JPS5891836A - Gold yarn and production thereof - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed Description of the Invention] Wooden BJ-kekin thread, especially a layer of non-thermoplastic material such as polyester resin, is used as a base material, and gold #1 is vapor-deposited thereon, and its production. Regarding legal VC.

Such threads are generally already twisted, and by making sheet-like elements T and I and cutting them into threads, it is easier to use industrial Vc weight than gold threads made by other methods. The base material made of non-thermoplastic resin satisfies the resistance and durability required for gold thread, and the metal vapor deposited chest gives off a glossy texture. By applying a top coat of heat-resistant and abrasion-resistant resin to the embossed vapor-deposited layer, it has the heat and abrasion resistance necessary for the yarn.

In this type of gold thread, silvery gold 11 is used as the metal for vapor deposition.
1 For example, aluminum, gold alloy, platinum, platinum Q) When metals such as aluminum, gold alloy, silver, balasicum, balasicum alloy etc. In order to obtain a golden texture, it is necessary to color the thread material with a yellowing colorant. Even when gold-colored metals such as cut gold are used, there are cases in which they are given a yellowish or reddish tinge due to the decorative nature of the gold thread or the diversification of tastes. Color is needed.

Conventionally, the material color of such gold thread was 4ml of thermosetting material mixed with dye! It depends on the method of undercoating or topcoating. According to the conventional method,
When dye is added to the coating agent of naturally hardening wood 111j, the color of VC will become unrecognizable in proportion to the mixing rate of 111, and the laminated color layer will be damaged. It's
: iJ IJ There is a problem that it is easy to tear and results in a product yarn with low durability. Furthermore, if the logical color layer is easily peeled off, even a long top coating with a heat-resistant and abrasion-resistant resin retention layer will have little effect. That is, coloring force; peeling tr;
means that the protective layer is peeled off from the base.

In addition, in the case of a dark color according to the conventional method, kneading in which a large amount of dye is added will result in poor traceability, so it is not recommended to repeat coating two or three times to deepen the color. As a result, the dyed 1F-containing thermosetting resin became 4-bound, and as a result, the threads became hard and resisted impact, and there were μ points where the material sheets were broken when the threads I and IJ were cut.

So xylophone tl! It is possible to remove the defects caused by 14ke hP and Sakiku Giwei, form a solid colored layer that does not peel off, and make the protective layer with the heat and abrasion resistant film effective, and it is The purpose of the present invention is to provide a method for producing a gold thread that has a high impact resistance, a high impact resistance, and a method for producing it.

Furthermore, the present invention improves peel resistance, thermal stability, and abrasion resistance←
To simply apply cotton coloring to a product yarn material laminate, and to convey a manufacturing method τD of gold thread that is capable of industrially producing gold thread with excellent heat resistance, abrasion resistance, and spot peeling resistance. is marked J.

Base material layer made of gold thread +-i non-thermoplastic resin of the present invention, ^A
11 layers of metal vapor deposited on the paulownia layer through an undercoat layer of thermosetting resin, and a first protective layer of thermosetting resin laminated on the outer surface of the base material layer. A 2-ply laminate enclosing a second protective layer made of heat-resistant and abrasion-resistant Japanese resin laminated with an adhesive, and a thread made of a composite laminate laminated with the first protective layer side inside. It is characterized in that the adhesive laminating the second shin protection layer contains a coloring agent and is colored by the adhesive.

Heat-raising μ-cho plastic fallen fat film VC is used in the manufacturing method of Kishite...
According to 21: (A metal vapor deposition layer is formed directly on the material or via an undercoat layer of a Vi thermosetting resin, a first protective layer of a thermosetting resin is formed on it, and the outer layer of the above base material is formed. A second protective layer made of a heat-resistant and wear-resistant resin film is laminated on the surface with a bonded adhesive coated with a material coloring agent, and the first protective layer is coated with two layers. Laminated on the inside, the resulting composite ceramic layer was used as a material.
It is characterized by cutting the filamentous Vc.

According to Kippatsu 111-1, when laminating the film constituting the second protective layer, the coloring agent must be incorporated into the product yarn in the form of a dry lamination adhesive (for example, a polyester-based or polyflex yarn). Therefore, it is possible to form a solid colored layer without plasticity. Therefore, the layer of heat-resistant and abrasion-resistant resin covering the outer surface of the colored layer also does not peel off. Therefore, by editing the book, you can make it look like a child's heart.

In addition, according to the material color of the present invention, in terms of the manufacturing method of the product, it has a heat resistance of 11'M. After the formation of the colored layer, the second retaining layer described in L can be applied. It can be easily attached to the torso.

blr<1. According to the method of the present invention, the non-thermoplastic resin h
A gold thread production method in which two laminates are made by laminating two laminates, each consisting of a base material made of I-Film, metal vapor-deposited, a first protective layer, a colored layer, and @22 protective film, and then cut into threads (11). It is possible to use the yarn without any problems, and to produce iron yarn with excellent heat resistance, abrasion resistance, and interlayer peeling resistance.

And it’s a tree! According to 8 God 1, by mixing the necessary amount of coloring agent into the adhesive, it is possible to create a dark color without the need for thick coating of thermosetting resin, and therefore even with a dark color, it is possible to achieve equilibrium resistance. You can get fine gold thread.

In the invention, even in dark colored colors such as red and positive, acidic colors such as red and dove are used in dry lamination adhesives that are generally used for laminating polynisdel resin films, etc. Mix an appropriate amount of metal-containing dye and apply it by roll-coding method, etc., and the colored layer, the second coat on top, will not cause any deterioration in the properties of the base material. It was discovered that the required dark gold thread could be obtained without any process.

Polynismol cypress paste on the 8-thread tri base material layer of Kien (7)
Use ITl, I heat chemical resistant ones, and set the deposition order Piv
R-Ki, gold alloy, platinum, platinum alloy, silver, silver alloy, parasicum, barasicum stand! When using IIIJ condition products such as
l 1. Toko 33I is made by adding 2g of Monogen (trade name) to 1/1 part of Tadokoron liquid or water! 7) J
C processing, i.e., silk-like thinning processing (add 50 g of water-smoothed sodium to 1/2 water on a t!rlJ stand).
Even after processing for 1 minute), no change was observed in the Komairo color. This is due to the adhesion between the colored layer and the second protective layer.1. Because of its good quality, it cannot be recognized as being rejected. It is easy to bleach or discolor when processed like the conventional process that results in a colored color as described above, and this is especially true for rocky colors such as Red Elephant.

The gold-deposited layer according to the present invention is applied to the laminate at the stage before the product-based material composite laminate, and is coated with a thermosetting resin during the first bonding NvIV.
Since the outer surface is covered with C, this semi-finished product is often used to attach two parts of the body, and during the pasting process, it is often damaged due to pus retention due to friction etc. during handling. Product Kaya thread V
In this case, the metal evaporated layer protects the outer surface (till) from wear and tear by the base material layer and the second protective film layer. long term vcfi
and hold it stably.

In addition, the product for the A button is made of wood, so the physical properties are solid and durable.

The gold thread of the present invention is made from a flat thread made by cutting the material composite m body into 9 cuts.
17. The flat yarn may be processed into twisted yarn according to a conventional method and used.

Below, we will explain one example of Kien [v].

Tenshi ml 1 Heat 2 pieces on base material (1) made of polyester Jugetsu film
Select from thermosetting melamine fat, thermosetting acrylic resin, thermosetting epoxy resin (7) 1 'Neta l Japanese ■ right '1t uh straddling 2 inserts E's mixed resin heat treatment The curable resin liquid K is coated with a light Angoo coat, and its acider coat layer (2) is a vapor-reducing layer (31) made of VC aluminum Vζ, and the gold vapor-deposited layer F31 K is heat-cured in the same manner as above. After forming the first film-retaining layer (4), the outer surface of the E base material layer (1) is coated with a polyester-based or 1-containing material mixed with an appropriate amount of a yellow acidic alloy-type coloring agent.
1 Poly, contact ff for dry lamination of Cretashi yarn
Ha J fil t Roll Co-1 Ink'
u L' (T, Holies 1 le tke u+Q) S
Rum bite now 1r-t -7・So gradient +1t1
1 1 l ・ ・ -〃 し - Laminate the second protective lees (6), 148 hours, 3 () ~ 40
Keep it warm at about ``C.'' Once the adhesive (5) is completely cured, the second abdominal layer (6) and the colored adhesive (5) with a colored layer are formed. Body (facing At. Prepare the body of the prisoner 7a-2, and cover them with the first protective layer 14)
Apply adhesive for dry lamination (7) with the side facing inside.
The laminate was laminated for 148 hours, kept warm for 10 to 4 hours, and the adhesive (7) was completely cured to completely adhere the laminate and the laminate. body t
βr constant width (generally about 0.
After 4M bending), it was cut to obtain a double-sided flat gold thread having the properties as described above.

Example 2 Gold alloy, silver, silver alloy, baladicum, baladicum alloy, platinum, platinum 0) A type of platinum given by Sogaya was used as a metalloid for vapor deposition. Create the required laminated body in the same manner as above, and use this? ] l - Cut in the same manner as in Example 1. I made a double-sided golden thread with the same special characteristics as described above.

Example 3 Gold was used as the metal for deposition, and as the colorant, red acidic @Kaya type MP, it color acidic metal-containing dye was selected from N pis, and rock-colored acidic metal-containing type dye. A required laminated body was prepared in the same manner as in Example 1 except for the point of use, and this was cut in the same manner as in Example 1. A double-sided dark golden flat gold thread having the characteristics of IFN 11 as described above was obtained.

In both embodiments, the base material ++1 has a thickness of approximately 9 to 25 mm.
The thickness of the undercoat 1f (21) can be approximately 1μ, and the thickness of the first protective layer (thickness Vi1) can be applied.
~2μ can be adopted, and the coating thickness of contact agent T51 F71 can be applied after 3μA.
It's J! F.

A material with a diameter of about 3 to 6 μm can be used. Adhesives containing colorants are good because even if they are boiled, their stability will be affected.

[Brief explanation of the drawing]

The drawing is an enlarged cross-sectional view showing one embodiment of the wooden spring i11. f+l...Base material, (2)...Undercoat layer, (
3)...Pure gold vapor deposited layer, (4)...First iron holding layer, (6
)...Colored A-filled adhesive, (6)...Second protective layer, (7)...Adhesive, Cap...Laminated body. (Hereafter k) Procedural amendment (Ryu) May 28, 1980, 3, Palace of the Director of the Permanent Licensing Agency, Person making the amendment 4, Agent, Heiwa Building, 2-10, Hirano-cho, Higashi-ku, Osaka, Telephone: 06-203
-0941 (6521) Eiji Saegusa, patent attorney. 5. Date of amendment order
Contents of amendment as shown in the attached sheet 1 The drawings are corrected as shown in the attached sheet. (and above) 1-

Claims (1)

[Scope of Claims] ■ A metal vapor deposited by non-thermoplastic resin, in contact with the indicating material layer, or via an undercoat layer of hardening river resin. Ministry layer, that l] FYJ layered Neboka Riki i1F! ! The outer surface of the base material layer is laminated with an adhesive and the second layer is made of a heat abrasion resistant resin. It is a thread made of a composite ceramic layer that is laminated with the plate layer side facing the same direction, and the adhesive that laminates the second security layer contains a darkening agent and is colored by it. Gold thread with Kotowo @ symbol. ■ Directly attached to the base material made of non-thermoplastic resin film, a metal layer is formed through an undercoat layer of thermosetting resin, and the first protective layer is made of Kumagawa pear oil on the soil of the seventh grade. The entire shape was removed, and a second protective layer of a heat-resistant and abrasion-resistant resin film was laminated on the outer surface of the base material using an adhesive containing a colorant, and the resulting HFC laminate was coated with 2 Bry, K, and %. A method for producing gold thread, which is characterized in that the VC layered material is used as a material and cut into threads.