JPS5773036A - Vinyl chloride resin composition - Google Patents

Vinyl chloride resin composition

Info

Publication number
JPS5773036A
JPS5773036A JP55148729A JP14872980A JPS5773036A JP S5773036 A JPS5773036 A JP S5773036A JP 55148729 A JP55148729 A JP 55148729A JP 14872980 A JP14872980 A JP 14872980A JP S5773036 A JPS5773036 A JP S5773036A
Authority
JP
Japan
Prior art keywords
stage
crosslinking agent
copolymer
aromatic vinyl
core polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP55148729A
Other languages
Japanese (ja)
Other versions
JPS592704B2 (en
Inventor
Takayuki Katsuto
Yoshiya Shiiki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kureha Corp
Original Assignee
Kureha Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kureha Corp filed Critical Kureha Corp
Priority to JP55148729A priority Critical patent/JPS592704B2/en
Priority to US06/313,198 priority patent/US4352910A/en
Priority to AU76732/81A priority patent/AU546182B2/en
Priority to EP81108757A priority patent/EP0050848B1/en
Priority to CA000388519A priority patent/CA1180484A/en
Priority to KR1019810004010A priority patent/KR860001212B1/en
Priority to MX189762A priority patent/MX160493A/en
Priority to DE8181108757T priority patent/DE3170754D1/en
Priority to BR8106824A priority patent/BR8106824A/en
Priority to NL8201149A priority patent/NL8201149A/en
Publication of JPS5773036A publication Critical patent/JPS5773036A/en
Publication of JPS592704B2 publication Critical patent/JPS592704B2/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE: A resin composition that contains a specific copolymer, thus showing extremely less whitening, even when deformation such as folding is caused in a molded product, as well as high impact strength.
CONSTITUTION: At the first stage, a latex containing 10W60pts.wt. of the core polymer consisting of 5W49% conjugate diene, 41W95% aromatic vinyl compound, or a mixture thereof with alkyl acrylate and 0W10% crosslinking agent is produced and at the second stage, a monomer mixture consisting of more than 60% conjugate diene, 0W5% crosslinking agent and the rest part of aromatic vinyl is added to the above core polymer to cover the core polymer by 20W75pts. to effect the polymerization. Further, at the third stage, 15W50pts. of monomer mixture consisting of alkyl methacrylate and aromatic vinyl including 0W10% crosslinking agent are polymerized in the presence of the resultant copolymer to produce a copolymer having a rigid polymer as the shell layer. The resultant copolymer is combined with a vinyl chloride resin at a ratio of 3W40% to 60W97%.
COPYRIGHT: (C)1982,JPO&Japio
JP55148729A 1980-10-23 1980-10-23 Vinyl chloride resin composition Expired JPS592704B2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
JP55148729A JPS592704B2 (en) 1980-10-23 1980-10-23 Vinyl chloride resin composition
US06/313,198 US4352910A (en) 1980-10-23 1981-10-20 Vinyl chloride resin composition with multi-stage impact modifier
AU76732/81A AU546182B2 (en) 1980-10-23 1981-10-22 Pvc composition with impact modifier
EP81108757A EP0050848B1 (en) 1980-10-23 1981-10-22 Vinyl chloride resin composition
CA000388519A CA1180484A (en) 1980-10-23 1981-10-22 Vinyl chloride resin composition including an impact modifier composite copolymer having a core and two layers
KR1019810004010A KR860001212B1 (en) 1980-10-23 1981-10-22 Vinyl chloride resin composition
MX189762A MX160493A (en) 1980-10-23 1981-10-22 VINYL CHLORIDE RESIN COMPOSITION
DE8181108757T DE3170754D1 (en) 1980-10-23 1981-10-22 Vinyl chloride resin composition
BR8106824A BR8106824A (en) 1980-10-23 1981-10-22 VINYL CHLORIDE RESIN COMPOSITION
NL8201149A NL8201149A (en) 1980-10-23 1982-03-19 POLYVINYL CHLORIDE MIXTURES.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55148729A JPS592704B2 (en) 1980-10-23 1980-10-23 Vinyl chloride resin composition

Publications (2)

Publication Number Publication Date
JPS5773036A true JPS5773036A (en) 1982-05-07
JPS592704B2 JPS592704B2 (en) 1984-01-20

Family

ID=15459297

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55148729A Expired JPS592704B2 (en) 1980-10-23 1980-10-23 Vinyl chloride resin composition

Country Status (10)

Country Link
US (1) US4352910A (en)
EP (1) EP0050848B1 (en)
JP (1) JPS592704B2 (en)
KR (1) KR860001212B1 (en)
AU (1) AU546182B2 (en)
BR (1) BR8106824A (en)
CA (1) CA1180484A (en)
DE (1) DE3170754D1 (en)
MX (1) MX160493A (en)
NL (1) NL8201149A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5933342A (en) * 1982-08-18 1984-02-23 Mitsubishi Rayon Co Ltd Vinyl chloride resin composition
JPS5951931A (en) * 1982-09-16 1984-03-26 Sumitomo Chem Co Ltd Vinyl chloride resin composition
JPS5998153A (en) * 1982-11-09 1984-06-06 Mitsubishi Rayon Co Ltd Vinyl chloride resin composition
JPS5998151A (en) * 1982-11-08 1984-06-06 Mitsubishi Rayon Co Ltd Vinyl chloride resin composition
JPS60208349A (en) * 1984-04-03 1985-10-19 Kanegafuchi Chem Ind Co Ltd Resin composition
JPS60235854A (en) * 1984-05-08 1985-11-22 Kanegafuchi Chem Ind Co Ltd Vinyl chloride resin composition having excellent solvent resistance
JPH02191652A (en) * 1989-12-22 1990-07-27 Kanegafuchi Chem Ind Co Ltd Vinyl chloride-based resin composition having excellent resistance to solvent
KR100417062B1 (en) * 2001-01-11 2004-02-05 주식회사 엘지화학 Method for preparing acryle rubber latex having bimodal particle distribution
WO2005063826A1 (en) * 2003-12-30 2005-07-14 Lg Chem, Ltd. Polymer latex having excellent impact-resistance and powder flow property and method for preparing the same
KR100708965B1 (en) 2004-09-01 2007-04-18 주식회사 엘지화학 Acrylic-conjugated diene-based composite rubber impact modifier having excellent impact resistance and weather resistance and manufacturing method thereof
JP2008528756A (en) * 2005-08-19 2008-07-31 エルジー・ケム・リミテッド Impact reinforcing agent for PVC resin and method for producing the same
JP2010515818A (en) * 2007-01-16 2010-05-13 エルジー・ケム・リミテッド Graft copolymer for transparent thermoplastic polyurethane resin, method for producing the same, and polyurethane resin composition containing the same

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1201547A (en) * 1982-07-13 1986-03-04 Akira Takaki Graft copolymer useful as reinforcements for vinyl chloride polymers and process for preparing the same
DE3300526A1 (en) * 1983-01-10 1984-07-12 Röhm GmbH, 6100 Darmstadt IMPACT MODIFIER
JPS60217252A (en) * 1984-04-12 1985-10-30 Kanegafuchi Chem Ind Co Ltd Vinyl chloride resin composition having improved impact resistance
US4602064A (en) * 1984-11-30 1986-07-22 The Dow Chemical Company Grafted rubber concentrates for use in impact resistant polymers
JPH062792B2 (en) * 1985-05-10 1994-01-12 三菱レイヨン株式会社 Lubricants for thermoplastics
JPH01313551A (en) * 1988-06-14 1989-12-19 Mitsubishi Rayon Co Ltd Polyvinyl chloride resin composition
US5047474A (en) * 1989-08-03 1991-09-10 Rohm And Haas Company Polymeric modifier compositions
DE4101969A1 (en) * 1991-01-24 1992-07-30 Basf Ag IMPACT-RESISTANT POLYVINYL HALOGENIDE MOLDING WITH HIGH TRANSPARENCY
WO1993021274A1 (en) * 1992-04-15 1993-10-28 The B.F. Goodrich Company Multilayer core-shell polymer compositions as toughener for thermosets and thermoplastics
DE69943227D1 (en) 1998-09-09 2011-04-07 Rohm & Haas A method of making a core cup impact modified emulsion
KR100454023B1 (en) 2000-10-27 2004-10-20 주식회사 엘지화학 Process for preparation of graft copolymer of methylmethacrylate -butadiene-styrene havng superior anti-stress whitening property
RU2212421C2 (en) * 2001-09-03 2003-09-20 Государственное унитарное предприятие Республики Татарстан Завод "СТРОЙПЛАСТ" при Государственном внебюджетном жилищном фонде Polyvinylchloride-based composition for profiled articles
TWI385187B (en) * 2006-08-29 2013-02-11 Mitsubishi Rayon Co Thermoplastic resin composition, and molded product
US9260603B2 (en) * 2013-03-15 2016-02-16 Sabic Global Technologies B.V. Polymer compositions, method of manufacture, and articles formed therefrom
CN109971086A (en) 2019-02-14 2019-07-05 山东东临新材料股份有限公司 A kind of opaque high-impact MBS of PVC easy processing and preparation method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL130337C (en) * 1967-08-19
US3644249A (en) * 1968-07-10 1972-02-22 Mitsubishi Rayon Co Polyvinyl chloride resin composition having excellent transparency, surface gloss and impact strength
US3886232A (en) * 1971-10-07 1975-05-27 Kureha Chemical Ind Co Ltd Process for producing vinyl chloride resin composition
BE790738A (en) * 1972-10-06 1973-04-30 Denki Kagaku Kogyo Kk COMPOSITION COMPRISING A CHLOROVINYL RESIN AND A NEW COPOLYMER GRAFT, AND ITS PREPARATION PROCESS
US3959895A (en) * 1974-06-27 1976-06-01 Monsanto Company Polyvinyl chloride polyblend molding
US4133788A (en) * 1978-01-23 1979-01-09 Borg-Warner Corporation Polymer latex which is cross-linked with a dialkyl tin diacrylate in the preparation of grafted copolymers

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5933342A (en) * 1982-08-18 1984-02-23 Mitsubishi Rayon Co Ltd Vinyl chloride resin composition
JPS5951931A (en) * 1982-09-16 1984-03-26 Sumitomo Chem Co Ltd Vinyl chloride resin composition
JPS5998151A (en) * 1982-11-08 1984-06-06 Mitsubishi Rayon Co Ltd Vinyl chloride resin composition
JPS5998153A (en) * 1982-11-09 1984-06-06 Mitsubishi Rayon Co Ltd Vinyl chloride resin composition
JPS60208349A (en) * 1984-04-03 1985-10-19 Kanegafuchi Chem Ind Co Ltd Resin composition
JPS60235854A (en) * 1984-05-08 1985-11-22 Kanegafuchi Chem Ind Co Ltd Vinyl chloride resin composition having excellent solvent resistance
JPH02191652A (en) * 1989-12-22 1990-07-27 Kanegafuchi Chem Ind Co Ltd Vinyl chloride-based resin composition having excellent resistance to solvent
KR100417062B1 (en) * 2001-01-11 2004-02-05 주식회사 엘지화학 Method for preparing acryle rubber latex having bimodal particle distribution
WO2005063826A1 (en) * 2003-12-30 2005-07-14 Lg Chem, Ltd. Polymer latex having excellent impact-resistance and powder flow property and method for preparing the same
US8048524B2 (en) 2003-12-30 2011-11-01 Lg Chem, Ltd. Polymer latex having excellent impact-resistance and powder flow property and method for preparing the same
KR100708965B1 (en) 2004-09-01 2007-04-18 주식회사 엘지화학 Acrylic-conjugated diene-based composite rubber impact modifier having excellent impact resistance and weather resistance and manufacturing method thereof
JP2008528756A (en) * 2005-08-19 2008-07-31 エルジー・ケム・リミテッド Impact reinforcing agent for PVC resin and method for producing the same
JP2011140668A (en) * 2005-08-19 2011-07-21 Lg Chem Ltd Impact resistance reinforcing agent for pvc resin and process for producing the same
US8008397B2 (en) 2005-08-19 2011-08-30 Lg Chem, Ltd. Impact strength modifiers for polyvinyl chloride resin and method of preparing them
JP2010515818A (en) * 2007-01-16 2010-05-13 エルジー・ケム・リミテッド Graft copolymer for transparent thermoplastic polyurethane resin, method for producing the same, and polyurethane resin composition containing the same

Also Published As

Publication number Publication date
JPS592704B2 (en) 1984-01-20
MX160493A (en) 1990-03-12
CA1180484A (en) 1985-01-02
AU546182B2 (en) 1985-08-22
EP0050848A3 (en) 1982-09-01
NL8201149A (en) 1983-10-17
EP0050848A2 (en) 1982-05-05
KR830007733A (en) 1983-11-07
BR8106824A (en) 1982-07-06
DE3170754D1 (en) 1985-07-04
US4352910A (en) 1982-10-05
KR860001212B1 (en) 1986-08-27
EP0050848B1 (en) 1985-05-29
AU7673281A (en) 1982-04-29

Similar Documents

Publication Publication Date Title
JPS5773036A (en) Vinyl chloride resin composition
JPS56118446A (en) Antistatic resin composition
JPS5688460A (en) Matte thermoplastic resin composition
JPS57212246A (en) Vinyl chloride resin composition
JPS578208A (en) High-alpha-methylstyrene content copolyymer, its production and composition containing the same
JPS57102940A (en) Polyvinyl chloride resin composition
CA2085917A1 (en) A process for preparing thermoplastic resin composition with excellent hcfc resistance
JPS5776047A (en) Thermoplastic resin composition
JPS55165942A (en) Thermoplastic resin composition
JPS5610542A (en) Iridescent resin composition
JPS5523144A (en) Vinyl chloride resin composition
JPS52152951A (en) Impact-resistant vinyl chloride resin composition
JPS57126812A (en) Production of transparent thermoplastic resin composition
JPS5494547A (en) Thermoplastic resin composition
JPS5686918A (en) Preparation of weather-resistant thermoplastic resin
JPS5740514A (en) Production of impact-resistant polystyrene
JPS5628233A (en) Resin composition
JPS57139135A (en) Vinyl chloride resin composition
JPS5676420A (en) Production of thermoplastic resin
JPS57167308A (en) Production of impact-resistant, weather-resistant thermoplastic resin
JPS55149337A (en) Resin composition
JPS5562950A (en) Vinyl chloride resin composition
JPS5569645A (en) Thermoplastic elastomer-grafted copolymer composition
JPS5562947A (en) Styrene-acrylonitrile resin composition and its production
JPS5361678A (en) Production of polyester-modified vinyl polymer