JPS58117863A - High speed tool steel with high wear resistance and toughness - Google Patents

High speed tool steel with high wear resistance and toughness

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Publication number
JPS58117863A
JPS58117863A JP19420681A JP19420681A JPS58117863A JP S58117863 A JPS58117863 A JP S58117863A JP 19420681 A JP19420681 A JP 19420681A JP 19420681 A JP19420681 A JP 19420681A JP S58117863 A JPS58117863 A JP S58117863A
Authority
JP
Japan
Prior art keywords
less
toughness
tool steel
wear resistance
speed tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19420681A
Other languages
Japanese (ja)
Inventor
Norimasa Uchida
内田 憲正
Hideki Nakamura
秀樹 中村
Kingo Kiyonaga
清永 欣吾
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Proterial Ltd
Original Assignee
Hitachi Metals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Metals Ltd filed Critical Hitachi Metals Ltd
Priority to JP19420681A priority Critical patent/JPS58117863A/en
Publication of JPS58117863A publication Critical patent/JPS58117863A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a high speed tool steel for a cold working tool with superior wear resistance and toughness by regulating the W content of a high speed tool steel and by adding Mo, Ni, etc. CONSTITUTION:The composition of a high speed tool steel for a cold working tool is composed of 0.6-0.8% C, 0.6-2.0% Si, 5.2-6.0% Cr, <2% W, <3% Mo (W+2Mo=4-6%), 0.5-2.2% V, <1.5% Mn, <2.0% Ni, <5% Co, <0.1% N and the balance Fe. To the composition may be added <=0.2% in total of one or more among Ti, Zr, Nb, Hf and Al and <0.05B. Hard carbides of Cr, W, Mo, V, etc. enhance the wear resistance, and Ni improves the toughness, so a high- speed tool steel with high wear resistance and toughness is obtd.

Description

【発明の詳細な説明】 本発明は優れた耐摩耗性と高靭性を有した冷間工具用高
速度工具鋼に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a high-speed tool steel for cold working tools having excellent wear resistance and high toughness.

従来、冷間工具用高速度工具鋼としてはJIS8KH9
クラスのものが用いられていたが、靭性が低いため強い
衡撃の加わる工具では早期に破損。
Conventionally, JIS8KH9 was used as high-speed tool steel for cold work tools.
Class materials were used, but due to their low toughness, tools that are subject to strong impact will break quickly.

欠けを生じて、その耐用寿命を著しく減じていた。This caused chipping, significantly reducing its useful life.

また5KH9クラスの靭性を改良せしめたいわゆるマト
リックス・・イスと呼ばれる高速度工具鋼も使用されて
おり、用途によってはかなりの効果が認められている。
In addition, a high-speed tool steel called Matrix Chair, which has improved toughness of 5KH9 class, is also used, and has been found to be quite effective in some applications.

しかし、H[60前後の硬さでシャルピー@隼値が5〜
−m/cJ以上といった極限の高靭性が要求される冷開
鍛造金型や冷間押出用金型などではまだマトリックスハ
イスクラスの高速度工具鋼では靭性が十分でなく耐用寿
命が低い。
However, the hardness of H [around 60 and the Charpy @ Hayabusa value is 5~
For cold-opening forging dies and cold extrusion dies, which require extremely high toughness such as -m/cJ or higher, matrix high-speed tool steels still do not have sufficient toughness and have a short service life.

これを解決するために本発明者らの一人により優れた特
性を有する冒速度工具鋼が発明された(%公昭55−4
9148号)。この高速度工具鋼はH)061程度で6
に9 m/−以上のシャルピー働撃値が得られるので、
この複重的の工具では著しい効果をあられしている。こ
の鋼はHRCso〜62の硬さが無理なく祷られるので
、耐摩耗性においても優れた晴であると言えるが、しか
し、高速加工、高圧下率加工材料の難加工材化など工具
の使用条件がますます厳しくなってきた現在では、さら
に耐摩れ性に優れていることが要求されている。また、
小径材では珀[61で6Kg m/−以上の高靭性を有
していると百りでも、100−2以上の大径材になると
ある程度の靭性低下は通常の高速度工具鋼と則様避ける
ことができない。
In order to solve this problem, one of the inventors invented a high-speed tool steel with excellent properties (% Kosho 55-4
No. 9148). This high-speed tool steel has a H)061 rating of 6
Since a Charpy force value of 9 m/- or more can be obtained,
This multi-layered tool has been shown to be extremely effective. This steel can reasonably be expected to have a hardness of HRCso~62, so it can be said that it has excellent wear resistance. Nowadays, as the conditions become more and more severe, there is a demand for even better abrasion resistance. Also,
Small diameter materials may have high toughness of 6Kg m/- or more, but when it comes to large diameter materials of 100-2 or more, a certain degree of decrease in toughness is avoided as usual with ordinary high-speed tool steel. I can't.

本発明は前記特公昭55−49148号の発明鋼よりさ
らに優れた耐摩耗性を有し、かつ同等の高靭性を有し、
しかも大径材でも靭性の低下が少ない昼速度工具鋼を提
供することを目的とする。
The present invention has even better wear resistance than the invention steel of Japanese Patent Publication No. 55-49148, and has the same high toughness.
Moreover, it is an object of the present invention to provide a daytime speed tool steel that exhibits little decrease in toughness even when used as a large-diameter material.

以下に各元素の成分限定理由を述べる。The reasons for restricting the composition of each element are described below.

Cは同時に含有するW、 Mo 、 Vと結合して硬い
炭化物を形成することにより耐摩耗性を付与する効果が
ある。、また、焼入時にマトリックス中に固溶してマル
テンサイトの硬さを高める効果をも有する。しかし過剰
に含有するとマルテンサイトな脆くしたり、造塊時にマ
クロ的偏析を生じさせたりして靭性な低下させるので、
Cの適性含有量を見出すためには細心かつ多大な実験を
要する。
C has the effect of imparting wear resistance by combining with W, Mo, and V contained at the same time to form a hard carbide. Also, it has the effect of increasing the hardness of martensite by being dissolved in the matrix during quenching. However, if it is contained in excess, it may become martensite brittle or cause macroscopic segregation during agglomeration, resulting in a decrease in toughness.
In order to find the appropriate content of C, careful and extensive experiments are required.

本発明における多くの実験結果を整理すると、CI)適
正含有量は0.6〜0.8俤であり、0.6チ未満では
目的とする硬さおよびMe耗性が得られず、08%を越
えると目的とする高靭性が得られなかった。
Summarizing the results of many experiments in the present invention, the appropriate CI) content is 0.6 to 0.8 tai, and if it is less than 0.6 tai, the desired hardness and Me abrasion resistance cannot be obtained, and 0.8% If it exceeds this, the desired high toughness cannot be obtained.

しかも、適正炭素含有量0.6〜0.8%の範囲におい
て同時に添加されるW、 Mo 、 Vの含有量により
、炭素含有讐はさらに厳密に管理されなければ、目的と
する高耐傘、高靭性なる性賀は得られない。すなわち本
発明鋼においてはCeq 二α24+0065Mo(%
)t−1033Lν(%)+ 0.2 V(%)とする
とき、C含有量はC−Ceqが+005〜−0.10g
となるように管理されなければならない。
Moreover, the content of W, Mo, and V added simultaneously within the appropriate carbon content range of 0.6 to 0.8% means that unless the carbon content is controlled more strictly, the desired high-resistance umbrella, High toughness cannot be obtained. That is, in the steel of the present invention, Ceq 2α24+0065Mo(%
) t-1033Lν (%) + 0.2 V (%), the C content is C-Ceq +005 to -0.10g
must be managed so that

以上の理由によりC含有蓋をC0,6〜0.8チ、望ま
しくはa65〜175%に限定した。
For the above reasons, the C-containing lid is limited to C0.6 to 0.8%, preferably a65 to 175%.

8iは焼もどし硬さを向上させ、とくに本発明のごとき
W、 Mo 、 Vの含有量が少ない場合にこの効果が
大きい。本発明の成分系で81の効果を有効に発弾させ
るためKは最低限06%の8iが必要であるが、逆に2
.0チを越えると機械加工性を減じるのでSiの含有量
を0.6〜2.0%、望ましくは08〜16チに限定し
た。
8i improves the tempering hardness, and this effect is particularly great when the content of W, Mo, and V is small as in the present invention. In order to effectively activate the effect of 81 with the component system of the present invention, K needs to be at least 0.6% of 8i, but on the contrary, 2.
.. If the Si content exceeds 0%, the machinability is reduced, so the Si content is limited to 0.6 to 2.0%, preferably 08 to 16%.

Crは本発明において重要な構成元素である。従来の高
速度工具鋼では五5〜4.5%のCrが含有されている
が、本発明における多くの実験事実から、本発明鋼のご
とき高1Illt岸高靭性を必要とする分野で用いられ
る場合にはCrの含有量が5.2〜6.0%である場合
の方が、耐摩耗性がより向上し、また大径材の靭性低下
が従来材に較べすくないことを発見した。しかもこのC
rの効果はCおよび81か上記の成分範囲にないと十分
に発弾されない。
Cr is an important constituent element in the present invention. Conventional high-speed tool steels contain 55 to 4.5% Cr, but based on many experimental facts in the present invention, Cr is used in fields that require high toughness such as the steel of the present invention. It has been discovered that when the Cr content is 5.2 to 6.0%, the wear resistance is further improved and the toughness of large-diameter materials is less reduced than that of conventional materials. Moreover, this C
The effect of r will not be fired sufficiently unless it is in C and 81 or the above component range.

Crが5,2%未満では上記効果が十分でなく、また6
優を越えると靭性が逆に低下するので、Crの含有量は
5.2〜6t)%に限定した。
If the Cr content is less than 5.2%, the above effects will not be sufficient;
If the Cr content exceeds excellent, the toughness decreases, so the Cr content was limited to 5.2 to 6 t%.

Wおよび1vloは焼もどし硬化にを与し耐摩耗性を附
与する効果を有する。しかしその含有量が多くなると焼
入後に未溶解炭化物の偏析として残存し、靭性な低下さ
せるので、焼もどし硬さを考慮しながら可能な限り少な
く含有することが望筐しい。
W and 1vlo have the effect of imparting temper hardening and wear resistance. However, if its content increases, it will remain as segregated undissolved carbides after quenching, reducing toughness, so it is desirable to contain it as little as possible while taking tempering hardness into consideration.

本発明鋼の用途ではH関6.2以上の硬さが必要であり
、 W+2Moが4チ未満ではこの硬さが得られない。
In the application of the steel of the present invention, a hardness of 6.2 or higher in terms of H is required, and this hardness cannot be obtained if W+2Mo is less than 4.

また6%を越えるとシャルピー衝撃値6ky m/cd
以上の高靭性が得られないので、W+2 Moを4〜6
俤に限定した。WとMoは重−バーセントでW量と論量
とがほぼ同じ効果を有している。しかし、本発明鋼の成
分糸ではWよりMoの効果が大きくあられれたので、W
2%以下、Mo5%以下でかツW+ 2 M。
Also, if it exceeds 6%, the Charpy impact value is 6ky m/cd.
Since higher toughness cannot be obtained, W+2 Mo is 4 to 6
Limited to 俤. W and Mo have almost the same effect in terms of weight percent and stoichiometric amount. However, in the component yarn of the steel of the present invention, the effect of Mo was greater than that of W, so W
2% or less, Mo5% or less, W+2M.

が4〜6優、望ましくはW1優以下、MO21〜29%
でかつW+ 2 Moが45〜6%に限定した。
is 4 to 6 excellent, preferably W1 excellent or less, MO21 to 29%
and W+2Mo was limited to 45 to 6%.

■はW、Moと同様、焼もどし2次硬化にを与するとと
もに、焼入したときに硬いVC炭化物として残存し、耐
摩耗性を附与する効果を有する。■が0.5%未満では
上記効果が少なく、逆に2.2%を越えると、未溶解炭
化′#J′jIkが多くなり過ぎ、靭性を低下するので
V t/−)含有量は05〜2,2%、望ましくは08
〜2.0優に限定した。
Similar to W and Mo, (2) not only contributes to secondary hardening during tempering, but also remains as a hard VC carbide when quenched, and has the effect of imparting wear resistance. If (2) is less than 0.5%, the above effect will be small, and if it exceeds 2.2%, undissolved carbonized '#J'jIk will increase too much and the toughness will decrease, so the Vt/-) content will be 05 ~2.2%, preferably 08
It was limited to ~2.0 well.

鳩は脱酸剤として添加される他に、焼入性を向上させる
目的で1.5%以下含有させるので鳩の含肩以は15%
以下に限定した。
In addition to being added as a deoxidizing agent, the content of pigeon is 1.5% or less for the purpose of improving hardenability, so the content of pigeon is 15% or less.
Limited to the following.

N1は軟性を高める目的で2.0%以下含有させるので
Niの含有量は2.0チ以下に限定した。
Since N1 is contained in an amount of 2.0% or less for the purpose of increasing flexibility, the Ni content is limited to 2.0% or less.

COは比較的靭性の低下を少なくして焼もどし硬さを上
げる効果を有するが、5qbを越えて含有すると靭性の
低下が大きくなるので、Coの含有量はSS以下に限定
した。
CO has the effect of relatively reducing the decrease in toughness and increasing the tempering hardness, but if it is contained in excess of 5 qb, the decrease in toughness becomes large, so the Co content was limited to SS or less.

Nは通常002俤程度含有するが、焼もどし硬さを高め
る目的で01%以下含有すると効果があるのでNの含有
量は0.1−以下に限定した。
Normally, the content of N is about 0.02%, but since it is effective to contain 0.1% or less for the purpose of increasing the tempering hardness, the N content is limited to 0.1% or less.

Ti 、 Zr 、 NJ Hf #Atはとくに含有
しなくても本願発明の目的は達成されるがこれにTi 
、 Zr、Nb。
Although the purpose of the present invention can be achieved even without the inclusion of Ti, Zr, NJ Hf #At, the addition of Ti
, Zr, Nb.

Hf 、 Atの一種または二種以上を合計で0.2チ
以下含有すると、結晶粒を微細化し靭性をさらに向上さ
せる効果があるので、Ti、 Zr、Nb、Hf 、A
tの一種または二種以上を合計で0.2%以下に限定し
た。
When one or more of Hf and At are contained in total at most 0.2 Ti, it has the effect of making the crystal grains finer and further improving the toughness.
The total amount of one or more types of t was limited to 0.2% or less.

Bもとくに含有しなくても本願発明の目的は十分達成で
きるが、これに130.05%以下を含有すると焼入性
の向上、結晶粒の微細化効果が認められたので、Bo、
o5チ以下に限定した。
Although the purpose of the present invention can be sufficiently achieved without specifically containing B, it has been found that containing 130.05% or less improves hardenability and refines grains, so Bo,
Limited to o5chi or less.

以下に実施例を示す。Examples are shown below.

実施例1 本発明にかかわる多くの笑験結果のうち、代表的なもの
を第1表に示す。
Example 1 Among the many experimental results related to the present invention, representative ones are shown in Table 1.

A〜Eは本発明@、F−Iは比較鋼、Jは特公昭55−
49148号で発明された鋼ですでに工業的に使用され
ている。KはJIS 8KH9である。第1表に示す熱
処理硬さは、10刈Ox6rmに加工した試料をメルト
バス中で1160℃xeo秒加熱後油冷し、その後厄気
運状炉中で560℃×1時間×2回の&返し焼もどしし
た後の測定結果である。またシャルピー衝撃値は10R
−Cノツチシャルピー衝撃試験の結果で。
A to E are according to the present invention @, F-I are comparative steels, and J is J.K.
The steel invented in No. 49148 is already in industrial use. K is JIS 8KH9. The heat treatment hardness shown in Table 1 is determined by heating a sample processed to 100°C x 6rm in a melt bath at 1160°C xeo seconds, cooling it in oil, and then heating it twice in a 560°C x 1 hour x 2 times. This is the measurement result after returning it. Also, the Charpy impact value is 10R.
-C notch Charpy impact test results.

熱処理条件は上記硬さテストと同じである。The heat treatment conditions were the same as those for the hardness test above.

その結果、本発明鋼はいずれもHFtC62以上の高硬
度が得られ、しかもシャルピー衝撃値は6Kfm/−以
上が得られている。比較鋼FはC@有蓋が低くiaJ硬
度が得られない。同じくGはV含廟蓋が高いのにC含有
量が低いのでC−Ceqが低下して高硬度が得られない
。HはSiが低くて高硬度が祷られない。工はtVio
の含有量が低く高硬度が得られない。従来鋼Jは硬さが
低目である。Kはシャルピー衝撃値が低い。
As a result, all of the steels of the present invention had a high hardness of HFtC62 or higher, and a Charpy impact value of 6 Kfm/- or higher. Comparative steel F has a low C @ cap and cannot obtain iaJ hardness. Similarly, G has a high V content but a low C content, so the C-Ceq decreases and high hardness cannot be obtained. H has a low Si content and cannot be expected to have high hardness. Engineering is tVio
The content is low and high hardness cannot be obtained. Conventional steel J has low hardness. K has a low Charpy impact value.

実施例2 実施例1の第1表に示すと同じ鋼を用いて、大越弐岸粍
試験を行なった。その結果を第1図に示す。本発明鋼A
−Eは従来鋼、lC較べて岸耗減少鎗が少なく、従来鋼
K (5KH9)とほぼ同程度の耐摩耗性を有している
ことが確認された。
Example 2 The same steel as shown in Table 1 of Example 1 was used to conduct the Okoshi Nigishi test. The results are shown in FIG. Invention steel A
It was confirmed that -E has less reduction in bank wear than conventional steel and 1C, and has almost the same level of wear resistance as conventional steel K (5KH9).

実施例3 実施例1に示す第1表の本発明鋼Bおよび従来vI/4
Jと同一組成で100■’X100■′の丸棒を作製し
た。これをソルトバス中で1160℃X10分加熱後亭
冷し、続いて電気抵抗炉中で560℃×1時間×2回の
焼もどしを行なりた。この鬼神試料の中心部より10)
L−Cノツチシャルピー衝撃試験片を採取し、テストを
行なりたところ、本発明鋼Bのシャルピー値は56峙−
m/−で硬さはHRC59,2でありた。従来鋼Jのシ
ャルピー値は五8 Kf−m/7で硬さはHRC565
であった。
Example 3 Invention steel B and conventional vI/4 shown in Table 1 shown in Example 1
A 100×100×1 round bar was prepared with the same composition as J. This was heated in a salt bath at 1160° C. for 10 minutes, cooled, and then tempered twice at 560° C. for 1 hour in an electric resistance furnace. From the center of this demon sample 10)
When an L-C notch Charpy impact test piece was taken and tested, the Charpy value of the invention steel B was 56.
m/- and hardness was HRC59.2. The Charpy value of conventional steel J is 58 Kf-m/7 and the hardness is HRC565.
Met.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は大越式犀耗試験結果を示す図である。 牛 1r!rU 1“+1.’l’  ”I’  Jり’l°°・ 殿+
Q  1lll  L’)  2 15’    高ユ
、I&q性高連膚工4゜浦ll^、Jるh ・ 1・  ・s++++、  If ”: ”’i属
珠式会社f・ ノ、 と  河 野    典  火成
    理    !( ・・1  ・・ト一   東4;ミ都「1(1111に
入り)内IWI’l11番2シ;11・゛f′r′属株
式会月内 電話 j[[284−4642に訂正する。
FIG. 1 is a diagram showing the results of the Okoshi type abrasion test. Cow 1r! rU 1"+1.'l'"I'Jri'l°°・ Tono+
Q 1lll L') 2 15' Takayu, I &Q's High School Worker 4゜urall^, Juruh ・ 1 ・ s++++, If ”: ”'I affiliated pearl company f・ノ, and Nori Kawano Ignari theory! (...1... Toichi East 4; Mito ``1 (Enter 1111) IWI'l 11th 2shi; 11.゛f'r' Group Stock Company Monthly Telephone j [[Correct to 284-4642 .

Claims (1)

【特許請求の範囲】 tC06〜Q、8%、8i0.6〜2.0%、Cr5.
2〜At)%、W2%以下1M03qb以下テカツW千
2MOカ4〜69b、vo、5〜2.2%、Mn15%
以下、Ni2.0%以下、 Co5%以下、NO,1%
以下残部Feおよび不純物よりなる高耐摩高靭性高7#
L工具鋼。 2Cα65〜0.75%lSi[18〜16%、Cr5
.2〜60%lW1チ以下、 Mo2以下−29%でか
つW+2Moが4.5〜6饅、■08〜2.0%、Mn
 ts4以下、NI2.0%以下、 Co5%以下。 NO,1%以下残部Feおよび不純物よりなる特許請求
の範囲第1項記載の高耐摩高靭性高速度工具鋼。 !、、  C0,6〜0.8%、SiO,6〜2.0%
、(、r5.2〜to%、w2俤以下、 Mo 3% 
以下テカツW+2Mo カ4〜6%、 vO,s〜2.
2’% 、 Mn15%以下、 Ni2.0%以下、 
Co55S以下、N01チ以下+ Ti、Zr、Nb、
Hf、Atの一種または二種以上を合計で0,2チ以下
、Bを005%以下、残部Feおよび不純物よりなる高
耐摩高靭性高速度工具鋼
[Claims] tC06-Q, 8%, 8i0.6-2.0%, Cr5.
2~At)%, W2% or less 1M03qb or less
Below, Ni 2.0% or less, Co 5% or less, NO, 1%
High wear resistance and high toughness consisting of the balance Fe and impurities.
L tool steel. 2Cα65~0.75% lSi [18~16%, Cr5
.. 2-60%lW1chi or less, Mo2 or less -29% and W+2Mo is 4.5-6, ■08-2.0%, Mn
ts4 or less, NI2.0% or less, Co5% or less. The high wear-resistant, high-toughness, high-speed tool steel according to claim 1, comprising NO, the balance being Fe and impurities of 1% or less. ! ,, C0.6-0.8%, SiO, 6-2.0%
, (, r5.2~to%, w2 俤 or less, Mo 3%
Below, Tekatsu W+2Mo is 4~6%, vO,s~2.
2'%, Mn 15% or less, Ni 2.0% or less,
Co55S or less, N01 or less + Ti, Zr, Nb,
A high-wear, high-toughness, high-speed tool steel consisting of a total of 0.2% or less of one or more of Hf and At, 0.05% or less of B, and the balance Fe and impurities.
JP19420681A 1981-12-02 1981-12-02 High speed tool steel with high wear resistance and toughness Pending JPS58117863A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19420681A JPS58117863A (en) 1981-12-02 1981-12-02 High speed tool steel with high wear resistance and toughness

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Application Number Priority Date Filing Date Title
JP19420681A JPS58117863A (en) 1981-12-02 1981-12-02 High speed tool steel with high wear resistance and toughness

Publications (1)

Publication Number Publication Date
JPS58117863A true JPS58117863A (en) 1983-07-13

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61276954A (en) * 1985-05-30 1986-12-06 Daido Steel Co Ltd Die steel and its manufacture
US5252119A (en) * 1990-10-31 1993-10-12 Hitachi Metals, Ltd. High speed tool steel produced by sintering powder and method of producing same
KR100368540B1 (en) * 2000-06-20 2003-01-24 기아특수강 주식회사 A low alloyed high speed tool steel for hot and warm working having good toughness and high strength and manufacture method thereof
JP2005530041A (en) * 2002-06-13 2005-10-06 ウッデホルム トウリング アクテイエボラーグ Cold work steel and cold work tool
CN103510021A (en) * 2013-04-07 2014-01-15 安徽美芝精密制造有限公司 Steel alloy, compressor slide sheet and preparation method of compressor slide sheet
CN105296868A (en) * 2014-12-31 2016-02-03 芜湖金龙模具锻造有限责任公司 Wear resisting ultrahard high-speed steel

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61276954A (en) * 1985-05-30 1986-12-06 Daido Steel Co Ltd Die steel and its manufacture
US5252119A (en) * 1990-10-31 1993-10-12 Hitachi Metals, Ltd. High speed tool steel produced by sintering powder and method of producing same
KR100368540B1 (en) * 2000-06-20 2003-01-24 기아특수강 주식회사 A low alloyed high speed tool steel for hot and warm working having good toughness and high strength and manufacture method thereof
JP2005530041A (en) * 2002-06-13 2005-10-06 ウッデホルム トウリング アクテイエボラーグ Cold work steel and cold work tool
JP4805574B2 (en) * 2002-06-13 2011-11-02 ウッデホルムス アーベー Cold work steel and cold work tool
US8900382B2 (en) * 2002-06-13 2014-12-02 Uddeholm Tooling Aktiebolag Hot worked steel and tool made therewith
CN103510021A (en) * 2013-04-07 2014-01-15 安徽美芝精密制造有限公司 Steel alloy, compressor slide sheet and preparation method of compressor slide sheet
CN103510021B (en) * 2013-04-07 2016-01-20 安徽美芝精密制造有限公司 Steel Alloy, compressor sliding blade and preparation method thereof
CN105296868A (en) * 2014-12-31 2016-02-03 芜湖金龙模具锻造有限责任公司 Wear resisting ultrahard high-speed steel

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