JPS58141388A - Manufacture of cylinder - Google Patents

Manufacture of cylinder

Info

Publication number
JPS58141388A
JPS58141388A JP2129782A JP2129782A JPS58141388A JP S58141388 A JPS58141388 A JP S58141388A JP 2129782 A JP2129782 A JP 2129782A JP 2129782 A JP2129782 A JP 2129782A JP S58141388 A JPS58141388 A JP S58141388A
Authority
JP
Japan
Prior art keywords
self
cylinder
pipe
uniformly
fluxing alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2129782A
Other languages
Japanese (ja)
Inventor
Hiroshi Kobayashi
弘 小林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP2129782A priority Critical patent/JPS58141388A/en
Publication of JPS58141388A publication Critical patent/JPS58141388A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer

Abstract

PURPOSE:To stick a self-fluxing alloy uniformly on the inner face of a pipe and to give corrosion resistance and wear resistance, by sealing the powder of the self-fluxing alloy in a pipelike steel material, diffusing it uniformly by rotating the pipe while sucking by vacuum and heating it from the outside. CONSTITUTION:A shaft for power transmission 4 and an end plate 3 for closing are attached to an end of a cylinder blank material 1 by welding. The shaft 4 is attached to a rotating jig so that the material 1 becomes parallel to the axial direction, and the powder of the self-fluxing alloy is distributed uniformly over the longitudinal direction of the material 1 from the tip 6' of a trumpet-shaped container 6. Open end of the material 1 is closed by welding 5' a mild steel plate 8, and a pipe 8 that communicates with the inside of the material 1 is welded at the center of the mild steel plate 8, and connected to a vauum pump 11 through a valve 10 and a rotary joint 12. The material 1 is sucked by vacuum while rotating it, and heated from the outer periphery while maintaining specified pressure. The self-fluxing alloy is heated to become uniform melting temperature and stuck fastly and uniformly.

Description

【発明の詳細な説明】 本発明はシリンダの製造方法に関し、特にシリンダ内面
に耐食性、耐摩耗性を付与する方法に関するものである
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a cylinder, and particularly to a method for imparting corrosion resistance and wear resistance to the inner surface of a cylinder.

合成樹脂の成形、押出、フィルム作製等の樹脂成形用お
よび押出機等は、シリンダとスクリュが一対となってス
クリュによシ成形する樹脂の供給、輸送、加熱、混線、
可塑化、押し出し圧力の蓄積、調整、押し出し量調整等
多くの用途と役割をはたしている。これらの役割を支え
ているのがシリンダであシ、使用中は樹脂が高圧になる
ため、この圧力を支える耐圧力が必要である。また、シ
リンダとスクリュのフライトとは運転中に接触し摩耗す
るため、耐摩耗が要求される。更に、使用樹脂によって
は運転中に腐食性物質が発生するため、耐食性も要求さ
れる。そのために、シリンダは鋼材に各種表面処理が施
こされている。
For resin molding, extrusion, film production, etc. of synthetic resin, extrusion machines, etc. are used as a pair of cylinder and screw to supply, transport, heat, cross-wire, etc. the resin to be molded by the screw.
It has many uses and roles such as plasticization, accumulation and adjustment of extrusion pressure, and adjustment of extrusion amount. The cylinder supports these roles, and since the resin is under high pressure during use, it must be able to withstand pressure to support this pressure. In addition, since the cylinder and the flights of the screw come into contact with each other during operation and wear out, wear resistance is required. Furthermore, since corrosive substances are generated during operation depending on the resin used, corrosion resistance is also required. To this end, the cylinders are made of steel that has been subjected to various surface treatments.

各種表面処理のうち窒化処理が施こされるものは窒化処
理時間が72時間と長く、処理時間が長い割には窒化処
理層の深さは0.1開栓度と浅く摩耗によシ滅肉しはじ
めると寿命が短かい。
Among various surface treatments, the nitriding treatment takes a long time of 72 hours, and although the treatment time is long, the depth of the nitriding layer is as shallow as 0.1 degree of opening, and it is destroyed by wear. Once it begins to produce meat, its lifespan is short.

また、浸炭処理では窒化処理時間よシ短かくて層は深い
が窒化処理よシ耐摩耗性が劣り、この画処理とも耐食性
は一般鋼材並で腐食性生物の発生する樹脂には使用でき
ず、使用範囲が限定される。その他として、C,o系や
N1系などの耐食、耐摩耗性のある材料をシリンダ内面
に遠心鋳造法により鋳造ライニングで施こす方法がある
。これらのライニング法では溶解設備、鋳造設備など大
がかシな設備が必要となシ、特殊な工場での施工しかで
きない欠点を有する。
In addition, carburizing takes a shorter time than nitriding and produces a deeper layer, but its wear resistance is inferior to that of nitriding, and the corrosion resistance of this carburizing process is comparable to that of general steel, so it cannot be used with resins where corrosive organisms are generated. The scope of use is limited. Another method is to apply a corrosion-resistant and wear-resistant material such as C, O-based or N1-based material to the inner surface of the cylinder as a cast lining by centrifugal casting. These lining methods have the disadvantage that they require large-scale equipment such as melting equipment and casting equipment, and can only be constructed in special factories.

一方、シリンダに耐摩、耐食性のある材料を薄肉として
圧入する方法が開発されているが薄肉の加工が困゛難な
ためコスト高となる。
On the other hand, a method has been developed in which a wear-resistant and corrosion-resistant material is press-fitted into the cylinder as a thin wall, but this increases the cost because it is difficult to process a thin wall.

本発明では、溶射用ノNi系(N1−1−cr十B−1
−sl)。
In the present invention, thermal spraying Ni-based (N1-1-cr + B-1
-sl).

Co系(Co−1−N 1−)Cr+B−1−8i )
  およびこれらにセラミック粉末(WC,NbC等)
を混合した自溶性合金粉末を用いて、長尺(100〜6
000t1m程釦で、直径は50〜8004程度のシリ
ンダに、鋳造ライニングと同程度の耐摩耗性および耐食
性を付与しようとするものであシ、長尺シリンダの内面
の溶射施工は不可能であるが、溶射に使用する上記の自
溶性合金粉末を用いて、溶射法を用いずに、シリンダの
内面に自溶性合金を真空中でライニングする方法を提供
するものである。
Co-based (Co-1-N 1-)Cr+B-1-8i)
and ceramic powder (WC, NbC, etc.)
Using a self-fusing alloy powder mixed with
The purpose is to provide a cylinder with a diameter of about 50 to 8,000 mm and a diameter of about 50 to 8,004 mm, with the same level of wear resistance and corrosion resistance as a cast lining, and it is impossible to thermal spray the inner surface of a long cylinder. The present invention provides a method of lining the inner surface of a cylinder with a self-fusing alloy in a vacuum using the self-fusing alloy powder used in thermal spraying without using a thermal spraying method.

すなわち本発明は、パイプ状の鋼材の内面へ自溶性合金
の粉末を常温+科人後、該パイプの内部を真空引きしな
がら内面の自溶性合金粉末が均一に分散するような周速
で)くイブを回転させながら外面よシ加熱し、自溶性合
金をパイプの内面に均一に固着することを特徴とするシ
リンダの製造方法に関するものである。
In other words, in the present invention, the self-fusing alloy powder is applied to the inner surface of a pipe-shaped steel material at room temperature and at a circumferential speed such that the self-fusing alloy powder on the inner surface is uniformly dispersed while the inside of the pipe is evacuated. The present invention relates to a method for producing a cylinder, which is characterized by heating the outer surface of the pipe while rotating the pipe, thereby uniformly fixing a self-fusing alloy to the inner surface of the pipe.

本発明方法は、樹脂成形用、土砂成形機、油圧ポンプ、
コンクリートポンプなどのシリンダ。
The method of the present invention can be used for resin molding, earth and sand molding machines, hydraulic pumps,
Cylinders such as concrete pumps.

化学配管用パイプ等、各種のシリンダ様のものの製造に
適用することができる。
It can be applied to the manufacture of various cylinder-like items such as chemical piping pipes.

以下、添付図面を参照して本発明方法を詳細に説明する
Hereinafter, the method of the present invention will be explained in detail with reference to the accompanying drawings.

第1図は本発明に使用するシリンダ素材の断面図である
。図中、1はシリンダ素材で、1例として外径450箇
、内径164111+++1長さ2,800闇で1.T
IS SCM 4の素材よシ内径を加工したも・のであ
る。この場合、素材は、自溶性合金の溶融温度である9
50°〜1100℃程度に耐える素材であり、かつ自溶
性合金と化合物をつくることができる素材であシ、はと
んどの鉄鋼材料が使用できる。なおJ・シリンダの強度
の点からは、ライニング後、低温の熱処理で強度が向上
する析出硬化型の材料を使用しても良い。加工した内径
側は、後のライニング工程で錆の発生があると好ましく
ないので、加工後の放置によって錆が発生しないように
防錆処理を施こしておく。
FIG. 1 is a sectional view of a cylinder material used in the present invention. In the figure, 1 is the cylinder material, and as an example, the outer diameter is 450, the inner diameter is 164111+++1, the length is 2,800 mm, and 1. T
It is made from IS SCM 4 material with the inner diameter processed. In this case, the material is 9, which is the melting temperature of the self-fusing alloy.
Almost any steel material can be used, as long as it is a material that can withstand temperatures of about 50° to 1100° C. and can form compounds with self-fusing alloys. Note that from the viewpoint of the strength of the J-cylinder, a precipitation hardening type material whose strength is improved by low-temperature heat treatment after lining may be used. It is undesirable if rust occurs on the processed inner diameter side in the subsequent lining process, so a rust preventive treatment is applied to prevent rust from occurring if left unattended after processing.

またシリンダ素材1の端面は端板を接続するために、溶
接のための開先2を取ってもよい。
Further, the end face of the cylinder material 1 may have a groove 2 for welding in order to connect the end plate.

以上のように加工されているシリンダ素材1をトリクレ
ン等の洗浄剤に−よシ脱脂洗浄する。
The cylinder material 1 processed as described above is degreased and cleaned using a cleaning agent such as Triclean.

ただし内径側に錆の発生がある場合はブラスト、酸洗な
どによシライニングする内径の表面を除錆する。
However, if there is rust on the inner diameter side, remove the rust from the inner diameter surface by blasting, pickling, etc.

その後、第2図に示すように、シリンダ1を回転するだ
めの動力伝達用軸4と、シリンダ1の片端を閉鎖できる
端板3を、シリンダ1の片端の端面に溶接5によシ取り
つける。この時、他の一端の穴は開放したままとする。
Thereafter, as shown in FIG. 2, a power transmission shaft 4 for rotating the cylinder 1 and an end plate 3 capable of closing one end of the cylinder 1 are attached by welding 5 to the end surface of one end of the cylinder 1. At this time, leave the hole at the other end open.

以上のように処理したシリンダ素材1を回転調整できる
回転駆動源(図示省略)に連結しているチャック(図示
省略)で軸4につなぎ、シリンダ素材1を任意の回転数
で回転できる冶具へ取りつける。この時の素材の取シつ
け位置は、シリンダ素材1の内径が地面と平行となるよ
うに取りつけると同時に、重量が重いため長手方向の1
〜3か所で下から回転しながら支える冶具(図示省略)
で重量を支える。
The cylinder material 1 processed as above is connected to the shaft 4 with a chuck (not shown) connected to a rotation drive source (not shown) whose rotation can be adjusted, and the cylinder material 1 is attached to a jig that can rotate at an arbitrary rotation speed. . At this time, the mounting position of the material should be such that the inner diameter of the cylinder material 1 is parallel to the ground, and at the same time, since it is heavy,
~ A jig that rotates and supports from below in three places (not shown)
supports the weight.

つぎに自溶性合金粉末(Ni残部、 Cr 16wt%
Next, self-fusing alloy powder (remaining Ni, Cr 16wt%
.

B4vrt%、 Si 4 wt%、 Fe 2 wt
’%、 Cu 3 wt%。
B4vrt%, Si4wt%, Fe2wt
'%, Cu3 wt%.

Mo 3 wt4. CO,5wt%、溶融温度105
0℃)をシリンダ1の直径、皮膜厚さ等を勘案して2.
6匂秤量した。この時、皮膜の厚さは、あまり薄いと不
均一になシやすいため、0.1■〜5籠程度となるよう
に適宜選択する。ここでは加工代を含め2mとなるよう
に施工した。また、自溶性合金は各種開発されておシ、
上記組成のもΩに限らす溶射用自溶性合金であればどの
材料でも使用することができる。
Mo 3 wt4. CO, 5wt%, melting temperature 105
0°C) by taking into account the diameter of cylinder 1, coating thickness, etc.
6 odor was weighed. At this time, the thickness of the film is appropriately selected to be about 0.1 to 5 cm, because if it is too thin, it tends to become uneven. In this case, the length was 2m including the machining allowance. In addition, various self-fusing alloys have been developed.
Any material can be used as long as it is a self-fluxing alloy for thermal spraying having the above composition.

秤量した自溶性合金粉末を、第5図に示すように10m
程度のバイブロ′の先端にラッパ状6の粉末を導入しや
すくした粉−未供給装置により、シリンダ1内径の表面
に均一に分散し、第4図に示すようにシリンダ1の長手
方向に亘って散布7する。
The weighed self-fusing alloy powder was heated to 10 m as shown in Figure 5.
By using a powder-unsupplying device that makes it easy to introduce the trumpet-shaped powder 6 to the tip of the vibro', the powder is uniformly distributed over the inner diameter surface of the cylinder 1, and spread over the longitudinal direction of the cylinder 1 as shown in Fig. 4. Spray 7.

その後、開放してあったシリンダ1端面を、第4図に示
すように軟鋼板8を溶接5′で取シっけて開基する。こ
の時、軟鋼板8の中心にはシリンダ1内部へ通ずるパイ
プ9を溶接しておき、パルプ10と真空ポンプ11が接
続できるようにしておく。
Thereafter, the open end face of the cylinder 1 is opened by removing a mild steel plate 8 by welding 5' as shown in FIG. At this time, a pipe 9 leading to the inside of the cylinder 1 is welded to the center of the mild steel plate 8 so that the pulp 10 and the vacuum pump 11 can be connected.

以上のように準備したシリンダ1を、先ずパルプ10を
取シつけて30 K4t/cm” ()で気密テストを
行い、溶接部5,5′の気密を確認する。気密確認後、
パルプ10の後へシリンダ素材回転中にも真空引きがで
きるロータリージヨイント12を取りつけ、真空ポンプ
11を接続し、シリンダ1内の圧力を10−2〜10−
5 トールに真空引きできるようにしておく。
First, pulp 10 is attached to the cylinder 1 prepared as described above, and an airtightness test is performed at 30 K4t/cm" () to confirm the airtightness of the welded parts 5 and 5'. After checking the airtightness,
A rotary joint 12 that can draw a vacuum even while the cylinder material is rotating is attached to the back of the pulp 10, and a vacuum pump 11 is connected to the cylinder 1 so that the pressure inside the cylinder 1 is adjusted to between 10-2 and 10-2.
5 Make sure that you can draw a vacuum to the Thor.

次いで、シリンダ素材を回転しながら真空引きしζ上記
圧力を保ちながらシリンダ素材の外周よりシリンダ1の
内−艇自溶性各金の溶融温度に均一になるように加熱す
る。
Next, the cylinder material is evacuated while rotating and heated from the outer periphery of the cylinder material while maintaining the above pressure so that the melting temperature of each self-fusing gold in the cylinder 1 becomes uniform.

加熱温度は使用する自溶性合金によって異なるが、その
自溶性合金のヒユージングポイントよシラ0℃程度まで
の高温は許容されるが、それ以上温度が高くなると自溶
性合金の粘度が低くなり、たれ流れるため、あまり高い
温度の加熱は好ましくない。また、加熱熱源としては。
The heating temperature varies depending on the self-fusing alloy used, but high temperatures up to about 0°C above the fusing point of the self-fusing alloy are permissible, but if the temperature rises higher than that, the viscosity of the self-fusing alloy will decrease. Heating at too high a temperature is not preferable because it will drip. Also, as a heating heat source.

酸素−アセチレン、酸素−プロパン、都市ガス。Oxygen-acetylene, oxygen-propane, city gas.

プロパンガス、電気(高、低周波、抵抗加熱を含む)9
重油、軽油等が使用でき、ここでは酸素−アセチレン多
孔トーチを用いた。
Propane gas, electricity (including high, low frequency, and resistance heating)9
Heavy oil, light oil, etc. can be used, and here an oxygen-acetylene porous torch was used.

シリンダ素材は、回転源と任意に変化できる変速機によ
多回転させるが、この時の回転数は、均一に加熱でき、
かつ溶融した皮膜が均一になるように回転数を選定する
必要があり、内径寸法や外径寸法によって回転スピード
が異なるのでとくに規定し々いが、ここでは60 rp
mで回転させた。
The cylinder material is rotated many times by a rotation source and a transmission that can be changed arbitrarily, but the rotation speed at this time can be heated uniformly.
In addition, it is necessary to select the rotation speed so that the molten film is uniform, and since the rotation speed varies depending on the inner diameter and outer diameter dimensions, it is difficult to specify, but here it is 60 rp.
Rotated at m.

こうして加熱すると、自溶性合金粉末は溶融し、シリン
ダ素・材1の内径に固着され、シリンダ1内面に自溶蒜
合金が均一にライニングされる。
When heated in this manner, the self-fusing alloy powder is melted and fixed to the inner diameter of the cylinder material 1, and the inner surface of the cylinder 1 is uniformly lined with the self-fusing garlic alloy.

その後、パルプ10を閉じ、ロータリージヨイント12
および真空ポンプ11を取シはずして高温のシリンダ素
材を、硅礫土、バーミックスあるいは高温に加熱された
炉による炉冷などの方法を用いて、シリンダ素材1と自
溶性合金の熱膨張係数の違いによる自溶性合金ライニン
グ層のき裂の発生を防止するため、最除冷し、冷却後、
端板6,8の取シはずしゃ、シリンダとしての所望の加
工を施こし、製品シリンダーを完成させる。
After that, the pulp 10 is closed and the rotary joint 12 is closed.
Then, the vacuum pump 11 is removed and the high-temperature cylinder material is cooled using a method such as quartz clay, varmix, or a furnace heated to high temperature.The difference in thermal expansion coefficient between the cylinder material 1 and the self-fusing alloy In order to prevent the occurrence of cracks in the self-fusing alloy lining layer due to
The end plates 6 and 8 are removed and processed as desired for the cylinder to complete the product cylinder.

第5図は、以上のようにして得られたシリンダの一例を
示す図、図中1はシリンダ素材、101は自溶性合金層
、102はシリンダ固定用フランジで、シリンダ素材1
へ溶接等により接合される。
FIG. 5 is a diagram showing an example of the cylinder obtained as described above. In the figure, 1 is a cylinder material, 101 is a self-fusing alloy layer, 102 is a flange for fixing the cylinder, and the cylinder material 1
It is joined by welding etc.

以上説明した本発明方法による効果をまとめると、次の
通シである。
The effects of the method of the present invention explained above can be summarized as follows.

(1)押出機、射出成形機などのシリンダは前述のごと
く耐摩耗性、耐食性、耐圧性などが要求される。耐圧性
などは一般鋼材で十分対応できるが、耐食性や耐摩耗性
は一般鋼材では対応できないため、一般鋼材内面のシリ
ンダとなる部分の表面に本発明による表面処理を行なう
ことにより、安価で、耐圧性、耐食性、耐摩耗性を持っ
たシリンダが製造できる。
(1) As mentioned above, cylinders for extruders, injection molding machines, etc. are required to have wear resistance, corrosion resistance, pressure resistance, etc. Pressure resistance can be adequately met with general steel materials, but corrosion resistance and wear resistance cannot be achieved with general steel materials. Therefore, by applying the surface treatment according to the present invention to the surface of the inner surface of the general steel material that will become the cylinder, it is possible to achieve low cost and pressure resistance. It is possible to manufacture cylinders with excellent durability, corrosion resistance, and wear resistance.

(2)  真空中で処理したものは、皮膜内のガスが脱
ガスされ、ポーラスのない均一な皮膜となると同時に、
酸化物のまき込の少ない良好な自溶性合金皮膜が得られ
る。
(2) For those treated in a vacuum, the gas in the film is degassed and a uniform film with no porosity is created.
A good self-fluxing alloy film with less oxide inclusion can be obtained.

(3)本発明で得られたシリンダを、約2年間使用して
点検したが、とくに異常な摩耗や腐食などは認められず
、良好な耐久性が得られた。
(3) The cylinder obtained according to the present invention was used for about two years and inspected, but no abnormal wear or corrosion was observed, and good durability was obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1〜4図は本発明方法の一例を操作態様に沿って示す
図、第5図は本発明方法で得られるシリンダの一例を示
す図である。 復代理人  内 1)  明 復代理人  萩 原 亮 − 篤5図 −421
FIGS. 1 to 4 are diagrams showing an example of the method of the present invention in accordance with the operation mode, and FIG. 5 is a diagram showing an example of a cylinder obtained by the method of the present invention. Sub-agents 1) Meifuku agent Ryo Hagiwara - Atsushi Figure 5-421

Claims (1)

【特許請求の範囲】[Claims] パイプ状の鋼材の内面へ自溶性合金の粉末を常温で封入
後、該パイプの内部を真空引きし々がら内面の自溶性合
金粉末が均一に分散するような周速でパイプを回転−さ
せながら外面よシ加熱し、自溶性合金をパイプの内面に
均一に固着することを特徴とするシリンダの製造方法。
After sealing the self-fusing alloy powder into the inner surface of a pipe-shaped steel material at room temperature, the inside of the pipe is evacuated and the pipe is rotated at a circumferential speed that uniformly disperses the self-fusing alloy powder on the inner surface. A method for manufacturing a cylinder, characterized by heating the outer surface and uniformly fixing a self-fusing alloy to the inner surface of the pipe.
JP2129782A 1982-02-15 1982-02-15 Manufacture of cylinder Pending JPS58141388A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2129782A JPS58141388A (en) 1982-02-15 1982-02-15 Manufacture of cylinder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2129782A JPS58141388A (en) 1982-02-15 1982-02-15 Manufacture of cylinder

Publications (1)

Publication Number Publication Date
JPS58141388A true JPS58141388A (en) 1983-08-22

Family

ID=12051204

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2129782A Pending JPS58141388A (en) 1982-02-15 1982-02-15 Manufacture of cylinder

Country Status (1)

Country Link
JP (1) JPS58141388A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004004923A3 (en) * 2002-07-02 2004-02-26 Jr Kenneth Casner Method for coating metallic tubes with corrosion-resistant alloys

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004004923A3 (en) * 2002-07-02 2004-02-26 Jr Kenneth Casner Method for coating metallic tubes with corrosion-resistant alloys

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