JPS577426A - Telomerization of acyclic conjugated diolefin - Google Patents
Telomerization of acyclic conjugated diolefinInfo
- Publication number
- JPS577426A JPS577426A JP8179380A JP8179380A JPS577426A JP S577426 A JPS577426 A JP S577426A JP 8179380 A JP8179380 A JP 8179380A JP 8179380 A JP8179380 A JP 8179380A JP S577426 A JPS577426 A JP S577426A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- reaction
- telomerization
- conjugated diolefin
- unidentate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To maintain the activity of a Pd catalyst in the telomerization of an acyclic conjugated diolefin with an organic compound having an active hydrogen, stably for a long period, by combining the Pd catalyst with unidentate and bidentate phosphines.
CONSTITUTION: In the telomerization of an acyclic conjugated diolefin with a telogen comprising an organic compound containing an active hydrogen, in the presence of a Pd catalyst, a unidentate phosphine (e.g. triphenyl phosphine) and a bidentate phosphine [e.g. (C6H5)2PCH2P(C6H5)2] are added to the reaction system. The amounts of the unidentate and the bidentate phosphines are ≥6mol and 0.3W 3mol per 1 g-atom of Pd, respectively. Although the reaction product can be separated by the direct distillation of the reaction mixture, the product can also be separated by extracting with a hydrocarbon when sulfolane or methylsulfolane is used as the reaction solvent. Since the reaction mixture is not heated in the latter separation process, the catalyst can be used stably for a long period.
EFFECT: High rate of reaction.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8179380A JPS577426A (en) | 1980-06-16 | 1980-06-16 | Telomerization of acyclic conjugated diolefin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8179380A JPS577426A (en) | 1980-06-16 | 1980-06-16 | Telomerization of acyclic conjugated diolefin |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS577426A true JPS577426A (en) | 1982-01-14 |
JPS646175B2 JPS646175B2 (en) | 1989-02-02 |
Family
ID=13756360
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8179380A Granted JPS577426A (en) | 1980-06-16 | 1980-06-16 | Telomerization of acyclic conjugated diolefin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS577426A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4536604A (en) * | 1984-03-15 | 1985-08-20 | Texaco Inc. | Butadiene reductive dimerization using a platinum catalyst and polymeric amine promoter |
US5198598A (en) * | 1991-07-19 | 1993-03-30 | Henkel Kommanditgesellschaft Auf Aktien | Telomerization process of a conjugated alkadiene with a polyol |
US5206396A (en) * | 1990-07-25 | 1993-04-27 | Henkel Research Corporation | Telomerization of 1,3-butadiene |
US5236909A (en) * | 1990-07-25 | 1993-08-17 | Henkel Research Corporation | Octyl ethers and octadienyl ethers |
WO2003040065A3 (en) * | 2001-11-09 | 2004-01-22 | Shell Int Research | Bidentate ligand for the telomerization of dienes |
-
1980
- 1980-06-16 JP JP8179380A patent/JPS577426A/en active Granted
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4536604A (en) * | 1984-03-15 | 1985-08-20 | Texaco Inc. | Butadiene reductive dimerization using a platinum catalyst and polymeric amine promoter |
US5206396A (en) * | 1990-07-25 | 1993-04-27 | Henkel Research Corporation | Telomerization of 1,3-butadiene |
US5236909A (en) * | 1990-07-25 | 1993-08-17 | Henkel Research Corporation | Octyl ethers and octadienyl ethers |
US5198598A (en) * | 1991-07-19 | 1993-03-30 | Henkel Kommanditgesellschaft Auf Aktien | Telomerization process of a conjugated alkadiene with a polyol |
WO2003040065A3 (en) * | 2001-11-09 | 2004-01-22 | Shell Int Research | Bidentate ligand for the telomerization of dienes |
JP2005507950A (en) * | 2001-11-09 | 2005-03-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Bidentate ligands for diene telomerization |
Also Published As
Publication number | Publication date |
---|---|
JPS646175B2 (en) | 1989-02-02 |
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