JPS5740502A - Depolymerization of acidic mucopolysaccharide - Google Patents
Depolymerization of acidic mucopolysaccharideInfo
- Publication number
- JPS5740502A JPS5740502A JP11468780A JP11468780A JPS5740502A JP S5740502 A JPS5740502 A JP S5740502A JP 11468780 A JP11468780 A JP 11468780A JP 11468780 A JP11468780 A JP 11468780A JP S5740502 A JPS5740502 A JP S5740502A
- Authority
- JP
- Japan
- Prior art keywords
- acidic mucopolysaccharide
- depolymerization
- acidic
- dimethylsulfoxide
- treated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
PURPOSE: Acidic mucopolysaccharide is treated with aqueous dimethylsulfoxide under an acidic condition of a specific pH to effect selective cleavage of β-D-hexosaminide linkages, thus producing depolymerization products such as disaccharide or its oligosaccharide used as a medicine.
CONSTITUTION: An acidic mucopolysaccharide such as chondroitin-6-sulfate is dissolved in aqueous dimethylsulfoxide at a pH higher than 2, preferably 3W5.5 and heat-treated at room temperature to 120°C, preferably 80W120°C under stirring to effect depolymerization of the acidic mucopolysaccharide. After completion of the reaction, water and sodium hydroxide are added and mixture is fractionated by the column chromatography to produce disaccharide consisting of uronic acid and hexosamine and its oligosaccharide. The amount of water in dimethylsulfoxide is preferably in the range from the stoichiometric amount necessary for hydrolysis to less than 20wt%.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11468780A JPS5740502A (en) | 1980-08-22 | 1980-08-22 | Depolymerization of acidic mucopolysaccharide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11468780A JPS5740502A (en) | 1980-08-22 | 1980-08-22 | Depolymerization of acidic mucopolysaccharide |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5740502A true JPS5740502A (en) | 1982-03-06 |
JPS645043B2 JPS645043B2 (en) | 1989-01-27 |
Family
ID=14644120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11468780A Granted JPS5740502A (en) | 1980-08-22 | 1980-08-22 | Depolymerization of acidic mucopolysaccharide |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5740502A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5320296B2 (en) * | 2007-10-01 | 2013-10-23 | 生化学工業株式会社 | Novel low molecular weight chondroitin sulfate and its use |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52155690A (en) * | 1976-06-22 | 1977-12-24 | Seikagaku Kogyo Co Ltd | Preparation of desulfated mucopolysaccharide |
-
1980
- 1980-08-22 JP JP11468780A patent/JPS5740502A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52155690A (en) * | 1976-06-22 | 1977-12-24 | Seikagaku Kogyo Co Ltd | Preparation of desulfated mucopolysaccharide |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5320296B2 (en) * | 2007-10-01 | 2013-10-23 | 生化学工業株式会社 | Novel low molecular weight chondroitin sulfate and its use |
US9149572B2 (en) | 2007-10-01 | 2015-10-06 | Seikagaku Corporation | Chondroitin sulfate having decreased molecular weight and use thereof |
Also Published As
Publication number | Publication date |
---|---|
JPS645043B2 (en) | 1989-01-27 |
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