JPS5854854B2 - ソウサケイヨリスイソカハンノウキオトリダスホウホウ - Google Patents
ソウサケイヨリスイソカハンノウキオトリダスホウホウInfo
- Publication number
- JPS5854854B2 JPS5854854B2 JP50048269A JP4826975A JPS5854854B2 JP S5854854 B2 JPS5854854 B2 JP S5854854B2 JP 50048269 A JP50048269 A JP 50048269A JP 4826975 A JP4826975 A JP 4826975A JP S5854854 B2 JPS5854854 B2 JP S5854854B2
- Authority
- JP
- Japan
- Prior art keywords
- reactor
- catalyst
- gas
- purge gas
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007789 gas Substances 0.000 claims description 74
- 239000003054 catalyst Substances 0.000 claims description 63
- 238000010926 purge Methods 0.000 claims description 46
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 42
- 239000001301 oxygen Substances 0.000 claims description 42
- 229910052760 oxygen Inorganic materials 0.000 claims description 42
- 239000001257 hydrogen Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 10
- 239000011261 inert gas Substances 0.000 claims description 9
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
- 239000003921 oil Substances 0.000 description 24
- 238000006477 desulfuration reaction Methods 0.000 description 19
- 230000023556 desulfurization Effects 0.000 description 19
- 229910052799 carbon Inorganic materials 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 14
- 239000003208 petroleum Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 description 12
- 238000011069 regeneration method Methods 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 11
- 150000002430 hydrocarbons Chemical class 0.000 description 11
- 230000028161 membrane depolarization Effects 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 10
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 230000008929 regeneration Effects 0.000 description 9
- 150000003464 sulfur compounds Chemical class 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000002184 metal Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000010909 process residue Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- -1 scale Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J33/00—Protection of catalysts, e.g. by coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Steering Control In Accordance With Driving Conditions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7405565,A NL184371C (nl) | 1974-04-25 | 1974-04-25 | Werkwijze voor het uit bedrijf nemen van een hydrogeneringsreactor, alsmede een werkwijze voor de katalytische hydrogenering van een zwavelverbindingen bevattende voeding. |
| NL7502315A NL7502315A (en) | 1975-02-27 | 1975-02-27 | Interrupting operation in catalytic hydrogenation reactors - by cooling purging and slowly introducing oxygen before opening |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS50154177A JPS50154177A (enrdf_load_stackoverflow) | 1975-12-11 |
| JPS5854854B2 true JPS5854854B2 (ja) | 1983-12-07 |
Family
ID=26644986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50048269A Expired JPS5854854B2 (ja) | 1974-04-25 | 1975-04-22 | ソウサケイヨリスイソカハンノウキオトリダスホウホウ |
Country Status (10)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3003185B1 (fr) | 2013-03-14 | 2016-06-03 | Air Liquide | Procede de traitement d'un reacteur catalytique |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1144863B (de) * | 1956-01-11 | 1963-03-07 | Exxon Research Engineering Co | Verfahren zur Regenerierung von molybdaenhaltigen Katalysatoren |
| US3033802A (en) * | 1959-05-22 | 1962-05-08 | Chemetron Corp | Stabilization of reduced metal catalyst and apparatus therefor |
| NL283488A (enrdf_load_stackoverflow) * | 1961-09-21 | |||
| BE757482R (fr) * | 1969-04-01 | 1971-03-16 | Chemetron Corp | Procede de production de catalyseurs oxyde de cuivre-oxyde de zinc reduits et stabilises pour la reaction de transformation du gaz a l'eau et nouveaux produits ainsi obtenus |
| NL7104842A (en) * | 1971-04-10 | 1972-10-12 | Passivating pyrophoric powder - by suspending in org liquid and treating with oxygen | |
| US3764558A (en) * | 1971-06-24 | 1973-10-09 | Sun Oil Co Pennsylvania | Constant low oxygen concentration gas regeneration of refining catalysts |
| US3838066A (en) * | 1971-10-01 | 1974-09-24 | Standard Oil Co | Method for stabilizing pyrophoric materials in a catalyst bed |
-
1975
- 1975-03-11 CA CA221,839A patent/CA1062641A/en not_active Expired
- 1975-04-21 IT IT22600/75A patent/IT1037563B/it active
- 1975-04-22 JP JP50048269A patent/JPS5854854B2/ja not_active Expired
- 1975-04-22 GB GB16588/75A patent/GB1508021A/en not_active Expired
- 1975-04-22 FR FR7512474A patent/FR2268859B1/fr not_active Expired
- 1975-04-22 SE SE7504666A patent/SE416817B/xx not_active IP Right Cessation
- 1975-04-22 DK DK172475A patent/DK172475A/da active IP Right Grant
- 1975-04-22 ES ES436838A patent/ES436838A1/es not_active Expired
- 1975-04-22 DE DE19752517869 patent/DE2517869A1/de active Granted
- 1975-04-22 NO NO751432A patent/NO146893C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO146893C (no) | 1982-12-29 |
| AU8034175A (en) | 1976-10-28 |
| ES436838A1 (es) | 1976-12-01 |
| NO751432L (enrdf_load_stackoverflow) | 1975-10-28 |
| FR2268859A1 (enrdf_load_stackoverflow) | 1975-11-21 |
| NO146893B (no) | 1982-09-20 |
| DK172475A (da) | 1975-10-26 |
| GB1508021A (en) | 1978-04-19 |
| DE2517869C2 (enrdf_load_stackoverflow) | 1988-02-18 |
| FR2268859B1 (enrdf_load_stackoverflow) | 1977-04-15 |
| CA1062641A (en) | 1979-09-18 |
| IT1037563B (it) | 1979-11-20 |
| SE416817B (sv) | 1981-02-09 |
| JPS50154177A (enrdf_load_stackoverflow) | 1975-12-11 |
| DE2517869A1 (de) | 1975-11-13 |
| SE7504666L (sv) | 1975-10-27 |
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