JPS577426A - Telomerization of acyclic conjugated diolefin - Google Patents

Telomerization of acyclic conjugated diolefin

Info

Publication number
JPS577426A
JPS577426A JP8179380A JP8179380A JPS577426A JP S577426 A JPS577426 A JP S577426A JP 8179380 A JP8179380 A JP 8179380A JP 8179380 A JP8179380 A JP 8179380A JP S577426 A JPS577426 A JP S577426A
Authority
JP
Japan
Prior art keywords
catalyst
reaction
telomerization
conjugated diolefin
unidentate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8179380A
Other languages
Japanese (ja)
Other versions
JPS646175B2 (en
Inventor
Noriaki Yoshimura
Masuhiko Tamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP8179380A priority Critical patent/JPS577426A/en
Publication of JPS577426A publication Critical patent/JPS577426A/en
Publication of JPS646175B2 publication Critical patent/JPS646175B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Catalysts (AREA)

Abstract

PURPOSE: To maintain the activity of a Pd catalyst in the telomerization of an acyclic conjugated diolefin with an organic compound having an active hydrogen, stably for a long period, by combining the Pd catalyst with unidentate and bidentate phosphines.
CONSTITUTION: In the telomerization of an acyclic conjugated diolefin with a telogen comprising an organic compound containing an active hydrogen, in the presence of a Pd catalyst, a unidentate phosphine (e.g. triphenyl phosphine) and a bidentate phosphine [e.g. (C6H5)2PCH2P(C6H5)2] are added to the reaction system. The amounts of the unidentate and the bidentate phosphines are ≥6mol and 0.3W 3mol per 1 g-atom of Pd, respectively. Although the reaction product can be separated by the direct distillation of the reaction mixture, the product can also be separated by extracting with a hydrocarbon when sulfolane or methylsulfolane is used as the reaction solvent. Since the reaction mixture is not heated in the latter separation process, the catalyst can be used stably for a long period.
EFFECT: High rate of reaction.
COPYRIGHT: (C)1982,JPO&Japio
JP8179380A 1980-06-16 1980-06-16 Telomerization of acyclic conjugated diolefin Granted JPS577426A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8179380A JPS577426A (en) 1980-06-16 1980-06-16 Telomerization of acyclic conjugated diolefin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8179380A JPS577426A (en) 1980-06-16 1980-06-16 Telomerization of acyclic conjugated diolefin

Publications (2)

Publication Number Publication Date
JPS577426A true JPS577426A (en) 1982-01-14
JPS646175B2 JPS646175B2 (en) 1989-02-02

Family

ID=13756360

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8179380A Granted JPS577426A (en) 1980-06-16 1980-06-16 Telomerization of acyclic conjugated diolefin

Country Status (1)

Country Link
JP (1) JPS577426A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4536604A (en) * 1984-03-15 1985-08-20 Texaco Inc. Butadiene reductive dimerization using a platinum catalyst and polymeric amine promoter
US5198598A (en) * 1991-07-19 1993-03-30 Henkel Kommanditgesellschaft Auf Aktien Telomerization process of a conjugated alkadiene with a polyol
US5206396A (en) * 1990-07-25 1993-04-27 Henkel Research Corporation Telomerization of 1,3-butadiene
US5236909A (en) * 1990-07-25 1993-08-17 Henkel Research Corporation Octyl ethers and octadienyl ethers
WO2003040065A3 (en) * 2001-11-09 2004-01-22 Shell Int Research Bidentate ligand for the telomerization of dienes

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4536604A (en) * 1984-03-15 1985-08-20 Texaco Inc. Butadiene reductive dimerization using a platinum catalyst and polymeric amine promoter
US5206396A (en) * 1990-07-25 1993-04-27 Henkel Research Corporation Telomerization of 1,3-butadiene
US5236909A (en) * 1990-07-25 1993-08-17 Henkel Research Corporation Octyl ethers and octadienyl ethers
US5198598A (en) * 1991-07-19 1993-03-30 Henkel Kommanditgesellschaft Auf Aktien Telomerization process of a conjugated alkadiene with a polyol
WO2003040065A3 (en) * 2001-11-09 2004-01-22 Shell Int Research Bidentate ligand for the telomerization of dienes
JP2005507950A (en) * 2001-11-09 2005-03-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Bidentate ligands for diene telomerization

Also Published As

Publication number Publication date
JPS646175B2 (en) 1989-02-02

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