JPS588416B2 - Hatsupou Polystyrene Banyou Shiagezai - Google Patents

Hatsupou Polystyrene Banyou Shiagezai

Info

Publication number
JPS588416B2
JPS588416B2 JP3209275A JP3209275A JPS588416B2 JP S588416 B2 JPS588416 B2 JP S588416B2 JP 3209275 A JP3209275 A JP 3209275A JP 3209275 A JP3209275 A JP 3209275A JP S588416 B2 JPS588416 B2 JP S588416B2
Authority
JP
Japan
Prior art keywords
adhesion
water
shiagezai
hatsupou
banyou
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP3209275A
Other languages
Japanese (ja)
Other versions
JPS51106136A (en
Inventor
浅井信通
大橋亘
長田義広
福田勲義
平木佐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takenaka Komuten Co Ltd
Nihon Kasei Co Ltd
Original Assignee
Takenaka Komuten Co Ltd
Nihon Kasei Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takenaka Komuten Co Ltd, Nihon Kasei Co Ltd filed Critical Takenaka Komuten Co Ltd
Priority to JP3209275A priority Critical patent/JPS588416B2/en
Publication of JPS51106136A publication Critical patent/JPS51106136A/en
Publication of JPS588416B2 publication Critical patent/JPS588416B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Paints Or Removers (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Description

【発明の詳細な説明】 この発明は断熱材として広く採用されでいるところの発
泡ポリスチレン版用の仕上材の提供に係わる。
DETAILED DESCRIPTION OF THE INVENTION This invention relates to the provision of a finish for expanded polystyrene plates, which are widely employed as insulation materials.

従来,発泡ポリスチレン版の仕上げはセメントモルタル
,無機材質プラスター,樹脂プラスター等を用いて鏝仕
上げを行ない表面にペイント塗装を施しでいたものであ
るが施工後剥離,亀裂等の支障が生じ易すくぞの改善が
要望されでいる。
Conventionally, foamed polystyrene plates were finished using cement mortar, inorganic plaster, resin plaster, etc. with a trowel, and the surface was then painted, but these problems tended to cause problems such as peeling and cracking after installation. Improvements are requested.

かかる支障の発生原因についでは.その下地との剛性の
差異あるいは物理的.化学的な接着機構不明のため叙上
要望の方針も立て難いのが実状である。
Regarding the cause of this problem. Difference in rigidity from the base or physical. The current situation is that it is difficult to formulate a policy for requesting a report because the chemical adhesion mechanism is unknown.

そこで.本発明者等は叙上支障発生の原因をば経験にも
とづいて一応理論的に究明し.これをもととして試作を
しでみて良結果を得たのが本発明仕上材である。
Therefore. The inventors of the present invention have theoretically investigated the cause of the occurrence of troubles in reading based on their experience. Based on this, a trial production was conducted and good results were obtained for the finishing material of the present invention.

すなわち,発泡ポリスチレン版への湿式材の仕上の支障
の原因は現在においても各種下地に対する接着機構が明
確にされでいないため断言することはできないが,統計
的にみると接着力の不足に起因するものが多いと考えら
れる。
In other words, although it is not possible to confirm the cause of the difficulty in finishing wet-laid materials on expanded polystyrene plates because the adhesion mechanism to various substrates is still not clear, statistically speaking, it is due to insufficient adhesion. It is thought that there are many things.

一般に物体の接着の現象は接着理論を大まかに考えると
機械的.物理的.化学的な力の結果であると説明されて
いる。
Generally speaking, the phenomenon of adhesion of objects is mechanical if we consider adhesion theory roughly. Physical. It is explained that it is the result of chemical forces.

機械的付着力は接着材が被接着材表面に存在する多くの
孔隙に浸入しで硬化し.いわゆる投錨力によつで被着材
相互の接着が行われるという説である。
Mechanical adhesion occurs when the adhesive penetrates into the many pores that exist on the surface of the bonded material and hardens. The theory is that the adherends are bonded to each other by so-called anchoring force.

物理的接着力は原子間分子間の引力で説明されCいる理
論であって現在最も信頼されている説である。
Physical adhesion is explained by the attraction between atoms and molecules, and is currently the most trusted theory.

化学的接着力は化学反応による一次結合と説明されでい
る。
Chemical adhesion is explained as a primary bond caused by a chemical reaction.

以上の機械的,物理的,化学的な作用が同時に起る場合
は極めて強い接着力が期侍されるがいずれの場合でも接
着材が被着材の接着面を良く漏らす事が重要な要件とな
っている。
When the above mechanical, physical, and chemical effects occur simultaneously, an extremely strong adhesive force is expected, but in any case, it is an important requirement that the adhesive leaks well from the bonding surface of the adherend. It has become.

発泡ポリスチレン版等非吸水性材に対する湿式材の接着
性は非吸水性建材の代表である硝子面への接着試験から
判る様に水/バインダー比を適正化する事により.かな
りの物理的,化学的接着力が得られるために機械的な接
着力に関しではさしで期待をもつ必要がない事が解る。
The adhesion of wet materials to non-water-absorbing materials such as expanded polystyrene plates can be determined by optimizing the water/binder ratio, as shown in adhesion tests to glass surfaces, which are representative of non-water-absorbing building materials. It can be seen that there is no need to have high expectations regarding mechanical adhesive strength since considerable physical and chemical adhesive strength can be obtained.

しかし,この現象はあくまでも水/バインダー比の適正
時に示す結果であって,逆に余剰水が湿式材,下地界面
に作用すると接着力は極端に減少する事となるものであ
る。
However, this phenomenon only occurs when the water/binder ratio is appropriate; on the other hand, if excess water acts on the interface between the wet material and the base, the adhesive strength will be extremely reduced.

従つC、過去に作業所でよく見受けられた例であるが左
官工の作業性のみを考慮したワーカビリテイ(180c
m前後)の湿式材をブレーンのままコンクリート下地と
同様な方法で発泡ポリスチレン版に塗装する事は当然良
結果をもたらし得ない訳である。
Compliant C, an example that was often seen in workshops in the past, is workability (180c) that only considers the workability of plasterers.
Naturally, it is not possible to produce good results if wet-laid materials (around 100 mm) are painted as blanks on expanded polystyrene plates in the same manner as concrete bases.

特にセメントモルタルを使用する場合には材料自体が水
和硬化する迄に一定の時間を要し.塗厚が大きく水量が
過多であると自重によるずり落ちも考えられる。
Especially when using cement mortar, it takes a certain amount of time for the material itself to hydrate and harden. If the coating is too thick and the amount of water is too large, it may slip off due to its own weight.

以上湿式材の水/バインダー比の不適による施工も支障
の大きな要素となるが水/バインダー比の適正化が,即
,接着性の改善につながる訳でなく,その他に発泡ポリ
スチレン版と湿式材相互の剛性の相違に関する問題も追
従する。
As mentioned above, the inappropriate water/binder ratio of the wet material is a major hindrance to construction work, but optimizing the water/binder ratio does not immediately lead to improved adhesion, and there is also the possibility that the foamed polystyrene plate and the wet material may not work properly. The problem regarding the difference in stiffness also follows.

一般に被着材と接着材が異種のものであると,両者の物
理的,化学的性質の相違によって接着面には必然的に残
留ひずみが発生する事になる。
In general, if the adherend and adhesive are of different types, residual strain will inevitably occur on the bonded surface due to differences in their physical and chemical properties.

発抱ポリスチレン版の様に空気泡を持つ剛性の極めて低
い材にプラスチックなどの湿式材を鏝で,押え塗装する
事は,その残留ひずみに性質は異るかも知れないが施工
時におけるひずみが付加される様になる。
When applying a wet material such as plastic with a trowel to a material with extremely low rigidity that has air bubbles, such as an expanded polystyrene plate, the residual strain may be different in nature, but the strain during construction is added. It becomes like being done.

また,その残留ひずみの合計は湿式材自体の強度が犬で
ある程大きくなる事が予想される。
Furthermore, the total residual strain is expected to increase as the strength of the wet material itself increases.

現在湿式材の中でボード用のせつこうブラスターが発泡
ボリスチレン版に対し比較的良好な結果を示しCいる理
由は硬化速度が速く,針状結晶による機械的な接着力が
期待できるためだけではなく.材自体の強度が弱く,す
なわち,剛性が低く乾燥による収縮量が難かである性質
をもつからであると考えられる。
Currently, among wet materials, plaster blasters for boards are showing relatively good results compared to foamed polystyrene plates.The reason for this is not only because the curing speed is fast and the mechanical adhesion force due to the needle-like crystals can be expected. .. This is thought to be because the strength of the material itself is low, that is, its rigidity is low, making it difficult to shrink due to drying.

以上の推論のみで発泡ポリスチレン版昏こ対する湿式材
の支障の改善の方針が究明到達し得たとするのは正確に
は疑問であるが.まとめると発泡ポリスチレン版をこ対
する湿式仕上材の性質.仕上方法に次の様な条件が考え
られる。
Although it is questionable whether it is possible to arrive at a policy for improving the problem of wet materials for foamed polystyrene plates based solely on the above reasoning. In summary, the properties of wet finishing materials used to coat expanded polystyrene plates. The following conditions can be considered for the finishing method.

(1)水/バインダー比をできるだけ下げる事。(1) Lower the water/binder ratio as much as possible.

(2)湿式材自体の強度が低く収縮の少ない事。(2) The wet material itself has low strength and little shrinkage.

(3)軽量である事。(3) It must be lightweight.

(4)塗厚の薄い事。(4) Thin coating thickness.

(5)施工の際,下地に応力の生じない事。(5) No stress will be generated on the base during construction.

(6)湿式材自体に接着剤を混和するか下地に接着を上
げる処理を行う事。
(6) Mix adhesive into the wet material itself or perform a process to increase adhesion to the base material.

(7)下地の剛性を向上させ機械的接着を得る処理を行
う。
(7) Perform treatment to improve the rigidity of the substrate and obtain mechanical adhesion.

本仕上材は上記諸条件を満足させることを方針に開発し
たものである。
This finishing material was developed with the aim of satisfying the above conditions.

つまり,本仕上材の組成は白色ボルトランドセメント,
特殊軽量骨材,石綿短繊維にその重量の5%の無機顔料
.5〜10%のエチレン酢酸ビニル共重合樹脂エマルジ
ョン(固型分50%),75%の水とからなる。
In other words, the composition of the final finishing material is white boltland cement,
Special lightweight aggregate, short asbestos fibers, and 5% of its weight of inorganic pigment. It consists of a 5-10% ethylene vinyl acetate copolymer resin emulsion (solid content 50%) and 75% water.

ここで.特殊軽量骨材とはガラス質閉鎖型多泡粒状体を
主体とする人工軽量骨材で耐熱性.断熱性等に優れた特
性を有するもので.石綿短繊維は亀裂防止.保水性の向
上を目的に添加したものであり.エチレン酢酸ビニル共
重合樹脂エマルジョンは,いわゆる接着剤で添加するこ
とによりセメント,軽量骨材,石綿短繊維中昏こ介在し
,その鎖状分子構造と共に分子間の間隙を充填し稠密な
ものとし,その結合,凝集力が発泡ポリスチレン表面と
の接着性を向上させるものであり,無機顔料は仕上材自
体に着色し,ペイント等の表面塗装を省略するために添
加したものである。
here. Special lightweight aggregate is an artificial lightweight aggregate that is mainly composed of glassy closed cell granules and is heat resistant. It has excellent properties such as heat insulation. Asbestos short fibers prevent cracks. It is added for the purpose of improving water retention. Ethylene-vinyl acetate copolymer resin emulsion is added as a so-called adhesive, intervening in cement, lightweight aggregate, and short asbestos fibers, and filling the gaps between molecules with its chain molecular structure to make it dense. The bonding and cohesive force improves the adhesion to the foamed polystyrene surface, and the inorganic pigment is added to color the finishing material itself and eliminate the need for surface coating such as paint.

この結果本組成の仕上材は低強度,軽量となり,水/バ
インダー比の低減あるいは接着材,保水剤の混和により
適度な接着力,収縮量の減少効果が得られ,上記諸条件
を満足するものとなる。
As a result, the finishing material of this composition has low strength and light weight, and by reducing the water/binder ratio or incorporating adhesives and water retention agents, an appropriate adhesive strength and shrinkage reduction effect can be obtained, and the above conditions are satisfied. becomes.

これを鏝仕上,刷毛仕上.吹付仕上等の直仕上で発泡ポ
リスチレン版に塗装すれば良い。
This is finished with a trowel and with a brush. It can be applied directly to the expanded polystyrene plate using a direct finish such as spray finishing.

以下.本発明の実施例を掲げる。below. Examples of the present invention are listed below.

実施例 仕上材の調合 上記組成の仕上材を発泡ポリスチレン版に厚5闘程度金
鏝で塗装し.7日及び28日室内自然放置後,仕上材層
をダイヤモンドカッター発泡ポリスチレン版表面迄カッ
トし,鉄製デスクを増り付け手動油圧試験機で接着試験
を行った。
Example Preparation of finishing material The finishing material of the above composition was applied to a foamed polystyrene plate with a metal trowel to a thickness of about 5 mm. After being left indoors for 7 and 28 days, the finishing material layer was cut to the surface of the expanded polystyrene plate using a diamond cutter, an iron desk was added, and an adhesion test was conducted using a manual hydraulic testing machine.

(イ)接着性試験 接着力(k9/cm2)は最大荷重(kg)/接着面積
(cm2)で示される。
(a) Adhesiveness test Adhesive strength (k9/cm2) is expressed as maximum load (kg)/adhesive area (cm2).

試験結果を下表に示す。(口)凝結時間 (ハ)強度 (ニ)硬度 1週硬度 3,2(ドロマイトプラスタ−JIS規格4
2週2,3以上) (ホ)特殊軽量骨材 叙上発明の実施により次記の如き効果が認められる。
The test results are shown in the table below. (1) Setting time (3) Strength (2) Hardness 1 week Hardness 3,2 (Dolomite plaster - JIS standard 4
(E) Special lightweight aggregate The following effects are recognized by implementing the described invention.

(イ)吹付仕上の場合,吹付タイルライクのテキスチュ
アーが得られ,左官技能工を必要としないので労務費が
安く済み工期も短縮できる。
(b) In the case of spray finishing, a texture similar to spray tiles can be obtained, and since a plasterer is not required, labor costs are low and the construction period can be shortened.

(100〜150m2/3名1組1日) 又,ローリングタワー程度によって施工が可能であるの
で仮設費も節約できる。
(100 to 150 m2/3 people per group per day) Also, since construction can be done at the level of a rolling tower, temporary construction costs can be saved.

(口)材料費が安く,着色は顔料の混入により表面ペン
キ塗装が不要となる。
(Example) Material costs are low, and coloring eliminates the need for surface painting due to the inclusion of pigments.

(・)塗装後.長期に渡たり剥離,亀裂等は全く認めら
れず支障が低減された。
(・) After painting. No peeling or cracking was observed over a long period of time, reducing problems.

Claims (1)

【特許請求の範囲】[Claims] 1 白色ボルトランドセメント,特殊軽量骨材,石綿短
繊維にその重量の5%の無機顔料、5〜10%のエチレ
ン酢酸ビニル共重合樹脂エマルジョン(固型分50%)
,75%の水とを調合してなることを特徴とする発泡ポ
リスチレン版用仕上材。
1 White Bortland cement, special lightweight aggregate, short asbestos fibers, 5% of the weight of inorganic pigment, 5-10% ethylene vinyl acetate copolymer resin emulsion (solid content 50%)
, 75% water.
JP3209275A 1975-03-17 1975-03-17 Hatsupou Polystyrene Banyou Shiagezai Expired JPS588416B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3209275A JPS588416B2 (en) 1975-03-17 1975-03-17 Hatsupou Polystyrene Banyou Shiagezai

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3209275A JPS588416B2 (en) 1975-03-17 1975-03-17 Hatsupou Polystyrene Banyou Shiagezai

Publications (2)

Publication Number Publication Date
JPS51106136A JPS51106136A (en) 1976-09-20
JPS588416B2 true JPS588416B2 (en) 1983-02-16

Family

ID=12349228

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3209275A Expired JPS588416B2 (en) 1975-03-17 1975-03-17 Hatsupou Polystyrene Banyou Shiagezai

Country Status (1)

Country Link
JP (1) JPS588416B2 (en)

Also Published As

Publication number Publication date
JPS51106136A (en) 1976-09-20

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