JPS5810471B2 - Method and apparatus for recovering and reusing cleaning liquid and heat in metal surface treatment process - Google Patents

Method and apparatus for recovering and reusing cleaning liquid and heat in metal surface treatment process

Info

Publication number
JPS5810471B2
JPS5810471B2 JP11638080A JP11638080A JPS5810471B2 JP S5810471 B2 JPS5810471 B2 JP S5810471B2 JP 11638080 A JP11638080 A JP 11638080A JP 11638080 A JP11638080 A JP 11638080A JP S5810471 B2 JPS5810471 B2 JP S5810471B2
Authority
JP
Japan
Prior art keywords
washing tank
tank
water
water washing
cushion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP11638080A
Other languages
Japanese (ja)
Other versions
JPS5741383A (en
Inventor
河合昇次
山田芳明
楠見謹四郎
柳下相三郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanshin Mfg Co Ltd
Original Assignee
Sanshin Mfg Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanshin Mfg Co Ltd filed Critical Sanshin Mfg Co Ltd
Priority to JP11638080A priority Critical patent/JPS5810471B2/en
Publication of JPS5741383A publication Critical patent/JPS5741383A/en
Publication of JPS5810471B2 publication Critical patent/JPS5810471B2/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/36Regeneration of waste pickling liquors

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

【発明の詳細な説明】 本発明は金属表面処理工程における第一回目の洗浄液が
水、第二回目の洗浄液が湯である場合のそれら洗浄液の
夜及び熱の回収再利用法とその装置に関するものである
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method and apparatus for recovering and reusing the heat and heat of the cleaning liquid when the first cleaning liquid is water and the second cleaning liquid is hot water in a metal surface treatment process. It is.

従来の金属表面処理工程においては、第1図に示すよう
に、水洗及び湯洗の水質を保つためこ一定量の水を補給
し、それら各種からオーバーフローさせて放出させてい
る。
In the conventional metal surface treatment process, as shown in FIG. 1, a certain amount of water is replenished to maintain the quality of water during washing and hot water washing, and overflow is discharged from these various types.

そして、湯洗槽1の温度を保つためにボイラーより生蒸
気を湯洗槽1へ直接供給しており、温水は熱回収せずそ
のま\放流している。
In order to maintain the temperature of the hot water washing tank 1, live steam is directly supplied from the boiler to the hot water washing tank 1, and the hot water is discharged as is without heat recovery.

このことは水質源の有効な利用の観点及び省エネルギー
の観点から問題があった。
This is problematic from the viewpoint of effective use of water resources and energy conservation.

それで本出願人は、上記従来技術の問題点こ鑑みてこれ
を解決するために、液の回収再利用と熱の回収再利用と
を関連させて行う方法と装置を開発した。
Therefore, in view of the above-mentioned problems of the prior art, the present applicant has developed a method and an apparatus for performing liquid recovery and reuse in conjunction with heat recovery and reuse in order to solve the problems.

この開発では、第2図に示すように湯洗槽に従属するク
ッションタンクと水洗槽との間には熱交換器を介装させ
て高温水を低温化し、得られた低温水を水洗槽に導入し
ているが、その低温水が不純なために水洗槽の水質が不
良となり、該水洗槽から湯洗槽(対象の金属製品が移さ
れるから、結局、湯洗槽の水質をも不良とする難点かあ
つだ。
In this development, as shown in Figure 2, a heat exchanger is installed between the cushion tank and the washing tank, which are subordinate to the hot water washing tank, to lower the temperature of the high-temperature water, and the resulting low-temperature water is transferred to the washing tank. However, because the low-temperature water is impure, the water quality in the washing tank becomes poor, and since the metal products are transferred from the washing tank to the hot water washing tank, the water quality in the washing tank also becomes poor. The difficulty is that it's hot.

そこで、本発明は、このような難点を解消するためにな
されたもので、湯洗槽及び水洗槽の水質の安定化を図り
、製品の精度を向上させることを目的とする。
Therefore, the present invention has been made to solve these difficulties, and aims to stabilize the water quality of the hot water washing tank and the cold water washing tank, and to improve the precision of the product.

以下、本発明を図示する一実施例に従って順次説明する
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be sequentially described below according to an illustrative embodiment.

第3図こおいて、1は湯洗槽であり、この中に生蒸気を
導入するパイプ2が臨んでおり、かつ、その一側に高温
水回収パイプ3が連通されると共にその他側に高温水放
出パイプ4が連通されている。
In Fig. 3, 1 is a hot water washing tank, into which a pipe 2 for introducing live steam faces, a high temperature water recovery pipe 3 is connected to one side, and a high temperature water recovery pipe 3 is connected to the other side. A water discharge pipe 4 is connected.

該高温水放出パイプ4の他端はクッションタンク5内に
連通している。
The other end of the high temperature water discharge pipe 4 communicates with the interior of the cushion tank 5.

該クッションタンク5は、熱交換器6を通るパイプ7に
よって水洗槽8の一側からクッションタンク11を結ぶ
低温水放出パイプ10に連通ずる。
The cushion tank 5 is connected to a low temperature water discharge pipe 10 connecting the cushion tank 11 from one side of the washing tank 8 by a pipe 7 passing through a heat exchanger 6.

前記パイプ7の前記タンク5と熱交換器6との間にポン
プ9が介装されている。
A pump 9 is interposed between the tank 5 of the pipe 7 and the heat exchanger 6.

な鉛、該ポンプ9と熱交換器6との間には、望ましくは
該熱交換器6のスケーリングを避けるために濾過機21
を設置する。
A filter 21 is preferably provided between the pump 9 and the heat exchanger 6 to avoid scaling of the heat exchanger 6.
Set up.

該クッションタンク11内こは吸水パイプ12が臨みポ
ンプ13を介して濾過機14に連通する1該濾過機14
は放出パイプ15を介し濾液貯水タンク16に連通する
A water suction pipe 12 faces inside the cushion tank 11 and communicates with a filter 14 via a pump 13.
communicates with a filtrate storage tank 16 via a discharge pipe 15.

該貯水タンク16は、途中にポンプ17を設けているパ
イプ18を介してイオン交換装置19に連通ずる。
The water storage tank 16 communicates with an ion exchange device 19 via a pipe 18 having a pump 17 provided therebetween.

該イオン交換装置19は、前記熱交換器6を通るパイプ
20と連通し、該パイプ20は前記高温水回収パイプ3
に連結され、またン該パイプ20の前記イオン交換装置
19と該熱交換器6とを結んでいる部分には分岐パイプ
22が連結され、その先端は水洗槽8に臨み、かくして
、循環型の液及び熱の回収再利用装置Aが構成されてい
る。
The ion exchange device 19 communicates with a pipe 20 passing through the heat exchanger 6, and the pipe 20 communicates with the high temperature water recovery pipe 3.
A branch pipe 22 is connected to the part of the pipe 20 that connects the ion exchange device 19 and the heat exchanger 6, and the tip thereof faces the washing tank 8, thus providing a circulation type system. A liquid and heat recovery and reuse device A is configured.

次に、上述のように構成された回収再利用装置Aによっ
て、洗浄液の夜及び熱の一収再利用法を説明する。
Next, a method for reusing cleaning liquid and heat once by using the recovery and reuse apparatus A configured as described above will be explained.

洗浄の対象とする金属の表面を尿洗槽8で洗ってから湯
洗槽1で洗うという作業を繰返して行う工程において先
ず、該装置Aによる液の循環を行なう。
In the process of repeatedly washing the surface of the metal to be cleaned in the urine washing tank 8 and then washing it in the hot water washing tank 1, the apparatus A first circulates the liquid.

このとき、湯洗槽1から放出される不純な高温水(約8
0℃)はパイプ4.クッションタンク5゜パイプ7を経
て熱交換器6で低温の純水と熱交換し、低温水(約40
℃)となって低温水放出パイプ10に送られ、そこを流
れている水洗槽8からの不純物を含む低温水と合流して
クッションタンク11に放出される。
At this time, impure high-temperature water (approximately 8
0℃) is pipe 4. Heat is exchanged with low-temperature pure water in heat exchanger 6 through cushion tank 5° pipe 7, and low-temperature water (approximately 40°
°C) and is sent to the low-temperature water discharge pipe 10, where it joins with the low-temperature water containing impurities from the washing tank 8 flowing there, and is discharged into the cushion tank 11.

そしてこの低温水は吸水パイプ12からポンプ13によ
って濾過機14に送られ、濾液となってパイプ15を通
して貯水槽16に放出される。
This low-temperature water is sent from the water suction pipe 12 to the filter 14 by the pump 13, and is discharged into the water storage tank 16 through the pipe 15 as a filtrate.

該貯水槽16からは濾液がパイプ18を通してポンプ1
7によってイオン交換装置19に送られる。
From the water storage tank 16, the filtrate passes through a pipe 18 to the pump 1.
7 to the ion exchanger 19.

このイオン交換装置19に送られる濾液はイオン交換を
するに適した温度に調整されている。
The filtrate sent to this ion exchange device 19 is adjusted to a temperature suitable for ion exchange.

イオン交換装置19では、濾液に含まれるカチオン(C
a++、Na+など)・アニオン(so4−など)がイ
オン交換されて除去され、その濾液は純水となる。
In the ion exchange device 19, cations (C
a++, Na+, etc.) and anions (so4-, etc.) are removed by ion exchange, and the filtrate becomes pure water.

イオン交換を終え純水となった低温水(約35℃)はパ
イプ20を通して一方では熱交換器に送られ、こ1で前
述した不純物を含む高温水(約80℃)と熱交換して高
温の純水(約75C)となり前記湯洗槽1に回収され、
そこで生蒸気の吹込により又は、その他の加温手段によ
って更に高温となる。
The low-temperature water (approximately 35°C) that has undergone ion exchange and has become pure water is sent to the heat exchanger through the pipe 20, where it exchanges heat with the high-temperature water (approximately 80°C) containing the impurities mentioned above and becomes high-temperature. pure water (approximately 75C) is collected in the hot water washing tank 1,
Then, the temperature is further increased by blowing in live steam or by other heating means.

他方、イオン交換を終え純水となった低温水(約35℃
)の一部分は分岐パイプ22によって水洗槽8に回収さ
れる。
On the other hand, low-temperature water (approximately 35℃) that has undergone ion exchange and has become pure water
) is collected into the washing tank 8 via the branch pipe 22.

以後、このような操作が繰返されて液の循環が行なわれ
る。
Thereafter, such operations are repeated to circulate the liquid.

以上述べたように、本発明においては、第一に金属表面
処理工程における第二回目の洗浄液を貯える湯洗槽から
放出される高温水を低温の純水で熱交換して低温水とし
第一回目の洗浄液を貯わえる水洗槽からの不純物を含む
低温水と合流させてクッションタンクに導入し、該クッ
ションタンク内の液を濾過し、その濾液をイオン交換し
、そのイオン交換による純水を前記高温水との熱交換に
より加熱して前記湯洗槽に回収すると共にその純水の一
部を低温のま\前記水洗槽に回収するようにして、金属
表面処理工程における洗浄液の夜及び熱の回収再利用法
を構成したので、一定量の液が、従来の如く補給するこ
となく、伺回でも洗浄液として循環して使用できるから
節水に協力しながら能率的な洗浄が行なわれ、また、水
洗槽の低温水と湯洗槽の高温水とを相互に利用して熱交
換を行うからその装置も簡易化し湯洗槽に導入される生
蒸気、その他の加温手段に要するエネルギーが少くなり
、省エネルギーの要請にも協力でき、これに加え湯洗槽
・水洗槽に回収される液を純液としているから、両槽の
水質を同時的に安定化し製品の不良化を防止できる。
As described above, in the present invention, firstly, the high-temperature water discharged from the hot water washing tank that stores the second cleaning solution in the metal surface treatment process is heat-exchanged with low-temperature pure water and converted into low-temperature water. The low-temperature water containing impurities from the washing tank storing the second washing solution is combined with the water and introduced into the cushion tank, the liquid in the cushion tank is filtered, the filtrate is ion-exchanged, and the purified water from the ion-exchange is produced. The pure water is heated by heat exchange with the high-temperature water and collected in the hot water washing tank, and a portion of the pure water is also collected at a low temperature into the water washing tank, thereby reducing the temperature and heat of the cleaning liquid in the metal surface treatment process. Since the collection and reuse method has been constructed, a certain amount of liquid can be circulated and used as a cleaning liquid even during visits without having to be replenished as in the past, so efficient cleaning can be carried out while helping to save water. Heat exchange is performed by mutually using the low temperature water in the washing tank and the high temperature water in the hot water washing tank, which simplifies the equipment and reduces the energy required for live steam introduced into the hot water washing tank and other heating means. In addition, since the liquid collected in the hot water washing tank and the cold washing tank is a pure liquid, the water quality in both tanks can be stabilized at the same time and the product can be prevented from becoming defective.

また、本発明においては、第二に、金属表面処理工程に
おける第一回目の洗浄液を貯える水洗槽及び第二回目の
洗浄液を貯える湯洗槽の各々を各クッションタンクに連
通し、該湯洗槽に従属するクッションタンクを熱交換器
を介装して前記水洗槽に従属するクッションタンクに連
通し一核水洗槽に従属するクッションタンクを濾過機と
イオン交換装置と前記熱交換器とを介装して前記湯洗槽
に連通し、から、該水洗槽に従属するクッションタンク
を該熱交換器を除き前記濾過機と前記イオン交換装置と
を介装して前記水洗槽こ連通して金属表面処理工程こお
ける洗浄液の夜及び熱の回収再利用装置を構成したので
、湯洗槽及び水洗槽のいずれにも純液を回収でき、それ
ら各槽内の水質を運転中終始良好な水質に保つことがで
き、よ)て、製品の品質精度を良好にすることができる
Further, in the present invention, secondly, each of the water washing tank for storing the first cleaning liquid and the hot water washing tank for storing the second cleaning liquid in the metal surface treatment step is communicated with each cushion tank, and the hot water washing tank is connected to the cushion tank. A cushion tank subordinate to the washing tank is connected to the cushion tank subordinate to the washing tank by interposing a heat exchanger, and a cushion tank subordinate to the washing tank is connected to a filter, an ion exchange device, and the heat exchanger. A cushion tank subordinate to the water washing tank is connected to the water washing tank by removing the heat exchanger and interposing the filter and the ion exchanger to connect the metal surface to the washing tank. Since we have constructed a system for recovering and reusing the cleaning liquid during the treatment process and the heat, it is possible to collect pure liquid in both the hot water washing tank and the cold washing tank, and the water quality in each tank is maintained at a good quality throughout the operation. As a result, the quality and accuracy of the product can be improved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図、第2図は従来の金属表面処理工程における洗浄
装置の概略説明図、第3図は本発明による金属表面処理
工程における洗浄液の液及び熱の回収再利用装置の概略
説明図である。 1・・・・・・湯洗槽、2,3,4・・・・・・パイプ
、5゜11・・・・・・クッションタンク、6・・・・
・・熱交換器、7・・・・・・パイプ、8・・・・・・
水洗槽、14・・・・・・酬過機、16・・・・・・貯
水槽、19・・・・・・イオン交換装置、10゜12.
15,18.20・・・・・・パイプ、22・・・・・
・分岐パイプ。
1 and 2 are schematic explanatory diagrams of a cleaning device in a conventional metal surface treatment process, and FIG. 3 is a schematic explanatory diagram of a cleaning liquid and heat recovery and reuse device in a metal surface treatment process according to the present invention. . 1... Hot water washing tank, 2, 3, 4... Pipe, 5゜11... Cushion tank, 6...
...Heat exchanger, 7...Pipe, 8...
Washing tank, 14... Refilling machine, 16... Water tank, 19... Ion exchange device, 10°12.
15, 18.20...pipe, 22...
- Branch pipe.

Claims (1)

【特許請求の範囲】 1 金属表面処理工程における第二回目の洗浄液を貯え
る湯洗槽から放出される高温水を低温の純水で熱交換し
て低温水としてこれを第一回目の洗浄液を貯える水洗槽
からの不純物を含む低温水と共にクッションタンクに導
入し、該クッションタンク内の液を濾過し、その濾液を
イオン交換し、そのイオン交換こよる純水を前記高温水
との熱交換により加熱して前記湯洗槽に回収すると共に
その純水の一部を加熱せず低温水のま\前記水洗槽に回
収するよう構成したことを特徴とする金属表面処理工程
における洗浄液の夜及び熱の回収再利用法。 2 金属表面処理工程における第一回目の洗浄液を貯え
る水洗槽及び第二回目の洗浄液を貯える湯洗槽の各々を
各クッションタンクこ連通し、該湯洗槽に従属するクッ
ションタンクを熱交換器を介して前記水洗槽に従属する
クッションタンクに連通し、該水洗槽に従属するクッシ
ョンタンクを濾過機とイオン交換装置と前記熱交換器と
を介装して前記湯洗槽に連通し、かつ、該水洗槽に従属
するクッションタンクを前記濾過機と前記イオン交換装
置とを介装して前記水洗槽に連通して構成したことを特
徴とする金属表面処理工程における洗浄液の威及び熱の
回収再利用装置。
[Scope of Claims] 1. High temperature water discharged from a hot water washing tank that stores the second cleaning solution in the metal surface treatment process is heat exchanged with low temperature pure water and used as low temperature water to store the first cleaning solution. The liquid in the cushion tank is introduced together with low temperature water containing impurities from the washing tank, the liquid in the cushion tank is filtered, the filtrate is ion exchanged, and the purified water resulting from the ion exchange is heated by heat exchange with the high temperature water. In the metal surface treatment process, the cleaning liquid is cooled and collected in the hot water washing tank, and a part of the pure water is collected in the cold water washing tank without being heated. Collection and reuse method. 2. The water washing tank that stores the first cleaning liquid in the metal surface treatment process and the hot water washing tank that stores the second cleaning liquid are connected to each cushion tank, and the cushion tank subordinate to the hot water washing tank is connected to a heat exchanger. communicates with a cushion tank subordinate to the water washing tank through the water washing tank, and communicates the cushion tank subordinate to the water washing tank with the hot water washing tank via a filter, an ion exchange device, and the heat exchanger, and A cushion tank subordinate to the washing tank is connected to the washing tank by interposing the filter and the ion exchange device. Equipment used.
JP11638080A 1980-08-26 1980-08-26 Method and apparatus for recovering and reusing cleaning liquid and heat in metal surface treatment process Expired JPS5810471B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11638080A JPS5810471B2 (en) 1980-08-26 1980-08-26 Method and apparatus for recovering and reusing cleaning liquid and heat in metal surface treatment process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11638080A JPS5810471B2 (en) 1980-08-26 1980-08-26 Method and apparatus for recovering and reusing cleaning liquid and heat in metal surface treatment process

Publications (2)

Publication Number Publication Date
JPS5741383A JPS5741383A (en) 1982-03-08
JPS5810471B2 true JPS5810471B2 (en) 1983-02-25

Family

ID=14685562

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11638080A Expired JPS5810471B2 (en) 1980-08-26 1980-08-26 Method and apparatus for recovering and reusing cleaning liquid and heat in metal surface treatment process

Country Status (1)

Country Link
JP (1) JPS5810471B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2502683C1 (en) * 2012-07-05 2013-12-27 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" (НИЦ "Курчатовский институт") Method of utilising blowdown water of circulating system

Also Published As

Publication number Publication date
JPS5741383A (en) 1982-03-08

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