JPS58142893A - Optical information recording medium - Google Patents

Optical information recording medium

Info

Publication number
JPS58142893A
JPS58142893A JP57024314A JP2431482A JPS58142893A JP S58142893 A JPS58142893 A JP S58142893A JP 57024314 A JP57024314 A JP 57024314A JP 2431482 A JP2431482 A JP 2431482A JP S58142893 A JPS58142893 A JP S58142893A
Authority
JP
Japan
Prior art keywords
recording medium
sealed
optical information
air
recording
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57024314A
Other languages
Japanese (ja)
Inventor
Masao Mashita
真下 正夫
Noburo Yasuda
安田 修朗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Tokyo Shibaura Electric Co Ltd filed Critical Toshiba Corp
Priority to JP57024314A priority Critical patent/JPS58142893A/en
Publication of JPS58142893A publication Critical patent/JPS58142893A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/257Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
    • G11B7/2572Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of organic materials
    • G11B7/2575Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers consisting essentially of organic materials resins
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/254Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/243Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
    • G11B2007/24302Metals or metalloids
    • G11B2007/24316Metals or metalloids group 16 elements (i.e. chalcogenides, Se, Te)
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/253Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
    • G11B7/2533Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/256Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers improving adhesion between layers

Landscapes

  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Read Only Memory (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)

Abstract

PURPOSE:To provide the titled recording medium which is prevented from generating the bad odor of a Te compound when being irradiated with an energy beam and has a high sensitivity and a long useful life, by a method wherein an organic protective layer is provided on a specified recording layer provided on a base, and the resulting material is sealed to be air-tight. CONSTITUTION:The recording layer 12 comprising Te and one or more substances selected from the group consisting of C, H, N, O, F, P, S, Cl, Br and I and having a thickness of 200Angstrom -1mum is provided on a surface of the base 11 such as a synthetic resin plate or a glass plate, and an ultraviolet-curing type resin is applied thereon to produce the organic protective layer 13, thereby obtaining the optical information recording medium. Then, two such recording media are so placed that the protective layers 13 are faced to each other with a spacer 14 therebetween, the assembly is sealed to be air-tight by an adhesive 15, and dry air is sealed into a hollow part 16 of the assembly. Accordingly, it can be contrived to suppress the oxidation of the recording layer and to produce pits of long useful life by using a low-energy beam.

Description

【発明の詳細な説明】 〔発明の属する技術分野〕 本発明は、光、熱等のエネルギービームO照射により、
配―膿に光学的に記鍮、再生が可能な光学的情報記録媒
体に係り、41に光、′熱等のエネルギービー^の照射
により発生するT・化合物特有の悪臭を防止しながら、
高感度、長寿命をe*とする光学的情報記録媒体に関す
る・ 〔従来技術とその問題点〕 光学釣情暢配鍮謙体として、従来、s1図に示すように
基IIl上に形成され丸紀−馴24Cエネルギービーム
を照射し、配−されるべき情報に対応し九ビット列1を
形威す為ようにし友ものがある。
[Detailed Description of the Invention] [Technical Field to Which the Invention Pertains] The present invention provides a method for irradiating an energy beam O such as light or heat.
Concerning an optical information recording medium that can optically record and reproduce the phlegm, while preventing the foul odor peculiar to T-compounds generated by irradiation with energy beams such as light and heat,
Concerning optical information recording media with high sensitivity and long life (e*) [Prior art and its problems] Conventionally, optical fishing rods have been formed on a base IIl as shown in figure s1, and are circular. There is a method in which a 24C energy beam is irradiated to form a 9-bit string 1 corresponding to the information to be distributed.

従来よ勤配―膳2としてテ・を使用することが知られて
いる。Te膿は小さいエネルギーで所望の孔(ビット)
が形成で勤る。すなわち高感度であるがテeは大気中に
放置された場合、酸素ヤ水によりIII化され、逓1u
ckる適度が遣い。このように酸化しえ?ed紀−■と
しての機能を失なう。
Traditionally, it has been known to use te as the ``te'' for the second sentence. Te pus can be used to create desired holes (bits) with small energy.
works in formation. In other words, although it is highly sensitive, if it is left in the atmosphere, it will be converted to III by oxygen and water, and it will become 1u.
The key to cking is moderation. Can it be oxidized like this? ed era - loses its function as ■.

従ってT・の大気中での安定性を増すため、Teに他O
元麿をS加す為ことが有効な場合がある。
Therefore, in order to increase the stability of T in the atmosphere, other O
It may be effective to add Motomaro to S.

しかしこれらにピットを形成する場合、記鍮部の一暮は
蒸気圧の高い成分として大気中に放出される。この蒸気
は〒・を含有し、悪臭を有し、かつ人体に壱書であゐ。
However, when pits are formed in these, the brass part is released into the atmosphere as a component with high vapor pressure. This vapor contains 〒・, has a foul odor, and is harmful to the human body.

〔発鳴の目的〕[Purpose of sounding]

本発明は上、配問題を鋳状する友め&Cなされ友もので
、ピット層成時に発生する悪臭の原因である蒸気を有機
保−■によって外部へ放出するの倉防止し、更に、この
部分を気對に對じることにより悪臭のもれを完全に防止
し、一方、配Iallの感lI。
The present invention solves the above problem of casting and curing, and prevents the vapor that is the cause of the bad odor generated during pit layer formation from being released to the outside by using organic storage.Furthermore, this part By taking this into account, we can completely prevent the leakage of bad odors, while at the same time reducing the sense of smell.

安定性はT・への−元素の添加によ)改轡された光学的
情報記鍮媒体を提供することを目的とする。
The objective is to provide an optical information storage medium whose stability has been modified (by the addition of -elements to T).

〔発明の概要〕[Summary of the invention]

本発明に係る光学的情報配鎌媒体は、基板上に普着され
た紀―膿J:に有機保■膿を軟け、更にこれを気密に対
しるようにしえものであゐ・また配鍮膜は’I’m ヘ
(’、H,N、0.F、P、8.CJ、lrおよび夏等
のうち、1積重えはそれ以上添加す為ようにして匹る。
The optical information distributing medium according to the present invention is capable of softening the organic impurity into the phlegm deposited on the substrate and further making it airtight. Brass film is 'I'm (', H, N, 0.F, P, 8.CJ, lr and summer, etc., one stack is equal to 1 stack for adding more.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、配―膜上に有機保■膿が設けられてお
抄、しかもこれが気密封じされて匹るので、エネルギー
ビームの照射によ妙ピットが形成されるl[lに発生す
ゐ悪臭を有する蒸気が外部にもれるのt−防止すること
がで龜、さらWc?aKctH,N、0.F、P、II
、C7,fir及び■等の少なくとも1横を添加すbこ
とくよって、紀碌麟の鹸化を少なくシ、長寿命かつ低エ
ネルギーでのビット形成(すなわち感度向上)を因るこ
とができる。
According to the present invention, an organic pus-retaining membrane is provided on the membrane, and this is hermetically sealed, so that strange pits are formed in the area when irradiated with an energy beam. Is it possible to prevent foul-smelling steam from leaking outside? aKctH,N,0. F, P, II
By adding at least one element such as , C7, fir, and (2), it is possible to reduce saponification of the metal and form a bit with a long life and low energy (that is, to improve sensitivity).

〔発明の実施例〕[Embodiments of the invention]

以下図園を参照しながら本発明の実施例を詳綱KWI@
す為。
The details of the embodiments of the present invention are explained below with reference to the illustrations.
To.

112■は本発明の一実施例を示す断面図である。112■ is a sectional view showing an embodiment of the present invention.

図において、11は1櫂で本実施例では合成樹脂の1つ
であ為アクリル頓を用いるものとする。しかし、他の合
成樹m*壜九はガラス板であっても良く、情報O記録お
よび再生方法によって適宜選択す為ことが可−でh為、
そして、この基板上に記録編12および有機保−■13
が順次形成され為、紀鍮膿12はT・へ(’、H,N、
0.P、P、8.Cj。
In the figure, reference numeral 11 indicates a paddle, and in this embodiment, acrylic material, which is one of the synthetic resins, is used. However, the other synthetic wood may be a glass plate, and can be selected as appropriate depending on the information recording and reproducing method.
Then, record part 12 and organic record part 13 are placed on this board.
are formed sequentially, so Kikusupus 12 goes to T (', H, N,
0. P, P, 8. Cj.

Brおよび!から選ばれ九111またはそれ以上を添加
し丸物質が用いられ、そのII厚は十分な感度を有する
九めK f!Goム〜1#mに選ぶ必要がある。
Br and! A material selected from 9111 or more is used, and its II thickness has sufficient sensitivity. It is necessary to select from Gom to 1#m.

例えば記録編12として7.とCおよびHからなる物質
上達んだ場合、テ・をターゲットとしてCおよびHを會
むガス、例えばメタン(CH,)とアルゴン(ムr)と
の混合ガス中でスパッタリングすることによ)得られる
。ここでTe g甲のC,Hの含4idkはCH4とム
rとの混合比および印加高局aI−力によ〕自由に制御
でき、例えばCH4/Ar−1の1合比で約0.3W/
dの高周波(13,56MH1)電力をTeターゲット
と基1[11との間に印加すると′reに対して原子数
比で0.2のCを含有し九−を形成することができる。
For example, 7. If a material consisting of C and H is successfully obtained, it can be obtained by sputtering using Te as a target in a gas that combines C and H, such as a mixed gas of methane (CH,) and argon (Mr). It will be done. Here, the 4idk content of C and H in TegA can be freely controlled by the mixing ratio of CH4 and Mr and the applied high local aI-force. 3W/
When a high frequency (13.56 MH1) power of d is applied between the Te target and the group 1[11, it is possible to form 9- containing C in an atomic ratio of 0.2 to 're.

この場合、膜の組成式はTe、−、Cx (H)  と
書き表わすことができ、膜が化学的に最も安定するHの
含有量はXによって決まる。ここでは、膜、〒に水素ガ
ス(Hl)が発生するほど多IIVc含有させない限り
、H含有量は任意に選ジことができる。さらに、膜厚は
スパッタリング時間に比例するので自由に制御できる。
In this case, the compositional formula of the film can be expressed as Te, -, Cx (H), and the H content at which the film is chemically most stable is determined by X. Here, the H content can be arbitrarily selected as long as the film does not contain so much IIVc that hydrogen gas (Hl) is generated. Furthermore, since the film thickness is proportional to the sputtering time, it can be freely controlled.

一方、有機保膳膳13は例えば−布によって形成できそ
の材料として1例えば紫外線硬化形樹脂が使用できる。
On the other hand, the organic tray 13 can be made of cloth, for example, and can be made of, for example, ultraviolet curing resin.

113図は上記の記鍮媒体を組み合せて気密封じした様
子を示す。14はスペーサーで15は接着剤で、これら
により気密封じを行なう。中空部16には例えば乾燥空
気が射入される。
Figure 113 shows how the above recording media are combined and hermetically sealed. 14 is a spacer, and 15 is an adhesive, which perform airtight sealing. For example, dry air is injected into the hollow portion 16.

−2図に示される本発明による配録媒体KIJI4図に
示すようにエネルギービーム17が照射されピットが形
成された場合、記録編の一部はM損保■1$13中に浸
透し、わずか有機保sI@13から外部へ放出されても
183図に示すように気密封しにしであるため(、大気
中にもれるおそれは殆んどない。
- When the energy beam 17 is irradiated and pits are formed as shown in Figure 2, a portion of the recording medium permeates into M Sompo ■1$13, and a small amount of organic Even if it were to be released to the outside from the container, there is little risk of it leaking into the atmosphere because it is airtightly sealed as shown in Figure 183.

さらに本発@における1鍮媒体は、例えばJ。Furthermore, the 1 brass medium in this publication @ is, for example, J.

組ectro cham !16cJoj、12$1.
P、699(1981)  K:示されえそれよ〕も優
れている。すなわち、この文献によゐ気密封じは寿命の
短かいTe+鯛を大気から遮断するためのものであるが
との種の構造では大気を完全に遮断することは不可能で
あや、寿命番長くする仁とには余り役立たない。しかる
に本発明では大気の侵入を防ぐための気密封じではなく
、気密封じ内のわずかの蒸気の大気へのもれt−Uぐた
めの4のである。紀鍮績にはそれ自身大気にふれて4十
分長寿命であるので大気を完全に通断する必要はない。
Group electro cham! 16cJoj, 12$1.
P, 699 (1981) K: Show Me! is also excellent. In other words, according to this document, the airtight seal is intended to shield the short-lived Te + sea bream from the atmosphere, but with the structure of the species, it is impossible to completely shut off the atmosphere, so it is necessary to extend the lifespan. It's not very useful for humanity. However, in the present invention, the airtight seal is not used to prevent air from entering, but rather to prevent a small amount of steam from leaking into the air within the airtight seal. Since the test tube itself has a long lifespan of 40 minutes in contact with the atmosphere, it is not necessary to completely pass through the atmosphere.

また1本発明における配録媒体は肉えばJJac。In addition, the recording medium in the present invention is JJac.

8ci、Technol Jon、18.P、70(1
981)に示さrLiも9よ如も優れている。すなわち
、この文献の有機膜#aisは短寿館のl+0膳を外気
から保編するためのものであるが、その目的のためには
ポーラスな有機膜では不十分である。しかるに本発明で
は単にピット形成時のわずかな蒸気をとらえる丸めKの
み形成したものであ)、本発明においては記録膜12そ
れ自身が長寿命であるため、上記文献のそれよプ大幅に
優れる。
8ci, Technol Jon, 18. P, 70 (1
The rLi shown in 981) is also superior to that of 9. That is, the organic film #ais in this document is for preserving the l+0 set of Tanjukan from outside air, but a porous organic film is insufficient for that purpose. However, in the present invention, only the rounded K is formed to catch a small amount of vapor when pits are formed.) Since the recording film 12 itself has a long life in the present invention, it is significantly superior to that of the above-mentioned document.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の光学的情報記録媒体の断面図、第2図乃
、fi−4図は本発明の一実施例を説明するための断面
図である。 11・基板      12・紀鎌膿 13 有横保−膜   14  スペーサー15・・接
着@      17  エネルギービーム(7317
)  代4人 弁理士 則 近 憲 佑 (ほか1名)
499−
FIG. 1 is a sectional view of a conventional optical information recording medium, and FIGS. 2 to 4 are sectional views for explaining an embodiment of the present invention. 11.Substrate 12.Ki Kamapyo 13 Yuyokoho-membrane 14 Spacer 15... Adhesion @ 17 Energy beam (7317
) 4 Patent Attorneys Kensuke Chika (and 1 other person)
499-

Claims (1)

【特許請求の範囲】[Claims] 基板と、この基板の上Km着された記録膜と、その1に
形成、されえ有機保−績とを有する光学的情報記#I一
体において、膣紀記鍮膜はテ・とC11(、N、0.F
、P、I、C7,Brおよびlから選ばれえ1種を九は
複数種とから構成され、かつ前記記録媒体の有機保1膿
備が気密封じされてな為ことを特徴とする光学的情報記
−媒体・
In the optical information recorder #I integrally having a substrate, a recording film deposited on the substrate, and an organic recording layer formed on the substrate, the vaginal recorder brass film is TE and C11 (, N, 0.F
, P, I, C7, Br and l, and the organic storage medium of the recording medium is hermetically sealed. Information record-media/
JP57024314A 1982-02-19 1982-02-19 Optical information recording medium Pending JPS58142893A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57024314A JPS58142893A (en) 1982-02-19 1982-02-19 Optical information recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57024314A JPS58142893A (en) 1982-02-19 1982-02-19 Optical information recording medium

Publications (1)

Publication Number Publication Date
JPS58142893A true JPS58142893A (en) 1983-08-25

Family

ID=12134717

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57024314A Pending JPS58142893A (en) 1982-02-19 1982-02-19 Optical information recording medium

Country Status (1)

Country Link
JP (1) JPS58142893A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58152252A (en) * 1982-03-05 1983-09-09 Daicel Chem Ind Ltd Information recording material
US4648276A (en) * 1984-01-27 1987-03-10 Klepper John R Apparatus for measuring the characteristics of an ultrasonic wave medium

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5662192A (en) * 1979-10-29 1981-05-27 Nippon Telegr & Teleph Corp <Ntt> Medium for optical recording use and preparation thereof
JPS5683851A (en) * 1979-12-12 1981-07-08 Toshiba Corp Optical recording material
JPS5894144A (en) * 1981-11-30 1983-06-04 Fujitsu Ltd Recording medium

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5662192A (en) * 1979-10-29 1981-05-27 Nippon Telegr & Teleph Corp <Ntt> Medium for optical recording use and preparation thereof
JPS5683851A (en) * 1979-12-12 1981-07-08 Toshiba Corp Optical recording material
JPS5894144A (en) * 1981-11-30 1983-06-04 Fujitsu Ltd Recording medium

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58152252A (en) * 1982-03-05 1983-09-09 Daicel Chem Ind Ltd Information recording material
US4648276A (en) * 1984-01-27 1987-03-10 Klepper John R Apparatus for measuring the characteristics of an ultrasonic wave medium

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