JPS5738742A - Preparation of 1,4-dihydroanthraquinone - Google Patents
Preparation of 1,4-dihydroanthraquinoneInfo
- Publication number
- JPS5738742A JPS5738742A JP11408080A JP11408080A JPS5738742A JP S5738742 A JPS5738742 A JP S5738742A JP 11408080 A JP11408080 A JP 11408080A JP 11408080 A JP11408080 A JP 11408080A JP S5738742 A JPS5738742 A JP S5738742A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- pref
- catalyst
- solvent
- sulfonic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare the titled substance useful as a raw material of pesticides, etc., economically, in an industrial scale, by oxidizing 1,4,4a,9a-tetrahydroanthraquinone, etc. with molecular oxygen in a solvent using an organic acid such as aromatic sulfonic acid in place of a base as a catalyst.
CONSTITUTION: The titled compound is prepared by oxidizing 1,4,4a,9a-tetrahydroanthraquinone or 1,4-dihydroanthraquinone with molecular oxygen, in a polar organic solvent pref. acetic acid or ethanol, in the presence of an organic acid having a pK value of about ≤1 as a catalyst, pref. at 20W100°C. The catalyst is pref. an aromatic sulfonic acid such as benzenesulfonic acid, etc., or an aliphatic sulfonic acid such as methanesulfonic acid, etc. The amount of the catalyst is 0.01W 5%, pref. 0.02W2% of the solvent.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11408080A JPS5738742A (en) | 1980-08-21 | 1980-08-21 | Preparation of 1,4-dihydroanthraquinone |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11408080A JPS5738742A (en) | 1980-08-21 | 1980-08-21 | Preparation of 1,4-dihydroanthraquinone |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5738742A true JPS5738742A (en) | 1982-03-03 |
JPS6237618B2 JPS6237618B2 (en) | 1987-08-13 |
Family
ID=14628552
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11408080A Granted JPS5738742A (en) | 1980-08-21 | 1980-08-21 | Preparation of 1,4-dihydroanthraquinone |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5738742A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01121462A (en) * | 1987-11-02 | 1989-05-15 | Hory Corp | Formwork for constructing water channel wall |
US4981982A (en) * | 1987-09-09 | 1991-01-01 | Yoshio Yokoyama | Condensation catalyst and catalytical condensation process for organic carboxylic anhydrides |
JP2015528823A (en) * | 2012-08-13 | 2015-10-01 | アディファルム・エアドゥ | Pharmaceutical formulations containing 3-formylrifamycin SV and 3- (4-cinnamyl-1-piperazinyl) amino derivatives of 3-formylrifamycin S and methods for their production |
-
1980
- 1980-08-21 JP JP11408080A patent/JPS5738742A/en active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4981982A (en) * | 1987-09-09 | 1991-01-01 | Yoshio Yokoyama | Condensation catalyst and catalytical condensation process for organic carboxylic anhydrides |
JPH01121462A (en) * | 1987-11-02 | 1989-05-15 | Hory Corp | Formwork for constructing water channel wall |
JP2015528823A (en) * | 2012-08-13 | 2015-10-01 | アディファルム・エアドゥ | Pharmaceutical formulations containing 3-formylrifamycin SV and 3- (4-cinnamyl-1-piperazinyl) amino derivatives of 3-formylrifamycin S and methods for their production |
Also Published As
Publication number | Publication date |
---|---|
JPS6237618B2 (en) | 1987-08-13 |
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