JPS58102469A - Cooled fuel cell - Google Patents

Cooled fuel cell

Info

Publication number
JPS58102469A
JPS58102469A JP56202323A JP20232381A JPS58102469A JP S58102469 A JPS58102469 A JP S58102469A JP 56202323 A JP56202323 A JP 56202323A JP 20232381 A JP20232381 A JP 20232381A JP S58102469 A JPS58102469 A JP S58102469A
Authority
JP
Japan
Prior art keywords
cooling
cell
carbon
air path
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56202323A
Other languages
Japanese (ja)
Inventor
Masahiro Ide
井出 正裕
Mutsuya Saito
斉藤 六弥
Hideo Ogino
秀雄 荻野
Osamu Tajima
収 田島
Yasuo Miyake
泰夫 三宅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Electric Co Ltd
Sanyo Denki Co Ltd
Original Assignee
Sanyo Electric Co Ltd
Sanyo Denki Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Electric Co Ltd, Sanyo Denki Co Ltd filed Critical Sanyo Electric Co Ltd
Priority to JP56202323A priority Critical patent/JPS58102469A/en
Publication of JPS58102469A publication Critical patent/JPS58102469A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074Heat exchange unit structures specially adapted for fuel cell
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

PURPOSE:To decrease temperature difference in a cell by placing a carbon cooling plate in which a cooling air path is formed by embeding alumite treated squar pipes between a unit cell and a cell stack stacked with a gas separating plate. CONSTITUTION:A unit cell 2 comprising an anode gas electrode, a cathode electrode, and an electrolyte matrix and a carbon gas separating plate 5 which has reaction gas supply grooves 3 and 4 on its both surfaces are stacked mutually to form a cell stack 1. A carbon cooling plate 7 having a cooling air path 6 is placed every four or five cells to form a cooled fuel cell. An alumite treated aluminum square pipe 8 is embedded in an air path 6 of the cooling plate 7 by installing a separation rib 9. Since aluminum has large heat conductivity compared with carbon, cooling effect by the air path 6 is increased and efficiency of a cell is improved.

Description

【発明の詳細な説明】 不発明は空冷式1科電池に係り、特に冷却板の改良C二
より空冷効果ン同上Tると共に電池内の温fl[jlt
’減少し、4池寿命の改善を図ることχ目的とする。
DETAILED DESCRIPTION OF THE INVENTION The invention relates to an air-cooled type 1 battery, and in particular improves the air cooling effect by improving the cooling plate C2, as well as reducing the temperature inside the battery.
The purpose is to reduce the amount of water and improve the lifespan of the four ponds.

この種りん酸燃料電池の作動温度!島、iso’h〜1
80℃であるが、IE池反応島により200℃以上にも
m度上昇するため冷却が必要である。空冷法としては電
池に供給される空気Y一部反応空気供給溝C,他の大部
分(導入交電量の約7596]を冷却板の空気通路(:
夫々供給する方法と、反応空気とは分離して冷却専用9
気を供給する方法とがある。いづれの場合も電池で発生
する熱は反応空気でも冷却されるが、電池スタックが大
型化するとこれだけでは不充分で大部分の冷却は前記冷
却板t−用いて集中的に行われる。従来411Ikスタ
ツクを構成するガス分離板の空気入口9mは約り50℃
出口側は約180℃で、この温1f1によって′照性特
性の不均一ひいては電池寿命の低下の原因(二なってい
た。
The operating temperature of this kind of phosphoric acid fuel cell! island, iso'h~1
Although the temperature is 80°C, the temperature rises to over 200°C due to the reaction islands in the IE pond, so cooling is required. As for the air cooling method, part of the air Y supplied to the battery is supplied to the reaction air supply groove C, and the other part (approximately 7596 of the introduced AC power) is supplied to the air passage of the cooling plate (:
The method of supplying each and the reaction air are separated and used exclusively for cooling 9
There are ways to supply energy. In either case, the heat generated by the battery is also cooled by reaction air, but as the battery stack becomes larger, this alone is insufficient and most of the cooling is performed intensively using the cooling plate t-. Conventional 411Ik stack has an air inlet of 9m at a gas separation plate with a temperature of approximately 50°C.
The temperature on the exit side was approximately 180° C., and this temperature 1f1 caused non-uniform illumination characteristics and shortened battery life.

本発明はか\る点I:Ilみ改良したものでその実施例
t−以下図について説明する。
The present invention has been improved in the following points, and an embodiment thereof will be described with reference to the following figures.

一般区二空冷式惺料電池の電池スタック(1)は、S1
図1;示すよう一二、陰・陽ガス極とその間を隔離する
電解質マトリクス(いづれも図示せず)よりなる単位ヤ
ル(21と1両−シ:夫々各反応ガス(水素及び空気)
の供給溝(31(4)v形設した炭素質ガス分離板(5
)とt交互6二積重し、数セル例えば4〜Sセル毎に冷
却空気通路(61t’lrTる炭素質冷却板(7)を介
在させて構成される。
The battery stack (1) of the general area 2 air-cooled air-cooled battery is S1
Figure 1; As shown in Figure 1, unit cylinders (21 and 1) consisting of negative and positive gas electrodes and an electrolyte matrix (none of which is shown) separating the anode and anode gas electrodes: each reactant gas (hydrogen and air), respectively.
A carbonaceous gas separation plate (5) with a supply groove (31 (4)
) and t alternately stacked 6 times, and a cooling air passage (61t'lrT) carbonaceous cooling plate (7) is interposed for every few cells, for example, 4 to S cells.

尚このスタック(1)の対向面には、水素ガス供給用の
一対のマニホルド及び空気供給用の一対のマニホルド(
いづれも図示せず)を気密的に貨看して電池に組立てら
れる。
Furthermore, on the opposing surfaces of this stack (1), a pair of manifolds for supplying hydrogen gas and a pair of manifolds for supplying air (
(none of which are shown) are assembled into a battery in an airtight manner.

さて従来の炭素質冷却板(7)は第2図に示すようにそ
の空気通路(6)も同材質であるが1本発明により改良
された炭素質冷却板(71は第!S@lに示すようにそ
の角穴に*l1ivyルマイト処理したアルミニワム製
角パイプ(8)ン埋設して空気通路(6)v構成したも
のである。又冷却表面積を大きくするため角パイプ(8
1に1〜2ケの仕切タブ(9)を一体に形成する。
Now, as shown in Fig. 2, the conventional carbonaceous cooling plate (7) has its air passages (6) made of the same material, but the carbonaceous cooling plate (71 is No. !S@l) improved by the present invention. As shown, an air passage (6) is constructed by embedding an aluminum square pipe (8) treated with lumite in the square hole.Also, in order to increase the cooling surface area, a square pipe (8) is buried in the square hole.
1 to 2 partition tabs (9) are integrally formed.

角パイプ(8)の埋設は、炭素質冷却板(71の角穴に
圧入してもよいし、二分割した冷却板の角穴奮構成する
溝間に挾看してもよい。
The square pipe (8) may be buried by being press-fitted into the square hole of the carbonaceous cooling plate (71), or by being inserted between the grooves forming the square hole of the cooling plate divided into two parts.

7/L/lニワムは従来の炭素質(カーボン)に比較し
、熱電導率は約1000倍であると同wlc仕切りフ(
90:よって表面積を広くしているので、空気通路(6
)による冷却効果が良好であり、従来よりも少ない風量
で冷却が可能であるから、ブロワの電力を低減して燃料
電池の効率も良くなる。
7/L/L Niwam has thermal conductivity approximately 1000 times higher than conventional carbonaceous material (carbon), according to the same WLC partition flap.
90: Therefore, since the surface area is widened, the air passage (6
) has a good cooling effect and can be cooled with a smaller air volume than before, reducing blower power and improving fuel cell efficiency.

又空気通路の熱伝導率が極めて良いので、冷却板+7’
lv介してスタック(1)の空気入口側と出口側の温i
mt’相当低減することができる、これを第4図に示し
、従来品(点線)では入口側は150℃出01!418
0℃であったが、本発明品(実線)では夫4150℃か
ら165℃となり1m度差が60℃から15℃(=改良
された。
Also, since the thermal conductivity of the air passage is extremely good, the cooling plate +7'
The temperature i on the air inlet side and outlet side of the stack (1) through lv
This is shown in Figure 4, where the conventional product (dotted line) has a temperature of 150°C on the inlet side.01!418
0°C, but the product of the present invention (solid line) went from 4150°C to 165°C, with a difference of 1 m degree from 60°C to 15°C (=improved).

上述の如く本発明によれば、炭素質冷却板にアルマイト
処理t’mt、、たアルミニワム製角パイプを堀設して
冷却空気通路を構成したので、従来のもの1=比し熱伝
導率の著しい差−二より冷却効果が良好で、スタックの
空気入口側と出口側の温度11tw低減して電池特性と
電池寿命の同上を計ることができる。又角パイプに仕切
りブχ形成して冷却表面積Y大きくすれば、冷却効果を
一層向上することが可能となるなどの特員がある。
As described above, according to the present invention, the cooling air passage is constructed by drilling an alumite-treated aluminum square pipe in the carbonaceous cooling plate, so that the thermal conductivity is lower than that of the conventional one (1 = 1). Significant difference - The cooling effect is better than the second one, and the temperature on the air inlet side and the outlet side of the stack is reduced by 11tw, and it is possible to measure the same battery characteristics and battery life. Furthermore, there are special features such as the ability to further improve the cooling effect by forming a partition χ on the square pipe to increase the cooling surface area Y.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の対象とする電池スタックの斜面図、第
2図及び!s5図は9気通路を有する冷却板の斜面図で
、 1Ji21Vは従来品、115図は本発明1・・・
電池スタック、2・・・単位セル、5.4・・・反応ガ
ス(水素及び空気)の供給溝、5・・・炭素質ガス分離
板、6・・・空気通路、7.7・・・冷却板、8・・・
1ルミニワム製角パイプ、9・・・仕切りブ。
Figure 1 is a perspective view of a battery stack that is the subject of the present invention, Figure 2 and! Figure s5 is a perspective view of a cooling plate with 9 air passages, 1Ji21V is the conventional product, and Figure 115 is the present invention 1...
Battery stack, 2... Unit cell, 5.4... Reactant gas (hydrogen and air) supply groove, 5... Carbonaceous gas separation plate, 6... Air passage, 7.7... Cooling plate, 8...
1 Luminiwam square pipe, 9... Partition block.

Claims (1)

【特許請求の範囲】[Claims] ■ 単位上ノνと員素質ガス分1II41iとt交互に
積重し、前記数セル毎C二炭素質冷却板を介在させてな
る゛電池スタックを備え、前記冷却板円感;、アルマイ
ト処理ン施した角パイプを埋設して冷却空気通路!形成
したことン特徴とする空冷式燃料′電池(■ 前記角パ
イプは一体C:形設した仕切りブによって放熱表面積ン
増大したこと奮特徴とする前記特許請求の範囲@1項記
載の空冷式1料1池
■ Equipped with a battery stack in which the unit top ν and the elemental gases 1II41i and t are stacked alternately, and a carbonaceous cooling plate is interposed every several cells, and the cooling plate has a circular shape; Create a cooling air passage by burying the square pipes! An air-cooled fuel cell (1) characterized in that the square pipe is an integral part (C): The air-cooled fuel cell according to claim 1 is characterized in that the square pipe is integrally formed (C): the heat dissipation surface area is increased by the formed partition plate. Fee 1 Pond
JP56202323A 1981-12-14 1981-12-14 Cooled fuel cell Pending JPS58102469A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56202323A JPS58102469A (en) 1981-12-14 1981-12-14 Cooled fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56202323A JPS58102469A (en) 1981-12-14 1981-12-14 Cooled fuel cell

Publications (1)

Publication Number Publication Date
JPS58102469A true JPS58102469A (en) 1983-06-18

Family

ID=16455638

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56202323A Pending JPS58102469A (en) 1981-12-14 1981-12-14 Cooled fuel cell

Country Status (1)

Country Link
JP (1) JPS58102469A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100804702B1 (en) 2006-11-15 2008-02-18 삼성에스디아이 주식회사 Fuel cell stack

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100804702B1 (en) 2006-11-15 2008-02-18 삼성에스디아이 주식회사 Fuel cell stack

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