JPS58223481A - Method for controlling ph of tap water - Google Patents

Method for controlling ph of tap water

Info

Publication number
JPS58223481A
JPS58223481A JP10656482A JP10656482A JPS58223481A JP S58223481 A JPS58223481 A JP S58223481A JP 10656482 A JP10656482 A JP 10656482A JP 10656482 A JP10656482 A JP 10656482A JP S58223481 A JPS58223481 A JP S58223481A
Authority
JP
Japan
Prior art keywords
slaked lime
water
dissolution tank
tank
dissolved
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10656482A
Other languages
Japanese (ja)
Other versions
JPS6223634B2 (en
Inventor
Isao Funahashi
舟橋 勲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KUREHA KAKOKI KK
Kureha Corp
Original Assignee
KUREHA KAKOKI KK
Kureha Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KUREHA KAKOKI KK, Kureha Corp filed Critical KUREHA KAKOKI KK
Priority to JP10656482A priority Critical patent/JPS58223481A/en
Publication of JPS58223481A publication Critical patent/JPS58223481A/en
Publication of JPS6223634B2 publication Critical patent/JPS6223634B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F15/00Other methods of preventing corrosion or incrustation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)

Abstract

PURPOSE:To control the pH of water of waterworks, by supplying water to the 1st dissolution tank until >=80wt% the supplied slaked lime is dissolved, removing the soln. therefrom, transferring the undissolved slaked lime into the 2nd dissolution tank, controlling the pH thereof to <=10 and supplying the soln. continuously to a trough. CONSTITUTION:Slaked lime of the amt. corresponding to the consumption in continuous operation of, for example, two days, is charged beforehand into the 1st dissolution tank 1, and water is introduced continuously therein from a supply pipe 3. The slaked like is dissolved under stirring and the approximately satd. aq. slaked lime soln. is removed from an outflow pipe 4. Slaked lime charged beforehand into the tank 1 is dissolved with <=80wt% thereof and to the extent that the pH of the outflow liquid does not decrease down to 12 or below. The undissolved slaked lime in the tank 1 is transferred in the form of slurry into the 2nd dissolution tank 2, where water is introduced continuously from a water supply pipe 5 and the aq. slaked lime soln. of <=10pH is obtd. from an outflow pipe 6. The aq. slaked lime solns. to be flowed from the 1st dissolution tank and the 2nd dissolution tank are supplied to a trough 7, whereby the pH of tap water is controlled.

Description

【発明の詳細な説明】 本発明は消石灰による上水道水のpH調整する方法に関
する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for adjusting the pH of tap water using slaked lime.

従来上水道において、管路に錆などが生じ赤水を生ずる
ことがあり、その防止が必要となっている。また水道施
設経費の大部分を占める管路の寿命は場所によってまち
まちであり、80年近く使用しても殆んど錆の生じない
ところもあれば、一方わずか2年はどで管路を交換せね
ばならない所もある。このよ5な管路の耐久性の相異は
水道水の水質によるもので、アルカリ度が高く腐蝕性の
小さい水はど管路の寿命が長いことが知られている。
Conventionally, in water supply systems, rust has sometimes formed in pipes, resulting in red water, and it is necessary to prevent this. Furthermore, the lifespan of pipes, which account for the majority of water facility costs, varies depending on the location, with some places showing almost no rust even after nearly 80 years of use, while others require replacement after just two years. There are some things you have to do. The difference in durability of these five types of pipes is due to the quality of tap water, and it is known that water pipes with high alkalinity and low corrosivity have a long lifespan.

管路の寿命を延ばし、水道水の赤水を防止するためには
水道水のpHを調整することが必要であり、このため苛
性ソーダ、ソーダ灰、消石灰などの注入が行なわれてお
り、最近では取扱いが容易であるとの理由から苛性ソー
ダが多く使われている。しかし苛性ソーダが単に7)H
調整機能しか有しないのに対し、消石灰を使用するとき
は管壁に炭酸カルシウムの被膜をつくり、管路の腐蝕を
防止する機能をも有することで消石灰の使用がよ5り望
ましいものである。
In order to extend the life of pipes and prevent red water from forming in tap water, it is necessary to adjust the pH of tap water, and for this purpose injection of caustic soda, soda ash, slaked lime, etc. Caustic soda is often used because it is easy to use. However, caustic soda is simply 7)H
While slaked lime only has an adjustment function, it is more desirable to use slaked lime because it also has the function of forming a calcium carbonate film on the pipe wall and preventing corrosion of the pipe.

pH調整のため消石灰を水道水に注入する方法としては
粉体注入法、スラリー注入法、溶液注入法があるが、粉
体注入は粉じんの問題や定量注入の難しさがあり、又ス
ラリー注入はスラリー濃度により違いもあるが、ストッ
クタンク内や配管内にスケーリングを生じ操作しずらく
なる。これに対し溶液注入は消石灰を溶解槽内で連続的
に溶解流出させる方法で流体移送上極めて優れている。
There are powder injection methods, slurry injection methods, and solution injection methods for injecting slaked lime into tap water to adjust pH, but powder injection has problems with dust and difficulty in quantitative injection, and slurry injection has problems. Although it varies depending on the slurry concentration, it causes scaling inside the stock tank and piping, making it difficult to operate. On the other hand, solution injection is a method in which slaked lime is continuously dissolved and discharged in a dissolution tank, and is extremely superior in terms of fluid transfer.

しかしこの溶液注入法では不溶解物が溶解構内に残り、
この不溶解物の処理に問題があった。
However, with this solution injection method, undissolved substances remain in the dissolution chamber,
There was a problem in processing this insoluble matter.

本発明者等はこの残存不溶物について検討した結果その
成分は消石灰が原水中の炭酸等と反応して生成した炭酸
力ルクウムと、この炭酸カルシウムの存在により溶解す
ることを妨げられた消石灰であること、又このものは溶
解槽内において流出消石灰水溶液のpHが12〜13に
維持されている間は殆んど溶解しないこと、更には溶解
させるためには非常に長時間を要することを知った。
The present inventors investigated this residual insoluble material and found that its components are carbonic acid produced by the reaction of slaked lime with carbonic acid, etc. in raw water, and slaked lime that is prevented from dissolving due to the presence of this calcium carbonate. In addition, I learned that this substance hardly dissolves while the pH of the slaked lime aqueous solution is maintained at 12 to 13 in the dissolution tank, and furthermore, it takes a very long time to dissolve it. .

そこで本発明者等は消石灰を完全利用を行い、即ち未溶
解のカルシウム化合物を残すことなく、かつ水道水のp
HH整を安定して行ない得る方法について検討して本発
明に達した。
Therefore, the present inventors have made full use of slaked lime, that is, without leaving any undissolved calcium compounds, and have
The present invention was achieved by studying a method for stably performing HH adjustment.

本発明は消石灰粉体の溶解槽と該溶解槽での未溶解分を
更に溶解させる溶解槽とを設け、第1の溶解槽で予め仕
込んだ消石灰の80重量−以上を溶解させるまで該溶解
槽に水を供給しつつ消石灰略飽和水溶液を取り出した後
、未溶解分を第2の溶解槽に移し、この槽に水を供給し
つつ溶解させてpH10以下の消石灰水溶液を連続的に
取り出し、両溶解槽より得た消石灰水溶液を連続的に着
水井に供給する水道水のPH調整方法である。
The present invention is provided with a dissolving tank for slaked lime powder and a dissolving tank for further dissolving the undissolved content in the dissolving tank, and the dissolving tank is used until at least 80 weight of the slaked lime charged in advance in the first dissolving tank is dissolved. After taking out a roughly saturated aqueous solution of slaked lime while supplying water, the undissolved portion is transferred to a second dissolution tank, and dissolved while supplying water to this tank, and a slaked lime aqueous solution with a pH of 10 or less is continuously taken out. This is a method for adjusting the pH of tap water by continuously supplying a slaked lime aqueous solution obtained from a dissolution tank to a receiving well.

次に附図により本発明を具体的に説明する。Next, the present invention will be specifically explained with reference to the accompanying drawings.

附図において1は第1の溶解槽、2は第2の溶解槽であ
り、両溶解槽は内部に攪拌機を有し、原水は第1の檜で
は槽下部より第2の槽では下部又は上面より供給し、消
石灰水溶液は上部より取り出すよう構成されている。こ
の第1の溶解槽に予め例えば2日間連続運転する相当量
の消石灰を投入し、下部の給水管3より水を連続的に導
入し、ゆるやかな攪拌下に消石灰を溶解させ略飽和の消
石灰水溶液を上部の流出管4より取り出す。この第1の
溶解槽では予め投入した消石灰の80重貴チ以下、流出
液のPHが12を割らない程度に溶解させる。第1の溶
解槽での未溶解分はスラリー状で第2の溶解槽に移し水
を給水管5より連続的に導入し、流出管6よりp)(1
0以下の消石灰水溶液が得られる。第1及び第2の溶解
槽より流出する消石灰水溶液は着水井Tに送られ水道水
のPK調整に供される。
In the attached diagram, 1 is the first dissolving tank, and 2 is the second dissolving tank. Both dissolving tanks have a stirrer inside, and the raw water is poured from the bottom of the tank in the first tank and from the bottom or top in the second tank. The slaked lime aqueous solution is taken out from the top. A considerable amount of slaked lime for continuous operation, for example, for two days, is charged into this first dissolution tank in advance, and water is continuously introduced from the water supply pipe 3 at the bottom, and the slaked lime is dissolved under gentle stirring to obtain a substantially saturated slaked lime aqueous solution. is taken out from the upper outflow pipe 4. In this first dissolving tank, the slaked lime charged in advance is dissolved to an extent of 80% or less and the pH of the effluent does not fall below 12. The undissolved content in the first dissolution tank is transferred to the second dissolution tank in the form of slurry, water is continuously introduced from the water supply pipe 5, and water is continuously introduced from the outflow pipe 6 (p) (1
A slaked lime aqueous solution with a concentration of 0 or less is obtained. The slaked lime aqueous solution flowing out from the first and second dissolution tanks is sent to the receiving well T and is used for PK adjustment of tap water.

同第1の溶解槽の未溶解分は一度に第2の溶解槽に移し
、第2の溶解槽に水のみを連続的に導入する如く運転し
てもよいが、他の態様としては第1の溶解槽の未溶解分
は一旦スドックタンク8に貯め、第2の溶解槽ヘボンプ
9により定量的に連続的に供給してもよい。
The undissolved content in the first dissolution tank may be transferred to the second dissolution tank at once, and the operation may be performed so that only water is continuously introduced into the second dissolution tank, but in another embodiment, the first The undissolved content in the dissolution tank may be temporarily stored in the sudock tank 8 and then quantitatively and continuously supplied to the second dissolution tank by the pump 9.

本発明の実施に際しては第1の溶解槽と第2の溶解槽と
は並行しズ運転され、略一定pHの消石灰水溶液が連続
的定量的に得られ、水道水の7)H調整が安定して行い
得る。
When carrying out the present invention, the first dissolution tank and the second dissolution tank are operated in parallel, so that a slaked lime aqueous solution with a substantially constant pH is obtained continuously and quantitatively, and the 7) H adjustment of tap water is stabilized. It can be done by

【図面の簡単な説明】[Brief explanation of drawings]

附図は本発明の実施に用いる装置の1例を示す。 1・・・第1の溶解槽、2・・・第2の溶解槽、3゜5
・・・給水管、4,6・・・流出管、7・・・着水井、
8・・・ストックタンク、9・・・ポンプ。
The accompanying drawing shows an example of an apparatus used to carry out the present invention. 1...First dissolution tank, 2...Second dissolution tank, 3゜5
... Water supply pipe, 4, 6 ... Outflow pipe, 7 ... Water landing well,
8...Stock tank, 9...Pump.

Claims (1)

【特許請求の範囲】[Claims] 消石灰の略飽和水溶液の注入により水道水のpHを調整
する方法において、第1溶解槽で供給消石灰の80重量
%以上を溶解させるまで核種に水を供給しつつ、消石灰
略飽和水溶液を取り出した後未溶解分を第2溶解槽に移
し核種に水を供給しつつ溶解させてpH10以下の消石
灰水溶液とし、両浴解槽より得た消石灰水溶液を連続的
に着水井に供給することを特徴とする水道水のpIi調
整方法。
In a method of adjusting the pH of tap water by injecting a substantially saturated aqueous solution of slaked lime, water is supplied to the nuclide until 80% by weight or more of the supplied slaked lime is dissolved in the first dissolution tank, and after the substantially saturated aqueous solution of slaked lime is taken out. The undissolved content is transferred to a second dissolution tank and dissolved while supplying water to the nuclide to form a slaked lime aqueous solution with a pH of 10 or less, and the slaked lime aqueous solution obtained from both bath dissolution tanks is continuously supplied to the receiving well. How to adjust the pIi of tap water.
JP10656482A 1982-06-21 1982-06-21 Method for controlling ph of tap water Granted JPS58223481A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10656482A JPS58223481A (en) 1982-06-21 1982-06-21 Method for controlling ph of tap water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10656482A JPS58223481A (en) 1982-06-21 1982-06-21 Method for controlling ph of tap water

Publications (2)

Publication Number Publication Date
JPS58223481A true JPS58223481A (en) 1983-12-26
JPS6223634B2 JPS6223634B2 (en) 1987-05-25

Family

ID=14436783

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10656482A Granted JPS58223481A (en) 1982-06-21 1982-06-21 Method for controlling ph of tap water

Country Status (1)

Country Link
JP (1) JPS58223481A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6434490A (en) * 1987-07-28 1989-02-03 Yoshinori Yasuda Mineral liquid and manufacture thereof
EP0536908B1 (en) * 1991-10-09 1996-02-14 Kureha Kagaku Kogyo Kabushiki Kaisha Method of improving city water and an apparatus therefor

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01168231U (en) * 1988-05-20 1989-11-27
JPH01168230U (en) * 1988-05-20 1989-11-27

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6434490A (en) * 1987-07-28 1989-02-03 Yoshinori Yasuda Mineral liquid and manufacture thereof
JPH0470956B2 (en) * 1987-07-28 1992-11-12 Yoshinori Yasuda
EP0536908B1 (en) * 1991-10-09 1996-02-14 Kureha Kagaku Kogyo Kabushiki Kaisha Method of improving city water and an apparatus therefor

Also Published As

Publication number Publication date
JPS6223634B2 (en) 1987-05-25

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