JPS582350A - Electrically conductive transparent resin - Google Patents

Electrically conductive transparent resin

Info

Publication number
JPS582350A
JPS582350A JP10097981A JP10097981A JPS582350A JP S582350 A JPS582350 A JP S582350A JP 10097981 A JP10097981 A JP 10097981A JP 10097981 A JP10097981 A JP 10097981A JP S582350 A JPS582350 A JP S582350A
Authority
JP
Japan
Prior art keywords
titanium oxide
electrically conductive
conductive transparent
antistatic
transparent conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10097981A
Other languages
Japanese (ja)
Inventor
Masaru Itakura
板倉 優
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KENEE KK
Original Assignee
KENEE KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KENEE KK filed Critical KENEE KK
Priority to JP10097981A priority Critical patent/JPS582350A/en
Publication of JPS582350A publication Critical patent/JPS582350A/en
Pending legal-status Critical Current

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  • Compositions Of Macromolecular Compounds (AREA)
  • Conductive Materials (AREA)

Abstract

PURPOSE:To obtain the titled colorable resin having stable electrical resistance and dry surface, effective for the antistatic treatment, and suitable as the antistatic parts of IC, etc., by compounding titanium oxide etc. to a plastic base. CONSTITUTION:A plastic matrix is compounded with a proper amount of an electrically conductive transparent particles, e.g. granular or acicular particles of titanium oxide having a diameter of 0.1mu and treated at 1,200 deg.C. Addition of 3% titanium oxide gives antistaticity without lowering the transparency of the original resin.

Description

【発明の詳細な説明】 この発明は、帯電防止VC肩効な透明導電樹脂に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a transparent conductive resin that is effective as an antistatic VC.

一般に合成樹脂a電気抵抗が非常VC高く、静電気を帯
電しやすい欠点がある。
In general, synthetic resin a has a very high electrical resistance (VC) and has the drawback of being easily charged with static electricity.

従来、帯電防止プラスチックとしてaグラハイドカーボ
ン混入グラスチックが知らnている。こrtrr高分子
高分子カーボンタグラスチック母材〜28%混入するこ
とVCJり電気抵抗値としてtoe〜108Ω/jの帯
電防止ツーラスチックとして製造されている。しかしな
がら、このカーホン人プラスチックa静亀気の発生防止
効果に丁ぐれているがカーボンの脱落に29汚nの原因
になっていた9、カーボンブラックで不透明な上、黒色
が工場I#理上嫌られn−る傾向にある。
Conventionally, a graphite carbon-containing glasstic is known as an antistatic plastic. This rtrr polymeric polymer carbon taglastic base material is mixed at ~28% and is manufactured as an antistatic toolastic with an electrical resistance value of toe ~108 Ω/j. However, although this carbon black plastic has an excellent effect of preventing the generation of static air, it causes 29 pollution due to the carbon falling off. There is a tendency for people to lose weight.

また、市販されている帯電防止剤入プラスチックに、動
物性脂肪からグリセリンを除去したBa肪酸系界面活性
剤tプラスチック[5〜IO%/i人すると、界面活性
剤の慟らきICjり、プラスチック表面に大気中の水分
を吸着して109〜1011Ω/1の抵抗を示し、静電
気の?4f亀を防止する効果が得らnl、透明度は乳白
色で完全とにいえないが層色剤でカラフルvc&!造す
ることができるものである。しか[、なから界面活性剤
の欠点として水分以外の汚れが吸者され□て表面が汚れ
や丁く、べとつき感が生じて工場雷埋上嫌われる点か多
い。また大気中の湿質条件vc、xv抵抗値が不安定で
ある等の欠点があった。
In addition, commercially available antistatic agent-containing plastics are supplemented with Ba fatty acid-based surfactant plastics made by removing glycerin from animal fat [5 to IO%/i]. The surface adsorbs moisture in the atmosphere and exhibits a resistance of 109 to 1011 Ω/1, reducing static electricity. The effect of preventing 4F tortoise is obtained.The transparency is milky white and not perfect, but the layer colorant makes it colorful VC&! It is something that can be built. However, one of the disadvantages of surfactants is that they absorb dirt other than moisture, leaving the surface with a dirty, sticky, and sticky feel, which is why many people dislike it when they are buried in factories. Further, there were drawbacks such as unstable humidity conditions in the atmosphere, such as unstable vc and xv resistance values.

この発明に上述した従来の欠点上改善するためになされ
たものであり、殊に抵抗値が安定し、表。
This invention was made to improve the above-mentioned conventional drawbacks, and in particular, the resistance value is stabilized.

面aサラサラしておV、透明で着色可能な透明導電樹脂
を提供するものである。。
The present invention provides a transparent conductive resin that is smooth on surface A, transparent, and colorable. .

以下、この発明にXる一笑施りllk夷験結果にもとづ
V)て具体的に曲、明する。
Hereinafter, the details will be explained based on the experimental results of this invention.

まず、この発明VCxる透明導電樹脂(C,S。First, the transparent conductive resin (C, S) of this invention VCx.

ポリマー)に、プラスチックの母材に透明導電粒子を適
当目配合するととVcxo、笛、気抵抗を低くし、更V
C粒子の働らきtrcxv、自己放電ケ起させて帯電防
止に有効な材料としたものである。
By adding appropriate amount of transparent conductive particles to the plastic base material (polymer), Vcxo, whistle, and air resistance can be lowered and Vcxo can be lowered.
The action of C particles is to cause self-discharge, making it an effective material for preventing static electricity.

上記透明導電粒子の添カロ剤に、しUえば酸化チタン(
’I’i02 )で0.1μの球状、針状粒子で120
0℃の処8itしたものであり、樹1信表面で放電r多
発し、3%混入で光分な透明性葡有し帯電を防止する。
If you add titanium oxide (
'I'i02) is 0.1μ spherical, acicular particle is 120
It was heated to 8 liters at 0°C, and many discharges occurred on the surface of the tree, and when it was mixed in at 3%, it became transparent enough to absorb light and prevents charging.

上述したx’;tvc製造された透明導電樹脂は、減衰
効果1丁なわち静電気を強制帯電し、シンクロスコープ
で帯電瀘が半分になるに要する時間ぽ殊に丁ぐ几でおり
、この減衰効果に、ざ〉加粒子の細かさと慴度汁布の多
さVCよるものである。
The transparent conductive resin manufactured by x';tvc mentioned above has one damping effect, that is, it forcibly charges static electricity, and the time required for the charging filter to be halved using a synchroscope is particularly effective. This is due to the fineness of the particles and the amount of liquid VC.

一般にIlp屯気の放電Jl[α単位面積当りの導電粒
子の数に目米倍するといわn5、静電気除去器具の場合
除v!L性能として良く知られている現象である。
In general, it is said that the discharge of Ilp air Jl [α is multiplied by the number of conductive particles per unit area n5, excluding the case of static electricity removal equipment v! This is a phenomenon well known as L performance.

添付の第1図は粒子の大きざとJ↑1位面積当り混入の
場合の減衰効果の比較図で69、ムはこの発明にIる母
材に添加剤として透明導電粒子tm人して21121厚
[成形した透明導電樹脂、Bぼ添加剤としてl&J粒子
のアルミ粉末を混入して1−厚に成形したもの、Ca添
加剤として2磯粒子のアルミ粉末を混入して2刷厚に成
形したものである。
The attached Figure 1 is a comparison diagram of the attenuation effect when mixed with the size of the particles and J↑1 area. [Molded transparent conductive resin, molded to 1-thickness by mixing L&J particle aluminum powder as B additive, and molded to 2-thickness by mixing 2-Iso particle aluminum powder as Ca additive It is.

なお、l OKV強制帯電[jる半減JtJJ?rシン
クロスコープで測定したta会であり、この時の気温a
25℃、湿度は50%であった。
In addition, l OKV forced charging [jru halved JtJJ? This is the ta meeting measured with a synchroscope, and the temperature a at this time is
The temperature was 25°C and the humidity was 50%.

ここでこの発明にIる透明導電樹脂に用いられる母材と
抵抗と半減期に下記の表に示したIうになっている。
Here, the base material, resistance, and half-life used in the transparent conductive resin according to the present invention are as shown in the table below.

〈表〉 以上詳細に説明したIうに、この発明にIる透明導電a
4脂F′X1電気抵抗値がlO〜lOΩの範囲で安定し
た領を示し、長期間効果を持続するとともに透明で着色
が可能であるから、B1望の着色を施丁ことvcxす、
カラフルなグラスチックの製造ができる。
<Table> As explained in detail above, the transparent conductive material according to the present invention
4-fat F'
You can make colorful glass sticks.

従って、この発明Vcxる帯電防止効果の丁ぐn。Therefore, the antistatic effect of this invention is very low.

た透明導電樹脂rxIo、マガジン、IO用トレー等の
帯電防止部品、半導体関係の梱包及び収納容器、帯電防
止袋、医療機器、精密機器、自動車内装品、或いはあら
ゆる防塵を要する部品等、多用途に使用範囲が拡大さn
る。
Widely used for antistatic parts such as transparent conductive resin rxIo, magazines, IO trays, semiconductor-related packaging and storage containers, antistatic bags, medical equipment, precision instruments, automobile interior parts, and all kinds of parts that require dustproofing. Expanded range of use
Ru.

【図面の簡単な説明】[Brief explanation of drawings]

添付した第1図に、添加剤の粒子の大きざと単位面積当
Dα人の場合の減衰効果の比較図である。 特許出願人 株式会社ケンニー 代理人 升埋士 佐 腰 英 餡 一5= +ff プ/ (a
The attached FIG. 1 is a comparison diagram of the attenuation effect in the case of additive particle size and Dα per unit area. Patent Applicant Kenney Co., Ltd. Agent Masuji Eiji Sakoshi Anichi 5= +ff pu/ (a

Claims (1)

【特許請求の範囲】[Claims] 所定の母材である樹脂に酸化チタン等の透明導電粒子の
添加剤を適当倉配合すること[jl)製造さnた透明導
電樹脂。
A transparent conductive resin is produced by suitably blending an additive such as a transparent conductive particle such as titanium oxide into a predetermined base material resin.
JP10097981A 1981-06-29 1981-06-29 Electrically conductive transparent resin Pending JPS582350A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10097981A JPS582350A (en) 1981-06-29 1981-06-29 Electrically conductive transparent resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10097981A JPS582350A (en) 1981-06-29 1981-06-29 Electrically conductive transparent resin

Publications (1)

Publication Number Publication Date
JPS582350A true JPS582350A (en) 1983-01-07

Family

ID=14288456

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10097981A Pending JPS582350A (en) 1981-06-29 1981-06-29 Electrically conductive transparent resin

Country Status (1)

Country Link
JP (1) JPS582350A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63175951U (en) * 1987-05-01 1988-11-15
US5929733A (en) * 1993-07-21 1999-07-27 Nagano Japan Radio Co., Ltd. Multi-layer printed substrate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63175951U (en) * 1987-05-01 1988-11-15
US5929733A (en) * 1993-07-21 1999-07-27 Nagano Japan Radio Co., Ltd. Multi-layer printed substrate

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