JPS58126145A - Soft urethane foam, surface thereof has metallic layer, and its continuous manufacture - Google Patents
Soft urethane foam, surface thereof has metallic layer, and its continuous manufactureInfo
- Publication number
- JPS58126145A JPS58126145A JP57009724A JP972482A JPS58126145A JP S58126145 A JPS58126145 A JP S58126145A JP 57009724 A JP57009724 A JP 57009724A JP 972482 A JP972482 A JP 972482A JP S58126145 A JPS58126145 A JP S58126145A
- Authority
- JP
- Japan
- Prior art keywords
- metal layer
- urethane foam
- base film
- soft
- flexible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は、表面に金属層を有する柔軟なウレタンフオー
ムとその連続的製造方法に関し、ｊ！に詳しくは、＊画
に金属蒸着層が転写されてなる金属ｍｔ有すａｍ軟！？
レタンフォーふト、該ウレタンフオームを効率よく連続
的Ｋｌｌ造する方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a flexible urethane foam having a metal layer on its surface and a continuous manufacturing method thereof. For more details, please refer to *Am Soft, which has a metal mt formed by transferring a metal vapor deposited layer to the image! ?
This invention relates to urethane foam and a method for efficiently and continuously manufacturing the urethane foam.
従来のこの種のウレタンフオームは、金属箔を接着剤を
介してウレタンフオームｊＩ＃に１１７１ Ｌ＆もので
あるが、金属層の機造上及び取扱い上の間層によ一１壺
属纏はある程度の厚みが必要であり、従って、かかる金
属？Ｉが積層され友ウレタンフオームは柔軟性に芝しく
、履−及び圧縮等により金属ＩｉＫ鹸中キレッを生じ友
妙する等の不都合があ沙１表面に金属層を有する柔軟な
ウレ！ンフオームＦｉ顧造できなかった。又、金属箔の
製造時及び積層時に＆いて一金属拒に皺中キレツを生じ
易い問題も有していた。Conventionally, this type of urethane foam is made by attaching metal foil to urethane foam jI# through an adhesive, but there is some degree of dependence due to the mechanical and handling of the metal layer. What thickness is required and therefore how much metal does it take? A flexible urethane foam with a metal layer on its surface has some disadvantages, such as the urethane foam with a metal layer on its surface, which has poor flexibility, but tends to crack in the metal layer due to wear and compression. It was not possible to create a form Fi. In addition, there is a problem in that the metal foil tends to crack during wrinkles when the metal foil is manufactured and laminated.
本発明けかかる間層を改良除去するためになされえもの
で、柔軟性に優れ、伸張、屈−１圧縮郷によっても金属
層に皺、キレツ部の不具舎を生じない１表面に金属層を
有する柔軟なウレタンフオームとその連続的ＩＩ造方法
を提供するものである。The present invention has been made to improve the removal of interlayers, and provides a metal layer on the surface that has excellent flexibility and does not cause wrinkles or cracked parts in the metal layer even when stretched or compressed. The object of the present invention is to provide a flexible urethane foam and a continuous manufacturing method thereof.
初めに、本発明の一つである、表面に金属層を有する柔
軟なウレタンフオームについて、添付図面に基づいて説
明する。First, a flexible urethane foam having a metal layer on its surface, which is one aspect of the present invention, will be explained based on the accompanying drawings.
第１図は、本発明であるところの、表面に金属層を有す
る柔軟なウレタンフオームの一実施例ムを
各示す斜視図で、金属層１１を接着剤層１２ｖｔ介して
軟質ウレタンフオーム１６上に積層して象るものである
。金属層１１は、あらかじめ、プ９ＸチッタスフイＮム
（Ｉｆ示せず）上に形成され先金属蒸着層を軟質ウレタ
ンフオーム上に転写することによって得られた−のであ
る。金属の種類としテハ、金、鍋、アルミニウム、ニッ
ケル、スズ、クロム、亜鉛などが用いられる。この金属
層の厚みはＱＪＩＡ 〜（Ｌ １．、ｕである。接着剤
としては、柔軟性を損なわないものを選択することが必
要であゆ、ネオプレン系、ウレタン系、５ＢＲ（スチレ
ン・ブタジェンゴム）系、Ｆ２ＶＡ（エチレン・酢酸ビ
ニル）ｉＡ、アクリル系の接着剤が適宜選択される。FIG. 1 is a perspective view showing one embodiment of a flexible urethane foam having a metal layer on the surface according to the present invention, in which a metal layer 11 is placed on a soft urethane foam 16 via an adhesive layer 12vt. It is modeled by stacking layers. The metal layer 11 was previously formed on a 9X titanium film (If not shown) and was obtained by transferring the previously deposited metal layer onto a soft urethane foam. The types of metals used include metal, gold, pot, aluminum, nickel, tin, chromium, and zinc. The thickness of this metal layer is QJIA ~ (L 1., u. It is necessary to select an adhesive that does not impair flexibility, such as neoprene, urethane, or 5BR (styrene-butadiene rubber). , F2VA (ethylene vinyl acetate) iA, and acrylic adhesives are appropriately selected.
第２図は表面に金属層を有する柔軟なウレタンフオーム
の４１ｋｍｌ！施例Ｂｌ示す斜視図で、金属層２１が軟
質ウレタンフオーム２６上に、軟質ウレタンフオーム２
ｊＳ（２１１１１１Ｈ１ｌｌ（フレームフミ車−シ膳ン
）によ炒積層され友場合である。Figure 2 shows 41km of flexible urethane foam with a metal layer on the surface! In the perspective view showing Example Bl, the metal layer 21 is on the soft urethane foam 26.
jS (211111H1ll (Frame Humidifier-Size)).
説明する。第６ＷＡは、この擬造方法の一実施例の概略
を示す説明図である。以下、この筒に基づいて説明する
。６４は供給ロールで、ａロールにはベースフィルム６
５上に金属層３１が積層されてなる転写フィルム６６が
巻かれている。この転写フィルム６６は巻き戻されつつ
、圧着ロール６７．４７によって、接着剤塗布装［６８
から吐出される接着剤６２１に介して、供給ロール６９
から供給される軟質ウレタンフオーム６６上に、ベース
フィルム３Ｓｔ外肯に、金属層６１會内肯として積層さ
れる。この後、必要に応じて設けられる、接着剤の硬化
促進のための加熱装置（図示せず）を通過させ、ギイド
ローＡ／４０の位置で、ベースフィルム６５のみを剥離
する。このベースフィルムは巻き取りロール４４に巻き
取られる。他方、軟質ウレタンフオーム５Ｂ上に金属層
６１が転写された、表面に金属層を有する柔軟なウレタ
ンフオームＡは、巻き取りローｙｖ４９に巻き取られる
。explain. The sixth WA is an explanatory diagram showing an outline of one embodiment of this counterfeiting method. The following explanation will be based on this cylinder. 64 is a supply roll, and the base film 6 is on the a roll.
A transfer film 66 having a metal layer 31 laminated thereon is wound on top of the transfer film 5 . While being rewound, this transfer film 66 is moved by an adhesive coating device [68
The supply roll 69
A metal layer 61 is laminated on the soft urethane foam 66 supplied from the base film 3St. Thereafter, it is passed through a heating device (not shown) provided as necessary for accelerating curing of the adhesive, and only the base film 65 is peeled off at the Gidlow A/40 position. This base film is wound onto a take-up roll 44. On the other hand, the flexible urethane foam A having a metal layer on its surface, on which the metal layer 61 is transferred onto the soft urethane foam 5B, is wound up on the winding row YV49.
接着剤の塗布は、スプレー、ナイフコーー等の一般に用
いられる方法でよく、この接着剤は金属層上Ｋ１１ｌ布
してもよい。The adhesive may be applied by a commonly used method such as spraying or knife coating, and the adhesive may be applied to the metal layer by a K11l cloth.
父、表面に金属層を有する柔軟なウレタンフオームは、
ロールに巻き取らずに適宜の寸法に裁断して製品として
もよい、更に、軟質ウレタンフオームの厚み、製品の使
用形態等によっては、ベースフィルムを剥さ表いてロー
ルに巻き取−文は裁＠を行ない、製品の使用時にベース
フィルムを＠すのが好ましい場合もある。このようにす
ると、製品の輸送尋に２いて、金属層表面に傷等の損傷
が生じない利点を有する。Father, a flexible urethane foam with a metal layer on the surface,
The product may be made by cutting it into appropriate dimensions without winding it into a roll.Furthermore, depending on the thickness of the soft urethane foam and the form of use of the product, the base film may be peeled off and wound onto a roll. In some cases, it may be preferable to remove the base film at the time of use of the product. This has the advantage that damage such as scratches will not occur on the surface of the metal layer during transportation of the product.
又、ベースフィルム上に剥離剤を介在させてコート層を
設叶、このコート層上に金属を蒸着させて金属層を設け
、転写フィル五とし、この転写フィルムをベースフィル
ムを外側として接着剤を介して軟質ウレタンフオーム上
に積層接着後、ベースフィルムの拳を剥して、金属層の
ＩＩ！面にコート層を設けた、表面に金属層を有する柔
軟なウレタンフオームとすることもできる。このコート
層用論料としては、たとえば、ウレタン樹脂、ビニル樹
脂ｌｌｌ！！斜等が用いられる。In addition, a coat layer is provided on the base film with a release agent interposed therein, and a metal layer is provided by vapor-depositing metal on this coat layer to form a transfer film. After laminating and adhering onto the soft urethane foam, the base film is peeled off and the metal layer II! It can also be a flexible urethane foam with a metal layer on the surface and a coating layer on the surface. Materials for this coating layer include, for example, urethane resin and vinyl resin! ! Diagonal etc. are used.
ｌ！に、このようにして得られ火、表面に金属層ｔＩＫ
する柔軟なウレタンフオームの両面又は片−の適宜の位
置に両面テープ等の粘着剤を設けておくのもよい。l! In this way, a metal layer tIK is formed on the surface of the flame obtained.
It is also advisable to apply an adhesive such as double-sided tape to an appropriate position on both sides or one side of the flexible urethane foam.
転写フィルムに用いられるペースフイルムトシては、特
に限定するｙＰｌＮはないが、通常、ポリエステル、ポ
リエチレン、ポリプロピレン、／ｌ墳化ビニル、ポリテ
トラフルオロエチレンなどのフィルム類があげられ、ま
たこれらのフィルム類の厚さとしては、１０〜４０Ｉ／
−程度の４のが好ましい。The paste film used for the transfer film is not particularly limited to yPIN, but it usually includes films such as polyester, polyethylene, polypropylene, /l molded vinyl, and polytetrafluoroethylene. The thickness is 10 to 40 I/
A rating of -4 is preferred.
金属層は、このベースフィルム上に、必要に応じて、シ
リコーン樹脂等の剥離剤を論布してか龜、この剥離剤上
に厚さ曲６〜１１１程度の金属蒸着層を股叶て得られる
。この蒸着垂真の種類としてハ、金、銀、アルミニウム
、ニッケル、スズ、タロム、亜鉛などが用いられる。こ
れらの金属の蒸着は、常法に従って行なわれるが、たと
えば５Ｘ１０ トル程度の真空下に２いて、金属の一類
に応じて蒸着ａ！ ｆ １２００〜２０００℃ｌｌ！ｔ
Ｌノ温度が用い６ｔｔ、る。アルミニウムの場合は、１
２００〜１４００１：程度の温度が好ましい。The metal layer is obtained by applying a release agent such as silicone resin on this base film, if necessary, and then forming a metal vapor-deposited layer with a thickness of about 6 to 111 mm on this release agent. It will be done. As the type of the vapor-deposited vertical material, gold, silver, aluminum, nickel, tin, tarom, zinc, etc. are used. The vapor deposition of these metals is carried out according to conventional methods, for example under a vacuum of about 5×10 Torr, and the vapor deposition a! f 1200~2000℃ll! t
The temperature of L is 6tt. For aluminum, 1
A temperature of about 200 to 14001: is preferable.
この金属層と軟質ウレタンフォー＾との接着に用いられ
る接着剤は、柔軟性を有することが必要で、前述した半
オブレン系、ウレタン系、８ＢＲ系、ＥＶＡ系、アクリ
１１＆−系の接着剤が選択される。The adhesive used to bond this metal layer and the soft urethane foam must be flexible, and the above-mentioned semi-openable adhesives, urethane adhesives, 8BR adhesives, EVA adhesives, and acrylic 11&- adhesives are suitable. selected.
第４図は ａ進方法の他＊ａｈ例の主要部分【概略的に
示し丸もので、金属層の接着手段として、軟質９レタン
フオームの加１１ｊ１着（）Ｌ／−ｊ、ｊｆｉ率−ν一
ン）を用い九場合である。供給ロール尋から供給される
軟質ウレタンフオーム４Ｍはバーナー４８によって表面
が加熱溶融されて、圧着ロール５７．６７．７７の閏で
、他の供給ローｌ＠／郷から供給される。金属層４１、
ベースフィルム４５からなる転写フィルム４６の金属層
４１と溶着され、ガイドロール５０．６０に＆いて、ベ
ースフィルム４５のみが剥され、表面に金属層を有する
柔軟なウレタンフオームＢは、巻キ取すロール（Ｓ示せ
ず）に巻１１取られ、又は所定寸法に裁断される。勿論
、ベースフィルムを剥さないで、転写７Ｉｆｉｆム力積
層され九つレタンフオームｔａｍｅリロールに巻き取や
、又は所定寸法に裁断し、使用時にベースフィルムのみ
ｔｌｌｌシて用いることもできる。In addition to the a-adic method, Fig. 4 shows the main parts of the *ah example [schematically shown as circles; as a means of bonding the metal layer, soft 9-lethane foam is added ()L/-j, jfi rate-ν This is the case of nine. The surface of the soft urethane foam 4M supplied from the supply roll 4M is heated and melted by the burner 48, and then supplied from another supply roll 1@/go by the press roll 57, 67, 77. metal layer 41,
The flexible urethane foam B having a metal layer on its surface is welded to the metal layer 41 of the transfer film 46 made of the base film 45 and placed on the guide roll 50, 60, and then only the base film 45 is peeled off. It is wound 11 on a roll (S not shown) or cut into a predetermined size. Of course, without peeling off the base film, it is also possible to transfer and laminate the film and wind it up on a reroll, or cut it to a predetermined size, and then use only the base film when using it.
このフレームラミネーＹＨンの条件は、一般のフレーム
ラミ車−ｖａンと＊Ｓでよ（、バーナーのｍ度は６００
〜１６００℃程度、ウレタンフオームの加熱ＩＩｊＩ！
融される厚さは０．２〜１．５鱈程度、ラミネ−）ｊ１
度は１５〜ｊｓ５１１／分程度である。The conditions for this frame lamination YH are a general frame lamination car -van and *S (the burner m degree is 600
Heating urethane foam at ~1600℃ IIjI!
The melted thickness is about 0.2 to 1.5 pieces, laminated) j1
The frequency is about 15 to 511/min.
本発明による１ｌｒｆ１に金属層を有する柔軟なウレタ
ンフオームは、軟質ウレタンフオームＩＩＩＩＫ、金属
蒸着層の転写からなる０Ｊ１５〜１１ノの厚さの金１１
１ｐＩＩｊｔ−自してなるために柔軟性を損なうことな
く、又、該ウレタンフオームの伸張、屈自、圧纏尋によ
っても金属層に鹸、キレツ等を生じない、集しい外ｍを
有するものであり、断熱材、外装材、衣、ｌＩ尋の幅広
い用途を有するものである。The flexible urethane foam with a metal layer on 1lrf1 according to the present invention consists of a soft urethane foam IIIK, a transfer of a metallized layer of gold 11 with a thickness of 0J15 to 11 mm.
1pIIjt - It has a convergent outer diameter that does not impair its flexibility because it is formed by itself, and does not cause cracks, cracks, etc. in the metal layer even when the urethane foam is stretched, bent, or compressed. It has a wide range of uses, including insulation, exterior materials, clothing, and clothing.
又、もう一つの発明である、表１ｉＫ金属層を有する柔
軟なウレタンフオームの１ｌＩＲ的製造方法は、本＠咽
のウレタンフオームを最も効率よく連続的Ｋｌｌ造する
ものであ伽、且つ本製造方法により初めて該ウレタンフ
オームを擬造することが嗜能となつ九ものである。In addition, another invention, the 1IR method for manufacturing a flexible urethane foam having a metal layer in Table 1, is the most efficient method for manufacturing the urethane foam continuously, and the present manufacturing method. It is a hobby to imitate the urethane foam for the first time.
第１１１１は、本発明による表面に金属層を有する柔軟
なウレタンフオームの一実施例の斜ｌ１ｗ、第２１１線
該ウレタンフオームの他ｔ！施例の斜視図、第６図は該
ウレタンフオームの製造方法の一実施例の説明−、第４
図は該製造方法の他奥株例の主要部分を説明する図であ
る。
Ａ、Ｂ・・・表面に金属層を有する柔軟なウレタンフオ
ーム、１１．２１．６１．４１・・・金属層、１２・・
・接着剤層、６２・・・接着剤、１６．２１１．６６．
４６・・・軟質ウレタンフオーム、墨４・・・供給ロー
ル、４４・・・巻暑取９０−ル、６５．４５・・・ベー
スフィルム、
６４．４６・・・転写フィルム、
ｓ７．４７．５７．６７．７７・・・圧着−−ル、墨８
・・・接着剤論布装置、４８・・・バーナー、！１９・
・・供ｌＩＦロール、４９・・・巻き取９ｇ−ル、４０
．５０．６０・・・ガイドロールThe 1111th line is an example of the flexible urethane foam having a metal layer on the surface according to the present invention, and the 211th line is t! A perspective view of the embodiment, FIG. 6 is an explanation of an embodiment of the method for manufacturing the urethane foam, and FIG.
The figure is a diagram illustrating the main parts of an example of the manufacturing method. A, B...Flexible urethane foam having a metal layer on the surface, 11.21.61.41...Metal layer, 12...
- Adhesive layer, 62...Adhesive, 16.211.66.
46... Soft urethane foam, ink 4... Supply roll, 44... Winding heat removal 90-roll, 65.45... Base film, 64.46... Transfer film, s7.47.57 .67.77...Crimp-le, black 8
...adhesive discussion device, 48...burner,! 19・
... Serving lIF roll, 49... Winding 9g roll, 40
．． 50.60...Guide roll
Claims (1)
写されてなる金属層を有する仁とを特徴とする、表１１
に金属層を有する柔軟なウレタンフオーム。 ２金属層の厚みがＱ０６乃＠（１１，＆であることを特
徴とする特許′ａ求のｍｉｓ第１項記載の表−に金属層
を書する柔軟＆？レーンフオーム。 五査属蒸着層から１に為金属層ｔプラスチツタスフイル
ムからなるベースフィルム上に設け、かくして１１６ｔ
した金属層−ベースフィルム一体構造物からなるｌｉ写
フィルムｔＩＩ曹手纜によって軟質？レーンフオーム上
に、ベースフィルム備が外１１１に１に為ように積項し
、その俵、ベースフィルムのみを稠すること１ｍ黴とす
る、褒＃に金属層を有する柔軟１に中し！ンフオームの
ａｍ的調造方法。 歳接着手段がｊＩ着剤によることを特徴とする特許ｍ求
のｌ１１８第６項記載の表面に金属層を有する柔軟＆？
レタンフオームの連続的製造方法。 Ｓ、ＩＩ着手樗が軟質ウレタンフオームの加熱溶着によ
ることを特徴とする特許請求の範囲第６項記載[Claims] 1. Table 11 characterized by a soft sheen form 1IIiK and a metal layer having a metal layer transferred thereto.
Flexible urethane foam with metal layer on top. 2 Flexible &? lane form in which the metal layer is written on the table described in the mis item 1 of the patent 'a request, which is characterized in that the thickness of the metal layer is Q06~@(11, &. From 1 to 1, a metal layer t is provided on a base film consisting of a plastic film, thus 116t
The lithographic film TII consists of an integrated structure of a metal layer and a base film, and is soft due to its texture. On the lane form, the base film is multiplied so that it is on the outside 111, and the bale is made into a 1m mold by hardening only the base film. A method for preparing am foam. The flexible &?
Continuous manufacturing method for retan foam. Claim 6, characterized in that the S and II start holes are formed by heat welding of soft urethane foam.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57009724A JPS58126145A (en) | 1982-01-25 | 1982-01-25 | Soft urethane foam, surface thereof has metallic layer, and its continuous manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57009724A JPS58126145A (en) | 1982-01-25 | 1982-01-25 | Soft urethane foam, surface thereof has metallic layer, and its continuous manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58126145A true JPS58126145A (en) | 1983-07-27 |
| JPH0160410B2 JPH0160410B2 (en) | 1989-12-22 |
Family
ID=11728245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57009724A Granted JPS58126145A (en) | 1982-01-25 | 1982-01-25 | Soft urethane foam, surface thereof has metallic layer, and its continuous manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58126145A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008279666A (en) * | 2007-05-11 | 2008-11-20 | Panefuri Kogyo Kk | Metallic tone decorative sheet and metallic tone decorative material |
| EP2368957A1 (en) * | 2010-03-26 | 2011-09-28 | Sika Technology AG | Reinforcement element for reinforcing cavities in structural parts |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4938972A (en) * | 1972-08-19 | 1974-04-11 | ||
| JPS5248908A (en) * | 1975-10-14 | 1977-04-19 | Exxon Research Engineering Co | Facsimile scanning system and method |
| JPS52124912A (en) * | 1976-04-09 | 1977-10-20 | Toyo Aluminium Kk | Production of metalized paper |
| JPS5582641A (en) * | 1978-12-19 | 1980-06-21 | Toyo Aluminium Kk | Method of making metalized sheet |
| JPS5587544A (en) * | 1978-12-26 | 1980-07-02 | Toyo Aluminium Kk | Preparation of metalized laminate |
-
1982
- 1982-01-25 JP JP57009724A patent/JPS58126145A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4938972A (en) * | 1972-08-19 | 1974-04-11 | ||
| JPS5248908A (en) * | 1975-10-14 | 1977-04-19 | Exxon Research Engineering Co | Facsimile scanning system and method |
| JPS52124912A (en) * | 1976-04-09 | 1977-10-20 | Toyo Aluminium Kk | Production of metalized paper |
| JPS5582641A (en) * | 1978-12-19 | 1980-06-21 | Toyo Aluminium Kk | Method of making metalized sheet |
| JPS5587544A (en) * | 1978-12-26 | 1980-07-02 | Toyo Aluminium Kk | Preparation of metalized laminate |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008279666A (en) * | 2007-05-11 | 2008-11-20 | Panefuri Kogyo Kk | Metallic tone decorative sheet and metallic tone decorative material |
| EP2368957A1 (en) * | 2010-03-26 | 2011-09-28 | Sika Technology AG | Reinforcement element for reinforcing cavities in structural parts |
| WO2011117405A1 (en) * | 2010-03-26 | 2011-09-29 | Sika Technology Ag | Reinforcing element for reinforcement in cavities of structural components |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0160410B2 (en) | 1989-12-22 |
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