JPS58136766A - Surface-coated sintered hard alloy member - Google Patents

Surface-coated sintered hard alloy member

Info

Publication number
JPS58136766A
JPS58136766A JP1844382A JP1844382A JPS58136766A JP S58136766 A JPS58136766 A JP S58136766A JP 1844382 A JP1844382 A JP 1844382A JP 1844382 A JP1844382 A JP 1844382A JP S58136766 A JPS58136766 A JP S58136766A
Authority
JP
Japan
Prior art keywords
layer
hard alloy
coated
sintered hard
wear resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1844382A
Other languages
Japanese (ja)
Inventor
Yusuke Iyori
裕介 井寄
Norio Takahashi
紀雄 高橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Proterial Ltd
Original Assignee
Hitachi Metals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Metals Ltd filed Critical Hitachi Metals Ltd
Priority to JP1844382A priority Critical patent/JPS58136766A/en
Publication of JPS58136766A publication Critical patent/JPS58136766A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

PURPOSE:To obtain a sintered hard alloy member with superior wear resistance and considerably improved chipping resistance by coating the surface of a sintered hard alloy substrate with a specified hard substance with superior wear resistance and by forming a metallic Ti layer at the uppermost part. CONSTITUTION:The surface of a sintered hard alloy substrate is coated with a single layer of 1 kind of component or a multiple layer of >=2 kinds of components selected from the carbides, nitrides and oxides of the IVa, Va and VIa group metals in the periodic table, Al, Si and B and solid solns. each consisting of >=2 kinds of said compounds. The tickness of the layer is adjusted to 1- 15mum. A metallic Ti layer is then formed at the uppermost part in 0.1-5mum thickness. Thus, a coated sintered hard alloy with high wear and mechanical impact resistances is obtd.

Description

【発明の詳細な説明】 本発明は超硬合金の表面上へのコーティングに関するも
のである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to coatings on cemented carbide surfaces.

超硬合金の表面に各種硬質物質を被覆したコーティング
部材は従来の超硬合金に比べ−C耐摩耗性が著しく向上
し現在人混に使用されている。
Coating members in which the surface of cemented carbide is coated with various hard substances have significantly improved -C wear resistance compared to conventional cemented carbide, and are currently being used by people.

しかし、表面被覆層にはバインダー金属が含有されない
ため被覆層にはクラックが容易に生じそのクラックが原
因となってfM、壊が進行する。
However, since the surface coating layer does not contain a binder metal, cracks easily occur in the coating layer, and the cracks cause fM and failure to proceed.

従ってコーティング部材は従来の超硬合金に比べて欠損
しやすいという欠点は避けがたい。
Therefore, it is difficult to avoid the drawback that the coated member is more easily damaged than conventional cemented carbide.

本発明は上記従来技術の欠点を改良し、血t I*粍性
にすぐれ、かつ耐欠損性を大巾に改善した新規な表向被
覆超硬部材を提供することを目的とする。
It is an object of the present invention to improve the above-mentioned drawbacks of the prior art and to provide a novel surface-coated carbide member that has excellent blood t I* resistance and greatly improved fracture resistance.

本発明の特徴は耐摩耗性にすぐれた各al硬質物質を超
硬合金に被覆し、さらに最上層に′1゛11゛1金属覆
する点にある。゛1゛1金属は当然のことながら炭化物
、窒化物のような硬質物質」、りも靭性に富むだめTi
被覆最上面からクラ・ツクが生じることを減することが
可能となる。従って、従来の硬質物質だけを被覆した場
合に比べて耐欠損性が大巾に改善される。さらにTiは
酸化物をつくりやすく、かつ生じだ′1゛i酸化物は耐
埠′耗性にすぐれるため、硬質物質だけを被覆したもの
に比べて耐り鱗耗性が劣化するということはない。
The feature of the present invention is that each Al hard material with excellent wear resistance is coated on a cemented carbide, and the top layer is coated with '1'11'1 metal.゛1゛1 Metals are naturally hard substances such as carbides and nitrides.
It becomes possible to reduce the occurrence of scratches from the top surface of the coating. Therefore, fracture resistance is greatly improved compared to the case where only a conventional hard material is coated. Furthermore, Ti is easy to form oxides, and the resulting oxides have excellent wear resistance, so there is no possibility that the wear resistance will deteriorate compared to those coated with only a hard material. do not have.

ここで、下層となる硬質層は周期律表の4a、5a16
a族の金属、AI、SiおよびHの炭化物、窒化物およ
び酸化物、さらにこれら2種以上の固溶体からなる群の
うちの1種の単層またId2褌以上からなる多重1mが
最も■ml摩耗性にすぐれる。またその下層の膜厚は1
〜15μmが望ましい。1μ未満では被覆の効果が得ら
れず15μmを越えるとクラックが生じやすく、欠損頻
度が犬となる。
Here, the lower hard layer is 4a and 5a16 of the periodic table.
A single layer of one of the group consisting of Group A metals, carbides, nitrides, and oxides of AI, Si, and H, and solid solutions of two or more of these, or a multiple layer of 1 m consisting of Id2 loincloth or more has the highest wear. Excellent sex. The thickness of the lower layer is 1
~15 μm is desirable. If it is less than 1 μm, no coating effect will be obtained, and if it exceeds 15 μm, cracks will easily occur and the frequency of breakage will be low.

最上部の金属被覆は上記の理由でTiが望ましくそのT
i被覆層の厚みは061〜5μmが望ましい。
The top metal coating is preferably Ti for the above reasons.
The thickness of the i-coating layer is preferably 0.61 to 5 μm.

0.1μ!n未満では耐欠損性の改善効果が得られない
。また5μmをこえた場合、金属としての性質が顕著と
なり被1表面が塑性変化を生じ耐摩耗性を劣化させる。
0.1μ! If it is less than n, the effect of improving fracture resistance cannot be obtained. If the thickness exceeds 5 .mu.m, the metal properties become noticeable, causing plastic changes in the surface of the substrate and deteriorating the wear resistance.

実施例1 P50系超硬合金表面にTiCを5μmの厚さに被覆し
、さらにTiQ属を2μmの厚さに被覆した(Aチップ
)。一方TiCだけを7μmの厚さに被覆したものを比
較拐とした(Bチップ)。これらのチップを用いて以下
の条件で切削テストを行なった。
Example 1 The surface of a P50 cemented carbide was coated with TiC to a thickness of 5 μm, and further coated with TiQ to a thickness of 2 μm (A chip). On the other hand, a chip coated only with TiC to a thickness of 7 μm was used for comparison (chip B). A cutting test was conducted using these chips under the following conditions.

切削材    SCM5(硬さHsilO)10謔巾の
溝付 切削速度   15om/分 送り      0.5關/rev 切込み    2− チップ形状  5NuN432 比較品のBチップは欠損し1分しか切8りできなかった
のに対[2、本発明の、へチップは15分間の切削でも
欠損せず良好な切削性能が得られた。
Cutting material SCM5 (Hardness HsilO) 10mm wide groove Cutting speed 15om/min Feed 0.5mm/rev Depth of cut 2-Chip shape 5NuN432 The B tip of the comparison product broke and could only cut for 1 minute. In contrast [2, the tip of the present invention did not break even after cutting for 15 minutes and good cutting performance was obtained.

実施例2 P20系超硬合金表面に下層よりTiC3z+m、 A
IzOx2μm1 Ti金属3μnlを被覆したコーテ
ィング工具を作製した(Cチップ)。一方TiC5am
、 A1zOs2μmだけを被覆したものを比較材とし
た(Dチップ)。これらのチップを用いて以下の条件で
フライス切削テストを行なった。
Example 2 TiC3z+m, A from the bottom layer on the P20 cemented carbide surface
A coated tool coated with 2 μm of IzOx and 3 μnl of Ti metal was prepared (C chip). On the other hand, TiC5am
, A comparative material was one coated with only 2 μm of A1zOs (D chip). A milling test was conducted using these chips under the following conditions.

被削材    80M3  (硬さI(s40)切削速
度   2oom/分 送り        0.25−/刃 切込み    2− テップ形状  SPK 42TR 比較品のDチップは50秒で欠損したが本発明のCチッ
プは20分切削においても欠損せず良好な切削性能が得
られた。
Work material 80M3 (Hardness I (s40) Cutting speed 2oom/min Feed 0.25-/Blade depth of cut 2-Tip shape SPK 42TR The comparison product D chip broke in 50 seconds, but the inventive C chip broke in 20 seconds. Good cutting performance was obtained with no damage during cutting.

このように超硬合金基体に硬質物質を被覆しさらに最上
層に′v1金属を被覆することにより、耐摩耗性および
機械的衝撃に富む被覆超硬合金を得ることができる。
By coating the cemented carbide substrate with a hard substance and further coating the top layer with the 'v1 metal, a coated cemented carbide having high wear resistance and mechanical impact can be obtained.

代理人出中寿徳 4 、Agent Hisanori Dechu 4,

Claims (1)

【特許請求の範囲】[Claims] 超硬合金基体の表面に、周期律表の4a、5aおよび6
a族の金属、AI、8i、i−よびBの炭化物窒化物お
よび酸化物、さらにこれらの2種以上の固溶体からなる
群のうちの1種の単1または2種以上の多重層からなる
膜4に15μmの被覆層を形成し、さらに最上部にTi
金属層を0.1〜5μm被覆したことよりなる表面クリ
超硬合金部材。
4a, 5a and 6 of the periodic table on the surface of the cemented carbide substrate.
A film consisting of a single layer or a multilayer of two or more of the group consisting of group a metals, carbides, nitrides and oxides of AI, 8i, i- and B, and solid solutions of two or more of these. 4, a 15 μm coating layer was formed on the top layer, and a Ti layer was added on top.
A surface-clear cemented carbide member coated with a metal layer of 0.1 to 5 μm.
JP1844382A 1982-02-08 1982-02-08 Surface-coated sintered hard alloy member Pending JPS58136766A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1844382A JPS58136766A (en) 1982-02-08 1982-02-08 Surface-coated sintered hard alloy member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1844382A JPS58136766A (en) 1982-02-08 1982-02-08 Surface-coated sintered hard alloy member

Publications (1)

Publication Number Publication Date
JPS58136766A true JPS58136766A (en) 1983-08-13

Family

ID=11971771

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1844382A Pending JPS58136766A (en) 1982-02-08 1982-02-08 Surface-coated sintered hard alloy member

Country Status (1)

Country Link
JP (1) JPS58136766A (en)

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