JPS5842636A - Resin composition - Google Patents
Resin compositionInfo
- Publication number
- JPS5842636A JPS5842636A JP14132781A JP14132781A JPS5842636A JP S5842636 A JPS5842636 A JP S5842636A JP 14132781 A JP14132781 A JP 14132781A JP 14132781 A JP14132781 A JP 14132781A JP S5842636 A JPS5842636 A JP S5842636A
- Authority
- JP
- Japan
- Prior art keywords
- specific resistance
- electric field
- carbon black
- liquid polyamide
- polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は電界緩和スリーブ、テープ用樹脂組成物に関す
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a resin composition for electric field mitigation sleeves and tapes.
高圧電カケ−プルの端末部や接続部に於て、高誘電率あ
るいは低固有抵抗を持ったいわゆる低インピーダンス材
料のスリーブやテープを用いて、これを電界集中部に覆
せることによってストレス緩和をおこない、端末部や接
続部をコンパクトにする検討が種々行なわれている。At the terminals and connections of high-voltage electrical cables, stress can be alleviated by using sleeves or tapes made of so-called low-impedance materials that have a high dielectric constant or low specific resistance, and cover the areas where the electric field is concentrated. Various studies are being conducted to make the terminal portion and the connecting portion more compact.
そしてこうした高誘電率あるいは低固有抵抗の材料とし
ては絶縁体ポリマーにカーボンブラック、金属粉、チタ
ン化合物等を添加した配合など種々なものが提案されて
いる。Various materials have been proposed as such materials having a high dielectric constant or low specific resistance, such as combinations of insulating polymers with carbon black, metal powder, titanium compounds, etc. added thereto.
しかし、従来のこれらの配合では電界解析の結果から最
も理想的な１０７〜ｌ ＱＩＯΩ−国の固有抵抗を持つ
材料が得られないという欠点があった。However, these conventional formulations have the disadvantage that a material having the most ideal resistivity of 107 to 1 QIO Ω cannot be obtained from the results of electric field analysis.
我々は種々の配合検討を行った結果、ポリオレフィン−
カーボンブラック系で１Ｑ１２〜ｌ ＱｌＢにした上に
液状ポリアミド化合物を追加することにより、電界解析
により理想的とされている固有抵抗１０”〜ｌ ＱＩＯ
Ω−譚の組成物が得られることを見出し、本発明を完成
した。As a result of various formulation studies, we found that polyolefin-
By adding a liquid polyamide compound to the carbon black-based 1Q12~l QlB, we have achieved a specific resistance of 10''~l QIO, which is considered ideal by electric field analysis.
It was discovered that a composition of Ω-tan can be obtained, and the present invention was completed.
実施例
第１表に示した配合でＩＢレシート作成シ、２ＭｅＶ加
速器により２ｏＭｒａｄ照射し、そのまま及び１６０°
Ｃ４日加熱後のサンプルについて誘電率及び固有抵抗の
測定を行った。Example IB receipts were created using the formulation shown in Table 1, irradiated with 20Mrad using a 2MeV accelerator, and used as is and at 160°.
The dielectric constant and specific resistance of the sample after heating for C4 days were measured.
結果は第２表に示しな通９であった。The results were 9 as shown in Table 2.
すなわち、比較例り、 Ｅ、 Ｆの様にエチレン酢ビ共
重合体にカーボンを追加するのみでは、固有抵抗が１０
７〜ＩＱＩＯの配合を得ることはできなかった。In other words, if only carbon was added to the ethylene-vinyl acetate copolymer as in Comparative Examples E and F, the specific resistance would be 10.
It was not possible to obtain a formulation of 7 to IQIO.
アセチレンブラック２０部添加のＤ配合は加熱なし、１
６０°Ｃ４日加熱後ともにｌ Ｑ１２で高すぎる。D formulation with 20 parts of acetylene black added: no heating, 1
After heating at 60°C for 4 days, l Q12 was too high.
ア七チレンブラック８０部添加のＥ配合は加熱なしだと
Ｉ Ｑ１０．１６０°Ｃ４日加熱後１０６以下と、性能
は非常に不六定であった。For formulation E containing 80 parts of a7ethylene black, the IQ was 10 without heating.IQ was 106 or less after heating for 4 days at 160°C, and the performance was very variable.
ア七チレンブラック４０部添加のＦ配合は加熱なし１０
６．１６０°Ｃ４日加熱後１０６以下と固有抵抗が低く
すぎる。F formulation with 40 parts of atylene black added is 10 without heating.
6. After heating at 160°C for 4 days, the specific resistance is 106 or less, which is too low.
カーボンブラックの種類をかえて種々検討したが、１０
７〜１０１Ｏの範囲は非常に不安定で、良好なものが得
られなかった。Various studies were conducted by changing the type of carbon black, but 10
The range of 7 to 101O was very unstable and good results could not be obtained.
金属粉末やチタン化合物の併用も検討したがやはり１０
７〜ｌ ＱＩＯのものは得られなかった。We also considered using metal powder and titanium compounds, but the result was still 10.
7-1 QIO was not obtained.
しかし、実施例Ａ、 Ｂ、 Ｃに示した如く、エチレン
酢ビ共重合体にカーボンブラックを２０部添加し更に液
状ポリアミド化合物を添加した、ものは、加熱なし、１
６０°Ｃ４日後ともに１０７〜１０１０で安定した性能
が得られた。However, as shown in Examples A, B, and C, in which 20 parts of carbon black was added to the ethylene vinyl acetate copolymer and a liquid polyamide compound was further added, no heating was performed, 1
Stable performance was obtained at 107 to 1010 after 4 days at 60°C.
電界解析によれば、１０７〜１０１Ｏの固有抵抗を持つ
材料であれば、電界の緩和状態が理想的でありこうした
材料によりスリーブやテープを作成して電界集中部に覆
せることにより、ケーブルの端末部や接続部をコンパク
トにすることが出来る。According to electric field analysis, a material with a specific resistance of 107 to 101 O provides ideal relaxation of the electric field, and by making sleeves or tapes from such materials and placing them over areas where the electric field is concentrated, cable terminals can be The parts and connections can be made more compact.
なお、ポリマーとしてはエチレン醋酸ビニル共重合体の
他に、エチレンエチルアクリレート、α−オレフィン重
合体、ポリブテン−１１エチレンプロピレンゴムなどを
用いてこれにカーボンブラックと液状ポリアミド化合物
を添加することにより、同様に固有抵抗が１０７〜ＩＱ
ＩＯΩ−ｍで安定な配合を得ることが出来た。In addition, in addition to ethylene vinyl acetate copolymer, ethylene ethyl acrylate, α-olefin polymer, polybutene-11 ethylene propylene rubber, etc. are used as the polymer, and carbon black and a liquid polyamide compound are added thereto. The specific resistance is 107~IQ
A stable formulation with IOΩ-m could be obtained.
第１表 配 合
本液状ポリアミド 日本ゼネラルミルズ化学■ 商品名
ネ＊ 液状ポリアミド 日本ゼネラルミルズ化学■ 商
品名＊＊＊ 液状ポリアミド ヘンケル日本■ 商品
名第２表 電気性能
５−Table 1 Compound Liquid polyamide Japan General Mills Chemical ■ Product name * Liquid polyamide Japan General Mills Chemical ■ Product name *** Liquid polyamide Henkel Japan ■ Product name Table 2 Electrical performance 5-
Claims (1)
合物とを添加することにより固有抵抗を１０７〜Ｉ Ｑ
ＩＯΩ−譚にしたことを特徴とする樹脂組成物。By adding carbon black and a liquid polyamide compound to polyolefin, the specific resistance can be increased from 107 to IQ.
A resin composition characterized by having IOΩ-tan.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14132781A JPS5842636A (en) | 1981-09-08 | 1981-09-08 | Resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14132781A JPS5842636A (en) | 1981-09-08 | 1981-09-08 | Resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5842636A true JPS5842636A (en) | 1983-03-12 |
Family
ID=15289351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14132781A Pending JPS5842636A (en) | 1981-09-08 | 1981-09-08 | Resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5842636A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63218830A (en) * | 1986-09-24 | 1988-09-12 | アメリカ合衆国 | Immediate frequency measuring system of heterodyne laser and measuring method thereof |
-
1981
- 1981-09-08 JP JP14132781A patent/JPS5842636A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63218830A (en) * | 1986-09-24 | 1988-09-12 | アメリカ合衆国 | Immediate frequency measuring system of heterodyne laser and measuring method thereof |
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