JPS58113211A - エチレンならびにエチレンとオレフインとの混合物の重合用新規触媒成分及びそれから得られる触媒 - Google Patents
エチレンならびにエチレンとオレフインとの混合物の重合用新規触媒成分及びそれから得られる触媒Info
- Publication number
- JPS58113211A JPS58113211A JP57226459A JP22645982A JPS58113211A JP S58113211 A JPS58113211 A JP S58113211A JP 57226459 A JP57226459 A JP 57226459A JP 22645982 A JP22645982 A JP 22645982A JP S58113211 A JPS58113211 A JP S58113211A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst component
- compound
- compounds
- catalyst
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims description 96
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 30
- 239000005977 Ethylene Substances 0.000 title claims description 30
- 239000000203 mixture Substances 0.000 title claims description 24
- 150000001336 alkenes Chemical class 0.000 title claims description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims 2
- 230000000379 polymerizing effect Effects 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims description 38
- 239000007788 liquid Substances 0.000 claims description 37
- 238000006116 polymerization reaction Methods 0.000 claims description 31
- 239000006185 dispersion Substances 0.000 claims description 30
- 239000000839 emulsion Substances 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 22
- 239000012071 phase Substances 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 12
- 150000003623 transition metal compounds Chemical class 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 9
- -1 aluminum halides Chemical class 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 150000004820 halides Chemical class 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 239000011261 inert gas Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000002736 metal compounds Chemical class 0.000 claims description 2
- 150000003377 silicon compounds Chemical class 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 241000272525 Anas platyrhynchos Species 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000001475 halogen functional group Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 27
- 238000000034 method Methods 0.000 description 22
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000003921 oil Substances 0.000 description 11
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 10
- 239000000725 suspension Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000010992 reflux Methods 0.000 description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000001282 iso-butane Substances 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000000877 morphologic effect Effects 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 241000270666 Testudines Species 0.000 description 2
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 2
- 239000012346 acetyl chloride Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- ZRHOFLXFAAEXEE-UHFFFAOYSA-J butanoate;titanium(4+) Chemical compound [Ti+4].CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O.CCCC([O-])=O ZRHOFLXFAAEXEE-UHFFFAOYSA-J 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012967 coordination catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- WDYVUKGVKRZQNM-UHFFFAOYSA-N 6-phosphonohexylphosphonic acid Chemical compound OP(O)(=O)CCCCCCP(O)(O)=O WDYVUKGVKRZQNM-UHFFFAOYSA-N 0.000 description 1
- 241000208140 Acer Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 102100026194 C-type lectin domain family 2 member B Human genes 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- 101000912618 Homo sapiens C-type lectin domain family 2 member B Proteins 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000269821 Scombridae Species 0.000 description 1
- 102100033213 Teneurin-1 Human genes 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000001266 acyl halides Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 150000001502 aryl halides Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002344 gold compounds Chemical class 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012705 liquid precursor Substances 0.000 description 1
- 239000006194 liquid suspension Substances 0.000 description 1
- 235000020640 mackerel Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 108010063973 teneurin-1 Proteins 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 210000004916 vomit Anatomy 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/909—Polymerization characterized by particle size of product
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25840/81A IT1169291B (it) | 1981-12-24 | 1981-12-24 | Componenti di catalizzatori per la polimerizzazione dell'etilene e sue miscele con olefine ed i soui catalizzatori da essi ottenuti |
| IT25840A/81 | 1981-12-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58113211A true JPS58113211A (ja) | 1983-07-06 |
| JPH0480045B2 JPH0480045B2 (en, 2012) | 1992-12-17 |
Family
ID=11217890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57226459A Granted JPS58113211A (ja) | 1981-12-24 | 1982-12-24 | エチレンならびにエチレンとオレフインとの混合物の重合用新規触媒成分及びそれから得られる触媒 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4517307A (en, 2012) |
| EP (1) | EP0083074B1 (en, 2012) |
| JP (1) | JPS58113211A (en, 2012) |
| KR (1) | KR900002359B1 (en, 2012) |
| AR (1) | AR248145A1 (en, 2012) |
| AT (1) | ATE47404T1 (en, 2012) |
| AU (1) | AU565828B2 (en, 2012) |
| BR (1) | BR8207449A (en, 2012) |
| CA (1) | CA1195680A (en, 2012) |
| DE (1) | DE3279988D1 (en, 2012) |
| ES (1) | ES8607345A1 (en, 2012) |
| GR (1) | GR78407B (en, 2012) |
| IN (1) | IN158358B (en, 2012) |
| IT (1) | IT1169291B (en, 2012) |
| NO (1) | NO163190C (en, 2012) |
| SU (1) | SU1545943A3 (en, 2012) |
| ZA (1) | ZA829392B (en, 2012) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010132919A (ja) * | 2001-06-20 | 2010-06-17 | Borealis Technology Oy | オレフィン重合触媒及びその調製方法 |
| JP2017531724A (ja) * | 2014-10-21 | 2017-10-26 | ノヴァ ケミカルズ（アンテルナショナル）ソシエテ アノニム | 連続溶液重合プロセス |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1178466B (it) | 1984-03-20 | 1987-09-09 | Montedison Spa | Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti |
| DE3765351D1 (de) * | 1986-07-31 | 1990-11-08 | Montedison Spa | Verfahren zur polymerisierung von alpha-olefinen oder ihrer mischungen mit aethylen unter anwendung eines mikrosphaeroidalen, teilchenfoermigen, festen katalysatorbestandteils oder eines deren vorlaeufer enthaltenden katalysators. |
| DE3765723D1 (de) * | 1986-07-31 | 1990-11-29 | Montedison Spa | Verfahren zur herstellung mikrospheroidaler fester katalysatorbestandteile oder ihrer vorlaeufer und ihre anwendung bei der herstellung von aethylenpolymeren. |
| US5648309A (en) * | 1990-06-01 | 1997-07-15 | Hoechst Aktiengesellschaft | Process for the preparation of a poly-1-olefin |
| IT1262934B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| FI95387C (fi) * | 1992-12-29 | 1996-01-25 | Borealis As | Menetelmä -olefiinien polymeroimiseksi sekä esipolymeroitu katalyyttikompositio ja menetelmä tämän valmistamiseksi |
| IT1269534B (it) * | 1994-03-11 | 1997-04-08 | Enichem Elastomeri Srl | Catalizzatore per la preparazione di copolimeri elastomerici etilene-propilene |
| CA2136278A1 (en) * | 1993-12-17 | 1995-06-18 | Viviano Banzi | Catalyst for the preparation of elastomeric ethylene-propylene copolymers |
| DE60120141T2 (de) * | 2001-06-20 | 2007-03-29 | Borealis Technology Oy | Herstellung einer Olefinpolymerisationskatalysatorkomponente |
| EP1323746B1 (en) * | 2001-12-19 | 2009-02-11 | Borealis Technology Oy | Production of supported olefin polymerisation catalysts |
| EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| EP1375528A1 (en) | 2002-06-18 | 2004-01-02 | Borealis Polymers Oy | Method for the preparation of olefin polymerisation catalysts |
| EP1403292B1 (en) | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| EP1489110B1 (en) * | 2003-06-20 | 2012-01-18 | Borealis Polymers Oy | Method for preparing an olefin polymerisation catalyst composition |
| EA012018B1 (ru) * | 2004-12-31 | 2009-06-30 | Бореалис Текнолоджи Ой | Способ получения катализатора полимеризации олефинов |
| US7749934B2 (en) * | 2005-02-22 | 2010-07-06 | Rohm And Haas Company | Protected catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers |
| EP1862480B1 (en) | 2006-05-31 | 2016-07-27 | Borealis Technology Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| EP1862479A1 (en) * | 2006-05-31 | 2007-12-05 | Borealis Technology Oy | Olefin polymerisation catalyst |
| EP1939227B1 (en) | 2006-12-28 | 2013-10-30 | Borealis Technology Oy | Catalyst preparation with phosphorous compound |
| EP2138517B1 (en) | 2008-06-26 | 2012-09-12 | Borealis AG | Catalyst preparation using H2 |
| EP2407492B1 (en) | 2010-07-13 | 2015-04-29 | Borealis AG | Catalyst component |
| EP2570438A3 (en) | 2010-07-13 | 2013-12-25 | Borealis AG | Catalyst component |
| ES2929284T3 (es) | 2014-06-27 | 2022-11-28 | Borealis Ag | Proceso mejorado para preparar un componente catalizador de polimerización de olefinas en partículas |
| ES2676219T3 (es) | 2014-06-27 | 2018-07-17 | Borealis Ag | Componente de catalizador para la preparación de poliolefinas nucleadas |
| WO2017009405A1 (en) | 2015-07-16 | 2017-01-19 | Borealis Ag | Catalyst component |
| EP4416194A1 (en) | 2021-10-14 | 2024-08-21 | Borealis AG | Process for forming a ziegler-natta catalyst component |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4156063A (en) * | 1971-06-25 | 1979-05-22 | Montecanti Edison, S.p.A. | Process for the stereoregular polymerization of alpha olefins |
| US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| IT1054410B (it) * | 1975-11-21 | 1981-11-10 | Mitsui Petrochemical Ind | Catalizzatori per la polimerizzazione delle alfa olefine |
| IT1078995B (it) * | 1977-05-24 | 1985-05-08 | Montedison Spa | Catalizzatori per la polimeriazzazione di olefine |
| JPS54158489A (en) * | 1978-06-05 | 1979-12-14 | Mitsubishi Petrochem Co Ltd | Polymerization of olefin |
| US4395359A (en) * | 1979-02-27 | 1983-07-26 | Union Carbide Corporation | Polymerization catalyst, process for preparing, and use for ethylene homopolymerization |
| DE3065499D1 (en) * | 1979-04-11 | 1983-12-15 | Mitsui Petrochemical Ind | Process for producing spherical carrier particles for olefin polymerisation catalyst, catalyst comprising such carrier particles, and use of such catalyst in olefin polymerisation |
| DE3064564D1 (en) * | 1979-04-30 | 1983-09-22 | Shell Int Research | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| US4250287A (en) * | 1980-03-14 | 1981-02-10 | Hercules Incorporated | 1-Olefin polymerization catalyst |
| US4325837A (en) * | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
-
1981
- 1981-12-24 IT IT25840/81A patent/IT1169291B/it active
-
1982
- 1982-12-15 NO NO824222A patent/NO163190C/no unknown
- 1982-12-16 SU SU823524065A patent/SU1545943A3/ru active
- 1982-12-17 KR KR8205665A patent/KR900002359B1/ko not_active Expired
- 1982-12-20 AU AU91693/82A patent/AU565828B2/en not_active Ceased
- 1982-12-21 ZA ZA829392A patent/ZA829392B/xx unknown
- 1982-12-21 CA CA000418215A patent/CA1195680A/en not_active Expired
- 1982-12-22 AT AT82111904T patent/ATE47404T1/de not_active IP Right Cessation
- 1982-12-22 AR AR82291664A patent/AR248145A1/es active
- 1982-12-22 EP EP82111904A patent/EP0083074B1/en not_active Expired
- 1982-12-22 GR GR70149A patent/GR78407B/el unknown
- 1982-12-22 US US06/452,152 patent/US4517307A/en not_active Expired - Fee Related
- 1982-12-22 DE DE8282111904T patent/DE3279988D1/de not_active Expired
- 1982-12-22 BR BR8207449A patent/BR8207449A/pt not_active IP Right Cessation
- 1982-12-23 IN IN1481/CAL/82A patent/IN158358B/en unknown
- 1982-12-23 ES ES518515A patent/ES8607345A1/es not_active Expired
- 1982-12-24 JP JP57226459A patent/JPS58113211A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010132919A (ja) * | 2001-06-20 | 2010-06-17 | Borealis Technology Oy | オレフィン重合触媒及びその調製方法 |
| JP2017531724A (ja) * | 2014-10-21 | 2017-10-26 | ノヴァ ケミカルズ（アンテルナショナル）ソシエテ アノニム | 連続溶液重合プロセス |
Also Published As
| Publication number | Publication date |
|---|---|
| NO163190C (no) | 1990-04-18 |
| BR8207449A (pt) | 1983-10-18 |
| ZA829392B (en) | 1983-11-30 |
| AU9169382A (en) | 1983-06-30 |
| JPH0480045B2 (en, 2012) | 1992-12-17 |
| GR78407B (en, 2012) | 1984-09-27 |
| ES8607345A1 (es) | 1986-06-01 |
| KR900002359B1 (ko) | 1990-04-12 |
| IN158358B (en, 2012) | 1986-10-25 |
| IT8125840A0 (it) | 1981-12-24 |
| CA1195680A (en) | 1985-10-22 |
| AR248145A1 (es) | 1995-06-30 |
| KR840002857A (ko) | 1984-07-21 |
| ATE47404T1 (de) | 1989-11-15 |
| SU1545943A3 (ru) | 1990-02-23 |
| AU565828B2 (en) | 1987-10-01 |
| US4517307A (en) | 1985-05-14 |
| NO163190B (no) | 1990-01-08 |
| EP0083074A1 (en) | 1983-07-06 |
| DE3279988D1 (en) | 1989-11-23 |
| NO824222L (no) | 1983-06-27 |
| EP0083074B1 (en) | 1989-10-18 |
| IT1169291B (it) | 1987-05-27 |
| ES518515A0 (es) | 1986-06-01 |
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