JPS5834849A - Resin composition - Google Patents
Resin compositionInfo
- Publication number
- JPS5834849A JPS5834849A JP13159581A JP13159581A JPS5834849A JP S5834849 A JPS5834849 A JP S5834849A JP 13159581 A JP13159581 A JP 13159581A JP 13159581 A JP13159581 A JP 13159581A JP S5834849 A JPS5834849 A JP S5834849A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- polycarbonate
- impact resistance
- polycarbonate resin
- polymethylpentene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011342 resin composition Substances 0.000 title description 6
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 10
- 239000004417 polycarbonate Substances 0.000 abstract description 10
- 229920000515 polycarbonate Polymers 0.000 abstract description 10
- 239000004431 polycarbonate resin Substances 0.000 abstract description 9
- 229920005668 polycarbonate resin Polymers 0.000 abstract description 9
- 239000011116 polymethylpentene Substances 0.000 abstract description 7
- 229920000306 polymethylpentene Polymers 0.000 abstract description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 6
- 229920000642 polymer Polymers 0.000 abstract description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 6
- -1 polyethylene Polymers 0.000 description 4
- 150000001491 aromatic compounds Chemical class 0.000 description 3
- 238000009863 impact test Methods 0.000 description 3
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003348 petrochemical agent Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- JMMZCWZIJXAGKW-UHFFFAOYSA-N 2-methylpent-2-ene Chemical compound CCC=C(C)C JMMZCWZIJXAGKW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000975394 Evechinus chloroticus Species 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- RMBGGQZGADTQLW-UHFFFAOYSA-N acetylene prop-1-ene Chemical group C#C.CC=C RMBGGQZGADTQLW-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 235000019463 artificial additive Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
本発＠ａ樹脂組成物に関する。さらに詳しくは、零連−
はポリカーボネート＃ｌｌ１ｒとポリメチルペｙデンよ
りなる機械的物性４ＩＫＩＴＩ＃ＩＩ寥性の優れた―脂
組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the @a resin composition. For more details, please refer to Zeroren-
relates to a fat composition with excellent mechanical properties 4IKITI#II consisting of polycarbonate #ll1r and polymethylpeyden.
ポジカーボネート樹脂は強靭で耐衝撃性１寸法安定性、
電気的譬性に優れ、しかも自己消火働でｈるために有用
なエンジ＆７リンダプツスチツタスとしてム範■ＥＩＩ
Ｊ！ｌされている。しかし、かかるボψカーボネート倒
履には、＃ＩＩＩｍ粘度が高く、成形加工性が晶いこと
、更に耐衝撃性にあっては成形品の厚さｋよる衝撃強度
依存性が高く１例えば！Ｌ２箇厚さく １／８’インチ
厚８）のフイゾットノツチ付衝撃値は延性破壊を示すの
に対し４４■厚さく１／１インチ厚さ）の場合には脆性
破壊を示し、厚さが厚い領域で衝撃強度が著しく低下す
るという問題がある。Positive carbonate resin is tough, impact resistant, dimensional stable,
EII has excellent electrical stability and is useful as an engine & 7 cylinder putty for self-extinguishing.
J! l has been used. However, such carbonate failure requires high #IIIm viscosity and excellent moldability, and furthermore, impact resistance is highly dependent on impact strength depending on the thickness k of the molded product. The impact value with a fissot notch for a thickness of L2 (1/8' inch) indicates ductile fracture, whereas for a thickness of 44 mm (1/1 inch), it indicates brittle fracture; There is a problem that the impact strength is significantly reduced.
そこで、これら衝撃強度の厚さ依存性や加工性を改良す
るために種々の提案がなされている。Therefore, various proposals have been made to improve the thickness dependence of impact strength and workability.
例えば特電８ｆ１４（ｔ−４５６６５号会報にはポリカ
ーボネートとポリエチレンとのブレンド＠層が。For example, Tokuden 8F14 (t-45665 newsletter) has a layer made of a blend of polycarbonate and polyethylene.
特電＠４０−１５６６４号会報にはポリカーボネートと
ポリプーピシン上のブレンド樹脂が、４１公昭４０−２
４１９１号会報にはポリカーボネートとエチンンープロ
ピレングーツタ共重合体とのブレンド樹脂が＊＊されて
いる。しかしながら、いずれのブレンド榔１１について
も耐衝撃性。The special electrician@40-15664 newsletter describes the blended resin on polycarbonate and polypoopicin,
Bulletin No. 4191 describes a blend resin of polycarbonate and ethyne-propylene gutta copolymer. However, both blends 11 have good impact resistance.
加工性が改良される面、荷重たわみ温度のような耐熱性
の低下が生ずる欠点があり、その用途が制限されている
。Although it improves processability, it has the drawback of decreasing heat resistance such as deflection temperature under load, which limits its use.
本発明者らは、前記蒼香族ポリカーボネート系複合１１
１ＪＩの聞厘点を解決すべく検討を加えた結果、４１定
割舎のポリメチルペンテンをポリカーボネート樹脂にブ
レンドするととｋより耐衝撃性、加工性は勿論のこと、
と（に荷重たわみ温度の高い樹脂組成物が得られること
を見い出し１本発明１１ｃＲ違した。The present inventors have discovered that the blue aromatic polycarbonate composite 11
As a result of our study to solve the problems with 1JI, we found that blending 41 Tewarisya's polymethylpentene with polycarbonate resin not only has better impact resistance and processability, but also
It was found that a resin composition having a high deflection temperature under load can be obtained by (1) and (1) of the present invention (11cR).
すなわち１本発明はポリカーボネ、−ト樹脂９０〜９９
重量部とボ替メチルペンテン１〜１０重量部よりなる樹
脂組成物である。That is, 1 the present invention uses polycarbonate resin 90-99
This is a resin composition consisting of 1 to 10 parts by weight of methylpentene and 1 to 10 parts by weight.
本発明の樹脂組成物は耐衡撃性と＜ Ｋ １／１インチ
厚さの衝撃強度が大巾に改良されているとともに、溶融
粘度が著しく低下しているので成形加工が容易であり、
しかも熱変形温度はボッカーボネート樹脂とはとんと変
わらない、従って耐熱性の制限を受けずに耐衡撃性を要
する用途に使用できる特徴を有している。The resin composition of the present invention has significantly improved impact resistance and < K 1/1 inch thickness impact strength, and has a significantly reduced melt viscosity, making it easy to process.
Furthermore, the heat distortion temperature is not much different from that of bocker carbonate resin, so it has the characteristic that it can be used in applications requiring equilibrium impact resistance without being subject to restrictions on heat resistance.
本発明に使用されるボッカーボネート樹脂とは、芳香族
ジヒドロキシ化合物とカーボネーＦ前駆体とをＳ液法或
いは溶融法で製造される芳香族ポジカーボネートである
。前記芳香Ｊｌ！ジヒドロキシ化合物の代表的な例を挙
げると次の過りである。ビスフェノールＡ（２，２−ビ
ス（４−１ドｐキシ７エエル）ブーパン）、ビスｃ４−
ヒトーキシ７エ品ル）メタン、２．２−ビス（４−ヒト
−キシ−５−メチル７エエル）プρパン、２，２−ビス
（４−＊トーキシー翫５−ジメチルフェニル）プッパソ
、２．２−ビス（４−に−ドｍキシー＆ｓ−ジブｗ Ａ
フェニル） ７’ ｇｓ パン、ビス（４−ヒト−キ
シフェニル）″？−ル７アイド、ビスｃ４−ヒト−キシ
フェニル）スルホン等が挙げられる。これらは単独で、
あるいは２種以上使用すること−できる。これらのうち
ビスＣ４−ヒト−キシ７エエル）アルカン類。The boccarbonate resin used in the present invention is an aromatic positive carbonate produced by an S liquid method or a melting method using an aromatic dihydroxy compound and a carbonate F precursor. Said fragrance Jl! Typical examples of dihydroxy compounds are as follows. Bisphenol A (2,2-bis(4-1dopxy7el)boupan), bisc4-
7-dimethylphenyl) methane, 2,2-bis(4-hydroxy-5-methyl-5-methyl)pan, 2,2-bis(4-*toxy-5-dimethylphenyl)pupaso, 2. 2-bis (4-ni-de m xie & s-jib w A
(phenyl) 7' gs pan, bis(4-human-xyphenyl)"-7-ido, bis(c4-human-xyphenyl) sulfone, etc. These include, alone,
Alternatively, two or more types can be used. Among these, bisC4-human-x7ethyl) alkanes.
ｑｌｉｋヒスフェノ゛−ルムが好ましい。The qlik hisphenomenon is preferred.
また前記カーボネーＦ曽厘体としてはカルボニルハライ
ド、カーボエールエステル属いは＾ρホルメート等いず
れであっても良い６代表的な例を挙げるとホスグ／、ジ
フェニルカーボネート、芳香族ジヒドロキシ化合物のジ
＾Ｗホルメート或いはそれらの混合物善が挙げられる・
好ましいポジカーボネート樹脂はビス（４−しド−キシ
７エエル）フルカン系、轡にビスフェノールＡを主原料
とする芳香族ポリカーボネートである。また、ポリカー
ボネート樹脂は。The carbonyl F derivative may be carbonyl halide, carbonyl ester, or ρ formate.6 Typical examples include phosg/, diphenyl carbonate, and di^W of aromatic dihydroxy compounds. Examples include formates or their mixtures.
Preferred positive carbonate resins are bis(4-doxy-7-ethyl)furcan-based aromatic polycarbonates containing bisphenol A as a main raw material. Also, polycarbonate resin.
多官能性芳香族化合物を共重合させた熱可麿性うンダ＾
分紋ポジカーボネートであってもよく。Thermoplastic powder made by copolymerizing polyfunctional aromatic compounds
It may also be made of positive carbonate.
また２種以上の芳香族ポリカーボネートを混合したもの
であってもよい。It may also be a mixture of two or more aromatic polycarbonates.
芳香族ポジカーボネートは１通常噛種以上の芳香族ジヒ
ドーキシ化合物Ｃ場合によっては更に多官能性芳香族化
合物を用いて）とホスゲンとから溶液法で、或いは１種
以上の芳香族ジヒドｇ−ｊｌ’シ化合物（場合によって
は更に多官能性芳香族化合物を用いて）とジフェニルカ
ーボネートとから溶融法で製造される。Aromatic positive carbonates can be prepared by a solution process from one or more aromatic dihydroxy compounds (usually using a polyfunctional aromatic compound in some cases) and phosgene, or from one or more aromatic dihydroxy compounds (C) and phosgene. It is produced by a melt method from a compound (optionally using a polyfunctional aromatic compound) and diphenyl carbonate.
本発明に使用されるボッカーボネート樹脂は。The bocker carbonate resin used in the present invention is:
通常１万〜１０万、好ましくは１５万〜５万の分子量を
有する。これらの分子量のポリカーボネートを製造する
に際し適当な分子量調節剤が使用されても良い、また反
応を促進するための触媒が使用されても良い。It usually has a molecular weight of 10,000 to 100,000, preferably 150,000 to 50,000. When producing polycarbonates having these molecular weights, an appropriate molecular weight regulator may be used, and a catalyst may also be used to promote the reaction.
本Ｊｌ明において用いられるポリメチルペンテンは４−
メチルペンテン−１のポリマーであって市販されている
ものでよいが、―磁流動性がポジカーボネート樹脂の骨
性に近いものが好ましい。The polymethylpentene used in this project is 4-
Commercially available methylpentene-1 polymers may be used, but those whose magnetic fluidity is close to that of positive carbonate resin are preferred.
ポリメチルペンテンは、ポリヵーボネーＦと１／／耐衝
撃性向上効果が顕著でなく、１０重景％を超えると耐熱
性の低下と耐衝撃性の向上効果が小さくなるので好まし
くない。Polymethylpentene is not preferable because it does not have a remarkable effect of improving impact resistance compared to polycarbonate F, and if it exceeds 10 weight percent, the heat resistance decreases and the effect of improving impact resistance becomes small.
本発明の樹脂組成物の製造は任意の方法で行なうことが
で會る。その方法として１ｇ４えばポリカーボネート樹
脂とポリメチルペンテンをタンブラ−で混合し、更に＃
出横に″ｃｍ！融混練する方法；あるいはパンパｖ４キ
ナー９−−ル啼で温蔵する方法等の混練方法によってブ
レンド樹脂をペレット化し、さらＥｌｌｌ細形する方法
があげられる。またボッカーボネート樹脂とポリメチル
ペンテンを混合したのち、直ＩＣＪ１ｊ＆ｌＪＩ！形機
で製品なｔｍする方法もある。The resin composition of the present invention can be produced by any method. The method is to mix 1g4 of polycarbonate resin and polymethylpentene in a tumbler, and then add #
The blended resin may be pelletized by a kneading method such as a method of melting and kneading, or a method of heating in a pampa v4 kina 9--l, and then further made into thin shapes. There is also a method of mixing the mixture with polymethylpentene and then producing the product directly using an ICJ1J&lJI!-forming machine.
本発明の樹層組成物には、更にその改質を目的として偽
の添加剤１例えばガラス鑵艙、カーボン毅艙の如き強化
剤、１ｍ安定剤、酸化防止剤。The tree layer composition of the present invention may further contain artificial additives 1, such as reinforcing agents such as glass crackers and carbon crackers, 1M stabilizers, and antioxidants, for the purpose of modifying the composition.
発泡剤、光安定剤、Ｓ燃温、可１Ｌ離璽剤。Foaming agent, light stabilizer, S fuel temperature, 1L release agent.
帯電防止剤、充填剤などを添加することができる。また
１例えばポリスチレン、ポリメチ廣メタタシレート、ム
ｓｓｔｍ、ムＢＳ樹脂、ポリエステル、ポリフェニン／
オキサイド等の他ｆ）４ＩＩＩ脂を１会することができ
る。Antistatic agents, fillers, etc. can be added. In addition, 1, for example, polystyrene, polymethyrometatasylate, musstm, mus BS resin, polyester, polyphenylene/
In addition to oxides, f) 4III fat can be added.
以下に本発明を実施例を以ってＩ！明する。The present invention will be described below with examples. I will clarify.
実施例１〜５及び比較例１〜２
ポリカーボネート樹脂（臂人化威−擬：パンライトＩ、
−１２２５）とポリメチルベンゾン（三井石油化学−１
１；ＩＩＴ−ｔ６）とを夫々所定の割合に針量しプレ／
グーで３０分１１１ＩｆｌＡ合した。ｌＩられた混合物
を５０−ベント付井出機（中央機械−Ｊｌ；Ｖ８に−５
０＞”Ｃ−１１１ｍしペレット化した。得られたペレッ
トを１２Ｄｔ：で乾燥したのち、射出威ｓＩｌにて１６
４ＷＸ１１７１１１ＸＡ１ａｍと６４ｍＸ１１７ｍＸ＆
！１５５ｍの２種の衝撃試験片および１２７肩Ｘ１１７
ｍＸ４５５■の荷重たわみ温度測定用試験片を作成した
。衝撃試験片はα２５ｍ１ｌのノツチを付けたのち、荷
重たわみ温度測定用試験片とともに温度２５’Ｃ。Examples 1 to 5 and Comparative Examples 1 to 2 Polycarbonate resin (Panlite I,
-1225) and polymethylbenzone (Mitsui Petrochemicals -1
1; IIT-t6) and the predetermined proportions respectively, and pre/
111IflA was combined with Goo for 30 minutes. The mixed mixture was transferred to a 50-vented well machine (Central Machinery-Jl; V8-5
0>"C-111m and pelletized. The obtained pellets were dried with 12Dt, and then pelletized with 16Dt.
4WX117111XA1am and 64mX117mX&
! 155m two types of impact test pieces and 127 shoulders x 117
A test piece for measuring deflection temperature under load of m×455× was prepared. The impact test piece was made with a notch of α25ml, and then heated to 25'C along with the test piece for measuring the deflection temperature under load.
湿度５０％にて２４時１ＩＪｌ＆瑠した。との旭瑠後衝
撃試験片を用いム８ＴＭ２５４ｅＣ従い衝撃強度を、ま
た荷重たわみ温度測定用試験片を用いム８ＴＭ６４８に
従い１＆４１＃／ｊの荷重下で荷重たわみ温度をそれで
れ測定した。その結果をＪ１１１真に示す、ここで、Ｉ
Ｉ撃強度は大きい１耐衝撃性が、また熱変形温度は高い
１耐熱性がそれぞれ優れていることを表わす。24 hours at 1 IJl & Rui at 50% humidity. The impact strength was measured according to Mu8TM254eC using the Asahiru post impact test piece, and the deflection temperature under load was measured under a load of 1 &41#/j using the test piece for measuring the deflection temperature under load according to Mu8TM648. The result is shown in J111, where I
A high impact strength (1) indicates excellent impact resistance, and a high heat distortion temperature (1) indicates excellent heat resistance.
また比較のため上記実施例１〜！１のポリメチルベンゾ
ンを用いない場合およびその代９にポリスチレン（新大
Ｓ＊石油化学−属；中蕩ポジエチレン７５００）を用い
た場合の結果を第１１！に＠せて示す。Also, for comparison, Example 1~! 11th shows the results when polymethylbenzone (1) is not used and when polystyrene (Shindai S*Petrochemicals - Group; Nakafu Posiethylene 7500) is used as the substitute (9). Indicate by @.
菖１表Iris 1 table
Claims (1)
／テン１〜１０重量部よりなる樹脂龜威物。PoV carbonate resin 90-9! A resin shell consisting of 1 to 10 parts by weight of 1 to 10 parts by weight and Boshimethylpe/tene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13159581A JPS5834849A (en) | 1981-08-24 | 1981-08-24 | Resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13159581A JPS5834849A (en) | 1981-08-24 | 1981-08-24 | Resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5834849A true JPS5834849A (en) | 1983-03-01 |
Family
ID=15061725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13159581A Pending JPS5834849A (en) | 1981-08-24 | 1981-08-24 | Resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5834849A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4548991A (en) * | 1983-05-09 | 1985-10-22 | The Dow Chemical Company | Blends of polycarbonate or polyestercarbonate with 4-methyl-1-pentene polymers |
| US4704432A (en) * | 1983-05-09 | 1987-11-03 | The Dow Chemical Company | Blends of polyestercarbonate with 4-methyl-1-pentene polymers |
| US4837277A (en) * | 1986-12-16 | 1989-06-06 | Mitsui Petrochemical Industries, Ltd. | Poly(4-methyl-1-pentane) composition and articles molded therefrom |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50158646A (en) * | 1974-06-13 | 1975-12-22 |
-
1981
- 1981-08-24 JP JP13159581A patent/JPS5834849A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50158646A (en) * | 1974-06-13 | 1975-12-22 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4548991A (en) * | 1983-05-09 | 1985-10-22 | The Dow Chemical Company | Blends of polycarbonate or polyestercarbonate with 4-methyl-1-pentene polymers |
| US4704432A (en) * | 1983-05-09 | 1987-11-03 | The Dow Chemical Company | Blends of polyestercarbonate with 4-methyl-1-pentene polymers |
| US4837277A (en) * | 1986-12-16 | 1989-06-06 | Mitsui Petrochemical Industries, Ltd. | Poly(4-methyl-1-pentane) composition and articles molded therefrom |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3217787B2 (en) | Multi-component polyester / polycarbonate blend with improved impact strength and processability | |
| TW500765B (en) | Thermoplastic resin composition and heat-resistant tray for IC | |
| US3933941A (en) | Thermoplastic blended composition comprising polyphenylene ether, aromatic polycarbonate and styrene resin | |
| JPH0475259B2 (en) | ||
| US4739001A (en) | Rubber-modified styrene resin composition | |
| JP2005112994A (en) | Thermoplastic resin composition | |
| JPS61500667A (en) | Color stabilizing composition and method of stabilizing polycarbonate-polyester compositions | |
| JPS5834849A (en) | Resin composition | |
| JPS60149656A (en) | Resin composition | |
| EP0535785A1 (en) | Flame retardant blends of polysulfone with polycarbonate and/or polyalkylene phthalate | |
| JPH0420026B2 (en) | ||
| JPH0245659B2 (en) | ||
| JP2977261B2 (en) | Resin composition | |
| JPH05156141A (en) | Molded polyester article and its preparation | |
| JPS6212939B2 (en) | ||
| JP2597668B2 (en) | Flame retardant polyester composition | |
| JPH041028B2 (en) | ||
| JPS601340B2 (en) | resin composition | |
| JP3380072B2 (en) | Reinforced aromatic polycarbonate resin composition excellent in fluidity and molded article | |
| JP5144426B2 (en) | Flame retardant resin composition and method for producing the same | |
| JPS6212816B2 (en) | ||
| US20040122171A1 (en) | Hydrolysis resistant polyesters and articles made therefrom | |
| JP2000143949A (en) | Polyester elastomer composition | |
| JPH02199143A (en) | Thermoplastic resin composition | |
| KR20210067104A (en) | Flame retardant polycarbonate and copolyester alloy resin composition with improved transparency and chemical resistance |