JPS5882578A - Solar cell - Google Patents
Solar cellInfo
- Publication number
- JPS5882578A JPS5882578A JP56180762A JP18076281A JPS5882578A JP S5882578 A JPS5882578 A JP S5882578A JP 56180762 A JP56180762 A JP 56180762A JP 18076281 A JP18076281 A JP 18076281A JP S5882578 A JPS5882578 A JP S5882578A
- Authority
- JP
- Japan
- Prior art keywords
- solar cell
- thin film
- heat
- layer
- adhered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010409 thin film Substances 0.000 claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 12
- 239000010439 graphite Substances 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 238000005979 thermal decomposition reaction Methods 0.000 claims abstract description 4
- 238000009413 insulation Methods 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 4
- 229910001218 Gallium arsenide Inorganic materials 0.000 abstract description 2
- 239000010410 layer Substances 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 230000002349 favourable effect Effects 0.000 abstract 2
- 239000010408 film Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910020442 SiO2—TiO2 Inorganic materials 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000002356 single layer Substances 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002470 thermal conductor Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
- H01L31/02168—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/052—Cooling means directly associated or integrated with the PV cell, e.g. integrated Peltier elements for active cooling or heat sinks directly associated with the PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Sustainable Energy (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、太陽電池の改良に係り、特に、受光面を有機
エステル化金属の熱分解により生成した透明かつ均一な
酸化物薄膜で被覆して受光”表面の熱劣化を防止し、或
いは、裏面に熱伝導率のよい等方性黒鉛を一体的に設け
て太陽電池に蓄積された熱を効果的に放熱し得るように
し、もって、太陽電池の耐熱性を高め、該太陽電池にレ
ンズ等１でよって集束した高エネルギー密度の太陽光を
照射し得るようにし、太陽電池の小型化、低廉化、及び
、高効率化を図ったものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the improvement of solar cells, and in particular, the light-receiving surface is coated with a transparent and uniform oxide thin film produced by thermal decomposition of an organic esterified metal to prevent thermal deterioration of the light-receiving surface. Alternatively, by integrally providing isotropic graphite with good thermal conductivity on the back side, the heat accumulated in the solar cell can be effectively dissipated, thereby increasing the heat resistance of the solar cell. The solar cell is made to be irradiated with sunlight with high energy density focused by a lens or the like, thereby making the solar cell smaller, less expensive, and more efficient.
第１図は、本発明による太陽電池の一実施例を説明する
ための側断面図で、図中、１は太陽電池素子、２は酸化
物薄膜、３は絶縁層、４は等方性黒鉛で、太陽電池素子
１は例えば周知のＣｄＳ 。FIG. 1 is a side sectional view for explaining one embodiment of the solar cell according to the present invention, in which 1 is a solar cell element, 2 is an oxide thin film, 3 is an insulating layer, and 4 is isotropic graphite. The solar cell element 1 is made of, for example, well-known CdS.
ＧａＡｓ 、 ＧＤａ −Ｓｉ 、 又はＰ−Ｎ接
合されたＳｉ等で構成され、該太陽電池素子の表面及び
裏面には例えば５ｉＯｚ、ＴｉＯ２、又は、ＴａｚＯｓ
等の単味酸化物薄膜、或いは、５ｉＯｚ−ＴｉＯｚの混
合酸化物薄膜２及び３が施こされておシ、斯様にして酸
化物薄膜が形成された太陽、電池素子１の裏面には前述
のごとくして形成された電気絶縁層３を介して等方性の
黒鉛４が一体的に取り付けられている。なお、上記実施
例には、表面保護被膜２と裏面の電気絶縁被膜３を同一
材料で同時に形成する例を示したが、電気絶縁被膜３は
上記実施例に限定されるものではなく、所定の温度に耐
えかつ太陽電池素子１の電流を等方性の黒鉛゛４の方へ
漏洩させないものなら前記以外のものでもよい。また、
表面の保護被膜２は太陽電池素子１の受光面の熱劣化を
防止するものであり、裏面の等方性黒鉛４は太陽電池素
子１の放熱をよくして該太陽電池素子の効率低下を防止
するものであるから、これらは、必ずしも同時に使用し
なければならないものではない。It is composed of GaAs, GDa-Si, or P-N bonded Si, and the front and back surfaces of the solar cell element are coated with, for example, 5iOz, TiO2, or TazOs.
A single oxide thin film such as the above or a mixed oxide thin film 2 and 3 of 5iOz-TiOz is applied, and the back surface of the solar battery element 1 on which the oxide thin film is formed is as described above. Isotropic graphite 4 is integrally attached via an electrical insulating layer 3 formed as follows. In addition, although the above embodiment shows an example in which the surface protective coating 2 and the electrical insulation coating 3 on the back surface are simultaneously formed of the same material, the electrical insulation coating 3 is not limited to the above embodiment, Materials other than those mentioned above may be used as long as they can withstand the temperature and do not cause the current of the solar cell element 1 to leak toward the isotropic graphite 4. Also,
The protective coating 2 on the front surface prevents thermal deterioration of the light-receiving surface of the solar cell element 1, and the isotropic graphite 4 on the back surface improves heat dissipation of the solar cell element 1 and prevents a decrease in efficiency of the solar cell element. Therefore, these do not necessarily have to be used at the same time.
なお、上記酸化物薄膜２は、太陽電池素子１を有機エス
テル化金属（例えばチタン）の醋酸エステル溶液（Ｔｉ
Ｏ２ａ度約５チ）をはけ、スプレー等によって塗布した
後乾燥し、次いで、Ｎ２等の不活性ガスをキャリアガス
とするハロゲンガスの流通雰囲気中にセットし、１℃／
ｍｉｎ以下の極めてゆるやかな昇温速度で加熱し、所望
温度に保持した後徐冷し、次いで、所望温度の真空中で
加熱保持した後徐冷して形成する。なお、この酸（Ｉｓ
’物薄膜の材料としては、太陽電池素子に最も効果的に
作用する光成分を通す材料を使用し、或いは、前記酸化
物薄膜を屈折率の異なる材料から成る複数の層で構成し
、所望の光成分のみを太陽電池素子に作用させるように
するとよい。斯様にして有機エステル化金属を熱分解し
て生成した酸化物薄膜は、従来のコーテング薄膜に比し
て耐熱性が非常に冒く、従って、レンズ等によって集束
した高エネルギー密度の太陽光を照射することが可能と
なり、従って、太陽電池を小型化、高効率化し、太陽電
池にかかるコストを低廉化することが可能となる。Note that the oxide thin film 2 is formed by coating the solar cell element 1 with an acetic acid ester solution (Ti
After brushing and spraying with O2a (approx.
It is formed by heating at a very slow temperature increase rate of min. or less, maintaining it at a desired temperature, and then slowly cooling it, and then heating and maintaining it in a vacuum at the desired temperature, and then slowly cooling it. In addition, this acid (Is
As the material for the oxide thin film, a material that passes the light component that acts most effectively on the solar cell element is used, or the oxide thin film is composed of multiple layers made of materials with different refractive indexes, and the desired It is preferable to allow only the light component to act on the solar cell element. The oxide thin film produced by thermally decomposing organic esterified metals in this way has much lower heat resistance than conventional coating thin films, and therefore cannot absorb high energy density sunlight focused by lenses etc. Therefore, it becomes possible to make solar cells smaller and more efficient, and to reduce the cost of solar cells.
また、前述のように、本発明による太陽電池は、高エネ
ルギー密度の太陽光を照射し得るものであるが、高エネ
ルギー密度の太陽光を照射すれば、当然に、熱が発生す
るが、この熱は、太陽電池の裏側に設けられた高耐熱、
良熱伝導体の等方性黒鉛４によって効果的に放熱される
が、この放熱を更に効果的に行うには、第２図に示すよ
うに、等方性黒鉛４に穴５をあけておき、紋穴５に鋼管
、或いは、ヒートパイプ等を通すようにすれば、これら
鋼管或いはヒートパイプを通して効果的に放熱を行うこ
とができる。Furthermore, as mentioned above, the solar cell according to the present invention can irradiate sunlight with high energy density, but naturally heat is generated when irradiated with sunlight with high energy density. Heat is generated by a high heat resistant device installed on the back side of the solar cell.
Heat is effectively dissipated by the isotropic graphite 4, which is a good thermal conductor, but in order to make this heat dissipation even more effective, holes 5 are made in the isotropic graphite 4 as shown in Fig. 2. If a steel pipe, a heat pipe, or the like is passed through the hole 5, heat can be effectively radiated through the steel pipe or heat pipe.
第１図及び第２図は、それぞれ本発明による太陽電池の
実施例を説明するための側断面図である。
１ 太陽電池素子、２・・・酸化物薄膜、３・・・絶縁
層、４・・・等方性黒鉛、５・・・穴。
第１図
第２図FIGS. 1 and 2 are side sectional views for explaining embodiments of the solar cell according to the present invention, respectively. 1 Solar cell element, 2... Oxide thin film, 3... Insulating layer, 4... Isotropic graphite, 5... Hole. Figure 1 Figure 2
Claims (4)
解により生成した均一の酸化物薄膜を肩することを特徴
とする太陽電池。(1) A solar cell characterized by having a transparent and uniform oxide thin film produced by thermal decomposition of an organic esterified metal on its light-receiving surface.
Ｊ ｊｍ断又は熱線反射型の薄膜を構成していることを
特徴とする特許請求の範囲第（１）項に記載の太陽電池
。(2), the thin film has a multilayer structure of multiple layers, and the ultraviolet W
The solar cell according to claim (1), comprising a J jm insulation or heat ray reflective thin film.
とする太陽電池。(3) A solar cell characterized by integrally having isotropic graphite on the back surface.
解により生成した均一の酸化物薄膜を゛有し、裏面に等
方性黒鉛を一体的に有することをｖｊ徴とする太陽電池
○(4) A solar cell whose characteristic is that the light-receiving surface has a transparent and uniform oxide thin film produced by thermal decomposition of an organic esterified metal, and the back surface has isotropic graphite integrally.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56180762A JPS5882578A (en) | 1981-11-11 | 1981-11-11 | Solar cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56180762A JPS5882578A (en) | 1981-11-11 | 1981-11-11 | Solar cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5882578A true JPS5882578A (en) | 1983-05-18 |
Family
ID=16088874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56180762A Pending JPS5882578A (en) | 1981-11-11 | 1981-11-11 | Solar cell |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5882578A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6372869A (en) * | 1986-09-16 | 1988-04-02 | Nippon Steel Corp | Stainless steel foil having superior heat conductivity |
| JP2001108954A (en) * | 1999-10-05 | 2001-04-20 | Ibiden Co Ltd | Heating device for glass substrate for liquid crystal display board |
| WO2009018016A2 (en) * | 2007-07-30 | 2009-02-05 | Dow Global Technologies Inc. | Solar heat management in photovoltaic systems using phase change materials |
| KR101090119B1 (en) | 2010-09-27 | 2011-12-07 | 김민혁 | Solar photovoltaic module having graphite sheet |
| EP2416378A4 (en) * | 2009-03-31 | 2017-06-07 | LG Innotek Co., Ltd. | Solar photovoltaic power generation apparatus and manufacturing method thereof |
| CN110178584A (en) * | 2019-06-12 | 2019-08-30 | 江苏舜大新能源科技有限公司 | A kind of intelligent flowerpot with solar battery |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3999283A (en) * | 1975-06-11 | 1976-12-28 | Rca Corporation | Method of fabricating a photovoltaic device |
| JPS5326147A (en) * | 1976-08-20 | 1978-03-10 | Siemens Ag | Filter for light detector |
| JPS5465491A (en) * | 1977-11-04 | 1979-05-26 | Nippon Toki Kk | Method of forming reflection preventive membrane of solar battery |
-
1981
- 1981-11-11 JP JP56180762A patent/JPS5882578A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3999283A (en) * | 1975-06-11 | 1976-12-28 | Rca Corporation | Method of fabricating a photovoltaic device |
| JPS5326147A (en) * | 1976-08-20 | 1978-03-10 | Siemens Ag | Filter for light detector |
| JPS5465491A (en) * | 1977-11-04 | 1979-05-26 | Nippon Toki Kk | Method of forming reflection preventive membrane of solar battery |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6372869A (en) * | 1986-09-16 | 1988-04-02 | Nippon Steel Corp | Stainless steel foil having superior heat conductivity |
| JP2001108954A (en) * | 1999-10-05 | 2001-04-20 | Ibiden Co Ltd | Heating device for glass substrate for liquid crystal display board |
| WO2009018016A2 (en) * | 2007-07-30 | 2009-02-05 | Dow Global Technologies Inc. | Solar heat management in photovoltaic systems using phase change materials |
| WO2009018016A3 (en) * | 2007-07-30 | 2009-04-09 | Dow Global Technologies Inc | Solar heat management in photovoltaic systems using phase change materials |
| EP2416378A4 (en) * | 2009-03-31 | 2017-06-07 | LG Innotek Co., Ltd. | Solar photovoltaic power generation apparatus and manufacturing method thereof |
| KR101090119B1 (en) | 2010-09-27 | 2011-12-07 | 김민혁 | Solar photovoltaic module having graphite sheet |
| CN110178584A (en) * | 2019-06-12 | 2019-08-30 | 江苏舜大新能源科技有限公司 | A kind of intelligent flowerpot with solar battery |
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