’ yf、)1J 4人 と (
7(は 以 1・ に ;)’< (j−IJij
合 lJ’ ?人”Jかある。。When the blending amount of carbon disulfide is less than 11 parts, the blending effect is (
J High hardness after vulcanization, 11”♂1ji1rus □
□Significantly low F′ of □ tall 5 cannot be expected.
-On the other hand, even if more than 10 parts are blended, the blending effect will not be that great. □ In the present invention, C1 raw III rubber is blended with carbon 21 fluid (1st grade r3' yf,) 1J 4 people and (
7 (hereinafter 1. ;)'< (j-IJij
Combined lJ'? There's a person called J.
ン昆 菖 1’j i人 (I )
taxi fL r、す素・6 )ノ、411代物の配
合剤であるカーホシノノツ′ノ(ニ)段イ゛jさせる1
53人(−d9す、麿1木的(こ11[・記(、lj:
jl f〕)人1..X、上−)で41さl′iろ。1'j i person (I) taxi fL r, Sono 6), 411th grade combination agent, carhoshinonotsu'no(2) step 1
53 people (-d9su, Maro 1 tree (ko11 [・ki (, lj:
jl f]) person 1. .. X, top -) and 41 l'iro.
IA) ノ、+−ホンノンッノノj〕0申早部をvf器
(、二と番〕、(二」ロー1頓11−1ムl 00中早
部1.lりij l)(配合【Jへき早の加Iiに1i
il(イ、1つ)を溶か(、た−(IにiWt、に素1
0小ii1部’a1+11 ;li、 li71丁!f
ii合りる。次(、:このン昆合1カを1吸引乾ナヘQ
l−r余′Jンのニー屋1化1、に素を除去し、1[(
,1化り多J崇44所定q)配合11)と1する。、(
2)バー小シーツ)・y′lbOΦ;一部を容器(lど
り、c IL 1.−’Q 11 ’−11x
1 0 () 申’l’、’ 部1、−、、
RJ Lノー’−(配Q ”I)\N所定ri
jの加!+:(i i’i’l ((Aつ)を加λ撹拌
況合−はる1、次に、+、I ’((’6.− 、’、
’i’、 r!a化j、jJ木溶液が存右−りる容器中
(こ19]又しill;閉じC夕f:Xt化炭72 /
、、配、Qすl\さli w> I+! 、Li2る。IA) ノ, +-honnon-no-no j] 0 Mon early part vf device (, 2 and number), (2' low 1 ton 11-1 ml 00 middle early part 1.l ij l) (combination [to J Haya no Ka Ii to 1i
Melt il (I, 1) (, ta-(iWt in I, 1 element in I)
0 small ii 1 part'a1+11; li, li71 ton! f
ii fits. Next (,: 1 suction of 1 kongo)
l-r Yu'Jn's knee shop 1 conversion 1, remove the element to 1 [(
, 1 Converter J Takashi 44 Predetermined q) Combination 11) and 1. ,(
2) Bar small sheet)・y'lbOΦ; Part of it is a container (l, c IL 1.-'Q 11'-11x
1 0 () shin'l',' part 1, -,,
RJ L No'-(Distribution Q "I)\N specified ri
J's addition! +:(i i'i'l ((A) added λ stirring condition - Haru 1, then +, I'(('6.- ,',
'i', r! A, jJ wood solution is present in the container (this 19) and ill; closed C: Xt carbonized charcoal 72 /
,,Ai, Qsl\Sali w> I+! , Li2ru.
この3J、)(5伺1 fL iグ木4吸1■シた)J
−・j(ンf−)ッノノを171’l −’l izに
配合−4る。This 3J,) (5 visit 1 fL igu tree 4 suck 1■shita) J
-・j(nf-)ccnono is blended into 171'l-'liz-4.
< rfN a 1ノ法 II )
1〔[オニに丁)8、カー小シブラ・ツク、1叫す爪ハ
リ4(;♀い!、二((!!の配合剤を独\゛!(こ已
合し熱墾1’l! Fiイ)1.(\二でいう他の配合
剤と(−1,酸化i1j j4j、ス−i’ 7”、、
Jン酌、老化防止剤、仲1g曲、Jll’l Miii
)り等をいう。これらのNL Q t’l’l ” 所
定’、) 配r> m + ill j;’HLJ、次
(−0−1Iヲヘイン1−ミルを用い7]混合しC1す
、1j[1舗条(′1と同1.調川、+1”I 1ij
l Cり、:′!惜埋りる。< rfN a 1 method II) 1 1. (with other compounding agents referred to in \2) (-1, oxidation i1j j4j, su-i'7",,
J'un, Anti-aging agent, Naka 1g song, Jll'l Miii
)ri etc. These NL Q t'l'l ``predetermined',) Arrangement r> m + ill j;'HLJ, then (7 using -0-1I washin 1-mil) mix C1, 1j [1 column ( Same as '1 1. Togawa, +1"I 1ij
lCri, :'! I regret it.
イ(ブf ljf’lυ(ψ用する原料−fノ、(61
特に1111限がイしく、pilバー(5E人′(1:
jノ\\ゝ)ボリノタシ[ン1)\、ポリrソノ゛
し′ ニア −f l、 、 ス f しノ ン
−ブ ′J シ 1 ン ](重 合 1本 f
)1.1、たけ、:L4IC−)σ目昆合物簀のシ■
ン糸[ムか々f)内(に1・力用される、。(61
The 1111 limit is especially good, and the pil bar (5E people' (1:
\\\ゝ)borinotashi[n1)\, polyrsono゛
[1] (Polymerization 1 line f
) 1.1, Take, :L4IC-) σ-order insect cage ■
The thread is used within the thread.
まI、二、本光明の−fl\絹成物(こあ−)−(は、
前記した二賄Its吹んl= IIuえて通1A)ゴム
組成1カ(ご配合さ1えるカー小ンf−)・・I′、)
、醇化叶11)、−47う′リン酸、11+ 17ご油
、と、化p/ノ11削、(j(1碕促進^(1、(」パ
ノ等σ)自11合剤か適宜J fl!配合される。7
1゛4十、実施例43よび比較例(51阜−5ε〜本ず
i: liIfを1,11体的(5二il!l!’!I
しJる1、なお、第1表中の配合数的は(jl\l J
il i;’1部ζ(0イ)、。I, 2, Honkomyo's -fl\silk product (koa-) - (ha,
The above-mentioned two parts are blown l = II u ettsu 1A) Rubber composition 1 part (mixture 1 car small f-)...I',)
, -47 U' phosphoric acid, 11 + 17 sesame oil, and chemical p/no 11 reduction, (j (1 碕 promotion ^ (1, (''Pano etc. σ) self 11 mixture or J as appropriate fl! is blended. 7 1゛40, Example 43 and Comparative Example (51㎜-5ε~honzu i: liIf is 1,11 body (52il!l!'!I
In addition, the number of combinations in Table 1 is (jl\l J
il i;'1 part ζ (0i),.
yHII虻1jylj−j −−4咥↓t−1’lj較
Jしし二二第1(l〈に小−!J配合(−1ム絹成物を
調製し!51.こ0) −i l、Ill成物の調t%
jグJ >A L;L、比較M i 、 3 a’r
J: 0!”i −−−/’ 1.Li山7’jのil
P Dノ))人、^I−イ1わら、1紅j V”l−i
ムと配合i’ill (1lll i1/li f′j
す6.除く)をハンハリーミ1リ−C3)5)間混合i
す、IJ(1硫剤’= Jilt 、i (2分[11
し尺八(,7、さ’31ご11−1しく゛ン1を白り・
テ)、二ど(5,1、すijjlい、比中21(す2d
31−び/′4は前記(−5/ご1昆合方法■を用いて
1.卯?”11゛ ]、と 、 べ r シ 1− ミ
几7 C)[ル 合 と(1鴇 1甲 し、5 〕、
二 西e 会 凸り をハシI\1J−ミl 1−1′
、:lブ)間ン昆合し5、カー小シフノ・y′ノ、11
11 ’Ai i’i!I A−、’li1え(2分間
混合し、さらに[i−ル・ 、F昌Th ii <
:l L、 u t、E 、J、 リ b
な −) だ 。 ま jこ 、 ゛ノ、h色 I
も111.13上(>S)は、前記り、、、 /、混合
/)f人I4−用い(原(81−Il、、ど配合剤(]
]J−小シl−ノック1111 ilA剤、二線ftl
i、’iζ:、メi1土’、 ) ”: !\ンハリ
ーミキリー C3分間!(〜合 1,2 、 カ
− ホ シ・ ) ノ ・・I ′ノ 、 l1
il 5%t 剤 、 −−1iii jヒ
kリ 累 をIl(1λ (? ブン 間)1コ
合 し−1、il I−)(ご 11−− ル Cン昆
ご リ る (−1、l:−二、、、J、す、1ム絹
成物4調シ1し7k。1さらに、実廁19’l 2
お 上 (す 11(よ !I I: 含 ノ°ノ
)人 [お 、J、1す li を 引 合 4つ
[県 C、原寸)置j’ lxど、ベイシトミル(−
混合熱I7j、j +11. L配合〜1をバンハリー
−ミ%−jl−−(’ 3分間j[シ合じ、ツノ−・1
(ツノラック、1j11随剤、ニー硫化rap号r ’
01111え(:2ブ)間Ifi a L、c ラI9
1 t−t I’v C混r’r 4 ;i> コ+
’ tJ J、0.11Xキ[1成物を調製しlご。yHII 1jylj-j --4 mouth↓t-1'lj comparison J Shishi 22 1st (l〈small-!J combination (-1 mu silk composition prepared!51.ko0) -i I, Ill composition preparation t%
j gu J > A L; L, comparison M i , 3 a'r
J: 0! "i ---/' 1. il of Li mountain 7'j
P Dノ))人, ^I-i 1 straw, 1 red j V”l-i
Combined with mu and i'ill (1llll i1/li f'j
6. (except for), mixed between Hanharimi1li-C3)5) i
S, IJ (1 sulfur agent' = Jilt, i (2 minutes [11
Shakuhachi
te), 2nd (5,1, sijjl, hichu 21(s2d)
31-bi/'4 is the above (-5/go1 combination method ■) 1. rabbit?"11゛], and be rshi 1-mi 几7C) A, 5],
2 West e meeting convexity Hashi I\1J-mil 1-1'
, :lbu) between kongoshi 5, car small shift no y'no, 11
11 'Ai i'i! I A-, 'li1e (mix for 2 minutes, then [i-le, F-Cho Th ii <
:l L, ut, E, J, Ri b
Na-). Ma jko, ゛ノ, h color I
111.13 Above (>S) is as above, /, Mixed /)
] J-Small-Knock 1111 ILA agent, two-line FTL
i, 'iζ:, May i1 Sat', ) ”: !\n Harry Mikili C3 minutes!
- Hoshi・)ノ・・I′ノ、l1
Il 5%t agent, --1iii jhikli cumulative Il (1λ (?bun interval) 1 piece)
Combined -1,il I-) , Actual 19'l 2
11 people (including ノ°ノ) [O, J, 1s li] 4 [Prefecture C, original size] Place j' lx, Basitomil (-
Mixing heat I7j,j +11. L combination ~ 1 Banhari-mi%-jl--(' 3 minutes j [shi combination, horn-1
(Tunorac, 1j11 adjunct, knee sulfide rap No.r'
01111e(:2b) Ifi a L, c La I9
1 t-t I'v C mixed r'r 4 ;i> Ko+
'tJJ, 0.11X [1] Prepare the product.
この、1、−)(二L(i:’;らIIたf Is @
lliカをl A 51:、1−ルク 5)巳)(・l
9!+ ) IJ−、にでる5口、−q) 1.’1
間カミ1(1全し、(−1111] IIQ L2/ご
際のIll l硫速匪、11【ひL−1ill M、冒
イ沖ハ、川 S(l1il島、 [ジー1−) スおよ
び t a II” δを1llll定1−(N、、
+、 T 4第 1 表 (ご 、7’< −tl
、 % お 、 J、リ ii: 3 ン入
は F IF−、r の 1山 ’−,) ”
(、’ il’+ろ。This, 1, -) (2L(i:'; et IIta f Is @
llika wo l A 51:, 1-luku 5) Sn) (・l
9! +) IJ-, 5 mouths to appear, -q) 1. '1
Interval 1 (1 complete, (-1111) IIQ L2/Ill 1 sulfur speed, 11 [hi L-1ill M, attack off the coast, river S (l1il island, [G1-) Su and t a II” δ is 1lllll constant 1-(N,,
+, T 4 Table 1 (Go, 7'< -tl
, % O, J, Lin ii: 3 lin is 1 pile of F IF-, r '-,)''
(, 'il' + ro.
すII 1tli il l:’ゴ σ)、叫
定 は し・ 」 メ −′ノ −(、’ Wt
)\ j−ル ′ノ のIl) !50゜、のトル′
ノに達−4るま℃の口1間(+9.’i)(分)で 訂
′ (曲 15 k 、1 。L l、−1)II
Ml lリ の 、11リ 定 (よ 、 :
’−1’ l−z ?I目戊 1勾をシ・−1・1
人とL、1iii記のく二と(Ill碕じで、ZS
J<r ’Jンヘ/し411+z i! li史@ ?
r 3111 ’ig シ/、二、、 tl、L 5
C) 冑)、100%、20096.300OR14C
)096の各しシ!’、/ ス1JIVI jy ”C
1,i J IS −K −630’l M ’S’
lk’jして測定を(+イτつた。さらIJ、 t
a II δt、t 20 ’CとG O”Cの測定
子(1(行4「)/こ。sII 1tli il l:'go σ), shout
Determined Hashi・"Me -'ノ-(,' Wt
) Tor' of 50°
Reached -4 degrees Celsius in 1 minute (+9.'i) (minutes) (Tune 15 k, 1. L l, -1) II
Mlli's, 11li fixed (Yo,:
'-1' l-z? I eye 1 degree shi-1・1
Man and L, 1iii.
J<r 'Jnhe/shi411+z i! li history @ ?
r 3111 'ig shi/, two,, tl, L 5
C) helmet), 100%, 20096.300OR14C
) 096 each! ', / s1JIVI jy "C
1,i J IS -K -630'l M 'S'
lk'j and measure (+Iτt. Also IJ, t
a II δt, t 20 'C and G O''C measuring element (1 (row 4'')/ko.
第1イ1ミに7I々されることく、二硫化炭素を配合し
!、:実流1!l!l i −=−/Iは二硫化炭素を
未配合の比較例1・・・−4に比較()4、加lii!
1時間が短り、1空度おJ、びモジlラスが向」、!J
るど」(に 【旧1 δが低下しくいるのり(1〕か6
9゜
比較1!”I !、)・−・7 Ll、 、T」が(化
がJ免供与体eある1〜リヂAカーネオ−1へ上ステル
の配合効果を調べたもの−で゛あるが、1−リ’fAカ
ーボネートコニステルづるにt;Lっで、加硫時間(よ
やや短縮されるものの、1i1 1>( d) 、”、
びLジ1ンスlt 4;E 、!:んど向.にI!f、
−15+an j51;I高くなっζしまい好ましい
結果はIBgられ4rい,。Contains carbon disulfide to prevent 7I from being added to the 1st and 1st! , :Actual flow 1! l! l i -=-/I is compared to Comparative Example 1...-4 in which carbon disulfide is not added ()4, addition lii!
1 hour is shortened, 1 hour is shortened, 1 hour is shortened, 1 hour is shortened, and 1 hour is shortened. J
"Nori" (Ni [Old 1 δ is decreasing (1) or 6
9° comparison 1! ``I!,)...7 Ll, , T'' is (an investigation of the effect of blending upper stell with 1-LigiA carneo-1, which has a J donor e), but 1-Li 'fA carbonate conistert; vulcanization time (although it is somewhat shortened, 1i1 1>(d),'',
4;E,! :Ndo direction. niI! f,
−15+an j51; I becomes high ζ and the favorable result is IBg 4r.
以]−説明しlj J、うに、原1′+1ゴl\に特定
早の二硫化炭素を配合しlこ本発明のゴム組成物ト1加
Vli速度が速,−1、す、7111 kMi ’L’
j l!l: 、 ’I−!jに硬麿やモジコラスが向
上し、しかも(all δが低下することから、高硬
麿の低qゾ1動(1(抗タイX7川として好適に使用さ
れる。-Explanation: When the rubber composition of the present invention is blended with carbon disulfide at a specific rate, the rubber composition of the present invention has a Vli rate of -1, 7111 kmi. 'L'
j l! l: , 'I-! It is suitable for use as a low qzo 1 movement (1 (anti-tie
Claims (1)
r 二1ift化炭素を1〜101ffi部配合した
ことを特徴どするゴム組成物。Original: l'l -r l\100 K, n for parts, t,
A rubber composition characterized in that it contains 1 to 101 parts of carbon diift.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22713282A JPS59120639A (en) | 1982-12-27 | 1982-12-27 | Rubber composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22713282A JPS59120639A (en) | 1982-12-27 | 1982-12-27 | Rubber composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS59120639A true JPS59120639A (en) | 1984-07-12 |
Family
ID=16855973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22713282A Pending JPS59120639A (en) | 1982-12-27 | 1982-12-27 | Rubber composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59120639A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6247512B1 (en) * | 1996-09-03 | 2001-06-19 | Michelin Recherche Et Technique S.A. | Tire having tread portion with rubber to control wear |
-
1982
- 1982-12-27 JP JP22713282A patent/JPS59120639A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6247512B1 (en) * | 1996-09-03 | 2001-06-19 | Michelin Recherche Et Technique S.A. | Tire having tread portion with rubber to control wear |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE60219696T2 (en) | ATOMIC TEMPERATURE HARDENABLE ORGANOPOLYSILOXANE COMPOSITIONS | |
MX170568B (en) | IMPROVEMENTS TO NON-EXUDING GRAINED DENTIPHER | |
DE3635719C2 (en) | Organopolysiloxanzubereitung | |
DE2040386A1 (en) | Organopolysiloxane mixtures vulcanizable at room temperature and processes for producing silicone rubbers therefrom | |
DE2433697A1 (en) | PROCESS FOR MANUFACTURING COMPOUNDS TO BE CROSSED TO ELASTOMERS | |
EP0106101B1 (en) | Process for preparing highly elastic cold curing polyurethane foams | |
DE2117027B2 (en) | Organopolysiloxane molding compounds that can be stored at -20 degrees C and harden to form elastomers under normal atmospheric conditions | |
DE2234790B2 (en) | Silicone molding compound which is stable in the absence of water but cures under the action of moisture and vulcanizable at room temperature | |
JPS59120639A (en) | Rubber composition | |
DE2225698B2 (en) | Aqueous siloxane bag slip agent for tire manufacture | |
JPS5734143A (en) | Rubber composition | |
ATE320467T1 (en) | LIQUID EBONITE MIXTURES AND COATINGS AND CEMENTS PRODUCED THEREFROM | |
CH525006A (en) | Skin treatment prepn contg diorganopolysiloxanes | |
US1594491A (en) | Luminous compound | |
EP0006528B1 (en) | Tubular polyamide films | |
DE2107971C3 (en) | Hardening accelerator for storage-stable mixtures that harden with atmospheric moisture and are based on liquid monomeric, oligomeric or polymeric compounds with terminal mercapto groups and peroxides of zinc or cadmium as hardeners | |
US1782693A (en) | Sulphur and resin compound | |
US328366A (en) | Chaeles walpuski | |
US1392240A (en) | Rubber composition and method osi making the same | |
GB1151679A (en) | Improvement of Green Strength of Rubber Compounds | |
DE1188809B (en) | Process for the production of filler-containing or pigmented, fiber-forming polyhexamethylene diammonium adipates or lactam polycondensates | |
DE709404C (en) | Overcoats for printing rollers | |
US1926285A (en) | Method of tihckening latex and product thereof | |
DE556313C (en) | Process for the production of objects from aqueous emulsions or dispersions of rubber or similar substances | |
DE839857C (en) | Activator and filler for rubber compounds |