JPS5811833B2 - Method for producing powdered oil and fat with foaming properties - Google Patents

Method for producing powdered oil and fat with foaming properties

Info

Publication number
JPS5811833B2
JPS5811833B2 JP54028920A JP2892079A JPS5811833B2 JP S5811833 B2 JPS5811833 B2 JP S5811833B2 JP 54028920 A JP54028920 A JP 54028920A JP 2892079 A JP2892079 A JP 2892079A JP S5811833 B2 JPS5811833 B2 JP S5811833B2
Authority
JP
Japan
Prior art keywords
powdered
fat
oil
acetylated monoglyceride
emulsification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP54028920A
Other languages
Japanese (ja)
Other versions
JPS55120746A (en
Inventor
俊昭 中瀬
裕三 池添
光治 夕田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN BITAMIN KK
Original Assignee
RIKEN BITAMIN KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN BITAMIN KK filed Critical RIKEN BITAMIN KK
Priority to JP54028920A priority Critical patent/JPS5811833B2/en
Publication of JPS55120746A publication Critical patent/JPS55120746A/en
Publication of JPS5811833B2 publication Critical patent/JPS5811833B2/en
Expired legal-status Critical Current

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  • Edible Oils And Fats (AREA)

Description

【発明の詳細な説明】 本発明は適当量の水又は牛乳に溶解し常温でホイツピン
グする事により極めて短時間でホイツピングクリームが
得られる粉末ホイツピングクリームミックスの主成分で
ある起泡性を有する粉末油脂の製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention provides a foaming agent which is the main component of a powdered whipping cream mix that can be dissolved in an appropriate amount of water or milk and whipped at room temperature to obtain whipping cream in a very short time. The present invention relates to a method for producing powdered oil and fat having the following.

従来、粉末ホイツピングクリームミックスは新鮮生牛乳
から分離して得られる生クリームに比較して四季を通じ
て性能が一定であり、又保存貯蔵性に優れている点を特
長として製造が行なわれ、その後の技術的進歩により現
在市販されている数種類のミックスについては極めて短
時間でホイップし、しかも保型性のよいものもみうけら
れる。
Traditionally, powdered whipping cream mixes have been produced with the characteristics of consistent performance throughout the seasons and superior storage stability compared to fresh cream obtained by separating fresh raw milk. Due to technological advances, several types of mixes currently on the market can be whipped in an extremely short time and have good shape retention.

従って単に性能的な面からのみ評価すればほぼ満足出来
るものといえるが、反面風味、食感に関してはかなり悪
く、特に訓練された官能検査パネルでなくとも、口どけ
が悪く口中にベラトリと残る感じや、のどを通過した時
感じる臭味、舌で感じる苦味などを明らかに感じる。
Therefore, if evaluated solely from a performance standpoint, it can be said to be almost satisfactory, but on the other hand, the flavor and texture are quite poor, and even without a particularly trained sensory evaluation panel, it does not melt in the mouth and leaves a sticky feeling in the mouth. You can clearly feel the odor and taste that you feel when it passes through your throat, and the bitterness that you feel on your tongue.

これらは短時間でホイップし、保型性を良くする目的で
使用されている不飽和脂肪酸を含む構成脂肪酸から成る
乳化剤に主原因があるが、この外にも乳化剤量が多い場
合とか天然又は合成糊料を使用した場合にもみられる現
象で、これまでの技術的知見ではホイツプ性及保型性と
風味及食感の良いことは矛盾する現象と考えられており
、同時に満足させる事は困難とされていた。
The main cause of these problems is the emulsifier made of constituent fatty acids including unsaturated fatty acids, which is used for whipping in a short time and improving shape retention, but there are also other causes such as when the amount of emulsifier is large, natural or synthetic. This phenomenon is also seen when starch is used, and according to the technical knowledge up to now, whipping properties and shape retention and good flavor and texture are considered to be contradictory phenomena, and it is difficult to satisfy them at the same time. It had been.

本発明者らは上述したような粉末ホイツピングクリーム
ミックスの性能及び風味、食感を同時に満足させうる起
泡性粉末油脂の開発について鋭意研究の結果、融点35
〜45℃の油脂に対して10〜40チのアセチル化モノ
グリセリド又はアセチル化モノグリセリドとレシチンを
混合し、次いでカゼインナトリウム、粉末水飴、ぶどう
糖、砂糖、乳糖、デキストリン、リン酸または縮合リン
酸のアルカリ塩類などの1種または2種以上を溶解した
水溶液に加え、2段均質化乳化を行うに際して1段目の
乳化圧を少なくとも150KP/cm2以上、2段目の
乳化圧を50に2/cm2以下で乳化した後乾燥粉末化
することにより、ホイツピングの速さ及び保型性の良い
、なおかつ風味、食感の優れた粉末油脂を製造し得るこ
とを見出した。
As a result of intensive research into the development of a foaming powdered fat that can simultaneously satisfy the performance, flavor, and texture of the powdered whipping cream mix described above, the present inventors found that the melting point is 35.
Mix 10 to 40 grams of acetylated monoglyceride or acetylated monoglyceride and lecithin to oil and fat at ~45°C, then add sodium caseinate, powdered starch syrup, glucose, sugar, lactose, dextrin, phosphoric acid or an alkali salt of condensed phosphoric acid. When performing two-stage homogenization emulsification, the emulsification pressure in the first stage should be at least 150 KP/cm2 or more, and the emulsification pressure in the second stage should be at least 50 2/cm2. It has been found that by emulsifying and then drying and powdering, it is possible to produce powdered fats and oils that have good whipping speed and shape retention, as well as excellent flavor and texture.

本発明は起泡性を有する粉末油脂中の乳化剤として従来
必要とされていた不飽和脂肪酸を有する乳化剤を全く使
用せず、アセチル化モノグリセリド又はアセチル化モノ
グリセリドとレシチンを油脂中に一定量加えることによ
り、性能、風味、食感及び長期保存性に優れたホイツピ
ングクリームミックス用の起泡性粉末油脂を製造するこ
とに関する。
The present invention does not use any emulsifiers containing unsaturated fatty acids, which were conventionally required as emulsifiers in powdered fats and oils that have foaming properties, but by adding a certain amount of acetylated monoglyceride or acetylated monoglyceride and lecithin to the fats and oils. This invention relates to the production of foamable powdered fats and oils for whipping cream mixes that are excellent in performance, flavor, texture, and long-term storage stability.

以下、本廃明の構成について詳しく説明する。The configuration of the present invention will be explained in detail below.

一般に起泡性を有する粉末油脂の油脂原料は融点35〜
45℃であることが必要であり、好ましくはラウリン系
の硬化油脂例えば硬化ヤシ油、硬化パーム核油またはこ
れらのエステル交換反応油脂(必要とあらば少量の高融
点硬化油脂を配合しても良い)などが用いられ、ホイツ
ピング性を持たせるためにグリセリン飽和脂肪酸モノエ
ステル脂肪球凝集により粘性を高める効果としてはグリ
セリンネ飽和脂肪酸モノエステルと抱水性の強いプロピ
レングリコール飽和脂肪酸エステルを使用し、これらの
油脂と乳化剤の混融物を粉末油脂担体として必要な糖類
、でんぷん分解物、カゼインナトリウム及少量の安定剤
とリン酸塩を溶解した水溶液に加えて混合し、次いで2
段均質化により必要な粒子の大きさに乳化した後乾燥粉
末化すど示により製造される。
In general, powdered oil and fat raw materials with foaming properties have a melting point of 35~
The temperature must be 45°C, and preferably lauric hydrogenated oils such as hydrogenated coconut oil, hydrogenated palm kernel oil, or transesterified oils and fats thereof (if necessary, a small amount of high melting point hydrogenated oils may be blended) ), etc. are used, and glycerin saturated fatty acid monoester and propylene glycol saturated fatty acid ester with strong water-holding properties are used to increase the viscosity by aggregating fat globules. A mixture of oil and emulsifier is added to an aqueous solution containing saccharides, starch decomposition products, sodium caseinate, and a small amount of stabilizer and phosphate necessary as a powdered oil carrier, and then mixed.
It is produced by emulsifying it to the required particle size by step homogenization and then drying and powdering it.

上述処方中で最も重要なのは乳化剤の種類、組合せ及使
用量である。
The most important factors in the above formulation are the type, combination and amount of emulsifier used.

これまでの知見では上記3種の乳化剤は必要不可欠とさ
れ、どれ1つ欠けても満足のゆく性能は得られないとさ
れていた。
According to the knowledge up to now, the above three types of emulsifiers are indispensable, and if any one is missing, satisfactory performance cannot be obtained.

しかしこれら乳化剤により製造された粉末油脂を使用し
たホイツピングクリニムミックスの評価については再三
述べて来たように官能的に満足出来るものではない。
However, as has been stated repeatedly, the evaluation of whipping clinic mixes using powdered fats and oils produced using these emulsifiers is not sensually satisfactory.

そこで先ず風味、食感の点で問題の有るグリセリンネ飽
和脂肪酸モノエステルを全く使用しない事により風味を
良くし、ホイツピングクリームの必要とされる性能及食
感を飽和脂肪酸系のグリセリンモノエステル、グリセリ
ンモノジエステル、ソルビタンエステル及ショ糖エステ
ルの種類と組み合せ及使用量について研究した結果、性
能と食感を同時に満足させるものは全く出来ないとの結
論に達した。
First of all, we improved the flavor by not using glycerine saturated fatty acid monoester, which has problems in terms of flavor and texture, and achieved the required performance and texture of whipping cream using saturated fatty acid glycerin monoester. As a result of researching the types, combinations, and amounts of glycerin monodiester, sorbitan ester, and sucrose ester, we came to the conclusion that it is impossible to create a product that satisfies performance and texture at the same time.

そこでこれら以外のものについて更に検討した結果、ア
セチル化モノグリセリドを使用する事1より目的を達成
出来る事を見出した。
Therefore, as a result of further investigation into substances other than these, it was found that the objective could be achieved more easily by using acetylated monoglyceride.

アセチル化モノグリセリドはモノグリセリドを無水酢酸
でアセチル化するか又は油脂(トリグリセリド)とトリ
アセチンでエステル交換反応するかして得られたものを
精製したものである。
Acetylated monoglycerides are purified products obtained by acetylating monoglycerides with acetic anhydride or transesterifying fats and oils (triglycerides) with triacetin.

特に本発明では前者の部分アセチル化したものが、その
特異的な物性、即ち低温におけるフレキシブルな性状及
びワキシーでありながら体温付近でシャープに融解する
性質から有効であり、アセチル化モノグリセリドを使用
する事によってのみ口どけの良い食感のものをつくり得
ることがわかった。
Particularly in the present invention, the former partially acetylated one is effective because of its unique physical properties, namely its flexible properties at low temperatures and the property of being waxy but melting sharply at around body temperature. It was found that only by using this method can a product with a texture that melts in the mouth be produced.

従来アセチル化モノグリセリドのホイツピングクリーム
への使用自体は文献、パンフレット等にもみられ目新し
いとは言えないが、それらの効果はあくまでグリセリン
飽和脂肪酸エステルの補助的添加剤として粉末ホイツピ
ングクリームミックスの長期安定性を保障するという点
であって、今回我々の見出したものとは本質的に異る。
Conventionally, the use of acetylated monoglycerides in whipping cream has been seen in literature, pamphlets, etc., and cannot be said to be new. This is essentially different from what we found this time in that it guarantees long-term stability.

本発明のアセチル化モノグリセリドとしてはグリセリン
飽和脂肪酸モノエステルを30〜70係部分アセチル化
したものが使用可能であるが、その物性から好ましくは
50係前後アセチル化したものが好ましい。
As the acetylated monoglyceride of the present invention, glycerin saturated fatty acid monoesters which have been acetylated at 30 to 70 degrees can be used, but in view of their physical properties, those which have been acetylated at around 50 degrees are preferred.

アセチル化モノグリセリド又はアセチル化モノグリセリ
ドとレシチンの融点35〜45℃の油脂に対する比率は
10〜40係の範囲が好ましい。
The ratio of acetylated monoglyceride or acetylated monoglyceride and lecithin to fats and oils having a melting point of 35 to 45°C is preferably in the range of 10 to 40 parts.

アセチル化モノグリセリドさレシチンを併用する場合は
アセチル化モノグリセリドに対してレシチンは1〜10
係の範囲が好ましい。
When using lecithin with acetylated monoglyceride, the ratio of lecithin to acetylated monoglyceride is 1 to 10.
The preferred range is

アセチル化モノグリセリドの量が10係以下であると腰
の出が遅く保型性も悪くなる。
If the amount of acetylated monoglyceride is less than 10%, the elasticity will be slow and the shape retention will be poor.

又40係以上になるとやはり同様の欠点が現われてくる
Also, when you reach 40 or more, the same drawbacks appear.

レシチンの使用はアセチル化モノグリセリドの使用範囲
に幅を持たせ製造時の計量のバラツキなどの影響を少な
くする効果を有する。
The use of lecithin has the effect of widening the range of use of acetylated monoglyceride and reducing the influence of variations in measurements during production.

本発明では前述のアセチル化モノグリセリドとレシチン
で充分であるが、これに更に従来使用されていたグリセ
リン飽和脂肪酸モノエステル、プロピレングリコール飽
和脂肪酸モノエステル、ソルビタン脂肪酸エステル及び
ショ糖脂肪酸エステルなどを配合してもその量が少なけ
れば本発明による性能、食感を変えることはないが、こ
れらのうちショ糖脂肪酸エステルの少量の使用は乳化を
促進する効果は認められるが、単に乳化剤の量が増すだ
けで量が過ぎれば食感を悪くするなど、必要なものとは
いえない。
In the present invention, the above-mentioned acetylated monoglyceride and lecithin are sufficient, but in addition, conventionally used glycerin saturated fatty acid monoester, propylene glycol saturated fatty acid monoester, sorbitan fatty acid ester, sucrose fatty acid ester, etc. may be blended. However, if the amount of sucrose fatty acid ester is small, the performance and texture of the present invention will not change. However, although the use of a small amount of sucrose fatty acid ester has the effect of promoting emulsification, it only increases the amount of emulsifier. If the amount is too much, the texture will deteriorate and it is not necessary.

また性能の長期安定性についても複雑な乳化系よりも本
発明の如く単純な系の方がより良いと言える。
Furthermore, in terms of long-term stability of performance, it can be said that a simple system like the present invention is better than a complicated emulsification system.

粉末化するための基材については水溶性たん白糖類など
が使用されるが、カゼインナトリウム、粉末水飴、ぶど
う糖、砂糖、乳糖、デキストリンなどが好ましい。
As the base material for powdering, water-soluble proteins and sugars are used, and sodium caseinate, powdered starch syrup, glucose, sugar, lactose, dextrin, etc. are preferable.

これらの基材は粉末油脂組成物中の20〜30係の範囲
で使用されるが、1種よりも2種以上併用した方が粉質
的な面及び性能の安定性からも好ましい。
These base materials are used in the range of 20 to 30 percent in the powdered oil and fat composition, but it is preferable to use two or more types in combination rather than one type from the viewpoint of powder quality and stability of performance.

リン酸または縮合リン酸のアルカリ塩はカゼインナトリ
ウムの溶解を助ける意味からも少量必要であり、保存中
の安定性の上からも必要であり、その量は粉末油脂組成
物中のo、ooi〜2係の範囲である。
A small amount of phosphoric acid or an alkali salt of condensed phosphoric acid is necessary to help dissolve sodium caseinate, and it is also necessary from the viewpoint of stability during storage, and the amount is determined from o, ooi to This is the range of Section 2.

安定剤については本発明の目的からは使用しないのが望
ましいが食感に影響しない程度の微量の添加は問題ない
For the purposes of the present invention, it is desirable not to use stabilizers, but there is no problem in adding them in trace amounts that do not affect the texture.

本発明品の粉末油脂はグリセリンネ飽和脂肪酸モノエス
テルを使用していない為、ホイツピング時の脂肪球の凝
集を速め腰の出を速くする為には。
The powdered oil and fat of this invention does not contain glycerine saturated fatty acid monoester, so it can speed up the aggregation of fat globules during whipping and accelerate the release of hips.

機械的に乳化の段階で油滴を出来るだけ細かくしておく
ことが好ましい。
It is preferable to mechanically make the oil droplets as fine as possible during the emulsification stage.

低くとも150Kp/cm2以上、好ましくは200〜
300Ky/cm2で1段目の乳化を行い、2段目とし
ては50Kp/cm2以下の圧で2段乳化を行うのが好
ましい。
At least 150Kp/cm2 or more, preferably 200~
It is preferable to carry out the first stage emulsification at a pressure of 300 Kp/cm2 and the second stage to carry out a two-stage emulsification at a pressure of 50 Kp/cm2 or less.

従って本発明の均質化の工程での条件は、品質を発揮維
持する為にも極めて重要であるといえる1本発明の起泡
性を有する粉末油脂の乾燥粉末化方法は噴霧乾燥、ドラ
ム乾燥、泡沫乾燥、凍結乾燥など適宜な乾燥方法を採用
し得るが、生産性及び経済性から噴霧乾燥法が好ましい
Therefore, it can be said that the conditions in the homogenization process of the present invention are extremely important in order to exhibit and maintain quality. Any suitable drying method such as foam drying or freeze drying may be used, but spray drying is preferred from the viewpoint of productivity and economy.

本発明は適当量の水又は牛乳に溶解し常温で央イツピン
グする事により極めて短時間でホイツピングクリームが
得られる粉末ホイツピングクリームミックスの主成分で
ある起泡性を有する粉末油脂を提供することにある。
The present invention provides a powdered fat and oil having foaming properties, which is the main component of a powdered whipping cream mix that can be dissolved in an appropriate amount of water or milk and whipped at room temperature to produce whipping cream in a very short time. It's about doing.

又、本発明品はホイツピングクリームミックスのみなら
ず、粉末状のアイスクリームミックス、ソフトクリーム
ミックスあるいは起泡性のデザート食品など広範囲の用
途の主成分としても使用可能である。
Furthermore, the product of the present invention can be used not only as a whipping cream mix but also as a main ingredient in a wide range of applications such as powdered ice cream mixes, soft serve mixes, and foaming dessert foods.

以下、本発明を実施例で説明する。The present invention will be explained below with reference to Examples.

実施例 比較例1〜3、実施例1〜4の各配合組成牛乳化剤、粉
末化基材を先づ温湯50〜70℃に溶解し、次いで油脂
成分、アセチル化モノグリセリドを加え、2段均質化乳
化を行う。
Examples Comparative Examples 1 to 3 and Examples 1 to 4 Each composition The emulsifying agent and the powdered base material were first dissolved in warm water of 50 to 70°C, and then the oil and fat components and acetylated monoglyceride were added, followed by two-stage homogenization. Perform emulsification.

この際の固型分濃度は40〜50係とする。The solid content concentration at this time is between 40 and 50.

先づ1段目の乳化圧を200に9/cm2.2段目の乳
化圧を40Kp/cm2で乳化した後、スプレードライ
ヤーで大凧130〜140℃、内温80〜90℃にて乾
燥粉末化して起泡性の粉末油脂を得た。
First, the emulsification pressure in the first stage is set to 200 at 9/cm2.After emulsifying at the emulsification pressure in the second stage at 40Kp/cm2, dry powder with a spray dryer at 130-140℃ and internal temperature 80-90℃. A foamable powdered oil and fat was obtained.

性能の評価方法 ホイツピングクリームミックス処方 比較例、実施例の粉末油脂 70% 粉末水飴 15係 粉 糖 15%ホイップクリ
ームのつくり方と評価 ホイップクリームミックス130gをボウルに入れ、牛
乳(10℃)180ccを加えゆるやかに30秒間攪拌
して合わせる。
Performance evaluation method Whipping cream mix formulation Comparative example, Examples Powdered oil and fat 70% Powdered starch syrup 15% Powder Sugar 15% How to make and evaluate whipped cream Put 130g of whipped cream mix in a bowl and add 180cc of milk (10℃) Add and stir gently for 30 seconds to combine.

次にサンビーム社のミックスマスターを用いて500r
pmで2分間ホイップする。
Next, use Sunbeam's Mixmaster to mix 500r.
Whip for 2 minutes at pm.

ホイップの過程でクリームが硬くなり絞り可能な状態と
なった時の時間を測定し腰の出る速さとする。
During the whipping process, the time it takes for the cream to harden and become squeezable is measured and determined as the speed at which it becomes firm.

次にホイップしたクリームを袋に入れ口金より絞り出し
、花形の形、保型性を観察すると共に、クリームの艶、
組織も評価する。
Next, put the whipped cream into a bag and squeeze it out from the nozzle, and observe the flower shape and shape retention, as well as the gloss of the cream.
Also evaluate the organization.

最後にクリームを食べてみて風味及口どけ、食感を官能
的に評価する。
Finally, try eating the cream and sensually evaluate its flavor, melt-in-your-mouth texture, and texture.

長期安定性は室温にて3ケ月放置後の起泡性粉末油脂に
つき、前記処方にて評価した性能である。
Long-term stability is the performance evaluated using the above formulation for foaming powdered fats and oils after being left at room temperature for 3 months.

表22段均質化の際の1段目の乳化圧の影響実施例2の
処方にて試験した。
Table 2: Effect of emulsification pressure in the first stage during two-stage homogenization The formulation of Example 2 was tested.

性能評価については前述の方法と同じ。The performance evaluation is the same as the method described above.

Claims (1)

【特許請求の範囲】[Claims] 1 融点35〜45℃の油脂に対して10〜40%のア
セチル化モノグリセリド又はアセチル化モノグリセリド
とレシチンを混合し、次いでカゼインナトリウム、粉末
水飴、ぶどう糖、砂糖、乳糖、デキストリン、リン酸ま
たは縮合リン酸のアルカリ塩類、などの1種または2種
以上を溶解した水溶液に加え、2段均質化乳化を行うに
際して、1段目の乳化圧を少くとも150Kp/cm2
以上、2段目の乳化圧を50Kp/cm2以下で乳化し
た後、乾燥粉末化して得られる起泡性を有する粉末油脂
の製造法。
1 Mix 10-40% of acetylated monoglyceride or acetylated monoglyceride and lecithin with fats and oils with a melting point of 35-45°C, then add sodium caseinate, powdered starch syrup, glucose, sugar, lactose, dextrin, phosphoric acid or condensed phosphoric acid When performing two-stage homogenization emulsification by adding one or more kinds of alkaline salts, etc.
The above is a method for producing a powdered fat and oil having foaming properties, which is obtained by emulsifying at a second stage emulsification pressure of 50 Kp/cm2 or less and then drying and powdering.
JP54028920A 1979-03-13 1979-03-13 Method for producing powdered oil and fat with foaming properties Expired JPS5811833B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP54028920A JPS5811833B2 (en) 1979-03-13 1979-03-13 Method for producing powdered oil and fat with foaming properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54028920A JPS5811833B2 (en) 1979-03-13 1979-03-13 Method for producing powdered oil and fat with foaming properties

Publications (2)

Publication Number Publication Date
JPS55120746A JPS55120746A (en) 1980-09-17
JPS5811833B2 true JPS5811833B2 (en) 1983-03-04

Family

ID=12261827

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JPS5811833B2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5651964A (en) * 1979-10-01 1981-05-09 Minaminihon Rakunou Kyodo Kk Preparation of whipping cream powder
JPS56140866A (en) * 1980-04-07 1981-11-04 Minaminihon Rakunou Kyodo Kk Acid-resistant whipping cream powder and its preparation
JPS5925644A (en) * 1982-08-04 1984-02-09 Kao Corp Emulsified fat and oil composition
DE3566945D1 (en) * 1984-03-30 1989-02-02 Procter & Gamble Cooking fat compositions
GB8421535D0 (en) * 1984-08-24 1984-09-26 Unilever Plc Flavour precursor mixture
AU2002352153A1 (en) * 2001-12-21 2003-07-09 Unilever N.V. Instant emulsion
JP5084039B2 (en) * 2008-05-21 2012-11-28 ミヨシ油脂株式会社 Milky powder oil
JP2013255440A (en) * 2012-06-11 2013-12-26 Taiyo Yushi Kk Powdered oil and fat, and method for producing the same

Also Published As

Publication number Publication date
JPS55120746A (en) 1980-09-17

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