JPS58121690A - Sic light emitting diode - Google Patents

Sic light emitting diode

Info

Publication number
JPS58121690A
JPS58121690A JP57003574A JP357482A JPS58121690A JP S58121690 A JPS58121690 A JP S58121690A JP 57003574 A JP57003574 A JP 57003574A JP 357482 A JP357482 A JP 357482A JP S58121690 A JPS58121690 A JP S58121690A
Authority
JP
Japan
Prior art keywords
type
layer
light emitting
layers
type sic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57003574A
Other languages
Japanese (ja)
Inventor
Toshitake Nakada
中田 俊武
Akira Ibaraki
茨木 晃
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Electric Co Ltd
Sanyo Denki Co Ltd
Original Assignee
Sanyo Electric Co Ltd
Sanyo Denki Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Electric Co Ltd, Sanyo Denki Co Ltd filed Critical Sanyo Electric Co Ltd
Priority to JP57003574A priority Critical patent/JPS58121690A/en
Publication of JPS58121690A publication Critical patent/JPS58121690A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/26Materials of the light emitting region
    • H01L33/34Materials of the light emitting region containing only elements of Group IV of the Periodic Table
    • H01L33/343Materials of the light emitting region containing only elements of Group IV of the Periodic Table characterised by the doping materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/0004Devices characterised by their operation
    • H01L33/0008Devices characterised by their operation having p-n or hi-lo junctions
    • H01L33/0016Devices characterised by their operation having p-n or hi-lo junctions having at least two p-n junctions

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)

Abstract

PURPOSE:To form a multicolor or all color light emitting diode which has a simple structure and which can be readily manufactured by accumulating a plurality of N type SiC layers having different impurity states on a P type SiC layer. CONSTITUTION:6H type first n type SiC layer 22, P type SiC layer 23 and second n type SiC layer 24 are sequentially laminated by epitaxial grown on a 6H type n type SiC substrate 21. The layers 22 and 24 respectively contain Ga and Al impurities, and the layer 23 contains as acceptor impurity Al. Accordingly, a green color light emitting junction 25 is formed in the boundary between the layers 22 and 23, and a blue color light emitting junction 26 is formed in the boundary between the layers 24 and 23.

Description

【発明の詳細な説明】 本発明は5IC(炭化ケイ素)発光ダイオードに関する
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a 5IC (silicon carbide) light emitting diode.

SiCは間接遷移型のW−W化合物であり、種々の結晶
構造が存在し、その禁止帯幅は2.39〜5.536V
4で多岐にわたる。従って赤色から青色まで全ての可視
光を発光させることが可能である。
SiC is an indirect transition type W-W compound, and there are various crystal structures, and its forbidden band width is 2.39 to 5.536V.
4 and wide variety. Therefore, it is possible to emit all visible light from red to blue.

第1図は従来のGaP(ガリウム燐)多色発光ダイオー
ドで採用されているnPPn構造をS1Cに適用した本
のであり、(1)は6H(ヘキサゴナ−/L’ ) タ
イプのn型S10基板、(2)〜(5)Fi該基板上に
順次エピタキシャル成長にて積層され、夫々6Hタイプ
である第1n型S10層、第1PtjIIS10層、第
2P型SiC層及び第2n型StC層である。
Figure 1 is a book in which the nPPn structure adopted in conventional GaP (gallium phosphide) multicolor light emitting diodes is applied to S1C, and (1) is a 6H (hexagonal/L') type n-type S10 substrate, (2) to (5) Fi are a first n-type S10 layer, a first PtjIIS10 layer, a second P-type SiC layer, and a second n-type StC layer, each of which is 6H type, and are epitaxially grown on the Fi substrate.

第1n型5i−0層(2)はドナー不純物としてN(窒
素)を含むと共に、Ga(ガリウム)を含むことにより
緑色発光中心としてのGa−N対を有し、また第1P型
S1C層(3)はアクセプター不純物として、Gaを含
んでおり、従って第1n型SIC層(2)と第1P型S
iO層(3)との界面には緑色発光接合(6)が存在す
ることとなる。
The first n-type 5i-0 layer (2) contains N (nitrogen) as a donor impurity and Ga (gallium), so it has a Ga-N pair as a green emission center, and the first P-type S1C layer ( 3) contains Ga as an acceptor impurity, and therefore the first n-type SIC layer (2) and the first P-type S
A green light-emitting junction (6) is present at the interface with the iO layer (3).

第2n型S10層(5)はドナー不純物としてNを含む
と共にAn(アルミニウム)′f:含むことにより青色
発光中心としてのAl−N対を有し、また$2P型Si
O層(4)はアクセプター不純物としてAIを含んでお
り、従ッテjl 2 n型SiC層(5)ト第2P型S
iO層(4)との界面には青色発光接合(7)が存在す
ることとなる。
The second n-type S10 layer (5) contains N as a donor impurity, and contains An (aluminum)'f:, thereby having an Al-N pair as a blue emission center, and also contains $2P type Si.
The O layer (4) contains AI as an acceptor impurity, and the second p-type S
A blue light-emitting junction (7) is present at the interface with the iO layer (4).

(8)は基板(1)裏面に形成されたオーミック性の第
1電極、(9)は第2n型S10層(5)上に形成石れ
たオーミック性の第2電極、αOは第2n型SiC層(
5)の一部をエツチング除去したのちに露出した第2P
型SIC層(4)表面に形成されたオーミック性の第5
電極である。
(8) is the first ohmic electrode formed on the back surface of the substrate (1), (9) is the second ohmic electrode formed on the second n-type S10 layer (5), and αO is the second n-type electrode. SiC layer (
5) The second P exposed after removing a part of it by etching
Ohmic fifth layer formed on the surface of the type SIC layer (4)
It is an electrode.

斯る装置では第1電極(8)−第3電極αO間に順方向
バイアスを印加すると緑色発光接合(6)付近より緑色
光が発し、また第2電極(9)−第3電極αO間に順方
向バイアスを印加すると青色発光接合(7)付近より青
色光が発する。更に第1電極(8)−第3電極00間及
び第2電極(9)−第5電極αO間の夫々に適当な電流
を流せば緑から青までの色を発光させることが可能であ
る。
In such a device, when a forward bias is applied between the first electrode (8) and the third electrode αO, green light is emitted from near the green light emitting junction (6), and between the second electrode (9) and the third electrode αO. When a forward bias is applied, blue light is emitted near the blue light emitting junction (7). Furthermore, by flowing appropriate currents between the first electrode (8) and the third electrode 00 and between the second electrode (9) and the fifth electrode αO, it is possible to emit light in colors from green to blue.

上記発光は夫々のn型SLC層(2’)(5)に含まれ
たドナー不純物量及びアクセプター不純物(Ga、A 
l )により形成されたドナー準位とアクセプター準位
との間で生じる電子と正孔との再結合により生じるもの
である。またこのとき上記第1、第2P型Si、0層(
3)(4)は単にPn接合を形成している第1、第2n
型SiC層(2)(5)に正孔を供給する供給源の役割
を果しているのみである。
The above light emission is caused by the amount of donor impurities and acceptor impurities (Ga, A
This is caused by the recombination of electrons and holes that occur between the donor level and acceptor level formed by (1). At this time, the first and second P-type Si, 0 layers (
3) (4) simply refers to the first and second n junctions forming a Pn junction.
It only serves as a source for supplying holes to the type SiC layers (2) and (5).

本発明は斯る知見に基づいてなされたもので、構造が簡
単で製造が容易な多色発光S10ダイオード等を提供せ
んとする本のであり、その特徴はP型S1C層上に異な
る不純物状態を有した複数のN型SIC層が堆積してい
ることである。以下実施例に基づき本発明を説明する。
The present invention has been made based on such knowledge, and is a book that attempts to provide a multicolor light emitting S10 diode etc. that has a simple structure and is easy to manufacture. A plurality of N-type SIC layers are deposited. The present invention will be explained below based on Examples.

第2図は本発明の一実施例を示し、(ハ)は6Hタイプ
nm51c基板、に)〜(財)は該基板上に順次工型5
i−0層(イ)及び第2n型S10層(財)は夫々第1
図の第1n型5i−0層(2)及び第2n層SiC層(
5)と同一の不純物を含み、またP型SICFm@はA
lをアクセプター不純物として含んでいる。従って第1
n型SIC層四とP型S10層(2)との界面には緑色
発光接合(ホ)が、また第2n型5i−Cjl(財)と
pmsxc@(至)との界面には青色発光接合(ホ)が
夫々形成されている。
FIG. 2 shows an embodiment of the present invention, in which (c) is a 6H type nm51c substrate, and (c) to (b) are sequentially formed molds 5 on the substrate.
The i-0 layer (A) and the second n-type S10 layer (F) are the first
The first n-type 5i-0 layer (2) and the second n-type SiC layer (
5), and P-type SICFm@A
Contains l as an acceptor impurity. Therefore, the first
There is a green light-emitting junction (e) at the interface between the n-type SIC layer 4 and the p-type S10 layer (2), and a blue light-emitting junction at the interface between the second n-type 5i-Cjl (foundation) and pmsxc@ (to). (e) are formed respectively.

勾、翰は基板(ハ)裏面及び第2n型5iCjl−表面
に夫々形成され九オーミック性の第1及び第2電極、@
は第2n型StC@−の一部を除去して露出したP型S
’xC@@上に形成されたオーミック性の第3電極であ
る。
The slope and the fence are formed on the back surface of the substrate (c) and the surface of the second n-type 5iCjl-, respectively, and are 9-ohmic first and second electrodes, @
is the P-type S exposed by removing a part of the second n-type StC@-
It is an ohmic third electrode formed on 'xC@@.

斯る装置では第1図装置と同様に第1電極(2)−第3
電極四間、第2電極(至)−第3電極四間に夫々順方向
バイアスを印加すれば緑及び青色の発光が得られ、また
両電極間に適当な電流を同時に印加すると青から緑まで
の種々の発光色が得られる。
In such an apparatus, the first electrode (2) - the third electrode are connected similarly to the apparatus shown in FIG.
By applying a forward bias between the four electrodes and between the second and third electrodes, green and blue light emission can be obtained, and by applying an appropriate current between both electrodes at the same time, light emission from blue to green can be obtained. A variety of luminescent colors can be obtained.

本実施例装置では、P型51aIl@の両側に第1及び
第2n型SIC層−を成長させているので第1図の従来
構造に比してP型SIC層が一つ少なくてすむ。従って
P型SIC層製造のための一工程が省略でき生産コスト
を低くすることができる。
In the device of this embodiment, since the first and second n-type SIC layers are grown on both sides of the P-type 51aIl@, one less P-type SIC layer is required compared to the conventional structure shown in FIG. Therefore, one step for manufacturing the P-type SIC layer can be omitted, and production costs can be reduced.

第5図は他の実施例を示し、赤から青までの金色を発光
可能な金色発光SICダイオードに本発明を適用したも
のである。
FIG. 5 shows another embodiment in which the present invention is applied to a gold light emitting SIC diode capable of emitting gold colors ranging from red to blue.

図中、01は6HタイプHmSi−C基板、(2)〜(
至)は該基板上に順次エピタキシャル成長により積層さ
れた6Hタイプの第1n型S1C層、第1P型SIC層
、第2n型stc層、第5nl!SiC層、第2P型S
tC層である。
In the figure, 01 is a 6H type HmSi-C substrate, (2) to (
(to) is a 6H type first n-type S1C layer, first P-type SIC layer, second n-type STC layer, and fifth nl! layer, which are sequentially laminated on the substrate by epitaxial growth. SiC layer, second P type S
This is the tC layer.

第1nIJiSiCIll@はドナー不純物としてNを
含むと共にBe(べIJIJウム)を含んで赤色発光第
1、第2 nft1s ICJl@Hと同様に不純物と
してGa、N及びAI、Nを含み、夫々緑色及び青色発
光中心としてのGa−N対及びAI−N対を有している
。更に第1、第2P型5i−OJl(至)(至)は共に
アクセプタ不純物としてAJを含んでいる。
The 1st nFT1s ICJl@H contains N as a donor impurity and also Be (Be) and emits red light.Similar to the 1st and 2nd nft1s ICJl@H, it contains Ga, N and AI, N as impurities, and emits green and blue light, respectively. It has a Ga-N pair and an AI-N pair as luminescent centers. Further, both the first and second P-type 5i-OJl (to) (to) contain AJ as an acceptor impurity.

従ッテ第1n型SLC@@と第1P型51CJ11@と
の界面は赤色発光接合(至)となり、また第2n型st
c層(至)と第lPmSi、C11(至)との界面は緑
色H〜(41d夫*基t1.ee裏面、12Pmsic
Jlc!4表面、第2P型Si、Cjl(至)を除去し
て露出した第3n型5iCJIC11表面及び第2 P
mIs 1011% 〜第2nmSiCjll(ロ)を
除去して露出した第1P型stcm@表面に夫々形成さ
れたオーミック性の第1〜第4電極である。
The interface between the first n-type SLC@@ and the first P-type 51CJ11@ becomes a red light-emitting junction (to), and the second n-type
The interface between the c layer (to) and the 1st PmSi, C11 (to) is green
Jlc! 4 surface, the 2nd P type Si, the 3rd n type 5iCJIC11 surface exposed by removing Cjl, and the 2nd P type
mIs 1011% - Ohmic first to fourth electrodes are respectively formed on the first P-type stcm@ surface exposed by removing the second nm SiCjll (b).

斯る装置では、第1電極(イ)−第4電極榊間、第6電
極(転)−第4電極−間及び第2電極@ルー第5電極−
間に夫々順方向バイアスを印加すると赤色発光接合(ロ
)、緑色発光接合(至)及び青色発光接合員付近から夫
々赤色光、緑色光及び青色光が得られる。
In such a device, the distance between the first electrode (a) and the fourth electrode Sakaki, between the sixth electrode (rotation) and the fourth electrode, and between the second electrode and the fifth electrode
When a forward bias is applied between them, red light, green light, and blue light are obtained from the vicinity of the red light-emitting junction (b), the green light-emitting junction (to), and the blue light-emitting junction, respectively.

また上記3電極間に夫々適当な電流を同時に印加すると
、赤から青までの種々の発光色を得ることが可能である
Furthermore, by simultaneously applying appropriate currents between the three electrodes, it is possible to obtain various luminescent colors from red to blue.

また、本実施例も第1の実施例と同様に第1P型SiC
層(至)が赤色発光接合(ロ)及び緑色発光接合に)に
対して共通P型層となっているので生産コストが安くな
る。
Further, in this example, similarly to the first example, the first P-type SiC
Since the layers (to) are common P-type layers for the red light-emitting junction (b) and the green light-emitting junction, production costs are reduced.

jJA図は更に他の実施例を示し、本発明をLED平面
表示装置に応用したものである。
Figure jJA shows still another embodiment in which the present invention is applied to an LED flat display device.

図中、θηはn型SiC基板、−は該基板上に形成され
アクセプター不純物としてAIを含むP型SiC層、■
は該P型S10層を絵素(財)単位に相互に電気的に分
離する溝、に)〜@は上記絵素(財)毎に形成された第
1〜第3n型5i−0層であり、該第1〜第3n型Si
C11mは夫々第2の実施例の第1〜第3n型5IC4
@@@(至)と同一材料からなり、赤色発光中心として
のBe−N対、緑色発光中心としてのGa−N対、青色
発光中心としてのAd−N対を夫々有している。従って
第1〜第6n型S1C層−〜に)とP型S10層−との
界面には夫々赤色発光接合−1緑色発光接合■、青色発
光接合−が夫々形成される。
In the figure, θη is an n-type SiC substrate, - is a p-type SiC layer formed on the substrate and containing AI as an acceptor impurity,
is a groove that electrically separates the P-type S10 layer from each other on a picture element (goods) basis; Yes, the first to third n-type Si
C11m are the first to third n-type 5IC4 of the second embodiment, respectively.
It is made of the same material as @@@ (to) and has a Be-N pair as a red emission center, a Ga-N pair as a green emission center, and an Ad-N pair as a blue emission center. Therefore, a red light emitting junction (1), a green light emitting junction (1), and a blue light emitting junction (2) are formed at the interfaces between the first to sixth n-type S1C layers (-) and the P-type S10 layer, respectively.

輔は上記絵素−毎にP型SIC層−上に形成されたオー
ミック性の共通電極、匈〜−は上記第1〜第5n型S1
C層−〜(ロ)上に夫々形成されたオiツク性の第1〜
第3電極である。
茈 is an ohmic common electrode formed on the P-type SIC layer for each picture element, and 匈 is the first to fifth n-type S1.
C layer-~ (b) The first layer of acidity formed on each layer.
This is the third electrode.

斯る装置において共通電極参めと第1〜第3電極−〜−
との各々の間に夫々順方向バイアスを印加すれば、上記
3接合−〜輪より夫々赤色光、緑色光及び青色光が得ら
れ、また上記各電極間に同時に順方向バイアスを印加す
ると共に各印加バイアスを調節することにより各絵素一
単位毎に赤〜青までの種々の発光色を得ることができる
In such a device, the common electrode and the first to third electrodes
If a forward bias is applied between each of the electrodes, red light, green light, and blue light are obtained from the three junctions. By adjusting the applied bias, it is possible to obtain various luminescent colors from red to blue for each pixel unit.

斯る装置はn型S1C基板ゆ上にP型SiC層四を形成
すると共に斯る層を絵素一単位に相互に電気的に分離し
た後、上記絵素(財)毎に上記第1〜第3n型SiO層
−〜−を選択的に形成することにより得られるので構造
が簡単で生産性に豊んでいる。
In such a device, four P-type SiC layers are formed on an n-type S1C substrate, and after these layers are electrically isolated from each other in units of picture elements, the above-mentioned first to fourth layers are formed for each picture element. Since it is obtained by selectively forming the third n-type SiO layers, the structure is simple and the productivity is high.

尚、上記第2〜第4図に示した実施例では成長層として
全て6HタイプSiC層を用いたが、例えば赤色発光中
心を有するn型S10層を3C(キュービック)タイプ
SiC層にすること本可能であり、この場合不純物とし
てFiB(ホウ素)、N〜が好適である。またP型S1
C層の不純物をAjとしたがGa、Be等を用いてもよ
い。更に本実施例におけるn型SIC層の成長ではP型
SiC層の不純物がn型S1C層に拡散して斯る層の発
光中心を変化しないようにすることが重要であり、従っ
て斯るn型S10層の成長は気相成長法が好適である。
In the embodiments shown in FIGS. 2 to 4 above, 6H type SiC layers were used as growth layers, but it is also possible to replace the n-type S10 layer with a red luminescent center with a 3C (cubic) type SiC layer, for example. It is possible, and in this case, FiB (boron) and N~ are suitable as impurities. Also, P type S1
Although the impurity of the C layer is Aj, Ga, Be, etc. may also be used. Furthermore, in the growth of the n-type SIC layer in this example, it is important to prevent the impurities of the P-type SiC layer from diffusing into the n-type S1C layer and changing the emission center of this layer. A vapor phase growth method is suitable for growing the S10 layer.

以上の説明から明らかな如く、本発明によればSiC結
晶より多色もしくは金色発光ダイオードを形成する場合
構造が簡単で生産性に豊むという効果が得られる。
As is clear from the above description, according to the present invention, when forming a multicolor or golden light emitting diode using SiC crystal, the structure is simple and the productivity is high.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来のnPPn構造の多色発光SiOダイオー
ドを示す断面図、第2図は本発明の一実施例を示す断面
図、第3図は他の実施例を示す断面図、第4図は更に他
の実施例を示す断面図である。 翰、04、(2)、(至)、輪、輪、64−n型SiC
層、翰、(至)、−・・・P型SXC層。
Fig. 1 is a sectional view showing a conventional multicolor light emitting SiO diode with an nPPn structure, Fig. 2 is a sectional view showing one embodiment of the present invention, Fig. 3 is a sectional view showing another embodiment, and Fig. 4. FIG. 7 is a sectional view showing still another embodiment. Kan, 04, (2), (to), ring, ring, 64-n type SiC
layer, 翰, (to), ---P type SXC layer.

Claims (1)

【特許請求の範囲】[Claims] (1)異なる不純物を有する複数のn型SIC層が一つ
のP型SiC層と夫々P−n接合を形成していることを
特徴とする810発光ダイオード。
(1) An 810 light emitting diode characterized in that a plurality of n-type SIC layers having different impurities each form a P-n junction with one P-type SiC layer.
JP57003574A 1982-01-12 1982-01-12 Sic light emitting diode Pending JPS58121690A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57003574A JPS58121690A (en) 1982-01-12 1982-01-12 Sic light emitting diode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57003574A JPS58121690A (en) 1982-01-12 1982-01-12 Sic light emitting diode

Publications (1)

Publication Number Publication Date
JPS58121690A true JPS58121690A (en) 1983-07-20

Family

ID=11561217

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57003574A Pending JPS58121690A (en) 1982-01-12 1982-01-12 Sic light emitting diode

Country Status (1)

Country Link
JP (1) JPS58121690A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60143679A (en) * 1983-12-29 1985-07-29 Sanyo Electric Co Ltd Sic light emitting diode
JPS6164175A (en) * 1984-09-06 1986-04-02 Ulvac Corp Amorphous semiconductor light-emitting diode and plane display device utilizing said diode
US5433167A (en) * 1992-02-04 1995-07-18 Sharp Kabushiki Kaisha Method of producing silicon-carbide single crystals by sublimation recrystallization process using a seed crystal

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50151484A (en) * 1974-05-27 1975-12-05
JPS5212554A (en) * 1975-07-21 1977-01-31 Nec Corp Vertical type current converter circuit
JPS5383588A (en) * 1976-12-29 1978-07-24 Mitsubishi Electric Corp Manufacture of substrate for semiconductor light emitting device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50151484A (en) * 1974-05-27 1975-12-05
JPS5212554A (en) * 1975-07-21 1977-01-31 Nec Corp Vertical type current converter circuit
JPS5383588A (en) * 1976-12-29 1978-07-24 Mitsubishi Electric Corp Manufacture of substrate for semiconductor light emitting device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60143679A (en) * 1983-12-29 1985-07-29 Sanyo Electric Co Ltd Sic light emitting diode
JPS6164175A (en) * 1984-09-06 1986-04-02 Ulvac Corp Amorphous semiconductor light-emitting diode and plane display device utilizing said diode
US5433167A (en) * 1992-02-04 1995-07-18 Sharp Kabushiki Kaisha Method of producing silicon-carbide single crystals by sublimation recrystallization process using a seed crystal

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