JPS58104188A - 酸性化された塩水溶液の製造方法 - Google Patents
酸性化された塩水溶液の製造方法Info
- Publication number
- JPS58104188A JPS58104188A JP57212591A JP21259182A JPS58104188A JP S58104188 A JPS58104188 A JP S58104188A JP 57212591 A JP57212591 A JP 57212591A JP 21259182 A JP21259182 A JP 21259182A JP S58104188 A JPS58104188 A JP S58104188A
- Authority
- JP
- Japan
- Prior art keywords
- alkali metal
- solution
- chamber
- aqueous
- acidified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007864 aqueous solution Substances 0.000 title claims description 16
- 150000003839 salts Chemical class 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title description 12
- 239000012528 membrane Substances 0.000 claims description 78
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 48
- 239000000243 solution Substances 0.000 claims description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 40
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 37
- 238000005341 cation exchange Methods 0.000 claims description 30
- -1 alkali metal cations Chemical class 0.000 claims description 23
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 21
- 238000010494 dissociation reaction Methods 0.000 claims description 20
- 230000005593 dissociations Effects 0.000 claims description 20
- 239000012266 salt solution Substances 0.000 claims description 18
- 239000003792 electrolyte Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- 229910052783 alkali metal Inorganic materials 0.000 claims description 14
- 150000001768 cations Chemical class 0.000 claims description 9
- 239000011780 sodium chloride Substances 0.000 claims description 9
- 239000003014 ion exchange membrane Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 45
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 32
- 238000000909 electrodialysis Methods 0.000 description 32
- 239000002585 base Substances 0.000 description 19
- 239000000460 chlorine Substances 0.000 description 19
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 18
- 229910052801 chlorine Inorganic materials 0.000 description 18
- 239000001257 hydrogen Substances 0.000 description 15
- 229910052739 hydrogen Inorganic materials 0.000 description 15
- 238000003860 storage Methods 0.000 description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 239000012267 brine Substances 0.000 description 6
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920000557 Nafion® Polymers 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 238000000502 dialysis Methods 0.000 description 4
- 150000004679 hydroxides Chemical class 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000010425 asbestos Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229910052895 riebeckite Inorganic materials 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- HSFWRNGVRCDJHI-UHFFFAOYSA-N Acetylene Chemical compound C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000012527 feed solution Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- QVBVQHTXLPNXEY-ZMFCMNQTSA-N (4r)-6-[2-[4-(4-fluorophenyl)-6-phenyl-2-propan-2-ylpyridin-3-yl]ethyl]-4-hydroxyoxan-2-one Chemical compound C([C@H](O)C1)C(=O)OC1CCC=1C(C(C)C)=NC(C=2C=CC=CC=2)=CC=1C1=CC=C(F)C=C1 QVBVQHTXLPNXEY-ZMFCMNQTSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 102000003812 Interleukin-15 Human genes 0.000 description 1
- 108090000172 Interleukin-15 Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 230000003187 abdominal effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Water Supply & Treatment (AREA)
- Health & Medical Sciences (AREA)
- Urology & Nephrology (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US327145 | 1981-12-03 | ||
| US06/327,145 US4391680A (en) | 1981-12-03 | 1981-12-03 | Preparing alkali metal hydroxide by water splitting and hydrolysis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58104188A true JPS58104188A (ja) | 1983-06-21 |
| JPS6110555B2 JPS6110555B2 (OSRAM) | 1986-03-29 |
Family
ID=23275342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57212591A Granted JPS58104188A (ja) | 1981-12-03 | 1982-12-03 | 酸性化された塩水溶液の製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4391680A (OSRAM) |
| EP (1) | EP0081092B1 (OSRAM) |
| JP (1) | JPS58104188A (OSRAM) |
| CA (1) | CA1215019A (OSRAM) |
| DE (1) | DE3276542D1 (OSRAM) |
| ES (1) | ES8403983A1 (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60106986A (ja) * | 1983-09-23 | 1985-06-12 | インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− | アルカリ金属ケイ酸塩の製法 |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3381495D1 (de) * | 1983-03-14 | 1990-05-31 | Allied Signal Inc | Saeurebildung in laugen mit gleichzeitiger herstellung von alkalimetall-hydroxid und salzsaeure durch wasserzersetzung in einem aus drei kammerntypen bestehenden elektrodialyseapparat. |
| US4636289A (en) * | 1983-05-02 | 1987-01-13 | Allied Corporation | Solution mining of sodium minerals with acids generated by electrodialytic water splitting |
| US4536269A (en) * | 1983-05-02 | 1985-08-20 | Allied Corporation | Multichamber two-compartment electrodialytic water splitter and method of using same for acidification of aqueous soluble salts |
| US4498706A (en) * | 1983-08-15 | 1985-02-12 | Intermountain Research & Development Corp. | Solution mining of trona or nahcolite ore with aqueous NaOH and HCl solvents |
| US4655928A (en) * | 1983-10-18 | 1987-04-07 | Gnb Incorporated | Membrane processes for metal recovery and pollution control in metal process industries |
| US4608141A (en) * | 1984-11-07 | 1986-08-26 | Allied Corporation | Multichamber two-compartment electrodialytic water splitter and method of using same for basification of aqueous soluble salts |
| US4652054A (en) * | 1985-04-16 | 1987-03-24 | Intermountain Research & Development Corporation | Solution mining of trona or nahcolite ore with electrodialytically-produced aqueous sodium hydroxide |
| JPH0724828B2 (ja) * | 1986-03-12 | 1995-03-22 | 日東電工株式会社 | 電解質の除去方法 |
| US4880513A (en) * | 1986-06-20 | 1989-11-14 | The Graver Company | Method and apparatus for generating acid and base regenerants and the use thereof to regenerate ion-exchange resins |
| US4740281A (en) * | 1986-10-14 | 1988-04-26 | Allied Corporation | Recovery of acids from materials comprising acid and salt |
| JPS63195565A (ja) * | 1987-02-09 | 1988-08-12 | Aichi Steel Works Ltd | 超音波探傷垂直試験方法 |
| US5162076A (en) * | 1988-11-30 | 1992-11-10 | Allied-Signal Inc. | Method for purification of acids from materials comprising acid and salt |
| US5135626A (en) * | 1988-12-01 | 1992-08-04 | Allied-Signal Inc. | Method for purification of bases from materials comprising base and salt |
| US4976838A (en) * | 1988-12-01 | 1990-12-11 | Allied-Signal Inc. | Method for purification of bases from materials comprising base and salt |
| US4936962A (en) * | 1989-03-01 | 1990-06-26 | Fmc Corporation | Process for adjusting the pH of an aqueous flowable fluid |
| US4938856A (en) * | 1989-03-01 | 1990-07-03 | Fmc Corporation | Process for mild heat treatment of a flowable fluid |
| WO1990012637A2 (en) * | 1989-03-15 | 1990-11-01 | Pulp And Paper Research Institute Of Canada | Electrodialytic water splitting process for the treatment of aqueous electrolytes |
| US5006211A (en) * | 1989-04-19 | 1991-04-09 | Pulp And Paper Research Institute Of Canada | Electrodialylic water splitting process for the treatment of aqueous electrolytes |
| AT392735B (de) * | 1989-10-31 | 1991-05-27 | Chemiefaser Lenzing Ag | Verfahren zur stufenweisen elektrodialyse von alkalisulfathaeltigen waesserigen loesungen sowie vorrichtung zur durchfuehrung des verfahrens |
| DE4006764A1 (de) * | 1990-03-03 | 1991-09-19 | Duerrwaechter E Dr Doduco | Verfahren und vorrichtung zum erzeugen von silbernitrat |
| US5126026A (en) * | 1990-09-28 | 1992-06-30 | Allied-Signal Inc. | Guard membranes for use in electrodialysis cells |
| US5288378A (en) * | 1990-09-28 | 1994-02-22 | Alliedsignal Inc. | Guard membranes for use in electrodialysis cells |
| US5200046A (en) * | 1990-12-12 | 1993-04-06 | Allied-Signal Inc. | Apparatus and method for electrodialytic treatment of salts to produce acid and/or base of improved purity |
| US5141620A (en) * | 1990-12-18 | 1992-08-25 | United Technologies Corporation | Device and method for separating and compressing carbon dioxide from a carbonate salt |
| US5194130A (en) * | 1990-12-21 | 1993-03-16 | Allied-Signal Inc. | Method to produce sodium citrate using electrodialysis |
| US5198086A (en) * | 1990-12-21 | 1993-03-30 | Allied-Signal | Electrodialysis of salts of weak acids and/or weak bases |
| US5352345A (en) * | 1991-05-07 | 1994-10-04 | Alliedsignal Inc. | Ion exchange resin regenerant waste recovery and recycling via bipolar membranes |
| SE9202419D0 (sv) * | 1992-08-24 | 1992-08-24 | Eka Nobel Ab | Reduction of chloride in pulping chemical recovery systems |
| JP3115440B2 (ja) * | 1992-12-10 | 2000-12-04 | ペルメレック電極株式会社 | 塩化アルカリ水溶液の電解方法 |
| US5431792A (en) * | 1993-12-20 | 1995-07-11 | Occidental Chemical Corporation | Method of making hypophosphorous acid |
| DE69532281T2 (de) * | 1994-05-20 | 2004-09-30 | United States Filter Corp., Palm Desert | Verfahren und vorrichtung zur elektrischen entionisierung mit polaritätsumschaltung und doppelumkehrung |
| US5567293A (en) * | 1994-12-22 | 1996-10-22 | Pulp And Paper Research Institute Of Canada | Electromembrane processes for the treatment of kraft mill electrostatic precipitator catch |
| IT1273492B (it) | 1995-02-03 | 1997-07-08 | Solvay | Cassone d'estremita' di un elettrodializzatore,elettrodializzatore munito di un tale cassone e utilizzazione di detto elettrodializzatore |
| US5961803A (en) * | 1995-07-12 | 1999-10-05 | Eka Chemicals Ab | Leaching process |
| US5833832A (en) * | 1996-08-30 | 1998-11-10 | Sachem, Inc. | Preparation of onium hydroxides in an electrochemical cell |
| US5853555A (en) * | 1997-04-03 | 1998-12-29 | Sachem, Inc. | Synthesis of onium hydroxides from onium salts |
| US6139714A (en) * | 1997-12-02 | 2000-10-31 | Gemma Industrial Ecology Ltd. | Method and apparatus for adjusting the pH of a liquid |
| US6482305B1 (en) * | 1999-09-01 | 2002-11-19 | Archer-Daniels-Midland Company | Electrodialysis water splitting process |
| IT1313862B1 (it) | 1999-11-11 | 2002-09-24 | Solvay | Cassone di estremita' di un elettrodializzatore, elettrodializzatoreche comprende tale cassone di estremita' e procedimento di |
| US7906005B2 (en) * | 2003-08-08 | 2011-03-15 | Hubbard Frank G | Means and method of chemical production |
| US7959780B2 (en) | 2004-07-26 | 2011-06-14 | Emporia Capital Funding Llc | Textured ion exchange membranes |
| US7780833B2 (en) | 2005-07-26 | 2010-08-24 | John Hawkins | Electrochemical ion exchange with textured membranes and cartridge |
| KR101333243B1 (ko) | 2005-10-06 | 2013-11-26 | 파이오네틱스 코포레이션 | 유체의 전기화학적 이온교환 처리 |
| US7682594B2 (en) * | 2006-06-21 | 2010-03-23 | National Central University | Method for producing photocatalyst |
| EP3824991B1 (en) | 2012-04-23 | 2022-07-27 | Nemaska Lithium Inc. | Process for preparing lithium sulphate |
| PT2855735T (pt) | 2012-05-30 | 2018-06-14 | Nemaska Lithium Inc | Processos de preparação de carbonato de lítio |
| EP4631606A2 (en) | 2013-03-15 | 2025-10-15 | Nemaska Lithium Inc. | Processes for preparing lithium hydroxide |
| DK3060522T3 (da) | 2013-10-23 | 2019-08-26 | Nemaska Lithium Inc | Processer til forberedelse af lithiumkarbonat |
| CN105849317B (zh) | 2013-10-23 | 2018-11-27 | 内玛斯卡锂公司 | 制备氢氧化锂的方法和系统 |
| PT3110988T (pt) | 2014-02-24 | 2019-09-10 | Nemaska Lithium Inc | Métodos para o tratamento de materiais que contêm lítio |
| US9757695B2 (en) | 2015-01-03 | 2017-09-12 | Pionetics Corporation | Anti-scale electrochemical apparatus with water-splitting ion exchange membrane |
| US10597305B2 (en) | 2015-08-27 | 2020-03-24 | Nemaska Lithium Inc. | Methods for treating lithium-containing materials |
| US10391222B2 (en) * | 2015-12-31 | 2019-08-27 | Baxter International Inc. | Devices for urea electrolysis and methods of using same |
| US10406270B2 (en) * | 2015-12-31 | 2019-09-10 | Baxter International Inc. | Devices for urea electrolysis with combination electrodialysis and urea oxidation cell and methods of using same |
| KR101794843B1 (ko) * | 2016-03-29 | 2017-11-07 | (주)테크윈 | 전해 시스템 및 이를 이용한 전해 방법 |
| CA2940509A1 (en) | 2016-08-26 | 2018-02-26 | Nemaska Lithium Inc. | Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid |
| KR102590935B1 (ko) | 2017-11-22 | 2023-10-20 | 네마스카 리튬 인코포레이션 | 다양한 금속의 하이드록사이드와 옥사이드 및 이들의 유도체를 제조하는 방법 |
| US12275650B2 (en) | 2019-05-22 | 2025-04-15 | Nemaska Lithium Inc. | Processes for preparing hydroxides and oxides of various metals and derivatives thereof |
| AU2019468159B2 (en) * | 2019-09-25 | 2022-12-01 | De Nora Permelec Ltd | Laminated structure including electrodes |
| JP2024515628A (ja) | 2021-04-16 | 2024-04-10 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | 次世代二酸化炭素回収のための電気化学的に強化されたプロセス |
| WO2023069370A1 (en) | 2021-10-18 | 2023-04-27 | The Regents Of The University Of California | Integration of direct air capture system into co2 mineralizaton process of concretes and aggregates |
| US11998875B2 (en) | 2021-12-22 | 2024-06-04 | The Research Foundation for The State University of New York York | System and method for electrochemical ocean alkalinity enhancement |
| US12203184B2 (en) * | 2022-07-18 | 2025-01-21 | The Regents Of The University Of California | Multi-chambered electrochemical cell for carbon dioxide removal |
| CN120731296A (zh) | 2023-01-31 | 2025-09-30 | 加利福尼亚大学董事会 | 氧选择性阳极 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2829095A (en) * | 1955-09-03 | 1958-04-01 | Noguchi Kenkyu Jo | Process for the production of acidic and alkaline solution from salt solution by multi-compartment electrolysis |
| US3111472A (en) * | 1957-08-24 | 1963-11-19 | Zaidan Hojin Noguchi Kenkyu Jo | Process of carrying out electrochemically electrolysis |
| US3562139A (en) * | 1968-08-05 | 1971-02-09 | Ionics | Cationic-anionic ion-exchange membrane |
| US3788959A (en) * | 1972-05-05 | 1974-01-29 | Sybron Corp | Electrodialytic recovery of acid and insoluble products from spent liquors |
| US3905886A (en) * | 1974-09-13 | 1975-09-16 | Aqua Chem Inc | Ultrafiltration and electrodialysis method and apparatus |
| US4024043A (en) * | 1975-12-31 | 1977-05-17 | Allied Chemical Corporation | Single film, high performance bipolar membrane |
| US4107015A (en) * | 1977-07-18 | 1978-08-15 | Allied Chemical Corporation | Method for removal of SO2 from gases |
| JPS5927389B2 (ja) * | 1978-02-15 | 1984-07-05 | 旭化成株式会社 | 陽イオン交換膜食塩電解方法 |
| DE2837313A1 (de) * | 1978-08-26 | 1980-03-13 | Metallgesellschaft Ag | Verfahren zur elektrolyse waessriger alkalihalogenid-loesungen |
| US4219396A (en) * | 1979-08-03 | 1980-08-26 | Allied Chemical Corporation | Electrodialytic process |
-
1981
- 1981-12-03 US US06/327,145 patent/US4391680A/en not_active Expired - Lifetime
-
1982
- 1982-11-11 EP EP82110382A patent/EP0081092B1/en not_active Expired
- 1982-11-11 DE DE8282110382T patent/DE3276542D1/de not_active Expired
- 1982-11-17 CA CA000415776A patent/CA1215019A/en not_active Expired
- 1982-11-26 ES ES517692A patent/ES8403983A1/es not_active Expired
- 1982-12-03 JP JP57212591A patent/JPS58104188A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60106986A (ja) * | 1983-09-23 | 1985-06-12 | インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− | アルカリ金属ケイ酸塩の製法 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES517692A0 (es) | 1984-04-16 |
| JPS6110555B2 (OSRAM) | 1986-03-29 |
| ES8403983A1 (es) | 1984-04-16 |
| CA1215019A (en) | 1986-12-09 |
| US4391680A (en) | 1983-07-05 |
| DE3276542D1 (en) | 1987-07-16 |
| EP0081092B1 (en) | 1987-06-10 |
| EP0081092A1 (en) | 1983-06-15 |
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