JPH0271906A - Surface coated tungsten carbide base sintered hard alloy made cutting tool excellent in plastic deformation resistance - Google Patents

Surface coated tungsten carbide base sintered hard alloy made cutting tool excellent in plastic deformation resistance

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Publication number
JPH0271906A
JPH0271906A JP22329988A JP22329988A JPH0271906A JP H0271906 A JPH0271906 A JP H0271906A JP 22329988 A JP22329988 A JP 22329988A JP 22329988 A JP22329988 A JP 22329988A JP H0271906 A JPH0271906 A JP H0271906A
Authority
JP
Japan
Prior art keywords
cutting tool
tungsten carbide
cutting
carbide
plastic deformation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22329988A
Other languages
Japanese (ja)
Inventor
Hironori Yoshimura
吉村 寛範
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP22329988A priority Critical patent/JPH0271906A/en
Publication of JPH0271906A publication Critical patent/JPH0271906A/en
Pending legal-status Critical Current

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  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Physical Vapour Deposition (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

PURPOSE:To enhance the plastic deformation resistance and execute the excellent wear resistance even in the severe condition of high depth cutting by providing the present cutting tool including 5 to 40wt.% of whisker. CONSTITUTION:The base body of a surface coated WC base sintered hard alloy made cutting tool includes 5 to 40wt.% of whisker consisted of Ti carbide, Ti nitride and one or two kinds of Ti carbide-nitride. With this arrangement, it is possible to enhance the plastic deformation resistance and, even in the condition of high speed cutting and high load cutting, execute the excellent cutting performance for a long period, while preventing the generation of the chipping and separation on a hard layer.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、すぐれた耐塑性変形性を有し、特に高速切
削や、高送り切削および高切込み切削などの苛酷な条件
下での断続切削やフライス切削などに用いた場合に、す
ぐれた切削性能を発揮する表面被覆炭化タングステン(
以下WCで示す)基超硬合金製切削工具に関するもので
ある。
[Detailed Description of the Invention] [Industrial Application Field] The present invention has excellent plastic deformation resistance, and is suitable for interrupted cutting under severe conditions such as high-speed cutting, high-feed cutting, and high-depth cutting. Surface-coated tungsten carbide that exhibits excellent cutting performance when used for cutting and milling.
The present invention relates to a cutting tool made of cemented carbide (hereinafter referred to as WC).

〔従来の技術〕[Conventional technology]

一般に、鋼や鋳鉄などの断続切削やフライス切削などに
、 結合用形成成分としてのGo、Ni、およびFe  (
以下鉄属金属という)のうちの1種以上:10〜25%
、 を含有し、さらに必要に応じて、 分散相形成成分としてTi 、Ta、Nb、およびWの
炭化物、窒化物、および炭窒化物、並びにこれらの2種
以上の固溶体(ただしWの炭化物、窒化物、および炭窒
化物を除く、以下これら全体を(Ti 、Ta、Nb、
W)C−Nで示す)のうちの1種以上:4〜25重量%
、 を含Hし、残りが分散相形成成分としてのWCと不可避
不純物からなる組成(以上ff1ffi%、以下%は重
量%を示す)を有するWCC超超硬合金基体表面に、化
学蒸着法や物理蒸着法を用いて、Tiの炭化物、窒化物
、炭窒化物、炭酸化物、および炭窒酸化物、並びに酸化
アルミニウム(以下、それぞれTtC,TiN、T1C
N。
In general, Go, Ni, and Fe (
One or more of the following: 10 to 25%
, and if necessary, carbides, nitrides, and carbonitrides of Ti, Ta, Nb, and W as dispersed phase-forming components, and solid solutions of two or more of these (however, carbides, nitrides of W, (Ti, Ta, Nb,
W) One or more of the following: 4 to 25% by weight
A chemical vapor deposition method or a physical Using a vapor deposition method, Ti carbides, nitrides, carbonitrides, carbonates, and carbonitrides of Ti, and aluminum oxides (hereinafter, TtC, TiN, and T1C, respectively) are produced.
N.

TiC0,TiCN0およびAg2o3で示し、Ag2
O3を除く全体を、TfC−N・0で示す)のうちの1
種の単層または2種以上の複層からなる硬質層を2〜6
μmの下均層厚で被覆してなる表面波51wc基超硬合
金製切削工具、 が広く用いられている。
Indicated by TiC0, TiCN0 and Ag2o3, Ag2
The whole excluding O3 is shown as TfC-N・0).
2 to 6 hard layers consisting of a single layer of seeds or a multilayer of two or more types
Surface wave 51wc-based cemented carbide cutting tools coated with a lower average layer thickness of μm are widely used.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかし、近年の切削工程の省力化および高速化に対する
要求は厳しく、これに伴って高速切削や、高送り切削お
よび高切込み切削などの重切削を余儀無くされる傾向に
あるが、上記の従来表面被覆WCC基超硬合金製切削工
具用いて断続切削やフライス切削を高速切削や重切削な
どの笥酷な条件で行なった場合、著しい発熱と衝撃によ
って基体が塑性変形し、この基体の塑性変形によって硬
質層にクラックが発生し易くなり、これが原因で切刃に
欠損やチッピングが発生するようになるばかりでなく、
場合によっては硬質層に剥離が生じるようになり、この
結果切刃の摩耗が皆しく促進することになることから、
きわめて短かい使用寿命しか示さないのが現状である。
However, in recent years there has been a severe demand for labor saving and speeding up of cutting processes, and as a result, heavy cutting such as high-speed cutting, high-feed cutting, and high-depth cutting has become necessary. When a WCC-based cemented carbide cutting tool is used to perform interrupted cutting or milling under harsh conditions such as high-speed cutting or heavy cutting, the base material undergoes plastic deformation due to significant heat generation and impact, and this plastic deformation causes the base material to become hard. Cracks are more likely to occur in the layer, which not only causes chipping and chipping of the cutting edge, but also
In some cases, peeling may occur in the hard layer, which will accelerate the wear of the cutting edge.
Currently, they only have an extremely short service life.

〔課題を解決するための手段〕[Means to solve the problem]

そこで、本発明者等は、上述のような観点から、上記の
従来表面被覆WCC基超硬合金製切削工具石目し、これ
にすぐれた耐塑性変形性を付与すべく研究を行なった結
果、上記の従来表面被覆WCC基超硬合金製切削工具お
ける基体に、Tiの炭化物、窒化物、および炭窒化物(
以下それぞれ、TiC,TiN、およびT1CNで示し
、これら全体をTiC−Nで示す)のうちのIFIiま
たは2種以上からなるボイス力を、基体全体に占める割
合で5〜40%含有させると、すぐれた耐塑性変形性を
もつようになり、この結果の表面被覆WCC基超硬合金
製切削工具、これを断続切削やフライス切削に、高速切
削や重切削などの4酷な条件で使用しても、硬質層に欠
損やチッピング、さらに剥離の発生が皆無となり、すぐ
れた切削性能を長期に互って発揮するようになるという
知見を得たのである。
Therefore, from the above-mentioned viewpoint, the present inventors conducted research to improve the texture of the conventional surface-coated WCC-based cemented carbide cutting tool and impart excellent plastic deformation resistance to it. In the conventional surface-coated WCC-based cemented carbide cutting tool mentioned above, Ti carbide, nitride, and carbonitride (
If IFIi or two or more of the following are expressed as TiC, TiN, and T1CN, and all of these are expressed as TiC-N, in an amount of 5 to 40% of the entire base, excellent The resulting surface-coated WCC-based cemented carbide cutting tool can be used in interrupted cutting, milling, high-speed cutting, heavy cutting, and other harsh conditions. They discovered that the hard layer is completely free from chipping, chipping, and peeling, and exhibits excellent cutting performance over a long period of time.

この発明は、上記知見にもとづいてなされたものであっ
て・ 結合相形成成分として鉄族金属のうちの1 [4または
2種以上:5〜20%、 を含有し、さらに必要に応じて、 分散相形成成分として(Ti 、Ta 、Nb 、W)
C−Nのうちの1種または2種以上二〇、5〜30%、
を自白°し、残りが分散相形成成分としてのWCと不可
避不純物からなる組成を有するWCC超超硬合金基体表
面に、 TiC−N・0およびAg2O3のうちの1種の単層ま
たは2種以上の複層からなる硬質層を0.5〜20μm
の平均層厚で被覆してなる表面被覆WCC基超硬合金製
切削工具おいて、上記wci超硬合金基体に、分散相形
成成分としてTiC−Nのうちの1種または2種以上か
らなるボイス力を、基体全体に占める割合で5〜409
6含有させることによって耐塑性変形性を向上せしめた
表面波1wc基超硬合金製切削工具に特徴を有するもの
である。
This invention was made based on the above findings, and contains one [4 or more of iron group metals: 5 to 20%] as a binder phase forming component, and further contains, if necessary, As dispersed phase forming components (Ti, Ta, Nb, W)
20, 5 to 30% of one or two or more of C-N;
A single layer of one type or two or more types of TiC-N.0 and Ag2O3 is applied to the surface of a WCC cemented carbide substrate having a composition in which the remainder consists of WC as a dispersed phase forming component and unavoidable impurities. A hard layer consisting of multiple layers of 0.5 to 20 μm
In the surface-coated WCC-based cemented carbide cutting tool formed by coating with an average layer thickness of The force is 5 to 409 as a proportion of the entire base.
A cutting tool made of surface wave 1wc-based cemented carbide is characterized by improved plastic deformation resistance by containing 6.

つぎに、この発明の切削工具において、WCC超超硬合
金基体成分組成および硬質層の平均層厚を上記の通りに
限定した理由を説明する。
Next, in the cutting tool of the present invention, the reason why the composition of the WCC cemented carbide base material and the average layer thickness of the hard layer are limited as described above will be explained.

^、WC基超硬基金硬合金基体組成 (a)鉄族金属 これらの成分には、分散相と強固に結合し、強度および
靭性を向上させる作用があるが、その含有量が5%未満
では前記作用に所望の効果が得られず、一方その含有量
が20%を越えると硬さ低ドが著しく、耐摩耗性が低下
するようになることから、その含有量を5〜20%と定
めた。
^, WC-based cemented carbide base alloy base composition (a) Iron group metals These components have the effect of strongly bonding with the dispersed phase and improving strength and toughness, but if their content is less than 5%, The desired effect cannot be obtained in the above action, and on the other hand, if the content exceeds 20%, the hardness will be significantly lower and the wear resistance will decrease, so the content is set at 5 to 20%. Ta.

(b)  (Ti 、Ta、Nb、W)C−Nこれらの
成分には、合金の硬さを高めて、耐摩耗性を向上させる
作用があるので、必要に応じて金白゛されるが、その含
有量が0 、596未満では所望の耐摩耗性向」二効果
が得られず、一方その含有量が3096を越えると靭性
が低下し、耐欠損性が損なわれるようになることから、
その含有量を0.5〜30%と定めた。
(b) (Ti, Ta, Nb, W)C-N These components have the effect of increasing the hardness of the alloy and improving its wear resistance, so they may be gold-plated if necessary. If the content is less than 0.596, the desired wear resistance effect cannot be obtained, while if the content exceeds 3096, the toughness will decrease and the fracture resistance will be impaired.
Its content was determined to be 0.5 to 30%.

(c) TiC−Nホイスカ これらの成分には、上記の通り耐塑性変形性を飛躍的に
向上させる作用かあるが、その含有量が5%未満では前
記作用に所望の効果を確保することができず、一方その
含有量が40%を越えると素地中に均一に分散分布させ
ることが困難になり、局部的材質ムラが生ずるようにな
ることから、その含有量を5〜40%と定めた。
(c) TiC-N Whisker These components have the effect of dramatically improving plastic deformation resistance as described above, but if their content is less than 5%, the desired effect cannot be ensured. On the other hand, if the content exceeds 40%, it becomes difficult to disperse and distribute it uniformly in the substrate, causing local unevenness in the material, so the content was set at 5 to 40%. .

B、硬質層の平均層厚 その平均層厚が0.5t13未満では、硬質層形成に伴
なう所望の耐摩耗性向上効果が得られず、一方その平均
層厚が20−を越えると、欠損やチッピングが発生し易
くなることから、その平均層厚を0.5〜20−と定め
た。
B. Average layer thickness of the hard layer If the average layer thickness is less than 0.5t13, the desired effect of improving wear resistance due to the formation of the hard layer cannot be obtained; on the other hand, if the average layer thickness exceeds 20- Since defects and chipping are likely to occur, the average layer thickness was set at 0.5 to 20-20.

〔実 施 例〕〔Example〕

つぎに、この発明の表面波IWc基超硬合金製切削工具
を実施例により具体的に説明する。
Next, the surface wave IWc-based cemented carbide cutting tool of the present invention will be specifically explained using examples.

原料粉末として、いずれも1〜5.51EIJの範囲内
の平均粒径を有するWC粉末、各種の(Ti。
As raw material powders, WC powders and various types of (Ti.

Ta、Nb、W)C−N粉末、CO粉末、Ni粉末、お
よびFe粉末を用意し、さらに10〜100の範囲内の
アスペクト比(長さ/径)を育するTiCホイスカ、T
iNホイスカ、およびT1CNホイスカを用意し、これ
ら原料をそれぞれ第1表に示される配合組成に配合し、
ホイスカを除く原料粉末をボールミルにて72時時間式
混合し、ついでこれにホイスカを加えて軽く混合し、乾
燥した後、LOton/cμmの圧力で圧粉体にプレス
成形し、この圧粉体に、I X 10’torrの真空
中、温度: 1380〜1400℃の条件での真空焼結
、または温度: H80〜1400℃、圧カニ 20(
1kg/cシの条件でのホットプレスを施し、研磨して
5PP432の形状としたWCC超超硬合金基体製造し
、引続いてこの基体の表面に、通常の化学蒸着装置を用
い、同じく第1表に示される組成および平均層厚の単層
または複層からなる硬質層を形成することにより本発明
表面技工WC基超硬合金製スローアウェイチップ(以下
、本発明被覆超硬チップという)1〜[5、およびWC
C超超硬合金基体ホイスカの含有がない従来表面被覆W
CC超超硬合金製スローアウェイチップ以下、従来被覆
超硬チップという)1〜15をそれぞれ製造した。
Ta, Nb, W)C-N powder, CO powder, Ni powder, and Fe powder were prepared, and TiC whiskers and T
Prepare an iN whisker and a T1CN whisker, mix these raw materials into the composition shown in Table 1,
The raw material powder excluding the whiskers was mixed in a ball mill for 72 hours, then the whiskers were added thereto and mixed lightly. After drying, it was press-molded into a green compact at a pressure of LOton/cμm. , vacuum sintering in a vacuum of I x 10'torr, temperature: 1380-1400°C, or temperature: H80-1400°C, pressure crab 20 (
A WCC cemented carbide substrate was produced by hot pressing and polishing at a pressure of 1 kg/c to form a 5PP432 shape. By forming a hard layer consisting of a single layer or multiple layers with the composition and average layer thickness shown in the table, the surface technology WC-based cemented carbide indexable tip of the present invention (hereinafter referred to as the coated carbide tip of the present invention) 1 to [5, and W.C.
C Cemented carbide base Conventional surface coating W that does not contain whiskers
CC cemented carbide indexable chips (hereinafter referred to as conventional coated carbide chips) 1 to 15 were manufactured, respectively.

ついで、この結宋得られた各種の被覆超硬チップについ
て、 被削材・SNCM439(硬さHB270)の角材、切
削速度: 100m/min、 送   リ:  0.3mm/rev、、切込み:41
111% の条件で鋼の高切込み乾式断続切削試験を行ない、切刃
の逃げ面摩耗幅が0.3mmに至るまでの切削時間を測
定すると共に、試験後の切刃状況を観察した。これらの
結果を第1表に示した。
Next, regarding the various coated carbide tips obtained, the work material was a square piece of SNCM439 (hardness HB270), cutting speed: 100 m/min, feed rate: 0.3 mm/rev, depth of cut: 41
A high-cut dry intermittent cutting test was conducted on steel under conditions of 111%, and the cutting time until the flank wear width of the cutting edge reached 0.3 mm was measured, and the condition of the cutting edge was observed after the test. These results are shown in Table 1.

〔発明の効果〕〔Effect of the invention〕

第1表に示される結果から、本発明被覆超硬チップ1〜
15は、基体かホイスカを含有することによってずくれ
た耐塑性変形性を具備するようになるので、高切込みの
苛酷な条件ドでらすぐれた耐19耗性を示すのに対して
、従来被覆超硬チップ]〜15は、発熱および衝撃によ
って基体が塑性変形することから、切刃に欠損やチッピ
ングか発生し、短かい使用寿命しか示さないことが明ら
かである。
From the results shown in Table 1, the coated carbide tips of the present invention 1 to
15 has excellent plastic deformation resistance due to the inclusion of whiskers in the base material, so it exhibits excellent wear resistance even under severe conditions with a high depth of cut. It is clear that carbide chips] to No. 15 have only a short service life because the base body undergoes plastic deformation due to heat generation and impact, resulting in chipping or chipping of the cutting edge.

上述のように、この発明の表面彼覆WC捕超硬り金製切
削工具は、これを構成する基体かすぐれた耐塑性変形性
を有するので、断続切削やフライス切削を、高速切削や
、高送りおよび高切込みなどの重切削条件で行なっても
切刃に欠損やチッピングの発生かなく、すぐれた耐摩耗
性を示し、著しく長期に亘ってすぐれた切削性能を発揮
するのである。
As mentioned above, the surface-covered WC superhard metal cutting tool of the present invention has excellent plastic deformation resistance in its base material, so it can be used for interrupted cutting, milling, high-speed cutting, and high-speed cutting. Even when cutting under heavy cutting conditions such as high feed and high depth of cut, the cutting edge does not break or chip, exhibiting excellent wear resistance, and exhibiting excellent cutting performance over an extremely long period of time.

Claims (2)

【特許請求の範囲】[Claims] (1)結合相形成成分としてCo、Ni、およびFeの
うちの1種または2種以上:5〜20重量%、を含有し
、残りが分散相形成成分としての炭化タングステンと不
可避不純物からなる組成を有する炭化タングステン基超
硬合金基体の表面に、Tiの炭化物、窒化物、炭窒化物
、炭酸化物、および炭窒酸化物、並びに酸化アルミニウ
ムのうちの1種の単層または2種以上の複層からなる硬
質層を0.5〜20μmの平均層厚で被覆してなる表面
被覆炭化タングステン基超硬合金製切削工具において、 上記炭化タングステン基超硬合金基体に、分散相形成成
分としてTiの炭化物、窒化物および炭窒化物のうちの
1種または2種以上からなるホイスカを、基体全体に占
める割合で5〜40重量%含有せしめたことを特徴とす
る耐塑性変形性のすぐれた表面被覆炭化タングステン基
超硬合金製切削工具。
(1) A composition containing 5 to 20% by weight of one or more of Co, Ni, and Fe as binder phase forming components, and the remainder consisting of tungsten carbide as a dispersed phase forming component and unavoidable impurities. A single layer or a composite layer of two or more of Ti carbides, nitrides, carbonitrides, carbonates, and carbonitrides of Ti, and aluminum oxide are formed on the surface of a tungsten carbide-based cemented carbide substrate having a In a surface-coated tungsten carbide-based cemented carbide cutting tool formed by coating a hard layer with an average layer thickness of 0.5 to 20 μm, the tungsten carbide-based cemented carbide substrate is coated with Ti as a dispersed phase forming component. A surface coating with excellent plastic deformation resistance characterized by containing 5 to 40% by weight of whiskers made of one or more of carbides, nitrides, and carbonitrides based on the entire substrate. Tungsten carbide-based cemented carbide cutting tool.
(2)結合相形成成分としてCo、Ni、およびFeの
うちの1種または2種以上:5〜20重量%、を含有し
、さらに、 分散相形成成分としてTi、Ta、Nb、およびWの炭
化物、窒化物、および炭窒化物、並びにこれらの2種以
上の固溶体(ただし、Wの炭化物、窒化物、および炭窒
化物は除く)のうちの1種または2種以上:0.5〜3
0重量%、 を含有し、残りが分散相形成成分としての炭化タングス
テンと不可避不純物からなる組成を有する炭化タングス
テン基超硬合金基体の表面に、Tiの炭化物、窒化物、
炭窒化物、炭酸化物、および炭窒酸化物、並びに酸化ア
ルミニウムのうちの1種の単層または2種以上の複層か
らなる硬質層を0.5〜20μmの平均層厚で被覆して
なる表面被覆炭化タングステン基超硬合金製切削工具に
おいて、 上記炭化タングステン基超硬合金基体に、分散相形成成
分としてTiの炭化物、窒化物および炭窒化物のうちの
1種または2種以上からなるホイスカを、基体全体に占
める割合で5〜40重量%含有せしめたことを特徴とす
る耐塑性変形性のすぐれた表面被覆炭化タングステン基
超硬合金製切削工具。
(2) Contains 5 to 20% by weight of one or more of Co, Ni, and Fe as binder phase forming components, and further contains Ti, Ta, Nb, and W as dispersed phase forming components. One or more of carbides, nitrides, carbonitrides, and solid solutions of two or more of these (excluding W carbides, nitrides, and carbonitrides): 0.5 to 3
Ti carbide, nitride,
Coated with a hard layer consisting of a single layer or a multilayer of two or more of carbonitride, carbonate, carbonitoxide, and aluminum oxide with an average layer thickness of 0.5 to 20 μm. In a cutting tool made of a surface-coated tungsten carbide-based cemented carbide, the tungsten carbide-based cemented carbide substrate is provided with a whisker comprising one or more of Ti carbides, nitrides, and carbonitrides as a dispersed phase forming component. A cutting tool made of a surface-coated tungsten carbide-based cemented carbide having excellent plastic deformation resistance, characterized in that the content thereof is 5 to 40% by weight relative to the entire base.
JP22329988A 1988-09-06 1988-09-06 Surface coated tungsten carbide base sintered hard alloy made cutting tool excellent in plastic deformation resistance Pending JPH0271906A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22329988A JPH0271906A (en) 1988-09-06 1988-09-06 Surface coated tungsten carbide base sintered hard alloy made cutting tool excellent in plastic deformation resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22329988A JPH0271906A (en) 1988-09-06 1988-09-06 Surface coated tungsten carbide base sintered hard alloy made cutting tool excellent in plastic deformation resistance

Publications (1)

Publication Number Publication Date
JPH0271906A true JPH0271906A (en) 1990-03-12

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Country Status (1)

Country Link
JP (1) JPH0271906A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5216845A (en) * 1990-10-10 1993-06-08 Gte Valenite Corporation Method of machining nickel based superalloys
US5232318A (en) * 1990-09-17 1993-08-03 Kennametal Inc. Coated cutting tools
US5279191A (en) * 1990-10-10 1994-01-18 Gte Valenite Corporation Reinforced alumina ceramic-metal bodies
US5325747A (en) * 1990-09-17 1994-07-05 Kennametal Inc. Method of machining using coated cutting tools
US5460640A (en) * 1990-10-10 1995-10-24 Valenite Inc. Alumina-rare earth oxide ceramic-metal bodies
EP0711844A1 (en) * 1990-08-31 1996-05-15 Valenite Inc. Ceramic metal articles and methods of manufacture

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3507632A (en) * 1965-11-22 1970-04-21 Karl Swoboda Composition of matter comprising hard materials

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3507632A (en) * 1965-11-22 1970-04-21 Karl Swoboda Composition of matter comprising hard materials

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711844A1 (en) * 1990-08-31 1996-05-15 Valenite Inc. Ceramic metal articles and methods of manufacture
US5232318A (en) * 1990-09-17 1993-08-03 Kennametal Inc. Coated cutting tools
US5325747A (en) * 1990-09-17 1994-07-05 Kennametal Inc. Method of machining using coated cutting tools
US5395680A (en) * 1990-09-17 1995-03-07 Kennametal Inc. Coated cutting tools
US5216845A (en) * 1990-10-10 1993-06-08 Gte Valenite Corporation Method of machining nickel based superalloys
US5279191A (en) * 1990-10-10 1994-01-18 Gte Valenite Corporation Reinforced alumina ceramic-metal bodies
US5460640A (en) * 1990-10-10 1995-10-24 Valenite Inc. Alumina-rare earth oxide ceramic-metal bodies

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